The Complete Organic Chemistry Worksheet

The Complete Organic Chemistry Worksheet.doc

Name ________________________________
Date ___________________________
Period ___

1. Name the following hydrocarbons.

CH3
CH3 CH2
CH3
a. CH3 CH2 CH CH CH3 e. CH3 CH CH CH CH3
CH2 CH3
CH3 CH3
CH3 CH2
CH3 f. CH3 CH2 CH CH CH
CH3
CH3 CH2
CH3
b. CH3 C CH CH3
CH2
CH3
g. CH3 CH CH CH3

CH3 CH CH2 CH3

c. CH3 C CH3 CH3

CH2

CH3 CH2 CH3

h. CH3 CH CH CH3
CH2 CH2 CH3
CH3 CH CH3
d. CH3 CH2 C CH2 CH3
CH2 CH3

2. Name the following hydrocarbons.

CH3
d. CH3CH2CHCH2CH3
a. CH3CH2CH2CHCH3
CH2

CH3 CH3

b. CH3CHCH2CH3
CH3 CH3

e. CH3CHCH2CHCH3
CH3

c. CH3CHCHCH3 CH3

f. CH3CHCHCH2CH3
CH2CH3
CH3

CH3
CH2
g. CH3CHCH2CH3 h. CH3CHCHCH3
CH2 CH3

CH3
3. Listed below are the condensed structural formulas or names of the nine isomers of heptane, C7H16. Write the formula and
name for each.

CH3
a. CH3CH2CH2CH2CH2CH2CH3 f. CH3CH2CHCH2CH2CH3

CH3 CH3 CH3

b. CH3CHCH2CHCH3 g. CH3CCH2CH2CH3

CH3 CH3 CH3

c. CH3C CHCH3
h. 2-methylhexane
CH3
i. 3-ethylpentane

4. Name (use common and systematic for benzene if appropriate) the compounds represented by the following formulas.

a. CH3CH CHCH2CH3 c. e.

b. CH3 d.
C CH f. CH CCH3
CH3

5. Draw the structural formulas for the following:

a. 3-heptyne

b. cyclopentene

c. 3-phenyl-2,2-dimethylhexane

d. 1,3-butadiene

e. 1-ethyl-2-methylbezene

f. 2,4-dimethyl-2-pentene
6. Listed below are the condensed structural formulas or the names for the eight isomers of C5H11Cl.Write either formula and the
name for each.
Cl
a. CH3CH2CH2CH2CH2Cl e. CH3CH2CHCH2CH3

CH3 CH3 Cl

b. CH3CHCH2CH2Cl f. CH3CH CHCH3

c. 2-chloropentane g. 1-chloro-2-methylbutane
d. 2-chloro-2-methylbutane h. 1-chloro-2, 2-dimethylpropane

7. Name the following compounds.

CH3 CH3

a. CH3CH2CCH2CH2Br h. CH3CHCH CHCH3

CH2 CH3 CH3

CH3 i.CH3C CCH2CH3

CH3 CH3 CH3
j. CH
b. CH2 CHCHCH CH2 2 CCH2C CH2
CH3 CH3
CH3
k.CH2 C C CH CHCH3
c. CH2 CHCCH3
CH3
CH3
Br
l.
d. C6H5Cl
e. CH3CH CHCH2CH3
CH3
Br
f. CH3C CHCH3
g. CH3CH2CH CH2

8. Draw structural formulas for the following.

a. 3-heptene

b. 2-methylnapthalene

c. trichloromethane

d. 2-chloro-3-phenylhexane

e. 1,3-cyclopentadiene

f. toluene (methylbenzene)

g. 1,4-dibromobenzene

h. 2-bromo-3-methyl-2-butene
9. Write structural formulas for the following compounds.
a. 2-chlorobutane

b. 2-butene

c. 2-ethyl-3-methyl-1-butanol

d. 3,3-dimethylbutanoic acid

e. 2,5,5-trimethyl-4-heptone

f. 1,8-nonadiyne

g. 1,3-diiodobenzene

h. ethoxybenzene

i. 1-butanol

j. 3-methyl-2-pentene

k. 2-ethyl-4-methylpentanal

l. 3-ethyl-2,4-dimethyl-3-hexanol

m. 5-chloro-3-ethyl-2-methylheptanoic acid

n. 2-phenylbutane

o. 7-bromo-2-naphthol

p. 4-bromobenzoic acid
10. Name the following organic compounds.

O
a. CH3CH CHCH2CH3 d. CH3CH2CH2C
CH3 OH H
CH3
O
e. CH3CCH2CH2CH2OH
b. CH3CH2CCHCH3 CH3
CH3
CH3
f. CH2 CHCCH CHCH3
c. CH3CHCH CH2
OH
CH3

11. Name the following organic compounds.

CH3
a. CH3CH2CHCH2Cl e. CH3CCH2CH3
CH3 OH
CH3

b. CH3C CHCH2Br f. CH3CH2C CHCH3

Br
CH3 CH3

g. CH3(CH2)2CH2NH2
c. Br

h. H2N C CH2CH3
d. CH3CH2CHCH2CH3
O
Cl

12. Each of the following formulas can be written as two compounds with different functional groups. Write the structural
formulas, name the compounds, and identify the functional groups.
a. C2H6O b. C3H6O c. C5H10
13. Draw structural formulas for the following.
a. Ethanal

b. 2-butanone

c. 2-methyl-2-propanol

d. ethanoic acid

e. trimethanamine

f. propane

g. 2-pentyne

h. cyclobutane

i. cyclohexanamine

j. 2-aminopentane

k. 2,4-nitrophenol

l. 1,3-nitrobenzoic acid

m. ethanenitrile

n. propenoic acid
14. Draw and name the five structural isomers of hexane (C6H14)

15. Draw the structural formula for each of the following.

a. 2-Methylpentane

b. 2,2,4-Trimethylpentane, also called isooctane. This compound is the reference for octane ratings for gasoline.

c. 2-tert-Butylpentane

d. The name given in part c is incorrect. Give the correct name for this hydrocarbon.

16. Name each of the following:

a. b. CH3
CH3 CH3
CH2CH2CH

CH C CH2CH2CH3 CH3
CH3 C CH2CH2CHCH2CH3
CH3 CH3
CH2CH3
CH3

c. CH3 CH2 CH2 CH CH3

CH2 CH3

17. Name each of the following alkenes.

CH3
a. b. CH3
CH2 CH CH2 CH3 C CH

CH3

CH3
c. CH3
CH3CH2CH CH CH CH
CH3
18. Give the structure for each of the following:

a. 3-hexene

b. 2,4-Heptadiene

c. 2-Methyl-3-octene

19. Give the structure for each of the following aromatic hydrocarbons.

a. o-Ethyltoluene

b. p-Di-tert-butylbenzene

c. m-Diethylbenzene

d. 1-Phenyl-2-butene

20. Name each of the following:

a.
Cl CH2 CH2 CH CH3

Cl

b. CH3CH2CH2CCl3

CH3 CH3

c. CCl CH CH
CH2CH3
CH3
Cl