Professional Documents
Culture Documents
Characteristics of Plastics
There are two general classifications of clear plastics used in aircraft: acrylics and cellulose
acetates. The technician needs to be able to distinguish between these two materials in order to
install and repair them properly. Acrylic materials, such as Plexiglas, are the more modern
materials and have replaced acetate materials in most usages. Acrylic plastics used in aviation
applications must comply with the appropriate military specification: MIL-P-6886 for standard
acrylics; MIL-P-8184 for craze-resistant acrylics; and MILP-5425 for heat-resistant acrylics.
Although these materials have been described here as clear, they are available in tints to reduce
light penetration. This is most evident when a green- or gray-tinted plastic is used for aircraft
windshields. This tinting performs the same purpose as the pilot wearing sunglasses; that is, ir
reduces the level of light intensity entering the cockpit. The two materials can be identified by
their visual and burning characteristics and by their reaction to certain chemicals and solvents.
When viewed edge-on, acrylic material appears clear or the color of the tinting if the material
is tinted. Some clear pieces of acrylic material appear slightly green or bluegreen. Acetate
material appears yellow when viewed edge on. When burned, acrylic burns with a clear flame
and gives off an aroma described as fairly pleasant or fruitlike. Acetate burns with a heavy
black smoke and a strong, pungent odor. If a sample of acrylic material is rubbed with a cloth
moistened in acetone, the plastic turns white. Acetone softens acetate but does not affect its
clarity. If zinc chloride is placed on acetate, it turns the material milky, but it has no. effect on
acrylic.
INSTALLATION, MAINTENANCE & REPAIR OF PLASTICS
Cleaning Plastics
The best way to clean plastic surfaces is by flowing fresh water across the surface and
then using the hand to gently remove any particles adhering to the surface. A mild soap and
water solution can be used if requited. The use of a cloth when cleaning plastics should be done
with care to prevent trapping particles in the cloth that can damage the surface as the cloth is
moved over the surface. When using a cloth, a clean soft cloth, not a shop rag (even if it is
clean), should be used. Shop rags often contain small metal particles even after having been
cleaned. These metal particles will damage the surface. There are several commercial cleaners
available that can be used to clean plastics. These commercial materials often include a wax
and an antistatic component that reduces the static build up on the plastic. Commercial waxes
that do not contain cleaning grit can be used to polish clean plastic surfaces. These waxes will
fill in some of the fine scratches that appear on plastic and improve the visual clarity to some
degree. Machines should not be used when polishing as their high speed of operation may heat
the plastic and cause distortion. Plastic should not be rubbed with a dry cloth, since this is likely
to scratch the surface and can cause a build-up of static electricity. Solvents such as lacquer
thinner, benzine, carbon tetrachloride, acetone, and other similar materials should never be
used on plastic sheet because they will penetrate the surface and cause crazing. Crazing is the
formation of a network of fine cracks in the surface of the material. The effect of crazing is to
destroy the clarity of vision through the material and to weaken the structural strength.
Manufacturer's manuals usually specify the types of cleaning agents suitable for the plastic
windshields and windows for specific aircraft. Certain neutral petroleum solvents such as
kerosene or aliphatic naphtha cleaning fluid are sometimes specified for the removal of oil or
grease. If these are used, the surface should be dried as quickly as possible and then washed
with water and a mild detergent. A detergent conforming to MIL-C-18687 is recommended.
Aromatic naphtha should never be used. Occasionally, paint may need to be removed from the
clear plastic parts, either from paint splatters or overspray. The technique used to remove the
paint depends upon the type of paint to be removed. There are three techniques that may be
used to remove paint: solvents, sandblasting, and trialene soap. When using solvents, the
technician should take great care in selecting the solvent to be used. Some solvents may cause
crazing. A commonly used generic solvent for paint removal is cyclohexanone. A number of
brand-name paint removers are also available. When the paint removal is complete, care must
be taken to remove all the paint remover from the plastic. Residual amounts of paint remover
could cause crazing when other surface treatments are used. The use of sandblasting to remove
paint is typically not applicable to aviation uses of clear plastics because it weakens the plastic
and clouds the vision through the plastic. Trialene soap may be used to remove acrylic-based
paints from Plexiglas as well as paint that has been in place for an extended period. When
dealing with chemicals to remove paint from plastics, the technician should follow the
instructions of the plastic's manufacturer and the paint-remover manufacturer as well as all the
safety precautions listed in the product usage instructions and material safety data sheets.
The inspection of windshields and windows is visual. The surfaces should be checked
for cracks and surface damage. Surface abrasion should be checked, and, if it is not deep, this
abrasion can be removed by an abrasion-removal process such as the Micro-Mesh process. Any
crazing (small fissures in the plastic) should be evaluated as to structural weakening of the
plastic and interference with pilot vision. If excessive crazing is found, the windshield or
window should be replaced. Any damage that is in the pilot's normal area of vision and that
cannot be restored to a clear vision area is cause for replacement of the plastic component.
Repair of Cracks
Cracks commonly appear on the edges of a piece of plastic radiating out from a pressure
point or a mounting hole. If the crack is in the pilot's normal vision area, the panel should be
replaced. If the crack is not in the normal vision area, the crack should be stop-drilled The
surface patch of the same thickness as the original material should be cut to extend beyond the
edges of the crack at least% in [1.91 cm] and formed to lay fully on the surface contour. The
edges of the patch should be tapered as shown and the patch spread with adhesive and
positioned on the surface of the panel being repaired. Pressure is then applied to the patch for
several hours. After 24 hours, the patch can be polished to achieve clear edges.
Repair of Holes
When a hole is found in a plastic windshield or window, any cracks radiating from the
holes should be stop-drilled. The hole is then dressed with a file and abrasive paper to remove
rough edges. If a surface patch is to be installed, this completes the hole preparation. If a plug
patch is to be installed, the hole should be trimmed out to a circle or oval that tapers outward,
as shown in Fig. For a surface patch, a patch is prepared in the same manner as for a patch over
a crack. The patch is shaped and extends beyond the edge of the damage at least% in [1.91 cm].
The patch is then attached with adhesive in the same manner as used for the patch over a crack.
For a plug patch, a plug is cut from material thicker than the original material. The plug is cut
to the proper size, as shown in Fig., and the taper is more severe than that of the prepared hole.
The plug is heated and pressed into the hole to allow the plug to match the edges of the hole.
After the plug has cooled, it is removed, adhesive is applied, and the plug is installed in the
hole. Pressure is applied until the adhesive has dried. The plug can then be trimmed down by
filing and sanding so that it is flush with the original panel on both sides. The patched area is
then buffed and polished to a clear surface.
COMPOSITES
Composite materials are not as new as most people think. Composite materials and
bonded structures have been in use for many years. Adobe bricks are appropriately considered
composite materials because they are made from a mixture of straw and mud bonded together.
Reinforced concrete used in driveways and roads is a composite material because it is made
from a combination of cement and reinforcing rods. The use of composite materials in
aerospace applications evolved from research done in England by the Royal Aeronautical
Establishment. The U.S. military and NASA have · continued their development.
The first fibrous-glass-reinforced- plastic (FRP) winged aircraft flew at Wright-
Patterson Air Force Base in the mid-1940s. This type of sttuctural fabrication was not placed
in common use because tests revealed that even though it exhibited high specific strength, the
glass reinforcement material had marginal rigidity compared to metallic structures. Expanding
on the abbreviated definition of a composite given earlier, a composite is an inhomogeneous
material that has been created by the synthetic assembly of two or more materials to obtain
specific characteristics or properties.
Unlike metal alloys, which are homogeneous, the component materials in composites
retain their identities. That is, the component parts of a composite do not dissolve or otherwise
merge completely into each other, even though they do act as one. Normally, the components
can be physically identified after assembly and continue to exhibit an interface between
themselves. An example of a material in common use that is not a composite by definition is a
two-part-mixture epoxy adhesive. When the two parts are mixed together, they form a third
material that becomes a very tough, useful adhesive. Each individual part can no longer be
identified. The previous examples of the adobe bricks and the reinforced concrete are
composites because the individual components can still be identified after compilation into a
new material
General Characteristics of Composites
Composite structures are those aircraft components that are manufactured using fibrous
materials combined with a specially formulated medium called a matrix. The matrix supports
the fibers, as shown in Fig. The original composite materials used in aircraft components were
limited to fiberglass fibers combined with thermoset polyester resins as the matrix and were
not used in critical applications.
A thermoset resin is a type of resin that, once cured, cannot return to the uncured, or
soft, state. Improved thermoset adhesives, such as epoxies and vinyl-ester resins,
bismaleimides, and thermoplastic adhesive, such as poly-ether-ether-ketones (PEEK), as well
as new fiber-reinforcement materials have been developed for applications that include critical
flight parts. Thermoplastic resins may be repeatedly softened with heat, even after they are
originally cured. Both thermosetting resins and thermoplastics increase the workability of a
material. In addition, thermosetting resins may be added to the material before the component
fabrication process begins.
When a matrix is added to the fibrous material as part of a material's manufacturing
process-but prior to its use--it is pre-impregnated The most critical properties of a composite,
which are controlled by the direction of the reinforcement fibers and the ability of the matrix
to transfer loads from one fiber to another, are called transverse properties. The load-carrying
properties of a fibrous composite are greatest when the load applied runs in the same direction
as the fibers.
Loads that do not run parallel to the reinforcement fibers must, at least in part, be
transferred through the matrix, which typically has the lowest load-carrying capability.
Therefore, to a point, the greater the ratio of reinforcement fibers to matrix, the greater the
strength of the composite. Kevlar®, a DuPont trade name, carbon fiber, commonly referred to
as graphite (even though it is not a mined material), boron, tungsten, quartz, silicon carbide,
ceramics, and SPECTRA®, a trade name of Allied Signal Corporation, are commonly used
composite materials. Collectively they are referred to as advanced composite materials. In
1969, Grumman aircraft, in conjunction with the U.S. Navy, fabricated the world's first primary
flight-critical structure made of advanced composites for a production aircraft. This was a
boron-epoxy combination horizontal stabilizer for the F-14 TOMCAT fighter. As the demand
for the use of composites increased, additional developments in the areas of specialized fiber-
reinforcement materials, adhesives, and processes have taken place. These developments have
made the use of composite material in aircraft more economical and sttucturally compatible.
As a result, bonded and composite structures can be found in a great many parts of
today's aircraft. Landing-gear doors, flaps, vertical and horizontal tail structures, propellers,
internal turbine engine parts, helicopter rotor blades, and flight-control surfaces are just a few
places where these structures are found. The advantages of the high material strength-to-
weight ratio coupled with corrosion and fatigue resistance frequently makes fibrous reinforced
composite materials the first choice of aircraft designers and manufacturers. When compared
to conventional sheet-metal structures, composites have a low sensitivity to sonic vibrations
(good vibration resistance). There are also lower assembly costs due to a reduction in the
number of mechanical fasteners and parts in a particular assembly. In addition, there are other
advantages such as reduced weight, high corrosion resistance, high deterioration resistance,
and the capability of achieving a smooth surface, thereby reducing aerodynamic and parasitic
drag.
Types of Composite Structures
Composite structures can either be a solid laminate or a honeycomb/rigid foam
sandwich construction. A solid laminate is made by bonding together several layers of
reinforcing fiber materials that have been impregnated with the resin matrix A sandwich
assembly is made by taking a high-density laminate or solid face and back plate and
sandwiching a low-density filler (core) between them. This filler can be honeycomb which may
be fabricated from reinforced paper, Nomex, fiberglass, aluminum, or carbon; a rigid foam (for
example, high-temperature polyurethane).
The sandwich arrangement creates an improved structural performance and high
strength-toweight ratio. Laminates depend more on the combination of the assembly materials
than sandwich assembles for their strength and durability. In sandwich applications the core
material is often constructed using mechanical principles in order to produce additional
strength, such as the inherent strength of a honeycomb design compared to a simple square
pattern. The selection of materials used for the face, core, and back materials as well as the
design configuration of the core material are varied by the design engineer, depending upon
application anticipated for the component part.
REINFORCEMENT MATERIALS FOR COMPOSITES
Reinforcement fibers are produced in several forms using various materials. Fiberglass
material is the most widely used in aircraft. It is manufactured in either S-glass fiber (structural)
or E-glass fiber (electrical) forms for aircraft applications. Glass can be found as chopped
strands, woven roving, woven fabrics, continuous-strand mats, chopped strand mats, and milled
fibers As stated, carbon, Kevlar, boron, tungsten, quartz, and ceramics are collectively known
as high-strength advanced composites. They are produced in the form of particles, flakes,
fillers, and fibers of various lengths. A detailed analysis of all composite forms is beyond the
scope of this text. However, due to the common use of fiber-form composites in the aviation
industry, further discussion of fiber forms is appropriate. Even in the fiber form, there are a
number of variations. There are hollow fibers, fibers of noncircular cross section, and solid,
circular cross-sectional fibers, as shown in Fig.
The most common of these are solid, circular cross-sectional fibers, which are
commonly found in general and commercial aviation applications These solid-circular cross-
sectional fibers are combined with strong, stiff, heat-resistant, synthetic resin matrices to form
a composite material. The engineering performance of a fiber-matrix combination depends
upon the fibers' orientation, length, shape, and composition. The mechanical properties of a
composite are directly proportional to the amount
of fiber that is oriented by volume in a particular direction. Since fiber length has a bearing on
the processability of the composite, this consideration is of major concern during part
fabrication. Continuous fibers are much easier to handle than short ones, but the former are
sometimes more limited in their ability to make compound curved shapes, particularly boron.
Continuous fibers can either be woven into fabrics that are bidirectional, woven at right angles
to each other), or unidirectional, woven in a continuous straight line. Filament winding consists
of resin-impregnated continuous fibers wrapped on a mandrel simulating the shape of the part,
using one continuous strand, as applied in the manufacture of helicopter rotor blades. Short
fibers are utilized in flat and irregular-shaped parts using either open- or closed-mold processes.
The fibers are manufactured by first creating individual filaments. These filaments are then
assembled into tows, as shown in Fig. Tows can have as many as 160 000 filaments. Tapes are
processed directly from the tow. In the case of fabric, the tows are then twisted together in
bundles to form yarns, and the yams are then processed into fabrics. A weave consists of warp
yarn, till yarn, and selvage. The warp yarn is the yam that runs parallel to the sewn or
manufactured edge of the roll and is usually made up of the longest threads. The till yarn is the
yam woven perpendicular to the manufactured edge. Fill yam is woven so that it passes over
and under warp yarns in a weave pattern. Selvage is a closely woven pattern used to prevent
the edges of the cloth from unravelling during handling. Selvage is typically removed from the
fabric during the composite-manufacturing process. To help the technician identify the warp
yam direction during the usage of the cloth, warp tracers, which are warp fibers of the same
composition but dyed a different color, are woven into the fabric. Bidirectional fabrics are
available with various weave patterns, yams per inch, and ounce per yard weight. A plain-
weave fabric pattern has an individual warp yam woven over one individual fill yam and under
the next. A plain weave is considered the most stable weave pattern, providing both openness
in the weave (for even resin flow) and weave stability (reducing slippage and draping during
the part lay-up).
Uniform strength is achieved in both directions. Satin weaves are manufactured when
the warp yarns are woven over several successive fill yams and then under one fill yam. When
the warp yarns are woven over three fill yams and under one fill yam, the pattern is known as
a crowfoot satin-weave pattern. If the warp yams are woven over four fill yams and under one
fill yam, the pattern is called a live-harness satin-weave pattern. An eight-harness satin-weave
pattern is identified by the warp yarns having been woven over seven fill yarns first and then
under one fill yarn. The satin weaves are more pliable than the plain-weave pattern and
therefore conform more easily to complex shapes. These bidirectional weave patterns allow the
material to retain high strength in both directions. Unidirectional fabrics are fabricated with all
structural fibers laying in the same lengthwise direction on the roll. Unidirectional fabrics use
a few fibers loosely woven at right angles to the warp yarn to keep the warp yarns together in
a flat shape.
COMPOSITE MATRICES
A composite matrix is the plastic-based medium that encapsulates, or surrounds, the
reinforcement fibers to protect them and help transmit the stress forces between the fibers.
These matrices can either be thermosetting or thermoplastic in makeup. They can be a two-part
liquid mixture that has a room temperature cure of 70°F (2l"C), or a factory mixed and frozen
system that requires an accurately controlled elevated temperature cure cycle up to 700°F (371
°C). Epoxy matrix is normally cured at either 250°F (121 °C or 350°F (177°C). Polyamide
adhesives cure in the 260°F (127°C) to 450°F (232°C) range but may require temperatures as
high as 600°F (316°C). Bismaleimide adhesives cure in the 350°F (177°C) range but require
higher postcure temperatures of up to 700°F (371 °C). A postcure requires additional time at
elevated temperatures to ensure the completeness of the bonding process. Postcures may also
be used to increase strength and relieve stress. The matrices can have metal flakes added to
them during the manufacturing process. In this combination the matrix provides an
impermeable barrier between the atmosphere and the metal flakes, both limiting the potential
for corrosion of the metal flakes and giving the part thermal and electrical conductivity.
Stainless steel wire whiskers are added to some matrices to give them additional impact
strength, heat distortion points, and lightning strike protection. Resin matrices are available to
the technician in many forms, including a one-part polymer, two-part liquid mixture, sheet-
film adhesive, and pre-impregnated reinforcement fibers. The term wet lay-up is frequently
used to describe the process of applying the two-part liquid mixture. In the two-part liquid
mixture, the technician must accurately proportion, by weight or volume (depending upon the
manufacturer's instructions), the two liquid components and mix them thoroughly before
applying the mixture to the fiber-reinforcement materials. This stage of the resin-curing
process, in the liquid form, is said to be in the A stage (it is in a runny liquid stage-the beginning
stage), This method is common for simple manufacturing or repair situations where accuracy
of the fiber-to-matrix ratio is not critical. The individual matrix components have a maximum
storage life prior to use, called a shelf life, that must be controlled. After the components have
been thoroughly mixed, the combination then has a pot life, which is the maximum time it can
be applied prior to gelling.
Another form of matrix application is a sheet-film adhesive, which must be stored at
low temperatures. It has maximum shelf life of 6 months. This stage of the resin-curing process,
in stiff sheet form, is known as the B stage (it's not a liquid or a cured solid-an intermediate
stage). A sheet-film foaming adhesive is used when bonding together sections of honeycomb.
The foaming adhesive expands during the cure cycle to fill voids (a pocket that lacks adhesive)
that may occur due to improper fit of the core pieces. A more accurate method of matrix
application involves using fiber reinforcement materials that have been pre-impregnated {pre-
preg) with matrix at the material manufacturer. It is during this stage in the resin-curing process
that the resin is blended with the reinforcement material and kept frozen in the Stage B
condition. The technician must assure that pre-preg materials are stored and used properly. Pre-
preg materials must be kept at O F ( -l8°C) or below until ready for use. There is a maximum
out time (accumulative time that the pre-preg roll is out of the freezer) that must be controlled
to assure "freshness" of the adhesive. The material must be checked by a chemical engineer for
usability. The pre-preg materials must be handled in a clean room environment (temperature
and humidity-controlled without dust and dirt). This does present a handling problem but helps
assure a good bond.
When the pre-preg material has been cured using the controlled, elevated-temperature
curing system, the resin is said to be in the C stage (fully cured). When using the wet lay-up
method, the technician can get a ratio of approximately 40 percent resin to 60 percent fiber
reinforcement, which is sufficient for most aerospace application. When using the pre-preg
method, accuracies of 30 percent resin to 70 percent fiber can be achieved. Remember that to
a point, the more the reinforcement fiber volume, the more strength the final assembly will
have. Solid microspheres, or solid beads of plastic, are often added to matrices to increase
strength while controlling costs. When solid beads of plastic are introduced to the resin mixture,
the mixture is often called syntactic foam. Syntactic foams are non-gas blown. Not only does
this mixture increase the matrix resin strength, but it also helps to solve problems in shrinkage
and warpage during the cure cycles. This mixture may be used on the edges of honeycomb core
as a potting compound prior to shaping in order to prevent core crush.
When hollow microspheres (micro balloons) of glass are introduced to the resin
mixture, the glass spheres have a tendency to disperse throughout the part being manufactured,
resulting in stronger edges and corners. Micro balloons are used as a filler to assure uniform
shrinkage without causing possible internal stresses during curing. Matrices with solid
microspheres or hollow microspheres added are isotropic, which means that they have no
specific orientation. The improved strength characteristics of both processes typically occur
with an overall improved strength-to-weight ratio, because the microspheres have less density
than the matrix.
The type of releasing media used is determined by the type of matrix form used, the
heat of the curing process, and the material from which the mold is fabricated. In low-volume
production processes and repairs, a vacuum bag, which is a plastic bag surrounding the part
material from which air has been evacuated, and a separate heat source may be used. Common
heat sources include controlled ovens, portable "hot bonders," and heat blankets. The resin-
matrix cures and the fiber-reinforcement materials are bonded in close proximity to each other.
The strength of the lay-up depends on the volume of the fibers and their orientation. High
volume and critical composite structures are often heated using an autoclave, which is an oven
that heats the material while it is under pressure.
Warp-Orientation Techniques