SMA BPK PENABUR Banda

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Name: _______________________________ Class/No.: _____________________ Date: ___________________

MID-SEMESTER 1 EXAMINATION 2122

JUNIOR COLLEGE 1
CHEMISTRY Time: 60 minutes

Instructions:
• Write down your name, class, student number and date on the provided space above.
• There are two parts in this test. Read carefully and answer them all on answer sheets.
• Write in dark blue or black pen. You may use pencil for drawing.
• You may use a calculator in this test.

1. Ruthenium are metals of group 8.

(a) The subatomic particles present in ruthenium are electrons, neutrons and protons.
A beam of protons is fired into an electric field produced by two charged plates, as shown in the diagram.

Beam of protons

(i) Describe how the beam of protons behaves when it passes through the gap between charged plates.
Explain your answer. [2]
(ii) Describe what happens when a beam of neutrons passes through the gap between the charged plates [2]
(b) A mass spectrogram of ruthenium is shown below:

Page 1 of 2
 (i) Write the isotopic symbols of the heaviest Ruthenium isotope. [1]
(ii) How many protons, neutrons, and electrons are there in Ruthenium-102 isotope? [3]
(iii) How many electrons are there in Ru3+? [1]
(iv) Write the 1s notation for rutherium atom. [1]
(v) Calculate the relative mass of ruthenium (show your working and answer to 2 decimal places) [3]
[Total: 13]

2. The table shows the first ionisation energies, IE, in kJ mol-1 of elements in Period 3 of the periodic table.

Element Na Mg Al Si P S Cl Ar

IE1 494 736 577 786 1060 1000 1260 1520

(a) Write an equation, including state symbols, for the first ionisation energy of magnesium [2]
(b) Explain why first ionisation energy of aluminium is less than first ionisation energy of magnesium [2]
(c) Identify the element in period 3 with the largest atomic radius. Explain your answer. [3]
(d) For element silicon sketch a graph to predict the log10 of successive ionisation energies (y-axis) against the
number of electrons removed(x-axis) [2]
(e) A successive ionisation energy of element X is shown in the table below

Electrons removed 1 2 3 4 5 6 7 8

IE / kJ mol-1 1000 2600 5020 7400 11000 13500 71300 84100

Which group in the periodic table does X belong to? [1]

[Total: 10]

3. A diprotic acid X contains 26.67% carbon, 2.22% hydrogen and 71.11% oxygen.
(a) Calculate its empirical for this acid (show your working) [2]
(b) If the relative formula mass of the acid X is 90, deduce the molecular formula of acid X. [2]
3 -3
(c) Calculate the mass of the acid needed to make 100 cm solution of acid of concentration 0.50 mol dm [2]
(d) Write down the neutralisation reaction of this diprotic acid with NaOH. (include state symbols) [2]
(e) 25 cm3 of diprotic acid of concentration 0.50 mol dm-3 is titrated with NaOH. The result of titration is shown in
the table below
Volume NaOH /cm3
Titration 1 22.40
Titration 2 21.10
Titration 3 21.20
(i) Which volume of titration will you use in your calculation? Give a reason for your choice. [2]
(ii) Using the volume you choose in (i) the concentration of NaOH solution. [2]
(f) Excess of diprotic acid X is reacted with sodium carbonate and measured using a gas syringe, which produces
36 cm3 of gas CO2 at r.t.p.
(i) Write the balanced chemical equation of diprotic acid X and sodium carbonate (include state symbols) [2]
(ii) Calculate the number of moles CO2 produced. [1]
(iii) By using your answer from f(i) and f(ii), calculate the mass of sodium carbonate used in the reaction [2]
[Total: 17]

Page 2 of 2
Data section
Contents: Tables of chemical data
1 Important values, constants and standards
2 Ionisation energies (1st, 2nd, 3rd and 4th) of selected elements in kJ mol–1
3 Bond energies
4 Standard electrode potential and reduction potentials, E⦵, at 298 K (25 °C)
5 Pauling electronegativity values
6 Typical proton (1H) chemical shift values (δ) relative to TMS = 0
7 Typical carbon (13C) chemical shift values (δ) relative to TMS = 0
8 Characteristic infrared absorption frequencies for some selected bonds
9 The Periodic Table of Elements

1  Important values, constants and standards

molar gas constant R = 8.31 J K–1 mol–1
Faraday constant F = 9.65 × 104 C mol–1
Avogadro constant L = 6.02 x 1023 mol–1
electronic charge e = –1.60 × 10–19 C
molar volume of gas Vm = 22.4 dm3 mol–1 at s.t.p. (101 kPa and 273 K)
Vm = 24.0 dm3 mol–1 at room conditions
ionic product of water Kw = 1.00 × 10–14 mol2 dm–6 (at 298 K (25 °C))
specific heat capacity of water c = 4.18 kJ kg–1 K–1 (= 4.18 J g–1 K–1)
 The Periodic Table of Elements
Group
1 2 13 14 15 16 17 18
1 2

H He
hydrogen helium
Key 1.0 4.0
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
6.9 9.0 relative atomic mass 10.8 12.0 14.0 16.0 19.0 20.2
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23.0 24.3 3 4 5 6 7 8 9 10 11 12 27.0 28.1 31.0 32.1 35.5 39.9
The Periodic Table of Elements

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.5 87.6 88.9 91.2 92.9 95.9 – 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium nihonium flerovium moscovium livermorium tennessine oganesson
– – – – – – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
138.9 140.1 140.9 144.4 – 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232.0 231.0 238.0 – – – – – – – – – – –