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Learning Objectives:
At the end of the 6 hours period students are expected to:
1. Write the correct chemical formula of a compound
2. Name the given chemical compound
3. Balance the chemical equations
4. Write a complete balance chemical equation
5. Explain the following laws:
a. Law of the Conservation of Mass
b. Law of Definite Proportion
c. Law of Multiple Proportions
Competency:
Writing a complete balance equation
Topic outline:
Nomenclature of inorganic compounds
Metals with fixed oxidation state
Law of definite proportion
Metals with variable oxidation state
Law of multiple proportions
Naming acids
Naming salts
Naming bases
The Chemical Equation and Information
Balancing
Law of conservation of mass
Types of chemical reaction
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behaves like a metal. It can form a binary compound with another nonmetal some examples are written
below with their corresponding chemical formula and names.
Some binary compounds of two nonmetals have common names, such as water for H2O and
ammonia for NH3.
For other binary compounds of this type, where more than one binary compound can be formed
from two elements, The Greek prefixes, as listed in Table 1, are used with each element. The mono prefix
is not used with the first element.
Greek Prefixes:
Greek Prefix Number
mono- 1
di- 2
tri- 3
tetra- 4
penta- 5
hexa- 6
hepta- 7
octa- 8
nona- 9
deca- 10
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MgO Mg is +2, O is -2 magnesium oxide
AgBr Ag is +1, Br is -1 silver bromide
CaH2 Ca is +2, H is -1 calcium hydride
Be3N2 Be is +2, N is -3 beryllium nitride
Naming Acids
An acid is a compound consisting of hydrogen combined with a non-metallic element or with a
polyatomic ion that has a negative oxidation number. In the formula for an acid, hydrogen is always
listed as the first element. (The only exception to this is water, H2O)
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There are several types of acids encountered in chemistry: binary acids, oxygen containing acids,
and organic acids. Their names are well established in traditional origins and there has been no
acceptable systematic scheme for naming these substances.
Examples:
1. HNO2 is named nitrous acid (the oxidation number of N = +3)
2. HNO3 is named nitric acid (the oxidation number of N = +5)
(NOTE: Nitrogen only forms these two acids.)
3. H2SO3 is named sulfurous acid (the oxidation number of S = +4)
4. H2SO4 is named sulfuric acid (the oxidation number of S = +6)
(NOTE: These are the most common oxygen acids of sulfur.)
5. H3PO3 is named phosphorous acid (the oxidation state of P = +3)
6. H3PO4 is named phosphoric acid (the oxidation state of P = +5)
(NOTE: These are the most common oxygen acids of phosphorus.)
NOTE: There is no molecular form of carbonic acid, H2CO3. An aqueous solution of carbon dioxide,CO2, contains
hydrogen carbonate ions, HCO3 -, and hydrogen ions, H+. Sometimes an element may form more than two oxygen-
containing acids. In these cases, additional prefixes hypo- and per- are used. An example of this is chlorine which
forms the acids: HClO, HClO2, HClO3, and HClO4. The most common oxygen acids of chlorine are:
HClO2 which is named chlorous acid
HClO3 which is named chloric acid
In the case of HClO, which contains one atom of oxygen less than chlorous acid, HClO2, (the –ous
ending acid) chlorine has a lower oxidation number and the prefix hypo- is added to the -ous acid name.
This results in the name hypochlorous acid for HClO. In the case of HClO4, the acid contains one more
oxygen than chloric acid, HClO3, (the acid with the name ending in -ic) chlorine has a higher oxidation
number and the prefix per- is added to the -ic acid name. This results in the name perchloric acid for
HClO4.
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Practice: These names of the oxygen-containing halogen acids are summarized in the following
examples: calculate the oxidation numbers of Cl in the following acids.
1. HClO = hypochlorous acid (oxidation no. of Cl = _________)
2. HClO2 = chlorous acid (oxidation no. of Cl = _________)
3. HClO3 = chloric acid (oxidation no. of Cl = _________)
4. HClO4 = perchloric acid (oxidation no. of Cl = _________)
Similar names are used for the acids formed by bromine and iodine, the two elements that are found in
the same family below chlorine in the periodic table.
HBrO = hypobromous acid HIO = hypoiodous acid
HBrO3 = bromic acid HIO3 = iodic acid
HBrO4 = perbromic acid HIO4 = periodic acid
(Note: HBrO2 and HIO2 are not stable and do not exist.)
Naming of Salts of Oxygen Acids
Salts are compounds formed when one or more of the replaceable hydrogen is replaced by a cation
(metal or positive polyatomic ion) or when one o more hydroxide ions of a base is replaced by an anion
(nonmetal or negative polyatomic ion).
The names of the salts are directly related to the formulas and names of the oxyacids using the following
general rules.
+ +
1. Since the H ion has +1 oxidation state, the charge on the oxyanion is equal to the number of H that
can be dissociated in water by a molecule of the acid.
2. An –ous acid always forms an -ite salt, an -ic always forms an –ate salt.
2-
Applying these rules, we can see that since sulfuric acid is H2SO4, the sulfate ion is SO4 or since
_
HNO2 is nitrous acid NO2 is the nitrite.
Common Oxyacids, Oxyanions, and an Example of a Salt of each
2-
H2SO3 sulfurous acid SO3 sulfite MgSO3 magnesium sulfite
2-
H2SO4 sulfuric acid SO4 sulfate K2SO4 potassium sulfate
2-
H2CO3 carbonic acid CO3 carbonate CaCO3 calcium carbonate
3-
H3PO3 phosphorous acid PO3 phosphite Na3PO3 sodium phosphite
3-
H3PO4 phosphoric acid PO4 phosphate Mg3(PO4)2 magnesium phosphate
If a salt is formed from an acid that contained two or more acid hydrogen atoms without replacing
all of the hydrogens, then a hydrogen salt is formed. Such salts contain the word hydrogen, or the prefix
bi-, in the middle of the salt names. (The use of hydrogen is currently preferred.) Prefixes are also used to
distinguish compounds where three hydrogens were replaceable.
Examples:
1.) NaHCO3 sodium hydrogen carbonate or sodium bicarbonate
-
(The HCO3 polyatomic ion is formed from a hydrogen carbonate ion, HCO3 )
2.) NaH2PO4 sodium dihydrogen phosphate
(These hydrogen phosphate ions Na2HPO4 disodium hydrogen phosphate are formed from
phosphoric. Also known as sodium hydrogen phoshate acid, H3PO4 )
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Naming Hydroxides
These are compounds that contain the –OH group. They are commonly called bases, alkalies or
just hydroxides. These are substances that donate their OH in water solution. That is, bases increase
-
the hydroxide ion in solution. To name this type of compound it must be remembered that OH group
bares a -1 oxidation state. For metals also with variable oxidation states we must indicate the oxidation
number in the name. Consider the following examples:
Chemical formula Chemical Name
NaOH sodium hydroxide
Mg (OH)2 magnesium hydroxide
Fe(OH)2 ferrous hydroxide or iron (II) hydroxide
Sn(OH)4 stannic hydroxide or tin (IV) hydroxide
Chemical equation is a notation that shows what substances are reacting (reactants) and what
new substances are produced (products). It is a shorthand notation for a chemical reaction. It also
describes the physical state of the reactants and products as solid, liquid, or gas.
Most importantly, the relative number of moles of reactants and products appears in the equation.
According to the law of conservation of mass, matter cannot be either gained or lost in the process of a
chemical reaction. The total mass of the products must be equal to the total mass of the reactants. In
short, the law of conservation of mass tells us that we must have a balanced chemical equation.
The practice of defining a unit for a quantity of small objects is common like a dozen of egg; a
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ream of paper is known examples. Similarly, a mole is 6.02 x 10 individual units of anything.
The mole (mol) and the atomic mass unit (amu) are related. The atomic mass of an element
corresponds to the average mass of a single atom in amu and the mass of a mole of atoms in
grams.
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4. The symbol ∆ over or under the reaction arrow means that heat energy is necessary for the
reaction to occur.
5. Arrow up (↑) or arrow down (↓) is sometimes used as a symbol for the formation of precipitate
(↓) or evolution of gas (↑) in the product side of the equation.
6. The equation must be balanced.
Examples:
∆
1) → +
Therefore the law of conservation of mass is obeyed, and the equation is balanced as written.
2) + → +
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3) + → +
To balance: place 3 as a coefficient of NaOH in the reactant side to balance the hydroxyl ion,
then the number of sodium atoms becomes 3; to balance the sodium atom, place 3 as a
coefficient of NaCl in the product side, then chlorine atoms becomes 3; check the number of
atoms of chlorine and iron in the product side. Now check if the equation is already balance.
+ → +
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Exercise: Write a balanced equation for the following reactions:
Many different chemical reactions occur in biological systems, in industries, and in environment.
Because of this it is useful to classify chemical reactions into general types. We will recognize various
patterns that reactions follow, and this help us to write a chemical equations.
1. Combination reactions that combine reactants to form one product. The reactants can be an
element or a compound
2. Decomposition reaction. Often heat is needed in order for the reaction to occur. There is only one
reactant that is decomposed to produce two or more products.
3. Single replacement (displacement) reaction. Usually it is a reaction between a free metal and an
acid to produce hydrogen gas and a salt solution. Also, a reaction between a free metal and a metal
in solution. For the reaction to occur the free metal should be more active than the metal in solution
(base on the electromotive series or activity series of metals; or if the free metal is above hydrogen.
Electromotive Series or Activity Series
Li
K
Ba
Ca
Na
Mg
Al
Zn
Fe
Cd
Ni
Sn
Pb
(H)
Cu
Hg
Ag
Au
For Nonmetals the series would be: Fluorine – chlorine – bromine - iodine
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4. Double displacement or metathesis reaction. In this reaction, two compounds react to form two or
more products. It is often described as exchange partners of the reactants to produce two new
products.
5. Neutralization reaction. It is a reaction between an acid or acid oxide (nonmetal oxide) and a base or
basic oxide (metal oxide). Often salt and water is produced.
1. Combination reactions
∆
a) metal + nonmetal → binary compound
Examples: 2-. + 3 . → 2-. .
2/0 + → /0
12 + 3 → 123
12 + → 12
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∆
OP
b) ℎ.8N <;? . → .8N@C; + BQ0;2 0 ?
∆
Example: 2R . → 2R . + 3
∆
c) 9;< . 8B@C; → SN;; 9;< . + 8BQ0;2 0 ?
∆
Example: T= → T= +
∆
O
d) N=82 <; → B@C; + N=82 C@8B@C;
Note: Except for group IA carbonate since it does not decompose easily.
∆
Example: → +
∆
e) GQCN80;2 7 N=82 <; 8N =@7 N=82 <; → 8B@C; + + G
Note: Except for group IA bicarbonate
∆
Example: G → + + G
∆
For Group IA bicarbonate: UN8>: V- =@7 N=82 <; → 7 N=82 <; + + G
∆
Example: 2H G → H + + G
WXYZ[\ Z]Z[\YX[ [^YYZ_\
f) Electrolysis of water (direct electric current): 2G `aaaaaaaaaaaaaaaab 2G +
3. Single replacement
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Exercise: Predict the product and balance the equation.
1. Ni + HgCl →
2. K + BaSO4 →
3. AgNO3 + Cd →
4. I2 + KBr →
5. Na + H2O →
6. Mg + HCl →
5. Neutralization
Generally it is a reaction between acid and a base producing salt and water
a) -7@C + h ?; → ? .< + i <;N
Example: G .+H G → H . + G
b) /;< . 8B@C; = ?@7 2ℎQCN@C; + 7@C → ? .< + i <;N
Example: /0 + G 3 I → /03 I + G
c) 2829;< . 8B@C; 7@C 2ℎQCN@C; + = ?; → ? .< + i <;N
Example: T j + 6R G → 2R T I + 3G
d) -9982@ + -7@C → 9982@>9 ? .<
Example: HG + G → HGI
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Exercise 5.1
a. SO2 = ________________________________________________________
b. N2O3 = ________________________________________________________
c. PBr3 = ________________________________________________________
d. P2O5 = ________________________________________________________
e. SO3 = ________________________________________________________
f.CCl4 = ________________________________________________________
g. SiO2 = ________________________________________________________
h. BCl3 = ________________________________________________________
i. CS2 = ________________________________________________________
j. CO = ________________________________________________________
a. PbI2 = ________________________________________________________
b. FeSO4 = ________________________________________________________
c. Ag2O = ________________________________________________________
d. NaCl = ________________________________________________________
e. Ca3N2 = ________________________________________________________
f. CuO = ________________________________________________________
g. SnO2 = ________________________________________________________
h.HgCl = ________________________________________________________
i. SeF4 = ________________________________________________________
j. SnO = ________________________________________________________
a. NH4Cl = ________________________________________________________
b. Ca(CN)2 = ________________________________________________________
c. NaCN = ________________________________________________________
d. (NH4)2S = ________________________________________________________
e. Fe(CN)3 = ________________________________________________________
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Exercise 5.2
Bases
3. Name the following bases using classical and stock system if applicable:
a. NaOH = ________________________________________________________
b.Sn(OH)4 = ________________________________________________________
c KOH = ________________________________________________________
d Fe(OH)3 = ________________________________________________________
e. Sn(OH)2 = ________________________________________________________
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Exercise 5.3
Salts
1. Name the following compounds.
a BaCrO4 = ________________________________________________________
b HIO = ________________________________________________________
c.KCNO = ________________________________________________________
d. H2O2 = ________________________________________________________
e. AlPO4 = ________________________________________________________
f. Pb(C2H3O2)2 = ______________________________________________________
g KH2PO3 = ________________________________________________________
h NH4CN = ________________________________________________________
i. NiC2O4 = ________________________________________________________
j. Na2SiO3 = ________________________________________________________
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Exercise 5.4
Acids
1. Name the following acids in water:
a.H2SO3 = ________________________________________________________
b. HNO3 = ________________________________________________________
c. HIO4 = ________________________________________________________
d. HF = ________________________________________________________
e. H2SO4 = ________________________________________________________
f. H3PO3 = ________________________________________________________
g. HClO = ________________________________________________________
h. HBr = ________________________________________________________
i. HClO3 = ________________________________________________________
j. HBrO3 = ________________________________________________________
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Exercise 5.5
Name: ___________________________________ Score: __________
Class Schedule: ___________________________ Date: ___________
Directions: Transcribe, complete and balance the following and identify the type of chemical reaction
involved:
4. magnesium + sulfur
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