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1. Reaction rate
2. Rate = change in concentration/change in time
3. Chemical kinetics
4. Rate law
5. Concentration of reactants at a fixed temperature
6. Instantaneous rate
7. Initial rate
8. 1/s
9. L/mol•s or L
10. Mol/L•s or mol
[
1. 𝑅𝑎𝑡𝑒 = 𝑘 𝐶𝐻 𝐶𝐻𝑂
3 ]2 𝑤𝑖𝑡ℎ 𝑘 = 6. 73×10−6 𝐿/𝑚𝑜𝑙/𝑠
2 2 −2 −1
2. 𝑅𝑎𝑡𝑒 = 𝑘[𝑁𝑂] [𝐶𝑙]2; 𝑘 = 9. 12 𝐿 𝑚𝑜𝑘 ℎ ; second order in NO; first order Cl2
[ ]
3. 𝑂𝑟𝑑𝑒𝑟 𝑤𝑖𝑡ℎ 𝑟𝑒𝑠𝑝𝑒𝑐𝑡 𝑡𝑜 𝐶𝑙𝑂2 : 2
1−
𝑂𝑟𝑑𝑒𝑟 𝑤𝑖𝑡ℎ 𝑟𝑒𝑠𝑝𝑒𝑐𝑡 𝑡𝑜 [𝑂𝐻 ]: 1
1
[
Rate law of this reaction: 𝑅𝑎𝑡𝑒 = 𝑘 𝐶𝑙𝑂2 ]2[𝑂𝐻1−]
2
𝐿
Value and units for the rate constant: 𝑘 = 230 2
𝑚𝑜𝑙 𝑠
4. Order with respect to [𝐻𝑏]: 1
Order with respect to [𝐶𝑂]: 1
1 1
Rate law of this reaction: 𝑅𝑎𝑡𝑒 = 𝑘[𝐻𝐵] [𝐶𝑂]
Value and units for the rate constant: 0.28 L/mol s
[ ]
5. Order with respect to 𝐶𝑙𝑂2 : 2
1−
Order with respect to [𝑂𝐻 ]: 1
[
Rate law of this reaction: 𝑅𝑎𝑡𝑒 = 𝑘 𝐶𝑙𝑂2 ]2[𝑂𝐻−]
Value and units for the rate constant: 119. 79
2. 𝑅𝑎𝑡𝑒 = 𝑘[𝐻2][𝐵𝑟2] 2
1st
3. 𝑅𝑎𝑡𝑒 = 𝑘[𝑁𝑂2][𝐹2] 2nd
4. 𝑅𝑎𝑡𝑒 = 𝑘[𝑙𝐶𝑙][𝐻2] 2nd
5. 𝑅𝑎𝑡𝑒 = 𝑘[𝑁2𝑂5] 1st
Reflection:
1. I learned that there are different rate laws and order of reaction. Rate laws expresses
the reaction rate as a function of reactant concentrations, product concentrations and
temperature. While order of reaction is a reaction can also be described in terms of the
order of each reactant.
2. I enjoyed most on reading the background information for the learners.
3. I want to learn more on this topic.
Activity 3: ESSAY
1. The reactants either may be moving too slowly to have enough kinetic energy to
exceed the activation energy for the reaction, or the orientation of the molecules when
they collide may prevent the reaction from occurring.
2. Many chemical reactions, and almost all biochemical reactions do not occur
spontaneously and must have an initial input of energy (called the activation energy)
to get started. Activation energy must be considered when analyzing both endergonic
ad exergonic reactions.
3. In terms of the collision theory, increasing the concentration of a reactant increases in
the number of collisions between the reacting species per second and therefore
increases the reaction rate.
4. There will be a chemical reaction. But, if proper orientation is not present even though
there is sufficient energy to initiate the reaction, then there will be no chemical
reaction.
5. I agree since according to collision theory, the rate at which molecules collide will
have an impact on the overall reaction rate. The more molecules present, the more
collisions will happen.
Reflection:
1. I learned that there are 3 basic requirements to have an effective collision which is the
reactants must collide with each other, the molecules must have the sufficient energy
to initiate a reaction and the molecules must have a proper orientation.
2. I enjoyed most on answering the crossword puzzle and the activity 5 which is spilling
the message.
3. I want to learn more on this particular topic.