N AR A Y A N A E D U C A TIO N A L S O C EITe

Y
A O R G A NIC C H E MIS T R Y
SYNOPSIS
•
•

CH3 CH3 Br CH3

Br CH3 Br CH3 Br

Br Br Br CH3 Br CH3 CH3

CH3 CH3 Br
[P] Br
[M] [N] [O] [Q]

IF

Br Br Br
Br
 Br

Cl

OH
Br

OH
Br

Br z
y
x , , , w
OHC Br
Br

(σ - π)
 X Y Z
HO
CO 2CH 3
N N
N
N CH CH2
OH
N
O

Mr

σ π C2 H 2

2σ 3π

C4 H 9O 2 N
 Br

Cl

Br
Cl

Br

Cl

Cl

Br
Br

Cl

Br

Cl

Br

Cl

Br

Cl
 Cl

Br

Me

O 2N
 OH

OH

OH

OH
 OH

Cl

OH

Cl

HO

Cl

HO Cl
•
•

•
•

CH3 CH3 Br CH3

Br CH3 Br

Br Br Br CH3 CH3
CH3 CH3 Br Br

[K] [L] [M] [N]

NO 2

Cl
CH3
Br
CH3
 Cl

O 2N NO 2

CONH2

Br H2C CH3
H3C CH2 CH CH CCH2CH3
Br
Br

C4 H 9Cl

[M] [P]
[N] [O]

HO NH2

CHO
 Br Br
Br Br
H3C H3C H3C H3C

H3C H3C H3C H3C

(I) (II) (III) (IV)

 

OH

CN
Br
 C4 H10O

H3C Cl

CH3
Cl Br
CH3 Br

CH3
Br Cl
Cl

(I) (II) (III)

Br Br

CH3 CH3
Cl Cl

(IV) (V)
 H
Cl
Cl C C Cl

Cl

Common name is DDT

Cl

HOOCCOOC2 H 5

CN
COOH

OH
 COOH COOH
Cl Br Cl

Br

Cl

COOH Br Cl
Br COOH
 OH
Cl Br

COOH

HO CN

H3C OH H3C OH

H3C OH H3C OH
 H3C H3C
CH3 CH3
H3C
H3C CH3 CH3

CH3

CH3 CH3
H3C CH3
CH3 H3C CH3

H3C H3C
, CH2

H3C

[M] [N]

? ?
H3C
(2) (1) CH3

CH3

M 1 M2 M 1 N 1
N2 N 1 M2 N2
 NH2
CH3

C2H5

Cl

O 2N NO2

NO 2

Cl
CH3

OMe
Cl

CH3
 CH3

= 3,6 - dimethyl cyclohexene

CH3

CH3
CH3

= 1, 2 - dimethyl cyclohexene

H3C CH3

= 6,6 - dimethyl cyclohexene

H3C CH3

= 1,5 - dimethyl cyclohexene

OH

OH

CH 2OH OCH 3
OH

CH3
 A

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