Aits 2021 PT III Jeem Sol

ALL INDIA TEST SERIES
PART TEST – III

JEE (Main)-2021
TEST DATE: 19-12-2020
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. C
Sol.       B
n2 n2 n2
  
T1 T1 T1
    B 
2 2 2
T T
T1   20 years
2
(   ) T  T
 one fourth of sample will remain after 2 half life = 40 years
2. B
IP
Sol. T  2
mg cm
2 / 3 m2
T  2
  
2mg  
2 2
2 2
T  2
3g
3. B
Sol. 5 VSD = 4 MSD
 1 VSD = 4/5 MSD
L.C = 1 MSD – 1 VSD
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-III-PCM(Sol.)-JEE(Main)/2021 2
1
= MSD = 1 mm
5
pitch
For screw gage (LC)= = 0.01 mm
100
4. A
Sol.  sin     sin 
 
    …(i) 

 sin       sin 
 
         …(ii)
From (i) and (ii)
    

      

5. A
1
Sol. I= 0E02c
2
= 3.3 W / m2
6. B
Sol. At a distance y from the free end, the speed of the wave is
yg
v  yg


 dy
dy
t   dt   y
0 gy

t2
g
…(i)
g
Also, v 0 
2
2v 02
  …(ii)
g
From equation (i) and (ii)
2 2v 0
t
g
7. B
Sol. At time t,
length of tube =   vt
c
 f
4(  vt)
Fundamental frequency
c  
f0   
4  4
At time t, length of tube =   vt
3 AITS-PT-III-PCM(Sol.)-JEE(Main)/2021
c
 f
4(   vt)
df cv
Or, 
dt 4(  vt)2
   vt
df cv
 
dt 4 2
8. A
Sol. Volume of cylinder = V
3 
  V  g  mg
4 
4m
V
3
In reference frame of vessel
 mA
mg - Vgeff  mA   geff  g  A
4 3
  4m  mA
 mg     g  A   mA 
4  3  3
2g
A
3
9. A
Sol. A satellite will appear motionless when its period of revolution is same as that of earth that is T =
24 hr. Let r be the radius of orbit from the centre of earth
GMm
Then, m 2r 
r2
2 1/3
 2  3  GMT 2 
 T  r  GM r  2 
   4 
1/ 3
 gR 2 T 2 
r    GM  gR2 
 4 
2
10. B
Sol. Let the intensity of individual wave be I, then S1 P
I0 = 4I y
I
 I 0 O
4 S
 x at P = d sin  S2
yd
 x  dtan  
D
d  d D   D 
x      
D 4 D 4d 4  d 
2  
   
 4 2

IP  I  I  2 I2 cos  2I
2
I0
IP 
2
11. C
320  330  V0  320
Sol. 5= 
3  330  10  3
 V0  5m / s
90
t   6 sec
15
12. B
Sol. K = h  w
K = 2h  w
= 2(h  w) + w
= 2K + w
Thus, the kinetic energy of photoelectrons will be more than double when incident frequency is
doubled.
13. C
 h
Sol. For narrow single slit diffraction width of central maxima is , where   and b is slit width.
b mv
14. C
u
Sol. The velocity vector is perpendicular to initial velocity vector at t = and at this instant its
gsin 
speed is v =u cot 
h
Since  =
mv
h
 
mucot 
h
 tan 
mu
15. A
Sol. U  eV
r 
= eV0 loge  
 r0 
 dU  eV0
f    r
 dr 
This force will provide the necessary centripetal force
mv 2 eV0
 
r r
eV0
v …(i)
m
nh
Also, mvr  …(ii)
2
Dividing (ii) by (i)
 nh  m
mr =  
 2  eV0
r n
16. C
Sol. The silvered lens can be replaced by a mirror of focal length d
given as O
For plano convex lens
1 1    1 10cm
  …(i)
f 40  R  f=20cm f=40cm
For lens,
1 1 1
 
v1  10  20
 v1  20cm
Distance of image from plano-convex is d + 20
For left surface of plano-convex lens
 1  1
 
   d  20  R
 d = 20 cm
17. A
 3
2
 1  2
2
Sol. AR 
 3 
  tan1  
 1  3
 
 
 y = 2sin  t  
 3
d2 y  
  a  22 sin  t  
dt 2  3 
amax  22  g
g
For which mass just breaks off the plank  
2
This will happen for the first time when
  
t   or t 
3 2 6
  2
t 
6 6 g
18. A
Sol. fv  B  mg fv B
6rvT + mg = mg
 m  m  g
 VT 
6r
m  m
 VT 
r mg
19. D
5 /4
Sol.  42   0.3  10 
4
/2
5
  45cm
4 /2
   36cm
 P   P0  sinkx
displacement
diagram
 2 
 P0 sin   24 
 36 
3
P  P0
2
20. B
Sol. The cut-off wavelength when V = V1 =10 kV is
hc
1   1243.125  10 13 m
eV1
The cut-off wavelength when V = V2 = 20 kV is
hc
2   621.56  10 13 m
eV2
1 3R
 z  1
2
The wavelength corresponding to k line is 
 4
Given that     2   3    1 
Putting all above
z = 29
SECTION – B
21. 5
1.5 f
Sol. M0   0
0.25 fe
and f0 + fe=35
22. 5
Sol. Applying conservation of mechanical energy,
K  U
1
m0 v 2  UB  UA  m0 (VB  VA )
2
or v  2  VB  VA  …(i)
potential at A
VA  potential due to complete sphere – potential due to cavity
1.5 GM  Gm 
  
R R / 2
3
4 R  R3
Here, m     
3 2 
4
And M  R 3 
3
Substituting m and M
5
VA   GR 2
3
Potential at B,
GM   R   1.5Gm
2
VB  1.5R 2
 0.5 2  R/2
R3    
4
 GR 2
3
1
 VB  VA  GR 2
3
So, from equ. (i)
2
v GR2
3
SECTION – C
23. 00002.72
L
Sol. T = 2
g
L 
or T2 = 42  
g
4 L2
g 2
T
g L 2T
  
g L T
g
% error in g =  100
g
 L 2T 
   100
 L T 
 1 
 10 1 
  2   100
 20 90 

 
=2.72%
24. 00002.30
Sol. In the middle right of the circuit the capacitor behaves like an open circuit A
for d.c. 0.2 mA current, so current will flow from A and B only. Let potential 0.2 mA
across A and B is V, so by Kirchoff’s loop law. 5k
VAB = (5000  0.2  103 + 0.3 + 5000  0.2  103)
VAB = 1 V + 0.3 V + 1V
VAB = 2.3 V
5k
25. 00000.03
I
Sol.   10log  
 I0 
I
60  10log  
 I0 
I = 106 W/m2
p 2
I=
2v
15
 p  10 6  2   330
11
 p  0.03 N / m2
Chemistry PART – II
SECTION – A
26. D
Sol. Cetyltrimethylammonium bromide is a cationic detergent
CH3
H3C (CH2)15 N CH3 Br
CH3
Sodium dodecylbenzene sulphonate and sodium lauryl sulphate both are anionic detergents.
H3C (CH2)11 SO 3 Na
H3C (CH2)10 CH2O SO3 Na

Sodium stearate  C17H35 COONa  is not a detergent.
27. B
Sol. (A) Ni – Mond process
(B) Pig iron can be moulded into a variety of shapes.
(C) Wrought iron is purest form of iron containing very low carbon content.
(D) Blister copper has blistered appearance due to evolution of SO 2(g).
28. A
Sol. Preferential adsorption of ions from solution is responsible for charge on colloid particles, and the
charge is responsible for stability of colloid.
29. C
Sol. Correct order of increasing field strength of ligands according to spectro-chemical series is
SCN  F  C2 O42  CN
30. C
Sol. (A) Acetone + chloroform shows –ve deviation from Raoult’s law.
(B) Chloroethane + Bromoethane is an example of ideal solution.
(C) Ethanol + acetone shows +ve deviation from Raoult’s law
(D) Benzene + Toluene is an example of ideal solution.
31. C
Sol. For adiabatic free-expansion of an ideal gas:
q  0, W  0,  U  0,  T  0
But free-expansion is an irreversible process
qsys 0
 Ssys   0
T T
In fact S sys   ve
32. B
Sol. Tb  Tb s  Tb o
 373.52  373 K  0.52 K
Tb  K b  m
Wsolute  1000
0.52  0.52 
150  Wsolvent
Wsolute
 0.15
Wsolvent
w Wsolute
Now %  100
W Wsolute  Wsolvent
Wsolute
  100
W
Wsolute  solute
0.15
 13%
33. D
Sol. Option (A) is correct.
Option (B) is correct.
Option (C) is correct.
Option (D) is incorrect.
Rhombic sulphur transforms to monoclinic sulphur when heated above 369 K.
34. A
Sol. Option (A) is incorrect.
Actually catalyst participates in the reaction.
Option (B), (C) and (D) are correct.
35. A
Sol. 10 M C2H5 OH  aq. solution means 10 mol/L.
Moles of solute  C2H5 OH  10 mole
Mass of solute  C2H5 OH   10  46  460 g
g
Mass of solution  1000mL  1  1000 g
mL
Mass of solvent = 1000 g – 460 g = 540 g
540
Moles of solvent H2O    30 mole
18
10 1
xsolute  
40 4
30 3
xsolvent  
40 4
Psolution  PCo2H5OH  x C2H5 OH  PHo2O  xH2O
1 3
 40   20 
4 4
= 10 + 15 = 25 mm of Hg.
36. C
Sol. The material obtained from bottom of blast furnace after smelting during metallurgy of Cu, which
is further subjected for bessemerization is called Matte.
37. B
Sol. Let us assume x mL of O3 in given sample (25 mL) of ozonised oxygen.
Now O3 present in the sample reacts with KI to liberate I2 according to following reaction
O3  2KI  H2 O 
 O2  I2  2KOH … (1)
The I2 liberated in above reaction [Eq. (1)] further reacts with Na2S2O3 according to the following
reaction
2 2.5
2Na 2 S 2 O 3  I2  2NaI  Na 2 S 4 O6 … (2)
n-factor of Na2S2O3 is above reaction = 1
 N of Na2S2O3 = M of Na2S2O3
According to reaction (2)

m moles of Na2S 2O3 0.08  15
m moles of I2    0.6 m mole
2 2
Now according to reaction (1)
m moles of O3 reacted = m moles of I2 formed = 0.6 m mole
Thus, volume of O3 at NTP = 0.6 × 22.4 = 13.44 mL
38. B
3
Sol. 1. Co NO2 6 
3
2 Co  NO2 5  ONO  
cis
3
3 Co NO2 4  ONO 2 
trans
facial
3
4. Co NO2 3  ONO 3 
meridonial
cis
3
5. Co NO2 2  ONO  4 
trans
3
6. Co  NO2  ONO 5 
3
7. Co  ONO 6 
Thus there are total 10 isomers for the given complex.
39. A
70 2
Sol. C2H6  g   O2  2CO2  g   3H2O   
2
Moles of electrons transferred in above net cell reaction = 14
Go  nFEcell
o
1229.41 103  14  96500  Ecell

o
1229.41 103
 Eocell   0.91 V
14  96500
40. B
Sol. For the reaction
2O3  g  
 3O2  g 
H  ve and S   ve
 G  H  TS
 G  ve
41. A
Sol. Rate of effusion is given by r  A (assuming all other conditions to be same) where A = area of
orifice.
rate of effusion from vessel A r 2
 2
rate of effusion from vessel B 
Given :   r
Rate of effusion from vessel A r 2 
  2 
Rate of effusion from vessel B r 1
42. A
Sol. More the –ve deviation from ideality, stronger the inter-molecular attraction force among gas
molecules and easier to liquefy the gas.
 Correct order of liquefiability H2  N2  CH4  CO 2
43. D
Sol. A   B 
  
2 mole 2 mole
Ps  P  x A  PBo  xB
o
A
1 1
1  PAo   PBo  … (1)
2 2
Now, A     B     C   
   
1mole 3 mole 4 mole
Ps   PAo  x A  PBo  xB  PCo  x C

1 3 4
1  PAo   PBo   0.8 
8 8 8
1 3
0.6  PAo   PBo  … (2)
8 8
Solving equations (1) and (2), we get
PAo  0.6 atm
PBo  1.4 atm
PAo 0.6 3
  
PBo 1.4 7
44. A
Sol. As2S3 is negatively charged colloid while Fe  OH3 ,TiO2 and basic dyestuff are positively
charged colloids.
45. C
Fe 3  K 4 Fe  CN6   Fe 4 Fe  CN6 
Sol. (A) 3
Potassium Pr ussian blue

ferrocyanide Blue colour 
Fe 2
 K 3 Fe  CN6  
 Fe3 Fe  CN6 
(B) 2
Potassium Turnbull blue

ferricyanide Blue colour 
(C) Fe2  K 4 Fe  CN6  
 K 2Fe Fe  CN6 

White precipitate
(D) Cu  K 4 Fe  CN6  

2
 Cu2 Fe  CN 6 
Re d  Brown
precipitate
 Only (C) option is incorrect.
SECTION – B
46. 6
Sol. Chalcopyrites - CuFeS2
Bauxite - Al2O3 .2H2 O
Limonite - Fe2 O3 .3H2O
Pyrolusite - MnO 2
Rutile - TiO2
Casseterite - SnO2
Calamine - ZnCO3
Cuprite - Cu2 O
Chalcocite = Cu2S
Argentite = Ag2 S
Cinnabar = HgS
Siderite - FeCO3
Thus, there are six oxide ores.
47. 6
Sol.
Hybridization Bond angle
H2 O sp3 104.5o
Bent (V – shape)
H2 S sp3 92o
Bent (V – shape)
ClF3 sp3 d Equatorial – axial = 87.5o
(Bent T-shape) Axial – axial = 175o
IF7 sp3 d3 Equatorial – equatorial = 72o
pentagonal bipyramidal Equatorial – axial = 90o
Axial – axial = 180o
XeF2 sp3 d 180o
Linear
SF6 sp3 d2 90o and 180o

Octahedral
sp3 d2 < 79o
 TeF5 
Square pyramidal
XeF4 sp3 d2 90o and 180o
Square planar
O3 sp2 117o
(Bent V-shape)
SO 2 sp2 119 o 30
(Bent V-shape)
SO 3 sp2 120o
Trigonal planar
SECTION – C
48. 00001.50
Sol. For adiabatic reversible process
T.V  1  constant … (1)
Now according to question
1
TV 2  constant … (2)
Comparing equation (1) and (2)
1
 1
2
  1.50
49. 00000.62
Sol. 2H2 O2  aq. 
 2H2 O     O 2  g 
Moles of electrons transferred during above reaction = 2
Go  nFEcell
o
120  103  2  96500  Eocell

120  10 3
Eocell   0.62 V
2  96500
50. 00004.43
Sol.   iCST … (1)
i 1

n 1
i 1
0.8 
2 1
i  1.8
w
0.745% KCl solution means that 0.745 g solute (KCl) is present in 100 mL solution.
V
0.745 1000
C   0.1M
74.5 100
Putting values of i and C in eq. (1)
  1.8  0.1 0.082  300

= 4.43 atm
Mathematics PART – III
SECTION – A
51. D
n
n 2n   1 2
Sol. C0  n C3  n C6  ..... = , n = 3,   integer
3
n 1
2n   1
= , n  3,   integer
3
 n = 10
52. C
3
3 3
6
 2 3 2 3 3 
3
 1 
1  sin  icos  1  sin 4  cos 4  2 sin 4   1 
4 4 2  1
Sol.   = 
3 3  1  cos2 3  sin2 3   2 cos 3    1 1 
1  cos  isin  
4 4  4 4 4   2
53. B
1 4 1 3 1 2 1 1 10 2
Sol. Required probability =         
5 5 5 5 5 5 5 5 25 5
54. A
a2  b2 ac  bd
Sol. A  AT     a2 + b2 + c2 + d2 = 6
2 2
ac  bd c  d 
a 2 a2 c2 c2 1
  b2    d2  4 2 4 2  6
a b c d
 2 2 2 2  
6  16 
a 4b2c 4 d2
  1  a2bc2d  4
16
55. C
x 2x xe x
sin x tan x ex  1 1 2 1
3 sin x 1  cos x 2 tan x 1 3
Sol. f x   lim f  x   3 2 
x x2 x x 0 2 2
2 3x 1 2 0 1
56. B
     
Sol. a  b  b  c  c  a  10
   
 b  2a and c  4a
   
 2a  3b  4c  8a  8
57. B
Sol. Let f(x) = x2 – 2kx + k2 – 1
 f(1) < 0 and f(k) < 0
 k  (0, 2)
58. B
1 1
Sol. 10  24i  2  10  24i  2  4 2 i
59. A
x 1 y z x y 1 z
Sol. Let     and   
3 2 1 1 2 3
 A  (3 + 1, 2, ) and B  (, 2 + 1, 3)
1
If AB is minimum      
4
60. C
r2  r  1 r r 1
Sol.  
 r  1 r r  1r  2   r  1r  1 r  r  2 
61. B
Sol. 88200 = 23 . 32 . 52 . 72
  = 27 and  = 15
  –  = 12
62. A
Sol. k = 14  36
63. C
6 6
C1 C1 1 1 175
Sol. Required probability = 1  5
 5
 6C2  2C1 5
 4
=
2 2 2 2 216
64. D
Sol.  is root of z117  1
 |z – |min = 0
65. B
Sol. Equation of plane is 2x + y – 3z = 7
66. D
y y z z 1
x     2 2 5
2 2 2 2  xy z
Sol. As 
5  16 
 xy2z2  512
67. C
  
Sol. r  a is maximum if r  î  2ˆj  kˆ
 
 r  a max  3
68. B
Sol. Required ways = 8 C5  10 C7  4 C1  7 C5  9 C7  4 C2  6 C5  8 C7  4 C3  5 C5  7 C7  3980
69. C
Sol. A = 3AT – 4I  AT = 3A – 4I  A = 9A – 16I  A = 2I  |A| = 23 = 8
70. B
Sol. Sum of roots = 0  a = 2
Also, product of roots < 0
a=2
SECTION – B
71. 0
         
Sol. r  a  b  r  r  a  b  0  r   a  b

 r 
 î  ˆj  , As r  1  r   î  ˆj  kˆ   0
2
72. 6
5! 3 5!
Sol. k  8 C5  5!  3 C1  7 C3   C2  6 C2   13560
2! 2!  2!
k
  24
565
SECTION – C
73. 00001.00
Sol. Let x2 + 14x + 53 = k2, k  integer
 x2 + 14x + 53 – k2 = 0 for some x  integer
 (14)2 – 4(53 – k2) = I2, I  integer
 k2 = 4  x = –7
74. 00003.00
13
Sol. 2a1  12d  52a1 (d is common difference)
2 
a
 a1 = 2d  17  3
a5
75. 00006.00
Sol. Equation of plane is x – 2y + z – 1= 0
2  2  3 1
 k  6
12  22  12
 k2 = 6

Aits 2021 PT III Jeem Sol

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Aits 2021 PT III Jeem Sol

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ALL INDIA TEST SERIES

PART TEST – III

TEST DATE: 19-12-2020

ANSWERS, HINTS & SOLUTIONS

H3C (CH2)10 CH2O SO3 Na

According to reaction (2)

1229.41 103  14  96500  Ecell

Ps   PAo  x A  PBo  xB  PCo  x C

Potassium Pr ussian blue

Potassium Turnbull blue

(D) Cu  K 4 Fe  CN6  

SF6 sp3 d2 90o and 180o

120  103  2  96500  Eocell

  1.8  0.1 0.082  300

Mathematics PART – III

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