AIITS 2325 HCT IV JEEM Sol

FIITJEE
ALL INDIA INTEGRATED TEST SERIES

HALF COURSE TEST – IV
JEE (Main)-2025
TEST DATE: 29-03-2024
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. B
Sol. As process is cyclic  U ABCA 0
 QABCA  WABCA
 QAB  QBC  QCA
 WAB  WBC  WCA (1)
Give QBC  QC A  WAB  WBC (2)
Subtracting (2) from (1),
QAB  WCA  0
(as process CA is isochoric)
 Process AB is adiabatic.
2. A
Sol. L f  Li 1  T 
LS f  LSi 1   S T 
 LSteel  LSi  S T
LC f  LCi [1  C T ]
 LCopper  LCi C T
For Lsteel  LCopper
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AIITS-HCT-IV-PCM(Sol.)-JEE(Main)/2025 2
 LSi  S T  LCi C T
LS  C 1.8  10 5 3
  i
 
LC  S 1.2  10 5 2
i
LSi 3
  in (1) only.
LCi 2
3. D
Sol. Range on the inclined plane
2
2 R u 2 21
 h max   
2 g 8
4. A
Sol. Let common acceleration be a m/s2
2kg F=2t
2t  FS  2a (i) Fs
FS  8a (ii) Fs
8kg
2t
FS   8  0.2  0.2 10
10
5 t
t  s, a 
2 5
dv t t 2 dx t3
 v  x m
dt 5 10 dt 30
5. C
Sol. F  t  P
Angular impulse about center of mass
P l
 F  t 
2
Angular impulse = Change in angular momentum
l ml 2 6P
P   
2 12 ml
Time taken by rod to turn by 90o is (Time period)/4
1 2   ml
   
4  2 12 P
6. A
7. B
1 1
Sol. mgl sin   mv2  I  2
2 2
2 2
1 1 mR v 3
 mv 2  2
 mv 2
2 2 2 R 4
3 AIITS-HCT-IV-PCM(Sol.)-JEE(Main)/2025
4 gl sin 
v 
3
MR 2 v 3MvR
I  I cm  mvR   MvR 
2 R 2
3 4 gl sin 
 mR  3m2 R2 gl sin 
2 3
8. B
Sol. I PQR  I AOB  M (ON )2
2
1  C 
I PQR  MR 2  M   (1)
4  2
1 2
But I PQR  MR (2)
2
From (1) and (2),
R
C
2
9. D
Sol. If a is the side length then v 0  2ga . (Before)
a 2ga v0
and v '  2g  1
 4
. (After)
2 2
2 4
10. A
Sol. F  xy 2iˆ  yx 2 ˆj , and displacement
dr  dxiˆ  dy ˆj
y
  a, a 2 
  xy iˆ  yx ˆj  .  dxiˆ  dy ˆj 
2 2
W  F .d r 
Path Path
a y  a2
  xy dx  yx dy   
2 2 2
 xy dx   yx 2 dy
Path x 0 y0
a a2 6 6
5 a a a 6  2a 6 a 6 2
W   x dx   y dy    
x 0 y 0
6 3 6 2
11. D
2v2 a 2 100 2
Sol. at  ai  t  
v1  v2 ai 200  100 3
12. C
13. A
14. A
 R  x  mgx
Sol. F  mg '  mg 1  
 R  R
mg g
As it is of restoring nature F   x or a   x
R R
2 R
T  2
 g
T  R
Required time is 
4 2 g
15. C
GM
Sol. At infinity V = 0, at the centre VC  
R
  GM   GMm
W  m  0  VC   m  0     R
  R 
16. C
Sol. x  v 1
x2  1  v
dv
 2x
dx
dv
a  v  2 x  x 2  1
dx
a  2  5  25  1
a  240
17. A
18. B
V
Sol.  100  0.5
V
Increase in pressure,
P   gh  1000 10  200  2 106 Pa
P 2 106
B   4 108 Pa
V 0.5 102
V
19. A
3mg  2 mg g
Sol. a 
2m 2
20. C
m
Sol. Since T  2
k
1 1
Here, m and k remain constant  f   H
T 4
SECTION – B
21. 245
Sol. Velocity of the parachute after falling 50 m
u= 2 g  50  1000 m / s
Thus 52  u 2  2  2.5  h
 h  195 m
The height at which parachute bails out = 195 + 50 = 245 m
22. 25
Sol. = 3x + 4y
  
F = – î – ĵ
x y

F = – (3 î + 4 ĵ ) N

 F
Acceleration a = = – ( 3î  4 ĵ ) m/s2 ( m = 1 kg )
m
 acceleration is constant,
   1  2
 position at time t, r = r0 + u t + at
2
 1
r = ( 6î  4 ĵ ) + 0 - ( 3î  4 ĵ )t2
2
  3t 2  ˆ
 i   4  2t  ˆj
2
r  6 
 2 
When the particle is crossing x -axis, y = 0
4 – 2 t2 = 0
hence t = 2 sec
  
Work done W = F . ( r – r0 )
W = ( 3î  4 ĵ ). ( 3î  4 ĵ )
= 9 + 16 = 25 J
23. 50
Volumesubmerged ρs
Sol.  and is independent of geff
Volume L
24. 8
Sol. As the spring is compressed by 2 metres with the application of a force of 200 N. Hence its force
constant k is given by
F 200
k= = = 100 N/m
2 2
Let  be the distance along the inclined plane in which the mass travels before it comes to rest.
Now applying the conservation of energy.
S
fixed inclined
 =30º plane
1 2
kx = mg h = mg  sin
2
1 1
Or × 100 × 42 = 20 × 10 ×  ×
2 2
or  = 800/100 = 8 m.
25. 5
26. 3
27. 50
28. 64
Sol. The extension in the length of spring is.
mg GMm 1
x= = 2
, x 2 ,
k r k r
x2 R2
 =
x 1 (R  h ) 2
2
 6400 
or x2 = 1 ×   = 64 cm.
 8000 
29. 3
Sol. k 1
4 k
m 3 2
2k 2k
k 1
4 k
m 5
k
4 k m 2k 6
Effective constant of spring (4) & (6)

= 3k
m
 Time period = T = 2
3k
30. 4
Sol. If x1 and x2 are their respective amplitude of motion, then
mx1  2m  x2   0......  i 
x1  x2  x0 .......  ii 
After solving above equations, we get
2 x0
x1 
3
Chemistry PART – B
SECTION – A
31. D
1 1 1
Sol. For H,  R H .12  2  2  For D
H 1 2 
3RH 1 1 1
=  R H .12  2  2 
4 D 1 2 
4 3RH 4
H  = D 
3R H 4 3R H
32. C
Sol. NO– > NO > NO+ (bond length)
Bond order 2.0 2.5 3
H2 > H2+ > He2+ (bond energy)

Bond order 1 0.5 0.5
(more antibonding)
NO2+ > NO2 > NO2– (bond length)

Bond angle 180º 133° 115°
33. C
Sol. Equation 1 Kc = x³ y³
Equation 2 Kc = (3x)³ (y)³
y’ = 3 times y
34. D
Sol. At half equivalence point (i.e. 25 ml of NaOH)
pH = pKa = 5  Ka = 10–5
A +H 2 O  1+A+OH 
K w 1014
Kh = = 5 =109
K a 10
Hence, pOH = 5 and pH = 14 – 5 = 9
35. D
Sol. r  K1[N2O2 ][H2 ]
[N2O2 ]
K2 
[NO]2
r  K1K 2 [NO]2 [H2 ]
r  K[NO]2 [H2 ]
36. D
Sol.
+
HF
EAS
37. C
Sol. H2O + Na  NaOH + ½ H2 
H2O + NaH  H2 + NaOH
38. B
Sol. The balanced equation is:
3MnO4  5FeC2O4  24H 3Mn2  5Fe3  10CO2  12H2O

Meq. of KMnO4 or MnO4 = 200  0.5 = 100
Meq. of FeC2O4= 300  0.6 = 180
100
Eq. of MnO4 = = 0.1
1000
 0.1 0.1
Moles of MnO4 =  = 0.02
n  factor 5
180
Eq. of FeC2O4 = = 0.18
1000
0.18 0.18
Moles of FeC2O4 =  = 0.06
n  factor 3
MnO4 is the limiting reactant

3 moles of MnO4 produces 10 moles of CO2
 10
0.02 moles of MnO4 produces =  0.02 = 0.066 moles of CO2
3
Volume of CO2 at NTP = 0.066  22.4 = 1.478  1.48 L
39. A
10
Sol.  Mmix   22.4  10 gm
22.4
 Let the volume of He = V1 ml
Let the volume of N2 = V2 ml
 V1 + V2 = 100
 V  V
 10   1   4  2  28
 100  100
V1  100  V1 
10  4   28
100  100 
Solving, V1 = 75%.
40. A
Sol. [Acidic strength  stability of conjugate base]
41. A
Sol. (Also check for stereoisomers)
Cl Cl
Cl Cl
Cl
Cl
Cl Cl
Cl Cl Cl Cl
Cl Cl
Cl
Cl Cl
Cl Cl Cl
42. C
Sol. CaCl2 + Na2CO3  CaCO3 + 2NaCl
(X) (Y )
CaCO3 + 2HCl  CaCl2 + CO2(g) + H2O(I)

(X) (Z)
 (X)CaCO3
(Y) NaCl
(Z) HCl
43. C
1 1
Sol. W = Area under curve = xbxh  (2V1 )(5P1 )  5P1 V1
2 2
44. B
2C(s) + 3H2(g)  C2H6(g) f H
0
Sol.
2x sub H  C,s  
=    B.E.  C  C   6 xB.E.  C  H 85  2x178  3x 436  (x  6y)
 3xB.E. H  H
x + 6y = 2829 … (1)
Similarly, for C3H8(g)
2x + 8y = 4002 …(2)
From Eqs. (1) and (2)
x = 345 KJ/mol, y = 141 kJ/mol
45. D
Sol. B2O3 +Mg  B+MgO
46. D
Sol. Ionic radii O2  F  Na  Mg2  Al3
47. D
Sol. 1
 3
2
 4 H
48. D
Sol. The formation of photochemical smog depends on several factors, including sunlight, temperature
and the pressure of pollutants such as nitrogen and volatile organic compounds.
49. A
Sol. Lattice energy is directly proportional to the charges of the ions and inversely proportional sum of
their radii:
Lattice energy  (Q1Q2) / (r1 + r2)
50. D
Sol. As per Hund’s rule of energy is given by (n +  ) value. If value of (n +  ) remains same then
energy is given by n only
SECTION – B
51. 5
Sol. Ephoton = work function + ½ mv2
=work function  eV0
 …(i)
Stopping potential
52. 3
Sol. Symmetrical molecules with resultant net zero dipole moment
53. 9

Sol. Al  OH4  =103M
4 
Al3+  OH  =Kinst Al  OH4  =1034×103 =1037 M5 -------------- (1)
3
Also, Al3  OH   KSP  1032 M4 ----------------(2)
Dividing equation (1) and (2), we get
10 37 M 5
 OH   = 32 4 =10 5 M
10 M
54. 2
T
Sol. r '  r  2  10
So, r = 2r
55. 6
Sol. Percentage labeling of oleum= Total mass of H2SO4 present in oleum after dilution.
= Mass of H2SO4 initially present + Mass of H2SO4 produced on dilution
121.15 % labeling means 100 g of oleum on dilution gives 121.15 g of H2SO4.
Let the mass of SO3 in the sample be x g, then mass of H2SO4 = (100 - x)g
SO3  H2O  H2SO4
x
Moles of SO3 =
80
x
 Moles of H2SO4 formed on dilution =
80
x
 Mass of H2SO4 formed on dilution =  98
80
98 x
Total mass of H2SO4 present in oleum after dilution = + (100 - x) = 121.15
80
On solving x = 94
 Mass of SO3 = 94 g
and mass of H2SO4 = 100 – 94 = 6 g
56. 3
Sol. Quasi aromatic compounds are stable in iconic form
O O
+
+
+
57. 3
Sol. Sp3 hybridized centre with 4 different groups attached is Chiral centre
OH
H 3C * N
*
*
Ph
58. 7
Na4OH + HCl HN2
Sol.
NH4Cl + H2O
HioN HN1
NH4  OH H  Cl
 ∆ HN 2 = ∆Hion + ∆ HN1
 ∆Hion = ∆ HN 2  ∆ HN1
59. 3
Sol. For a first-order reaction, the relation between the reaction constant (k) and time (t) for a given
percentage of competition (  ) is:
 1 
In    kt
 1 p 
For t (50% competition), p = 0.5
 1 
In    k.t 50
 1  0.5 
 1 
In    k.t 50
 0.5 
In (2) = k. t50
For t87.5 (87.5% completion), p = 0.875
 1 
In    k.t 87.5
 1  0.875 
 1 
In    k.t 87.5In(8)  k.t 87.5
 0.125 
Now we need to find the relationship betweent87.5 and t50
k.t
87.5 In(8)
k.t

50 In(2)
Since the k’s cancel out, we have:
t
87.5 In(8)
t

50 In(2)
Using the property of logarithms, we get:
t
87.5 In(2 3 )
t

50 In(2)
t
87.5
t
3
50
So, the value of x is 3.
60. 3
 V2 
Sol. ∆S = nR ln  
 V1 
3
∆system = 1x 8.314 In    3.37JK 1
2
∆surroundings =  ∆system = 3.37 JK1
∆surroundings = 3.37 JK1
∆surroundings = 3 JK1
So, rounded to the nearest integer,
Mathematics PART – C
SECTION – A
61. A
n 1 n 1 k
Sol.  w k  0 w
k 0 k0
  0
n 1
LHS =  z
k0
1 
 w k z2  z1  (w)k z2 
2 2
= n z1  0  0  n z2

= n z1  z2
2 2

62. B
1
 22
Sol. S =  1    3 hence for a  Q
 3
 b Q
63. C
Sol. Let x2 + 19x + 89 = t2
 x2 + 19x + 89  t2 = 0
will have integral roots
 (19)2  4(89  t2) = k2
{where k is another integer}
 k2  4t = 5 (k  2t) (k + 2t) = 5
 k  2t = 1 and k + 2t = 25
Or k  2t = 5 and k + 2t = 1
Or k  2t =  1 and k + 2t =  5
Or k  2t =  5 and k + 2t =  1
Solving we get x =  11 or x =  8
Hence sum of possible values of =  19
64. A
Sol. ab + bc = 2ac
Now a3b3 + b3c3 = (ab + bc)3  3ab2c (ab + bc)
= 8a3c3  3ab2c (2ac)
= 8a3c3  6a2b2c2
 a3b3 + b3c3 + c3a3 = 9a3c3  6a2b2c2
= a2c2(9ac  6b2)
65. D
Sol. Converse of p  q is q  p and its contrapositive will be  p   q
66. C
153
Sol. Let x = 2 2
16
N = x 1
  x 2  2x  1
N = (x 4  1)(x 4  1)(x 8  1)
  
N = x 4  1 x 2  2x  1 x 2  2x  1 x 8  1  
204
Let y = 2

N = y6  1  y3  1 y3  1  
  y2  y  1   y3  1   y  1  y2  y  1 
67. C
Sol. Out of all square marked with x. only one can contain mine. 1 2 3 4 5 6
th
If r column contains ‘n’ mines we denote it as (r, n)
0 0 X X X
(6, 1) (5, 1) (1 or 2, 2) + (6, 2) (4, 1) (1 or 2, 2) + (6, 2) (3, 1)
(1 or 2, 1)
0 2 X 1 X 2
2x 3x 5 C2  2x 5 C2  3x 5  95
0 0 X X X
68. D
Sol. Centre (2,  3) is mid point AB.
69. A
Sol. Applying condition of orthogonality we get
52 = 9 (2 + m 2)
25
 m2  2
9
7
m2 
9
70. D
Sol. Lines represents by 3x2  3y2  2xy
  3 1 x   
3  1 y 1  0 3x  y  1  0
x  3y  1  0
x  3y  1  0
are 3x  y  1  0 and x  3y  1  0
Lines represents by 3x2  3y2  2xy
  3 1 x   
3 1 y 1  0
3x  y  1  0
are 3x  y  1  0 and x  3y  1  0
 A = P 1P 2
= |x| = 1 sq. units
71. C
x y
Sol. The equation of two tangents can be considered as cos   sin   1 and x cosθ + y sinθ = 5
5 4
Let angle between them be α
4
cot   cot 
tan  5
4 2
1  cot 
5
cot 
 tan 
5  4 cot2 
1
 tan 
5 tan   4 cot 
5 tan   4 cot 
  20 if  is acute
2
1 1

5tan   4 cot  4 5
1
So,  tan max 
4 5
72. B
Sol. Let P a point on given hyperbola whose asymptotes are 2y = x and 2y =  x. Let PA and PB are
parallel to the asymptotes
Let PB  x = 2y + c
c c  16  c2 16  c2 
So, B  ,   and P  , 
2 4  2c 4c 
4 5
 BP 
c
4 5 c
Area of parallelogram OAPB = . 4
c 5
73. A
1
aexb
Sol. ae = 6 and 2 =2
1
 a  b  ae 
2
 6b = 2(a + b + 6)
 2b = a + 6
 b2 = (4a2 + 36  24b)  36
 b = 8, a = 10
2 2
Diameter of the bisector circle = 2 a  b  4 41
74. C
xy yx
Sol. t2  2  and t 
2 4
 yx  xy
  2 
 4  2
2
  y  x  8 x  y  4
2
 yx   x y 4 
   4 2 
 2   2 
Represents a parabola whose axis is y  x = 0 and tangent at vertex is x + y  4 = 0
75. C
Sol. Given statement is a tautology
76. A
y7 1
Sol. arg(z  2  7i) = cot 1 (2)   (x > 2 and y > 7)
x 2 2
 z  5i  
arg  
 z 2i 2
 x(x + 2) + (y  5) (y  1) = 0
77. A
sin 2cos  sin2
Sol. t1  
cos 32 cos  2cos  cos 3
sin(3  ) 1
=  (tan3  tan )
2 cos  cos  2
1
Similarly, t2   tan9   tan3 
2
1
t3   tan27  tan9 
2
1
t10   tan310   tan39  
2
1 1   
s10   tan310   tan     tan  10 
2 2 3 
78. D
      
Sol. Note sin  <  < tan  ;   0,  Hence, sin  cos   cos  cos  sin 
 2  18  18  18 
 
(B) Since,  2  so, sin 2  cos 2
4 2
    
(C) sin  sin   sin   tan
 10  10 10 10
  2  
(D) tan  sin2   sin  sin4
 12  10 10
79. C
h
Sol. tan(45  )  (i)
xy
h
tan(45  ) 
y
Solving (I)
1  tan  h

1  tan  x  y
1  tan  h h 1  tan  
 y
1  tan  y 1  tan 
h 1  tan 

x h
1  tan   1  tan 
1  tan 
h  1  tan   1  tan 

x  h  tan   x  h 1  tan 
2
1  tan   h
 x(1  tan )  h(1  tan )
1  tan 
 2
h 1  tan    1  tan 
2

 x 1  tan1  tan 
1  tan 
4h tan 
 x 1  tan  
1  tan 
4h tan 
x=  2h tan2
1  tan2 
80. A
6 1  2 5 
Sol. Here R  are required area of ∆ABC = R2  sin  sin  sin 
 2  3 6 2
9 3  3 1  sq. units
72
SECTION – B
81. 35
Sol. Let the roots of the equation x 3 + 5x2 + ax + b = 0 be
,,  and roots of equation x3 + 7x2 + ax + c = 0
Be , ,  ' then
         '  ' 
 (  )(   ')  0
    = 0 (because    ' )
       5    5
Similarly      '  7   '  7
So, . '  35
82. 05
Sol. Let the equation of AB be x cosα + y sinα = 13 where ‘α’ the
angle which OD makes with x-axis
7
1
tan   17  5 tan
7 12
1
17
 1
 tan 
2 2
 7  2
tan   tan   tan1  
 2 17  3
2 3
sin   ,cos  
13 13
Equation of AB is 3x + 2y = 13
83. 04
3
Sol. As tangents are perpendicular we get focal chord y  2  x  5
5
 y  x  x 5 x  y  4  ab  4
84. 13
1o
Sol. cot7  6  2 2 3
2
4 cos 36o  cot7.5o  5  6  2  1  3
85. 1
Sol. 3ab  a  b = 1
 (3a  1)(3b  1) = 4
 (a, b) = (1, 1)
86. 2
Sol. As 0  cos2 x  1
 Hence by quadratic
 a  2  a2  8a  16
0 1
2
 a  [3, 2]
87. 7
Sol. Number of ways of dividing objects = Number of non-negative integral solutions of the equation
x + y + z = 3n
Under the condition 0  x,y,z  2n
= Coefficient of x3n in the expansion of (1 + x + x 2 + x3 +…+ x2n)3
= Coefficient of x3n in the expansion of (1  x2n+1) (1  x)3
= 3n  2 C2  3.n  1 C 2
2
= 3n + 3n + 1
88. 3
2
Sol. cos  
82  82   6 
122  82  x2
2x 8x 8 2x12x 8
2
x  25
BC  x2  42  3
89. 5
Sol. For cos x  0  2sinx  0  x  2m mI

For cos x < 0  tanx  1  x   2m  1    mI
4
5 13
Hence, 0, 2,4 ,
4 4
90. 120
5!
Sol. Number of ways = 2.  120
2!

AIITS 2325 HCT IV JEEM Sol

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ALL INDIA INTEGRATED TEST SERIES

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