cc) (2) @) (4) (5) Department of physics Indian Institute of technology, Kanpur PHY201/SE321(Thermal physics) Assignment No, 5 (Due on 6-2-2012) Molar entropy of a certain fluid has been found to be related to its internal energy U and volume Vin the following way S=S)+ ain + pins we ye where 3°, U’, V are the molar entropy, Internal energy and volume at some appropriately chosen reference state and a and B are positive constant. Obtain the relationship between its (i) internal energy, temperature and specific volume, and (ii) pressure, temperature and volume. Obtain an explicit expression for the molar Helmholtz free energy of a monatomic ideal gas as @ function of T and molar volume V. ‘Acylinder contains an internal piston on each side of which is one mole of a monatomic ideal gas. The wall of the cylinder are heat conducting and the system is immersed in a heat reservoir at 273K, The initial volume of the two gaseous systems are 10 litres and 1 litre, respectively. The piston is now allowed to move reversibly so that the final volumes are 6 litres and 5 litres, respectively. (i) Use the expression derived in problem 2 to calculate the work delivered? (Ii) Does the entropy of the universe change in the process? [iii] Does the process violate the Kelvin-Planck statement of the second law? Calculate the pressure on each side of the internal piston in problem (3) for an arbitrary position of the piston, Using this obtain the work done and check this against the answer obtained in (3i) above. The variation of Gibbs free energy of a substance with temperature is given es Gaal tht fr Determine how the entropy and the enthalpy of this substance vary with temperature.we gee eg pi 7 Y= sere v T. Gi) Me abe Lave + fet ~—P v0 ay + | plas | De. MO de Webmste free Cnrrga of acmonatorr “heal § downturn clin of Tant¥.( Vo smc yrtaanee ) Fos VU—aT Ss fe bat Avy £7 ES ITNES EE LICA), Sts PARC ESRB) a1 le haw. Exp TeMOn Cun Abe be) abteciol bh fobleny ar ag: — [Saar — pay aye = c= & = S2RCE) ~ RATS) = Femail @S RE | EA&(E)— F [-PACS) + lv) = —SoT = ete (E) + Sat —Uh/¥) + fey3. Unkem Corsviont” anprraliin , Fi Re Ae hee {pw é ae oh dee Chains Je Yebhhette fooe =e AG. bu- Tos-S at = 6 — pov. -Ta-<3T . <_yhi= pou Fara ear = ~pey sat S or =pov- sot Bk Cnishiewt pean BEL Ga pAV 0 fren OT =e ASIF i Croom. we (free erry Ui cadres MIR ee Bg 3 I)_aTa/y f ei Lealeaale roe 8 ES) -OAE ee Ac 2 = Rt {Vent via Themen? 2) a —n ar a = a = hth [£) 2 Gee | L Pilger cons = ET | Y= erm E es = AEE EE eT —S2s00-— BG woe dg delish 5 Ep pt 8 20h 5 -= Q i (4) TALE Hh. nm yo peer”, & {so fk (ca) No ath atlhowsb) Anesot 6 token Fen i neveura ak s Connsid fo Aun esenah dima of north, He prown t NT eyete Ss eke Pld sited 4 fecnd bass fs WT a bred daow os pont oe hee ae RT 2 TR work dor mae on Cts oi “i ae . RT. 1 » emer. | teu=-#] de arp (w2) iar aU | fe cr} > Ser Cry | a At eZ) G Nek nok. done Gy J 0 on tro Anche, = CS KE eThs = Urls Ths 6 Game Boma of. ae altiined bg te efecnen of fat engGx Abs Ye Gm =aSelT ae CER we 5 = ZP Conee p des mt Speen. ui ihe tepverm alae C= Se Te Hak exbboctpy wie de 2 Urpu-ts Ree: = Soh es: GPU os arate eee + t{=a> ©) g b nto ee EAA. are b rire 7 Ca th 235 Pes