ASSIGNMENT Ne Lo et Problems 14.1, 14.2, 14.3 and 14.4 from Dittmann-Zemansky (10.14) The vapour pressure of benzene is 53.3 kPa at 333.6K but falls to 51.5 kPa when 19 grams of an involatile organic compound is dissolved in 500 grams of benzene. Using Raoult's law, find the molar mass of the compound. (10.2A] The addition of 5 grams of of a compound to 250 grams of naphthalene lowered the freezing point of the solvent by 0.78K. Find the molar mass of the compound. Experimentally the change in freezing point is = Kf*b, where bis the molality (number of moles/mass of the solvent) For naphthalene, Kf = 6.94 K kg/mole. Solution (10.34) The osmotic pressure of an aqueous 120KPa. Find the freezing point of the solution. For water Kf = 1.86 K kg/mole (see problem 10.2A). (10.44) The enthalpy of fusion of anthracene is 28.8k1/mole and its melting point is 217 deg C. Calculate its solubility in benzene at 25 deg C. Take x80 = 1 at T = Tfusion. (10.5) To determine the molar mass of an enzyme, the following experiments performed. The wide opening of a funnel is covered by 2 semipermeabale membrane, filled with water and dipped in the solution of the enzyme in water. Because of osmosis the water starts rising in the funnel and stops after rising height h. The data for heights at different concentrations of the solution is given below. Determine the molar mass of the enzyme. concentration (mg/cc) 3.221 4.618 5.112 6.722 height (cm) 5.746 8.238 9.119 11.990s4-1.: Te. Aes Sate bel r ees €Q)3> SP sagt at in(thepp) at a i ¢ 4 / en ASO = 6 Deas? at (TAT, Px) \ dv Ha anre gwela fy Rewer ot : = Cha i We Aart = Cr 5 OS) i. Vv a fo” adh = Grats veep c= a eon ty FR a = sat ae ne Tu (6 fo os ‘ Sm repens nttsnged Zerats se pea avg pms hare Gel Gon CE rope ar awe wap = wpa wre ae? = yh (¥) ) HL ) AF eee + ean IF(3) Tds= Gdr apa De Cott Swe ger Ab oo No _gpre j beet. do start pith Ae Th (TT AS = hCEaT + T Ca SB Oy casnise Ree ae : : ize) ae = ft | fee or) AAR Fe KBE EE Ag | | | : f |(Ht) ss {fers a) (Ye= ys Le (C2 k ou QCeon + Phe) ae St deer legen oe 7 on He aE = im pL: as ae Se Se oe SeiA UANATS LO eR —— fg Ge Pod c + (he ae 2G f-4 ic t =a ty Oe SS Ces Laer we z fe eee = a a re (44 6k fe) (G-fe) — Ceatteje =o SS ee | (3-€e) rere tel = Peeite t => =o(os) "Raoult fas P= 4a pe bo Php OE BS. LSP (a8 = aE Phyo Son cer 2 (eg) 3 z i 2 => ; Hs os4 i) ok ene * ——= (|0: 1 at} fo At ~ N Keb) ore = 644 x b % Sv Ks Sale ¢(ED) T= fo Ky Oxinhe pene . aeeh = (ns): \2ex.o7 Pe dyge cw) 3h oo oe AT, = Keb bs tadeb hy, 7 cone YAO ana 4 bbuoot a t = nee ante] Croly) ij | po Arie op 66Cex ASE ; [00° Sounesieas 0:04 = —=> Ne = [Is mS = de yee [ay afb ; CH — _ Bn droenisn aa’ ir ; eee) re “Li ss QOTt3 Niue cur | 09g atig=3 2 i pK om-Su