KENDRIYA VIDYALAYA SANGATHAN, KOLKATA REGION

TIME: 3HRS PRE-BOARD EXAMINATION, CLASS- XII, 2020-21

SUBJECT: CHEMISTRY THEORY (043), M.M.-70

MARKING SCHEME

QUESTI SECTION-A VALUE

ON ANSWERS/HINTS POINT
SL. NO. S
1
i) A) 1
ii) D) 1
iii) C) 1
iv) B) 1
iv) OR A) 1
2
i) c) 1
ii) a) 1
iii) a) 1
iv) a) 1
iv)OR b) 1
3 d) 1
4 d) 1
4.OR c) 1
5 b) 1
5.OR b) 1
6 b) 1
7 b) 1
8 a) 1
9 d) 1
10 c) 1
11 c) 1
11.OR b) 1
12 b) 1
12.OR A) 1
13 A) 1
14 D) 1
15 B) 1
16 A) 1
SECTION-B
17 i) a) Frenkel defect, b) Both Frenkel and Schottky defect. ½
+1/2=1
ii) a) < b) < c) 1
18 ∆Tf = Kf(WB x1000)/(MB x WA) ½

MB= Kf (WB x10000)/(∆Tf xWA)

=(8 x2.5 x 1000) /(2 x 100) 1

-1
=100 g mol 1/2
2
19 Rate =K[A]

2 2
i) Rate =K[2A] =4K[A] 1
The rate will become four times.

2 2
ii) Rate =K[A/2] =K x [A] /4
1
The rate will become one fourth (1/4).
OR
a) For correct difference one mark 1

nd
b)2 order 1

20 a) Due to strong metallic bonding. 1

b) For correct reason one mark 1

2+
21 E. config. of Ni(0)/Ni
2- - -
In [NiCl4] ,Cl provides weak ligand field , cannot pair up e s of 3d orbital. 1
 2
So it is paramagnetic and tetrahedral (square planar –dsp ) is not possible.

-
But in [Ni(CO)4], CO has strong ligand field and can pair up the e s and
3
shows tetrahedral geometry(Sp ) and is diamagnetic. 1
21.OR a) Pentammine sulphato cobalt(III) bromide. 1

4 0
b) t2g eg 1
22 a) Pentan-2-one respond to iodoform test but Pentan-3-one does not 1
respond .
b) For correct reason one mark 1
23 a) For correct conversion 1
b) For correct reaction 1
23.OR a) For correct reaction 1
b)Products are CH3OH and HCOOK 1
nd
24 For first and third step half mark each and 2 step one mark. ½
+1+1/2
=2
25 a) (CH3)2NH > CH3NH2 > (CH3)3N > NH3 . 1
b)The activating effect of –NH2 to be controlled by acetylation with acetic 1
anhydride followed by nitration and hydrolysis(reaction-one mark)
3
26 D=(Z x M)/(a x NA) ½

3
Z = (d x a x NA)/M
3 -8 3 23
={8.97 x (3.6) x(10 ) x6.022 x 10 }/63.5= 1
=3.96 =4 approx. 1
The nature of the cubic unit cell is FCC. 1/2

26.OR Z=4(FCC) ½
3
D=(Z x M)/(a x NA)

3
M=(d x a x NA)/Z
-8 3 23
={10.5 x (4.077 x 10 ) x 6.022 x 10 }/4 1
=107.09 g per mole. 1
 For correct answer half mark 1/2
st
27 a) 1 order reaction 1

b)Slope = -K/2.303 1

6
c)- K/2.303= -2X10 1

6 -1
K= 4.606 X10 s
OR
For first order reaction, K=(2.303/t )log (a/a-x) 1/2

st
1 case: K=(2.303/100 )log (100/100-60)
1
==(2.303/100 )log (100/40)= (2.303/100 )log (2.5)= (2.303/100 ) x 0.3979

-1
K =9.164 x 10-3 minute

nd
2 case: K=(2.303/t )log (a/a-x) ½

t= (2.303/K )log (a/a-x)=

1
-3
t= (2.303/9.164 x 10 )log (100/100-90)

-3
=(2.303/9.164 x 10 )log 10= 251.31 minutes.
28 a) HF < HCl < HBr < HI 1
b) For correct balanced equation one mark. 1
c) For correct reason one mark 1
+2
29 a) In ground state,Cu has completely filled d-orbital.In Cu ,it is having 1
9 0
incompletely filled d-orbital (3d 4s ).So it is transition element.But Zn has
completely filled d-orbital in ground as well as in its oxidation state.

b) Zero oxidation state in metal carbonyls, e.g. [Ni(CO)4 ]and maximum ½

 +8
oxidation in OsO4(Os ). +1/2=1

c) Due to lanthanide contraction. 1

30 a) For two correct differences - one mark. ½
+1/2=1
b) Hydrogen bond, disulphide linkage, Van der Waals and electrostatic 1
forces of attraction.

- +
c) Zwitter ionic form: CH3CH(COO )(NH3 ). 1
SECTION-D
-1 -1
31 a) Unit of specific conductance is Ohm cm . ½ +1/2
-1 2 -1
Unit of molar conductance is Ohm cm mol .

0
b) For getting E cell positive, nickel acts as cathode and aluminium acts as
anode.
2+ 3+
Cell reaction: 2Al(s) + 3 Ni (aq) 2Al (aq) + 3Ni(s) 1
(n=6)

0 0 0
E cell = E Ni2+ / Ni - E Al3+/Al =- 0.25 –(-1.66)=1.41 V 1
0 3+ 2 2+ 3
Nernst equation: Ecell = E cell -( 0.059/6)log{ [Al ] /[ Ni ]} 1
2 3
= 1.41 -( 0.059/6)log{ (0.001) /( 0.5 ) }
=1.46 Volt.
OR
a) For correct application one mark.1 1
0 0 0
b) ) According to Kohlrausch’s law Λ m (NH4OH)= λ NH4+ + λ OH- = ½

0 0 - 0 0 0 0
λ NH4+ + λ Cl + λ Na+ + λ OH - - λ Na+ - λ Cl-

1
0 0 0 - 0 0 0 0
=Λ m (NH4OH)= λ NH4+ + λ Cl + λ Na+ + λ OH - λ Na+ - λ Cl-

0 0 0
= Λ m (NH4Cl) + Λ m (NaOH) - Λ m (NaCl)
½
 = 129.8 + 248.1 - 126.4
-1 2 -1
=251.5 ohm cm mol
For correct unit half mark. 1+1
c) For explanation one mark and for figure one mark.

32 a) For correct reason one mark 1

b) For correct reason one mark 1
c) For each step of preparation (balanced equation) one mark 1+1+1
OR
a)For correct correct structure one mark each 1+1
b) i) For correct balanced equation one mark. 1
ii) For correct balanced equation one mark. 1
c) Phosgene, tear gas, mustard gas (any one). 1
33 a) Cu 3
CH3-CH(OH)-CH3 CH3-CO-CH3 (Acetone)
A (propan-2-ol) 573K B
‘B’ does not reduce Fehling’s solution. So it is ketone.
Iodoform Reaction:
CH3-CO-CH3 + 3I2 + 4NaOH CHI3 + CH3COONa + byproducts
B C(Iodoform)

b) i) and ii): For correct reaction one mark each. 1+1

OR
a)Any reaction given by aldehyde and ketone with hroxylamine to produce
1
oxime : CH3CHO + H2NOH CH3CH=NOH (Aldoxime)
b) Benzoic acid with Br2/FeBr3 gives meta-bromobenzoic acid.
1
c) Butanone < propanone< Propanal < Ethanal.
1

d) NH3 Br2+ NaOH

1+1
CH3CH2COOH CH3CH2CONH2 CH3CH2NH2
Heat A B
A =Ethanamide , B= Ethylamine.