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CHEM 101-GENERAL CHEMISTRY
CHAPTER 9
ENERGY & CHEMISTRY
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INSTR : FİLİZ ALSHANABLEH
CHAPTER 9
ENERGY & CHEMISTRY
• Defining Energy
• Energy Transformation & Conservation of Energy
• Heat Capacity & Calorimetry
• Enthalpy
• Hess’s Law & Heats of Reaction
• Heats of Reactions from Heat of Formation
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Forms of Energy
1 2
Kinetic energy = mv
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3
Forms of Energy
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Heat and Work
• Heat always flows from the warmer object to the cooler object.
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Energy Units
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Energy Transformation and Conservation of Energy
∆E = q + w
∆E = Efinal − Einitial
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Energy Transformation and Conservation of Energy
• The sign resulting from the difference in the final and initial
states indicates the direction of the energy flow.
q (+) q (-)
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Example Problem 9.1
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Problem 9.23
Answer
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Problem 9.24
Answer
(a) ∆E = - 43 J, w = 40 J q = - 83 J
(b) ∆E = 31 J, w = 34 J q=-3J
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Energy Transformation and Conservation of Energy
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Waste Energy
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Waste Energy
• Typical
efficiencies of
some common
energy
conversion
devices.
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Heat Capacity and Specific Heat
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Heat Capacity and Specific Heat
Answer:
∆T = Tfinal - Tinitial = 55.0 – 25.0 = 30 ºC
q = mc∆T
= (26.0x103 g)(0.449 J/g ºC)(30 ºC)
= 3.50x105 J
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Problem 9.31
• A copper nail and an iron nail of the same mass and initially at the
same room temperature are both put into a vessel containing
boiling water. Which one would you expect to reach 100 ºC first?
Why?
ciron = 0.449 J/gºC and ccopper = 0.384 J/gºC.
Answer:
• Copper will reach 100 ºC first. Because its heat capacity
that is specific heat less than specific heat of iron.
• Copper required less energy to reach expected temp.
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Example Problem 9.4
Answer:
qgold = ‒ qwater
mgold x cgold x ∆T = ‒ mwater x cwater x ∆T
mgold (0.129 J/gºC)(76.9 ‒ 2.30) = ‒ (250.0g) (4.184 J/gºC)(76.9 ‒ 78.0)
mgold = 120 g
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Calorimetry
qsystem = − qsurroundings
qgained = − qlost
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Calorimetry
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Coffee-Cup Calorimeter
qreaction = ‒ qalorimeter
qreaction = ‒ qwater
qreaction = ‒ qalorimeter
qreaction = ‒ Ccalorimeter x ∆T
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Example Problem
• 0.450 g of a particular fuel is burned in bomb calorimeter which has
calorimeter constant (heat capacity) 118 J/ºC and the temperature
increases by 5.28ºC. Calculate the energy density of this fuel, which is the
amount of energy liberated per gram of fuel burned.
Answer:
qreaction = ‒ qcalorimeter
qreaction = ‒ Ccalorimeter x ∆T
qcalorimeter = Ccalorimeter x ∆T = (118 J/oC )(5.28oC) = 623.04 J
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Enthalpy
∆H = qp
ΔH = Hproducts – Hreactants
• State function
• ΔH = q at constant pressure
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Enthalpy
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∆H of Phase Changes
• Phase changes occur under constant pressure conditions.
• The heat flow during a phase change is an enthalpy change.
• During a phase change, temperature does not change with heat
flow due to formation or breaking of intermolecular attractive
forces.
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∆H of Phase Changes
Answer:
nHCl = 1.6 g / (36.46 g/mol)
= 0.044 mol HCl gives off 14.8 kJ of heat
∆Hcond = ‒14.8 kJ / (0.044 mol)
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Heat of Reaction
• Enthalpy changes can be calculated for chemical reactions, in
addition to temperature changes and phase transitions that is
commonly referred to as the heat of reaction.
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Thermochemical Equations
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Thermochemical Equations
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Hess’s Law and Heats of Reaction
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Hess’s Law
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Example Problem
Consider the following data:
1 3
NH3 ( g )
→ N2 ( g ) + H2 ( g ) ∆H = 46 kJ
2 2
2 H2 ( g ) + O2 ( g )
→ 2 H2O( g ) ∆H = − 484 kJ
Answer
• Reverse the two reactions:
1 3
N2 (g ) + H2 (g )
→ NH3 (g ) ∆H = − 46 kJ
2 2
2 H2O( g )
→ 2 H2 ( g ) + O2 ( g ) ∆H = +484 kJ
4x 1 N (g ) + 3 H (g ) → NH (g ) ∆H = − 46 kJ
2 2 3
2 2
3x 2 H2O(g ) → 2 H2 (g ) + O2 (g ) ∆H = +484 kJ
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Example Problem (continued)
• Final reactions:
2 N2 (g ) + 6 H2 (g )
→ 4 NH3 ( g ) ∆H = − 184 kJ
6 H2O(g )
→ 6 H2 ( g ) + 3 O2 ( g ) ∆H = +1452 kJ
• Desired reaction:
2 N2 (g ) + 6 H2O(g )
→ 3 O2 ( g ) + 4 NH3 ( g )
ΔH = +1268 kJ
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Heats of Reaction for Some Specific Reactions
∆H o =∑ vi ∆H fo (products)i − ∑ v j ∆H fo (reactants) j
i j
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Example Problem
Answer:
∆H°= [2(∆Hf°)NaOH + 1 (∆Hf°)H2 ] - [2(∆Hf°)Na + 2(∆Hf°)H2O ]
∆H°= [2( -470) + 1 (0.0) ] - [2(0.0) + 2(-286) ]
∆H° = –368 kJ
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Example Problem 9.9
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Energy Density and Fuels
• Energy density is the
amount of energy that can
be released per gram of fuel
burned.
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