SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

SAFETY DATA SHEET
OXYPER® SCS, SCM ST
Revision Date 01.06.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
- Trade name OXYPER® SCS, SCM ST
- REACH : Registration number 01-2119457268-30
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance/Mixture
- Bleaching agents
- Cleaning agent
- Oxidizing agents
1.3 Details of the supplier of the safety data sheet
Company
SOLVAY CHEMICALS INTERNATIONAL SA
RUE DE RANSBEEK, 310
1120, BRUXELLES
BELGIUM
Tel: +32-2-2642111
Fax: +32-2-2641802
E-mail address
manager.sds@solvay.com
1.4 Emergency telephone number

+44(0)1235 239 670 [CareChem 24]
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification (Regulation (EC) No 1272/2008 )
Oxidizing solids, Category 3 H272: May intensify fire; oxidizer.
Acute toxicity, Category 4 H302: Harmful if swallowed.
Serious eye damage, Category 1 H318: Causes serious eye damage.
2.2 Label elements

Regulation (EC) No 1272/2008
Hazardous products which must be listed on the label
 CAS-No. 15630-89-4 disodium carbonate, compound with hydrogen peroxide (2:3)
Pictogram
Signal word
- Danger
P00000021112
Version : 4.00 / GB ( EN )
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SAFETY DATA SHEET
Hazard statements
- H272 May intensify fire; oxidizer.
- H302 Harmful if swallowed.
- H318 Causes serious eye damage.
Precautionary statements
Prevention
- P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
- P221 Take any precaution to avoid mixing with combustibles.
- P280 Wear protective gloves/ eye protection/ face protection.
Response
- P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
- P370 + P378 In case of fire: Use water spray to extinguish.
Disposal
- P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Other hazards which do not result in classification

Results of PBT and vPvB assessment
- This substance is not considered to be persistent, bioaccumulating and toxic (PBT).
- This substance is not considered to be very persistent and very bioaccumulating (vPvB).
SECTION 3: Composition/information on ingredients

3.1 Substance
- Chemical name Disodium carbonate, compound with hydrogen peroxide (H2O2)(2:3)
- Synonyms Sodium percarbonate, Sodium carbonate peroxyhydrate
- Formula 2Na2CO3.3H2O2
- Chemical nature Coated and stabilized product
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SECTION 12: Ecological information

12.1 Toxicity
Aquatic Compartment
Acute toxicity to fish
disodium carbonate, compound with LC50 - 96 h : 70.7 mg/l - Pimephales promelas (fathead minnow)
hydrogen peroxide (2:3) semi-static test
Analytical monitoring: yes
Unpublished reports
Harmful to fish.
Acute toxicity to daphnia and other aquatic invertebrates.
disodium carbonate, compound with EC50 - 48 h : 4.9 mg/l - Daphnia magna (Water flea)
Unpublished reports
Toxic to aquatic invertebrates.
Toxicity to aquatic plants

disodium carbonate, compound with ErC50 - 72 h : 2.62 mg/l - Skeletonema costatum (marine diatom)
hydrogen peroxide (2:3) static test
Test substance: Hydrogen peroxide
By analogy
Unpublished reports
Toxic to algae.
Toxicity to microorganisms no data available
Chronic toxicity to fish no data available
Chronic toxicity to daphnia and no data available

other aquatic invertebrates.
Chronic Toxicity to aquatic plants no data available
12.2 Persistence and degradability
Abiotic degradation
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- Prolonged skin contact may cause skin irritation.

In case of eye contact
Symptoms
- Redness
- Lachrymation
- Swelling of tissue
Effects
- Corrosive
- May cause irreversible eye damage.
In case of ingestion
Symptoms
- Severe irritation
- Nausea
- Abdominal pain
- Vomiting
- Diarrhoea
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
- Immediate medical attention is required.
- If accidentally swallowed obtain immediate medical attention.
- Oxygen or artificial respiration if needed.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
- Water
- Water spray
Unsuitable extinguishing media

- None
5.2 Special hazards arising from the substance or mixture

- Oxidizing
- Oxygen released in thermal decomposition may support combustion
- Contact with combustible material may cause fire.
- Contact with flammables may cause fire or explosions.
- Risk of explosion if heated under confinement.
5.3 Advice for firefighters

Special protective equipment for firefighters
- In the event of fire, wear self-contained breathing apparatus.
- Use personal protective equipment.
- Cool containers/tanks with water spray.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Keep away from incompatible products
Advice for emergency responders

- Sweep up to prevent slipping hazard.
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6.2 Environmental precautions

- Should not be released into the environment.
- Limited quantity
- Flush into sewer with plenty of water.
- Large quantities:
- If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and materials for containment and cleaning up

- Sweep up and shovel into suitable containers for disposal.
- Do not mix waste streams during collection.
- Avoid dust formation.
- Treat recovered material as described in the section "Disposal considerations".
- All receiving equipment should be clean, vented, dry, labelled and made of material that is compatible with the
product.
- Never return spills in original containers for re-use.
6.4 Reference to other sections

- Refer to protective measures listed in sections 7 and 8.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
- Ensure adequate ventilation.
- Keep away from heat and sources of ignition.
- Use only clean and dry utensils.
- Never return unused material to storage receptacle.
- Keep away from water.
Hygiene measures
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Handle in accordance with good industrial hygiene and safety practice for diagnostics.
7.2 Conditions for safe storage, including any incompatibilities

Technical measures/Storage conditions
- Keep only in the original container.
- Keep at temperature not exceeding 40°C
- Store in a receptacle equipped with a vent.
- Keep in a well-ventilated place.
- Keep in a dry place.
- Keep in properly labelled containers.
- Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Packaging material
Suitable material
- Stainless steel
- Plastic materials.
- Paper + PE coating.
Unsuitable material
- no data available
7.3 Specific end use(s)
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SAFETY DATA SHEET
- Contact your supplier for additional information
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Components with workplace occupational exposure limits

Components Value type Value Basis
disodium carbonate, compound with hydrogen TWA 5 mg/m3 Solvay Acceptable Exposure Limit
peroxide (2:3)
sodium carbonate TWA 10 mg/m3 Solvay Acceptable Exposure Limit
Derived No Effect Level (DNEL) / Derived minimal effect level (DMEL)
Route of Potential health Exposure

Product name Population Value Remarks
exposure effects time
disodium carbonate,
compound with
Workers Dermal Local effects Acute 12.8 mg/cm2
hydrogen peroxide
(2:3)
Workers Inhalation Local effects Long term 5 mg/m3
General
Dermal Local effects Acute 6.4 mg/cm2
population
sodium carbonate Workers Inhalation Local effects Long term 10 mg/m3

General
Inhalation Local effects Acute 10 mg/m3
population
Predicted No Effect Concentration ( PNEC )
Product name Compartment Value Remarks

disodium carbonate, compound with 0.035 mg/l
Fresh water
hydrogen peroxide (2:3)
Intermittent 0.035 mg/l
use/release
Sewage treatment 16.24 mg/l
plant
8.2 Exposure controls

Control measures
Engineering measures
- Provide appropriate exhaust ventilation at places where dust is formed.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures

Respiratory protection
- Respirator with a particle filter (EN 143)
- Recommended Filter type: P2 filter
Hand protection
- Wear suitable gloves.
- Non-recommended materials: Leather, cotton
Suitable material
- PVC
- Neoprene
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SAFETY DATA SHEET
- Natural Rubber
Eye protection
- Dust proof goggles obligatory.
Skin and body protection

- Wear suitable protective clothing.
Hygiene measures
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Handle in accordance with good industrial hygiene and safety practice for diagnostics.
Environmental exposure controls

- Dispose of rinse water in accordance with local and national regulations.
- Prevent further leakage or spillage.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance Form: granules

Physical state: solid
Colour: white
Particle size: 250 - 1,000 µm
Mean diameter, Sodium carbonate peroxyhydrate
Odour odourless
Odour Threshold no data available
Molecular weight 314.06 g/mol
pH 10.4 - 10.6 ( 10 g/l)
Melting point/freezing point Melting point/range:

Decomposes on heating.
Initial boiling point and boiling range Boiling point/boiling range:

Decomposes before melting.
Flash point Not applicable
Evaporation rate (Butylacetate = 1) no data available

Flammability (solid, gas) The product is not flammable.
Flammability/Explosive limit Explosiveness:
Not explosive
Auto-ignition temperature Decomposes on heating.
Vapour pressure ( 25 °C)

negligible
Vapour density Not applicable
Density Bulk density: 850 - 1,200 kg/m3
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SAFETY DATA SHEET
Relative density 2.01 - 2.16

Solubility Water solubility:
140 g/l ( 20 °C)
Partition coefficient: n-octanol/water Not applicable
Decomposition temperature Self-Accelerating decomposition temperature (SADT)
Decomposition temperature > 55 °C

50 kg
Decomposition temperature > 110 °C
Viscosity Viscosity, dynamic : Not applicable
Explosive properties no data available

Oxidizing properties The substance or mixture is classified as oxidizing with the category 3.
Oxidizing
9.2 Other information

no data available
SECTION 10: Stability and reactivity

10.1 Reactivity
- Decomposes when moist.
- Decomposes on heating.
- Potential for exothermic hazard
10.2 Chemical stability

- Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions

- Contact with combustible material may cause fire.
- Contact with flammables may cause fire or explosions.
- Risk of explosion if heated under confinement.
- Fire or intense heat may cause violent rupture of packages.
10.4 Conditions to avoid

- Exposure to moisture
- To avoid thermal decomposition, do not overheat.
10.5 Incompatible materials
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SAFETY DATA SHEET
- Water
- Acids
- Bases
- Heavy metal salts
- Reducing agents
- Organic materials
- Flammable materials
- Combustible material
10.6 Hazardous decomposition products

- Oxygen
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity
disodium carbonate, compound with LD50 : 1,034 mg/kg - Rat , male and female
hydrogen peroxide (2:3) This product is classified as acute toxicity, category 4
Unpublished reports
Acute inhalation toxicity no data available
Acute dermal toxicity

disodium carbonate, compound with LD50 : > 2,000 mg/kg - Rabbit , male and female
hydrogen peroxide (2:3) Not classified as hazardous for acute dermal toxicity according to GHS.
No mortality observed at this dose.
Unpublished reports
Acute toxicity (other routes of no data available

administration)
Skin corrosion/irritation Rabbit

slight irritation
Humans
No skin irritation
Serious eye damage/eye irritation Rabbit

Risk of serious damage to eyes.
Respiratory or skin sensitisation

disodium carbonate, compound with Buehler Test - Guinea pig
hydrogen peroxide (2:3) Does not cause skin sensitisation.
Unpublished reports
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SAFETY DATA SHEET
Conditions and measures related to protection of consumer (e.g. behavioural advice, personal protection and hygiene)
Consumer Measures : Keep out of the reach of children., Wash thoroughly after handling.,
When using do not eat, drink or smoke.
3.2.3 Contributing scenario controlling consumer exposure for: PC8 Biocidal products (e.g. Disinfectants, pest control)
PC35 Washing and cleaning products (including solvent based products), PC36 Water softeners, PC37 Water treatment
chemicals, PC39 Cosmetics, personal care products, Transfer of solid product., Load, Bleach,
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to 100 %
Mixture/Article (unless stated differently).
Physical Form (at time of use) : solid
Amount
Amount used per event : 0.070 kg
Frequency and duration of use

Exposure duration : 1 min
Frequency of use : 1 events/day
Consumer Measures : Use eye protection according to EN 166, designed to protect against
powders and dusts., Keep out of the reach of children., Wash
thoroughly after handling., When using do not eat, drink or smoke.
chemicals, PC39 Cosmetics, personal care products, Manual washing, Bleach,
Concentration of the Substance in Covers the percentage of the substance in the product up to 25 %.
Mixture/Article
Amount

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SAFETY DATA SHEET
SECTION 12: Ecological information

12.1 Toxicity
Aquatic Compartment
Acute toxicity to fish
disodium carbonate, compound with LC50 - 96 h : 70.7 mg/l - Pimephales promelas (fathead minnow)
Unpublished reports
Harmful to fish.
Acute toxicity to daphnia and other aquatic invertebrates.
disodium carbonate, compound with EC50 - 48 h : 4.9 mg/l - Daphnia magna (Water flea)
Unpublished reports
Toxic to aquatic invertebrates.
Toxicity to aquatic plants

disodium carbonate, compound with ErC50 - 72 h : 2.62 mg/l - Skeletonema costatum (marine diatom)
hydrogen peroxide (2:3) static test
Test substance: Hydrogen peroxide
By analogy
Unpublished reports
Toxic to algae.
Toxicity to microorganisms no data available
Chronic toxicity to fish no data available
Chronic toxicity to daphnia and no data available

other aquatic invertebrates.
Chronic Toxicity to aquatic plants no data available
12.2 Persistence and degradability
Abiotic degradation
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SAFETY DATA SHEET
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
- Trade name OXYPER® SCS, SCM ST
- REACH : Registration number 01-2119457268-30
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance/Mixture
- Bleaching agents
- Cleaning agent
- Oxidizing agents
1.3 Details of the supplier of the safety data sheet
Company
SOLVAY CHEMICALS INTERNATIONAL SA
RUE DE RANSBEEK, 310
1120, BRUXELLES
BELGIUM
Tel: +32-2-2642111
Fax: +32-2-2641802
E-mail address
manager.sds@solvay.com
1.4 Emergency telephone number

+44(0)1235 239 670 [CareChem 24]
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification (Regulation (EC) No 1272/2008 )
Oxidizing solids, Category 3 H272: May intensify fire; oxidizer.
Acute toxicity, Category 4 H302: Harmful if swallowed.
Serious eye damage, Category 1 H318: Causes serious eye damage.
2.2 Label elements

Regulation (EC) No 1272/2008
Hazardous products which must be listed on the label
 CAS-No. 15630-89-4 disodium carbonate, compound with hydrogen peroxide (2:3)
Pictogram
Signal word
- Danger
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SAFETY DATA SHEET
12.6 Other adverse effects
Ecotoxicity assessment
Acute aquatic toxicity According to the data on the constituents
Toxic to aquatic life.
According to the classification criteria for mixtures.
Chronic aquatic toxicity No adverse chronic effect observed up to and including the threshold of 1 mg/L.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product Disposal
- Dilute with plenty of water.
- Dispose of wastes in an approved waste disposal facility.
- Can be landfilled, when in compliance with local regulations.
- In accordance with local and national regulations.
Advice on cleaning and disposal of packaging

- Clean container with water.
- Empty containers should be taken to an approved waste handling site for recycling or disposal.
- Uncleaned empty packaging
- Dispose of as unused product.
- In accordance with local and national regulations.
SECTION 14: Transport information

ADR
14.1 UN number UN 3378
14.2 Proper shipping name SODIUM CARBONATE PEROXYHYDRATE
14.3 Transport hazard class 5.1

Label(s): 5.1
14.4 Packing group

Packing group III
Classification Code O2
14.5 Environmental hazards NO
14.6 Special precautions for user

Hazard Identification Number: 50
Tunnel restriction code (E)
For personal protection see section 8.
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SAFETY DATA SHEET
RID

Label(s): 5.1
14.4 Packing group

Packing group III

IMDG

Label(s): 5.1
14.4 Packing group

Packing group III

Marine pollutant

EmS F-A , S-Q
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
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SAFETY DATA SHEET
IATA

Label(s): 5.1
14.4 Packing group

Packing group III

Packing instruction (cargo aircraft) 563
Max net qty/pkg 100.00 kg
Packing instruction (passenger aircraft) 559
Max net qty/pkg 25.00 kg
ADN

Label(s): 5.1
14.4 Packing group

Packing group III

Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of
transport regulations for hazardous materials, it would be advisable to check their validity with your sales office.
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Other regulations
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning
the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), as amended
- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on
classification, labelling and packaging of substances and mixtures, as amended
- Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks
related to chemical agents at work,as amended
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SAFETY DATA SHEET
Notification status
Inventory Information Status
United States TSCA Inventory - Listed on Inventory
Mexico INSQ (INSQ) - One or more components not listed on
inventory
Canadian Domestic Substances List (DSL) - Listed on Inventory
New Zealand. Inventory of Chemical Substances - In compliance with the inventory
Australia Inventory of Chemical Substances (AICS) - Listed on Inventory
Japan. CSCL - Inventory of Existing and New Chemical Substances - Listed on Inventory
Korea. Korean Existing Chemicals Inventory (KECI) - Listed on Inventory
China. Inventory of Existing Chemical Substances in China (IECSC) - Listed on Inventory
Philippines Inventory of Chemicals and Chemical Substances (PICCS) - Listed on Inventory
EU. European Registration, Evaluation, Authorisation and Restriction of - If product is purchased from Solvay in
Chemical (REACH) Europe it is in compliance with REACH,
if not please contact the supplier.
15.2 Chemical safety assessment

- A Chemical Safety Assessment has been carried out for this substance.
- Sodium carbonate peroxyhydrate
- See Exposure scenario
SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.

- H272 May intensify fire; oxidizer.
- H302 Harmful if swallowed.
- H318 Causes serious eye damage.
- H319 Causes serious eye irritation.
Further information
- This sheet was updated (refer to the date at the top of this page). Subheadings and text which have been modified
since the previous version are indicated with two vertical bars.
- Distribute new edition to clients
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. Such information is only given as a guidance to help the user handle, use, process, store, transport, dispose
and release the product in satisfactory safety conditions and is not to be considered as a warranty or quality specification. It
should be used in conjunction with technical sheets but do not replace them. Thus, the information only relates to the
designated specific product and may not be applicable if such product is used in combination with other materials or in any
other manufacturing process, unless otherwise specifically indicated. It does not release the user from ensuring he is in
conformity with all regulations linked to its activity.
Annex
Scenario List
1. ES1 : Formulation & (re)packing of substances and mixtures...................................................................19

2. ES2 : Industrial use, and, Professional use, of cleaning products and other mixtures containing
the substance ...............................................................................................................................................................23
3. ES3 : Consumer use, of cleaning products and other mixtures containing the substance...............29
1. ES1 : Formulation & (re)packing of substances and mixtures
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1.1. Scenario description
Main User Groups : SU 3 Industrial uses: Uses of substances as such or in preparations at

industrial sites
Sectors of end-use : SU 3 Industrial uses: Uses of substances as such or in preparations at
industrial sites
SU 10 Formulation [mixing] of preparations and/ or re-packaging
(excluding alloys)
Environmental release category : ERC2 Formulation of preparations
ERC6b Industrial use of reactive processing aids
ERC7 Industrial use of substances in closed systems
Process category : PROC1 Use in closed process, no likelihood of exposure
PROC2 Use in closed, continuous process with occasional controlled
exposure
PROC3 Use in closed batch process (synthesis or formulation)
PROC4 Use in batch and other process (synthesis) where opportunity for
exposure arises
PROC5 Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/ or significant contact)
PROC8a Transfer of substance or preparation (charging/ discharging) from/
to vessels/ large containers at non-dedicated facilities
PROC8b Transfer of substance or preparation (charging/ discharging) from/
to vessels/ large containers at dedicated facilities
PROC9 Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC14 Production of preparations or articles by tabletting, compression,
extrusion, pelletisation
Product category : PC8 Biocidal products (e.g. Disinfectants, pest control)
PC14 Metal surface treatment products, including galvanic and
electroplating products
PC15 Non-metal-surface treatment products
PC20 Products such as pH-regulators, flocculants, precipitants,
neutralization agents
PC25 Metal working fluids
PC34 Textile dyes, finishing and impregnating products; including
bleaches and other processing aids
PC35 Washing and cleaning products (including solvent based
products)
PC36 Water softeners
PC37 Water treatment chemicals
PC39 Cosmetics, personal care products
1.2. Conditions of use affecting exposure
1.2.1 Contributing scenario controlling environmental exposure for: ERC2 Formulation of preparations, ERC6b Industrial
use of reactive processing aids, ERC7 Industrial use of substances in closed systems
Amount
Annual site tonnage (tonnes/year): : 15000
Maximum daily local emission to waste : 1000 kg
water
Environmental factors
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 10
Other given operational conditions affecting environmental exposure
Number of emission days per year : 300

Emission or Release Factor: Water : 2%
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SAFETY DATA SHEET
Technical conditions and measures / Organizational measures

Air : Wet scrubber for dust elimination of waste gases
Conditions and measures related to sewage treatment plant

Type of Sewage Treatment Plant : Municipal STP, or, Onsite STP
Flow rate of sewage treatment plant : 2,000 m3/d
effluent
Percentage removed from waste water : 99.3 %
Conditions and measures related to external treatment of waste for disposal

Disposal methods : Contaminated packaging material is decontaminated and deposited
or incinerated, Solid waste substance is transferred into wastewater.
1.2.2 Contributing scenario controlling worker exposure for: PROC1 Use in closed process, no likelihood of exposure,
PROC2 Use in closed, continuous process with occasional controlled exposure, PROC3 Use in closed batch process
(synthesis or formulation), PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises,
PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/ or significant
contact), PROC8a Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-
dedicated facilities, PROC8b Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities, PROC9 Transfer of substance or preparation into small containers (dedicated filling line,
including weighing), PROC14 Production of preparations or articles by tabletting, compression, extrusion, pelletisation
Physical Form (at time of use) : Solid, low dustiness

Exposure duration : >4h
Frequency of use : 220 days/year
Remarks : Covers daily exposures up to 8 hours (unless stated differently).
Other operational conditions affecting workers exposure

Outdoor / Indoor : Indoor
Technical conditions and measures

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
Local exhaust ventilation - efficiency of at least (Effectiveness (of a measure): 90 %)
Conditions and measures related to personal protection, hygiene and health evaluation
Wear eye protection/ face protection., Chemical goggles should be consistent with EN 166 or equivalent., Wear
protective gloves., PVC, Natural Rubber, Neoprene gloves, Wear suitable working clothes.
In case of dust clouds, effective dust mask., Wear respiratory protection., Wear a half mask respirator with type P2L
filter or better, Wear a respirator providing a minimum efficiency of (Effectiveness (of a measure): 90 %)
Additional good practice advice beyond the REACH Chemical Safety Assessment
Additional good practice advice : Keep away from food and drink., Keep away from tobacco products.,
Keep working clothes separately., Wash hands before breaks and
after work.
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1.3. Exposure estimation and reference to its source
Environment
Release factor Value type Compartment Environmental RCR

exposure
ERC2, ERC6b, PEC Fresh water 0.0031 mg/L 0.31
ERC7
PEC Marine water 0.0031 mg/L 0.31
PEC STP 1 mg/L 0.215
Human Health
Contributing Specific conditions Value type Level of Exposure RCR

Scenario
PROC1 Worker - dermal, short-term - local 0.1 mg/cm2
Worker - inhalative, long-term - 0.01 mg/m³
local
local
local
PROC4 Worker - dermal, short-term - local 1 mg/cm2
local
local
PROC8a Worker - dermal, short-term - local 1 mg/cm2
local
PROC8b Worker - dermal, short-term - local 1 mg/cm2
local
local
local
RCR = Risk characterisation ratio
ERC2, ERC6b, Exposure Assessment Method : Used EUSES model.

ERC7
PROC1 Exposure Assessment Method : Used ECETOC TRA model.
PROC8a Exposure Assessment Method : Used ECETOC TRA model.
PROC8b Exposure Assessment Method : Used ECETOC TRA model.
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SAFETY DATA SHEET
1.4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario
1.4.1 Environment
If a DU has OC/RMMs outside specifications in the ES, then the DU can evaluate whether he works inside the boundaries set
by the ES through scaling in EUSES.
The main driving parameters are :
- local amount used (tonnage)
- release factor prior to on-site treatment
- on-site wastewater treatment presence and efficiency
- dilution factor
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are
managed to at least equivalent levels.
1.4.2 Health
Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions
outlined in section 2 are implemented.
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SAFETY DATA SHEET
2. ES2 : Industrial use, and, Professional use, of cleaning products and other mixtures
containing the substance
Main User Groups : SU 3 Industrial uses: Uses of substances as such or in preparations at

industrial sites
Sectors of end-use : SU1 Agriculture, forestry, fishery
SU5 Manufacture of textiles, leather, fur
SU22 Public domain (administration, education, entertainment, services,
craftsmen)
Environmental release category : ERC8a Wide dispersive indoor use of processing aids in open systems
ERC8b Wide dispersive indoor use of reactive substances in open
systems
ERC8e Wide dispersive outdoor use of reactive substances in open
systems
Process category : PROC2 Use in closed, continuous process with occasional controlled
exposure
PROC4 Use in batch and other process (synthesis) where opportunity for
exposure arises
PROC8a Transfer of substance or preparation (charging/ discharging) from/
to vessels/ large containers at non-dedicated facilities
PROC8b Transfer of substance or preparation (charging/ discharging) from/
to vessels/ large containers at dedicated facilities
PROC9 Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring
PROC15 Use as laboratory reagent
PROC19 Hand-mixing with intimate contact and only PPE available
PC14 Metal surface treatment products, including galvanic and
electroplating products
PC15 Non-metal-surface treatment products
PC20 Products such as pH-regulators, flocculants, precipitants,
neutralization agents
PC25 Metal working fluids
PC34 Textile dyes, finishing and impregnating products; including
bleaches and other processing aids
products)
2.2.1 Contributing scenario controlling environmental exposure for: ERC8a Wide dispersive indoor use of processing aids
in open systems, ERC8b Wide dispersive indoor use of reactive substances in open systems, ERC8e Wide dispersive
outdoor use of reactive substances in open systems
Amount
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SAFETY DATA SHEET

Emission or Release Factor: Water : 100 %

effluent
2.2.2 Contributing scenario controlling worker exposure for: PROC2 Use in closed, continuous process with occasional
controlled exposure, PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises, PROC8a
Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities,
PROC8b Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at dedicated
facilities, PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing),
PROC15 Use as laboratory reagent, PROC19 Hand-mixing with intimate contact and only PPE available Industrial use and
Professional use
Physical Form (at time of use) : Solid, low dustiness



after work.
2.2.3 Contributing scenario controlling worker exposure for: PROC10 Roller application or brushing, PROC13 Treatment of
articles by dipping and pouring, PROC19 Hand-mixing with intimate contact and only PPE available, OC8 Indoor
Mixture/Article
Physical Form (at time of use) : Liquid, vapour pressure < 0.5 kPa


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SAFETY DATA SHEET
after work.
2.2.4 Contributing scenario controlling worker exposure for: PROC10 Roller application or brushing, OC9 Outdoor
Mixture/Article


Outdoor / Indoor : Outdoor

after work.
2.2.5 Contributing scenario controlling worker exposure for: PROC11 Non industrial spraying, OC8 Indoor



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SAFETY DATA SHEET
Wear a respirator providing a minimum efficiency of (Effectiveness (of a measure): 90 %)
after work.
2.2.6 Contributing scenario controlling worker exposure for: PROC11 Non industrial spraying, OC9 Outdoor
Amount
Concentration after dilution for use :
maximum


Outdoor / Indoor : Outdoor

Wear a respirator providing a minimum efficiency of (Effectiveness (of a measure): 90 %)
after work.
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SAFETY DATA SHEET
Environment

exposure
ERC8a, ERC8b, PEC Fresh water 0.0004 mg/L 0.04
ERC8e
PEC STP 0.004 mg/L < 0.01
Human Health

Scenario
PROC2 Industrial use Worker - dermal, short-term - local 1.37 mg/kg bw/day
local
local
PROC8a Industrial use, and, Worker - dermal, short-term - local 13.7 mg/kg bw/day
Professional use
local
PROC8b, Industrial use Worker - dermal, short-term - local 6.85 mg/kg bw/day
PROC9
local
local
PROC19 Industrial use Worker - dermal, short-term - local 141 mg/kg bw/day
local
PROC9 Professional use Worker - dermal, short-term - local 13.7 mg/kg bw/day
local
PROC8b, Professional use Worker - dermal, short-term - local 6.85 mg/kg bw/day
PROC9
local
PROC19 Professional use Worker - dermal, short-term - local 141 mg/kg bw/day
local
PROC10 Professional use, Indoor Worker - dermal, short-term - local 27.4 mg/kg bw/day
local
PROC13 Professional use, Indoor Worker - dermal, short-term - local 13.7 mg/kg bw/day
local
PROC19 Professional use, Indoor Worker - dermal, short-term - local 141 mg/kg bw/day
local
PROC10 Professional use, Worker - dermal, short-term - local 27.4 mg/kg bw/day
Outdoor
local
PROC11 Professional use, Indoor Worker - dermal, short-term - local 107 mg/kg bw/day
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SAFETY DATA SHEET
local
PROC11 Professional use, Worker - dermal, short-term - local 107 mg/kg bw/day
Outdoor
local
ERC8a, ERC8b, Exposure Assessment Method : Used EUSES model.

ERC8e
PROC4
PROC8a
PROC8b, PROC9
PROC15
PROC19
PROC9
PROC8b, PROC9
PROC19
PROC13
PROC19
2.4.1 Environment
- dilution factor
2.4.2 Health
Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions
outlined in section 2 are implemented.
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SAFETY DATA SHEET
3. ES3 : Consumer use, of cleaning products and other mixtures containing the substance
Main User Groups : SU 21 Consumer uses: Private households (= general public =

consumers)
Sectors of end-use : SU21 Private households (=general public = consumers)
Environmental release category : ERC8a Wide dispersive indoor use of processing aids in open systems
ERC8b Wide dispersive indoor use of reactive substances in open
systems
products)
3.2.1 Contributing scenario controlling environmental exposure for: ERC8a Wide dispersive indoor use of processing aids
in open systems, ERC8b Wide dispersive indoor use of reactive substances in open systems
Amount
Maximum daily local emission to waste : 1370 kg
water

Emission or Release Factor: Water : 100 %

effluent
chemicals, PC39 Cosmetics, personal care products, Transfer of solid product., Load, Laundry detergent,
Mixture/Article
Amount

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SAFETY DATA SHEET
chemicals, PC39 Cosmetics, personal care products, Transfer of solid product., Load, Bleach,
Amount

Consumer Measures : Use eye protection according to EN 166, designed to protect against
powders and dusts., Keep out of the reach of children., Wash
thoroughly after handling., When using do not eat, drink or smoke.
chemicals, PC39 Cosmetics, personal care products, Manual washing, Bleach,
Mixture/Article
Amount

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SAFETY DATA SHEET
Environment

exposure
ERC8a, ERC8b PEC Fresh water 0.0004 mg/L 0.04
PEC STP 0.004 mg/L < 0.01
Human Health

Scenario
For all PC Transfer of solid Consumer - dermal, short-term - 0.19 mg/cm2
product., Load, Laundry local
detergent
For all PC Transfer of solid Consumer - dermal, short-term - 0.75 mg/cm2
product., Load, Bleach local
For all PC Manual washing, Bleach, Consumer - dermal, short-term - 0.08 mg/cm2
Worst case local
ERC8a, ERC8b Exposure Assessment Method : Used EUSES model.

For all PC Exposure Assessment Method : Used ECETOC TRA model.
- dilution factor
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SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

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SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

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SAFETY DATA SHEET

OXYPER® SCS, SCM ST

Revision Date 01.06.2017