Activity 1: IT’S HUNT TIME

Y M Y E Y J P U K C Y L K Z

N C R D N L C R B O Q T E U N
I P F Z P O U G L E C X Q C O
O M U T Y B H L R T W J L K I
P H B W P Q I Q V U B C Y O S
G T Y K M G Z R Y L W J M Q S
N O N D A L C U P O U D A B E
I W A T I D N K V S L Z S O R
Z Q I Y G E S J T I D C S Q P
E V S N O I T A V E L E S Y E
E B X P E G U H G C X Z O B D
R Y U L U J S S A M R A L O M
F M O L E S O L U T E P U Y I
A M Y R N F T G C F V L T Q R
T N I O P G N I L I O B E B C

COLLIGATIVE FREEZING POINT SOLUTE

MOLAR MASS BOILING POINT MOLE
MOLE SOLUTE ELEVATION
MASS SOLUTE DEPRESSION

Activity 2: PROBLEM SOLVING

1. Given: 38.7f of nonelectrolyte solute
218g of water = 0.218 kg of water
F = -5.53.
of water is 1.86/m
Unknown: Molar mass of the solute
Solution:
5.53 𝑚𝑜𝑙
𝑚 =− 1.86 = 2. 97 𝑘𝑔
𝑚

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 2. 97
𝑚𝑜𝑙
𝑘𝑔 )(0. 218 𝑘𝑔) = 0. 65 𝑚𝑜𝑙𝑒
38.7𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.65 𝑚𝑜𝑙𝑒
= 59. 54𝑔/𝑚𝑜𝑙

2. Given: 36g of nonvolatile solute

100 g of water = 0.1 kg of water
Unknown: Molar mass of the solute
Solution:
37.2
𝑚 =− 1.86 = 20 𝑚𝑜𝑙/𝑘𝑔
𝑚

𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 20 ( 𝑚𝑜𝑙

𝑘𝑔 )(0. 1 𝑘𝑔) = 2 𝑚𝑜𝑙
36𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 2 𝑚𝑜𝑙
= 18 𝑔/𝑚𝑜𝑙

3. Given: 27.3 g of nonvolatile molecular substance

300g of water = 0.3 kg of water
F = -0.49.
of water is 1.86/m
Unknown: molar mass of the solute
Solution:
0.49
𝑚 =− 1.86 = 0. 26 𝑚𝑜𝑙/𝑘𝑔
𝑚

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 26
𝑚𝑜𝑙
𝑘𝑔 )(0. 3 𝑘𝑔) = 0. 078 𝑚𝑜𝑙
27.3𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.078 𝑚𝑜𝑙
= 350 𝑔/𝑚𝑜𝑙

4. Given: 2.55g of a substance

150g of water = 0.15 kg of water
F= -0.42.
of water is 1.86/m
Unknown: molar mass of the solute
Solution:
0.42
𝑚 =− 1.86 = 0. 23 𝑚𝑜𝑙/𝑘𝑔
𝑚

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 23
𝑚𝑜𝑙
𝑘𝑔 )(0. 15 𝑘𝑔) = 0. 0345 𝑚𝑜𝑙
2.55𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.0345 𝑚𝑜𝑙
= 73. 91 𝑔/𝑚𝑜𝑙
 5. Given: 1.80 g of unknown solute
1000g of water = 1 kg of water
F= -0.186.
Of water is 1.86/m
Unknown: molar mass of the solute
Solution:
0.186
𝑚 =− 1.86 = 0. 1 𝑚𝑜𝑙/𝑘𝑔
𝑚

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 1
𝑚𝑜𝑙
𝑘𝑔 )
(1 𝑘𝑔) = 0. 1 𝑚𝑜𝑙
1.80
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.1𝑚𝑜𝑙
= 18 𝑔/𝑚𝑜𝑙

Activity 3:CALCULATING MOLAR MASS FROM BOILING POINT ELEVATION

1. Given: 97.30g of mystery compound
500g of water = 0.5 kg of water
B = 100.78
Of water is 0.51/m
Unknown: molar mass of the solute
Solution:
0.78
𝑚 = 0.51/𝑚 = 1. 53 𝑚𝑜𝑙/𝑘𝑔
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 1. 53( 𝑚𝑜𝑙
𝑘𝑔 )
(0. 5 𝑘𝑔) = 0. 77 𝑚𝑜𝑙
97.30𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.77 𝑚𝑜𝑙
= 127. 19 𝑔/𝑚𝑜𝑙

2. Given: 5g of an organic solid

100g of benzene = 0.1 kg of benzene
B = 80.10
Of benzene is 2.53/m
Unknown: molar mass of the solute
Solution:
2.32
𝑚 = 2.53/𝑚 = 0. 92 𝑚𝑜𝑙/𝑘𝑔
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 92( 𝑚𝑜𝑙
𝑘𝑔 )(0. 1 𝑘𝑔 𝑏𝑒𝑛𝑧𝑒𝑛𝑒) = 0. 092 𝑚𝑜𝑙
5𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.092 𝑚𝑜𝑙
= 54. 35 𝑔/𝑚𝑜𝑙

3. Given: 0.1665 of eugenol

1.0g of chloroform = 0.001 kg of chloroform
Of chloroform is 3.63/m
Unknown: molar mass of the solute
Solution:
3.68
𝑚 = 3.63/𝑚 = 1. 01 𝑚𝑜𝑙/𝑘𝑔
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 1. 01( 𝑚𝑜𝑙
𝑘𝑔 )
(0. 001 𝑘𝑔 𝑜𝑓 𝑐ℎ𝑙𝑜𝑟𝑜𝑓𝑜𝑟𝑚 = 0. 00101 𝑚𝑜𝑙
0.1665𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.00101 𝑚𝑜𝑙
= 164. 85 𝑔/𝑚𝑜𝑙

4. Given: 0.64 of adrenaline

36g = 0.036 kg
 Of is 5.03/m
Unknown: molar mass of the solute
Solution:
0.49
𝑚 = 5.03/𝑚 = 0. 01 𝑚𝑜𝑙/𝑘𝑔

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 01 )
𝑚𝑜𝑙
𝑘𝑔
(0. 036 𝑘𝑔) = 0. 00036 𝑚𝑜𝑙
0.64𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.00036 𝑚𝑜𝑙
= 1777. 78 𝑔/𝑚𝑜𝑙

5. Given: 5g of large biomolecule

16g of carbon tetrachloride = 0.016 kg of carbon tetrachloride
Of carbon tetrachloride is 5.03/m
Unknown: molar mass of the solute
Solution:
1.35
𝑚 = 5.03/𝑚 = 0. 27 𝑚𝑜𝑙/𝑘𝑔

(
𝑚𝑜𝑙 𝑠𝑜𝑙𝑢𝑡𝑒 = 0. 27 𝑘𝑔)
𝑚𝑜𝑙
(0. 016 𝑘𝑔) = 0. 00432 𝑚𝑜𝑙
5𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 = 0.00432 𝑚𝑜𝑙
= 1157. 41 𝑔/𝑚𝑜𝑙

Reflection:
1. I learned that freezing point or boiling point data can be used to determine the molar
mass of an unknown solute.
2. I enjoyed most on reading the background information for the learners.
3. I want to learn more about calculating molar mass from boiling point elevation.

Activity 1: PROBLEM SOLVING ON SOLUTION PREPARATION

1. 23.5g NaCl is dissolved in enough water to make 0.683L of solution.
a. What is the molarity (M) of the solution?
23.5g NaCl = 0.40 mol
M = 0.59
b. How many moles of NaCl are contained in 0.0100L of the above NaCl solution?
Mol = mv
(0. 59)(0. 0100 𝐿) = 0. 0059
c. What volume (L) of this NaCl solution would contain 0.200 moles of NaCl?
V = 0.340 L
2. 12.5g glucose is dissolved in enough water to make 750.0 mL of solution.
a. What is the molarity (M) of the solution?
12.5g = 0.069 mol
M = 0.092
b. How many moles of glucose are contained in 237mL of the above glucose
solution?
Mol = mv
(0. 092)(0. 237 𝐿) = 0. 022
c. What volume (L) of this glucose solution would contain 0.079 moles of glucose?
V = 0.86 L

Activity 2: PREPARING DISINFECTANT SOLUTION AT HOME

 1. From 1L of household bleach available,
a. How much volume of 1:10 household bleach solution will you able to prepare?
1
10
= 1𝐿
10 L of household bleach can be prepared.
b. How much volume of water is needed?
9 L of water will be needed because 1L of bleach is available and the ration of the
solution is 1:10.
c. It has been mentioned earlier that household bleach is a solution of sodium
hypochlorite which generally contains 5% (50g/liter or 50000 ppm) available
chlorine, how many percent of chlorine is present in this solution?
0.05
10𝐿
= 0. 5% of chlorine is present in the solution.
2. Prepare 100mL of 1:100 bleach solution from 1:10 bleach solution
a. How much volume of bleach solution will you need?
1000𝑚𝐿
100𝑚𝐿
= 10 𝑚𝐿 of 1:10 bleach solution will be needed
b. How much volume of water is needed?
90mL of water will be needed because 100mL of bleach solution is available and
the ratio of solute to solution is 1:100.
c. Determine the percentage of chlorine concentration from the solution?
0.05
100𝑚𝐿
= 0. 05% of chlorine is present in this solution.

Reflection:
1. I learned that there are many ways of preparing a solution depending of what is the
available material and amount of solution needed in the experimentation.
2. I enjoyed most on reading the background information for the learners.
3. I want to learn more on the this topic especially in problem solving.