+E E#&.

ffi (A*trf,l+€) 4€+49+4i*+#rft

2012

QUALIFYNC IXAMINATION IOR AP?LICANTSIOR JAPANESE

GOWRNMENT(MONBUKAGAKUSHO)SCHOLARSHIPSz(]Iz

+t++\* t6FE
EXAMINATIONQUESTIONS

(ag4F1+&g+4)

COLLEGEOI TECENOLOGYSTUDENTS

1Z+
CIIXMTSTRY

EE *d$6rdll60 t
 (20r2)

CHEMISTRY
(Pru Pii tun nift, dd fi8 hi I ile)

Ifnme$ary, nsethefollowiq daranr aswer lhe quesiions

below
Atomicweiehl:H=1.0,C=12.0,O=i6.0,Na=23.0.S=12.0.Cl=35.5,Cu=636
Ianday s onsrant F = 9.65x lO4C/nol
Molarvolme of gasat tne$.n&rd stat€:22.4L/nol

w.ile lh€ hmher of you amwer in th€ box provided. Cnooselhe one auemadvethat besl

L Answer the followins questio.s.

(A) Wnat n lh€ oxidatior nunber of mSanese in KMrOa?

o - r(-2) @ +n(+3) @ +N(+4) @ +v(+6) 6) +vn(+?)

(B) whici is . r€doxreodion?

O NaCl + AgNOr + AgCl + NaNOI

@ca(oF), + 2Ecl - cacl? + 2Eo
O2NallCOr + Na,COr + H,O + Co,
@ HCI + NHr - NlIlrCl
@c,HjoH + 30: + 2co2 + 3H?o
(C) Which of lhe following elendrs hasthe g@t*i cleclronesalivitvvalue?

OAI @ c O F @Na oo

b -l'ealklre gmdp"
LD,wn'ch olr\e lollow'fg commud. belones

(E) Nlich ofthe followihg gaseshls fie higtest densitvat lhe Rr'nd'rd sbte?

o ct: @ o : O r , o so:

(FJWh(h or tnefollowing.ompoun[noplicallvacive?

O NHzcH:cooH @ cHrcF,clt(NHrcooH O (CH lC(llHtCOOH

@ Hooc(cHrlcooH O NH:(CH,),NII:

2. A nixtue of 6.0 nol of H: ga md 4 5 nol of Ir vtpor was heated al a c@stanl

tenperaluE in t r€adior vesselmd allowed lo each €qnilibriun Al th. equilibriun
rheanoutofHlws 8.0nol. Answe.lhe followingquestDns

(A | ' alc' la,erh" \alLeofLheeqd,librm con tM' lor H rEl Ir(e) 2 HIG)

O8 @16 Ol2 O64 Ol23

(B) A mixturcof 2.0 nol of H: s6 and2.0 mol of Ir vaporwasheated!t thesanc co.stanl
tententuie in lhe sanc rcaclionvcscl andallowcdto reachequilibdun Calculate

O ().4onol O l.2nol O l.6mol O 2.5nol O:l2mol

3. Thesolutionwasprcparcd
by dissolviq 4.0sofNaOH in l000nL of walr.

(A) wrlal is lhc nolarityoltbis solulion?

C) O.050Dol/L O 0.10noUL O 0.25nrol/L @ l0 mol/L O l.5nol/L

(B) what is thepH valueoflhissolution?

Or aO4 @1 €i l0 O13

(Cl Hownucbofa 0.10not/L HrSOa

solution
is requned
lo neullalize
20 nL of thisNaOH

i t 5 . 0m L O 10mL @ 20mL @ 25mL O 50mL

4. The rhffiochenical €qn.lion Ior lhe combustionof propaneis siv€n as follosj
CrHs(s)+ 5 O:(s)- 3 CO:G)+4Hio(4 LH: -222okl

(A) Eow nany kilojoulcs arc liberatedwhen 8.80 s of CrHs(s)!€rcts rccordineto tnh

O) 111kJ (D 222W o 333kJ €) 444 kJ J

fomtion of COld md E?O(l) &e 394 k mol and 286 kJ/nol,

Calculatethe bat of fodation of CrEsG).

O 106tj/mol @ 5021d/molO 610Ltmol @ 896U/nol O l040k mol

5, An aqueoussohtior of CISOI was electrcltzed wnh phtinnm electrodesfor 2.0 hous wi$

LAr\u1d' 's rhccold -ombi0alionolelecuodeedCFnftredg^-

O o: aranode @ H2'r catnod€

@ so, atetbode @ so: al anode

(B) How mny mulonbs wqe flowed in tbis electolysis?

O rooc @ r 8 0c @) 360C @ 54oo

c O ro8ooc

((J Hoq mtryglmolt L weeJellortd on+epld' nur elrmde"

O 0890s @ l T a E G )l 5 6 e @ ? t 2 s O 142c
6. The conbuslion ol 12.0 mg ol a nonocsboxylic a.id, which cortains only carbon,
hydrcem md oxyed, g.v€ 17.6mg oI COzmd 7.20 mg ofH:O.

(A) wnich is the conpNilioml fomnla of thh conpoud?

O cHro @ cHo: @ cH:o1 @ crHro, O crH6o:

(B) Del@in€ the nolecnld w€igni oflnis conpomd.

o30 @60 @45 @46 @74

?. Answcr inc followi.g qu€siios abouta synlheiicpolynd.

(A) Cnoosethe coftd conbimtion ofnononeB iflhe polymerhs amidebonds.

O elnykn€ mdpropylchc O propyl€hernd vinyl chbnde

@ hdmelhylenedianine andadipic acid @ viryl alcohol md ethylene
O t€repnt fic acidefld etnybne slycol

{B) wlicn of the following polymes is nade or repestilg uniis linked by anide bonds?

O PE @ tET O Nylon6.6 @ Pvc O PvA