1: Metanol

2: Agua
1 2
A 8.08097 8.07131
𝐿𝑜𝑔𝑃_𝑖^𝑠𝑎𝑡=𝐴−𝐵/
(𝐶+𝑇) B 1582.271 1730.63
C 239.726 233.426

Presión constante = 759.8124 mmHg

Tsat (1) = 64.54 °C

Tsat (2) = 99.99 °C T (°C) PsA
64.54 759.8124
67.07 838.7344
Ptot = 759.8124 mmHg 69.61 924.3574
A12 = 0.8041 72.14 1017.1147
A21 = 0.5619 74.67 1117.4573
77.20 1225.8550
79.73 1342.7954
82.27 1468.7851
84.80 1604.3492
87.33 1750.0315
89.86 1906.3949
92.39 2074.0211
94.93 2253.5106
97.46 2445.4832
99.99 2650.5774

xA,yA vs T
100.00
96.00
92.00
88.00
84.00
T (°C)

80.00
76.00
72.00
68.00
64.00
60.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

xA, yA

CompxAR CompyAR
CompxARM CompyARM
ExperimentalxA ExperimentalyA
Temp. constante = 50 °C

Psat (1) = 416.5845 mmHg P (mmHg) PsA

Psat (2) = 92.2999 mmHg 92.30 416.5845
115.46 416.5845
138.63 416.5845
161.79 416.5845
184.95 416.5845
208.12 416.5845
231.28 416.5845
254.44 416.5845
277.61 416.5845
300.77 416.5845
323.93 416.5845
347.09 416.5845
370.26 416.5845
393.42 416.5845
416.58 416.5845

xA,yA vs P
420.00 1.00
390.00 0.90
360.00 0.80
330.00 0.70
300.00 0.60
P (mmHg)

270.00
0.50
240.00 yA 0.40
210.00
0.30
180.00
0.20
150.00
120.00 0.10
90.00 0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 0.00 0.10 0.20 0.3

xA

CompxAR CompyAR Raoult

CompxARM CompyARM Diagon
 𝐿𝑛𝛾_𝐴=𝐴_12 ((𝐴_21 𝑥_2)/(𝐴_12
𝑥_1+𝐴_21 𝑥_2 ))^2 P   B PvB
xA 
 A PvA   B PvB
𝐿𝑛𝛾_𝐵=𝐴_21 ((𝐴_12 𝑥_1)/( 〖𝐴 _12  A PvA
𝑥_1+𝐴 〗 _21 𝑥_2 ))^2 yA  xA
P

Raoult Raoult modificado

PsB xAsupuesto gA gB xA yA xA calculado
183.3127 1 1 1.75400194 1.00000000 1.00000000 1.00000000
205.1787 0.83260714 1.012276393 1.54032322 0.87543004 0.96636130 0.83260714
229.2208 0.67740110 1.051410558 1.37208032 0.76329108 0.92858946 0.67740110
255.6103 0.53801595 1.119728427 1.24543017 0.66211320 0.88633068 0.53801595
284.5279 0.41876523 1.215225899 1.15580807 0.57061795 0.83920875 0.41876523
316.1641 0.32187514 1.329967321 1.09629489 0.48769129 0.78682420 0.32187514
350.7194 0.24589291 1.453290424 1.05852765 0.41236057 0.72875340 0.24589291
388.4046 0.18698963 1.576439762 1.03505663 0.34377500 0.66454772 0.18698963
429.4411 0.14103745 1.694227795 1.02054914 0.28118907 0.59373267 0.14103745
474.0610 0.10464911 1.804288696 1.01160427 0.22394830 0.51580705 0.10464911
522.5072 0.07532747 1.905908465 1.00614391 0.17147719 0.43024206 0.07532747
575.0341 0.05129557 1.999205289 1.00290238 0.12326878 0.33648049 0.05129557
631.9072 0.03129259 2.084672364 1.00109760 0.07887575 0.23393584 0.03129259
693.4037 0.014414 2.162944385 1.00023616 0.03790280 0.12199152 0.01441400
759.8124 0 2.234684378 1.00000000 0.00000000 0.00000000 0.00000000

xA vs yA
1.00
0.90
0.80
0.70
0.60
0.50
yA

0.40
0.30
0.20
0.10
0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

xA

Raoult Raoult modificado

Diagonal
 Raoult Raoult modificado
PsB xAsupuesto gA gB xA yA xA calculado
92.2999 0 2.234684378 1 0.00000000 0.00000000 0.00000000
92.2999 0.02961064 2.092209485 1.00098413 0.07142857 0.25771042 0.02961064
92.2999 0.06382884 1.949342768 1.00445026 0.14285714 0.42929871 0.06382884
92.2999 0.10377282 1.807147913 1.01141794 0.21428571 0.55175484 0.10377282
92.2999 0.15079244 1.66738885 1.02333685 0.28571429 0.64353853 0.15079244
92.2999 0.20636275 1.532818935 1.04219026 0.35714286 0.71489127 0.20636275
92.2999 0.27175935 1.40733902 1.07046714 0.42857143 0.77195168 0.27175943
92.2999 0.34745994 1.295636901 1.1108075 0.50000000 0.81862308 0.34746027
92.2999 0.43251964 1.201969005 1.16524104 0.57142857 0.85750603 0.43251964
92.2999 0.52451793 1.12854647 1.23440704 0.64285714 0.89039997 0.52451793
92.2999 0.62036293 1.074813651 1.31744319 0.71428571 0.91858966 0.62036293
92.2999 0.71731339 1.038201651 1.41261318 0.78571429 0.94301690 0.71731339
92.2999 0.81349601 1.015450266 1.5180615 0.85714286 0.96438783 0.81349601
92.2999 0.90787441 1.003531648 1.63223802 0.92857143 0.98324227 0.90787441
92.2999 1 1 1.75400194 1.00000000 1.00000000 1.00000000

xA vs yA
1.00
0.90
0.80
0.70
0.60
0.50
yA

0.40
0.30
0.20
0.10
0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

xA

Raoult Raoult modificado

Diagonal
P   B PvB
PvA   B PvB
PvA
xA
P

Raoult modificado
yA
1.00000000
0.93037348
0.86646653
0.80643875
0.74843175
0.69065492
0.63154148
0.56983193
0.50454368
0.43489164
0.36021512
0.27992652
0.19347846
0.10034326
0.00000000
Raoult modificado
yA
0.00000000
0.22351822
0.37390629
0.48287001
0.56631631
0.63316978
0.68889060
0.73705933
0.78014322
0.81988029
0.85748909
0.89381056
0.92942124
0.96472175
1.00000000
T (°C) xA yA
100 0 0
96.4 0.02 0.134
93.5 0.04 0.23
91.2 0.06 0.304
89.3 0.08 0.365
87.7 0.1 0.418
84.4 0.15 0.517
81.7 0.2 0.579
78 0.3 0.665
75.3 0.4 0.729
73.1 0.5 0.779
71.2 0.6 0.825
69.3 0.7 0.87
67.5 0.8 0.915
66 0.9 0.958
65 0.95 0.979
64.5 1 1