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E Book Teknologi Gula
E Book Teknologi Gula
TO
SUGAR TECHNOLOGY
by
E. MOURIS
Revised edition
1984
TO
SUGAR TECHNOLOGY
by
E. Mouris
revised edition
1984
AND CHEMISTRY
result, you will find that not two men in twenty can
Mark Twain
1. INTRODUCTION
1 . 1. What is sugal'?
Crystallised sunlight.
Apart from water and the air around us, there is nothing
catalyst.
chemical equation:
+ catalyst
chlorophyll
------.--
. C12H22011
solar energy
2
1
HC - - - ( / - - 0 CH~OH
1
HCOH
I,
- j! - C - - -
I,
I 0 I
HOCH HOCI ·j
1 I
HCOH HCUr!
I I
HC- HC-
I I
CH~OH
Glucoseteil r rucrosctci I
S.lccharosc
rI.;, D -G Iucop y ra nosido-Il D- i ~u ~ to i u r:l nosid
(Schreibwcisc n:lch F1SCHER-TOLLENS)
CH,OH
H OH OH H
S:lccharosc
(Schreibwcisc nam HA WOR TH)
C12H22011 + 12°2 ~ 11 H2 0 + 12 CO 2
(Enzyme) + (energy).
2. HISTORY OF SUGAR
beet sugar.
3.1. Sugar c a n e .
!~ ~ I~
~
1)111' : ! 1JI \ 1\
1111 )11, ' , !I ,lil
,"'I ~ , 'I 1 1 11
1
)11:;1:
1
;1/;:11
,~\\\llr I' ; I!, f I/~
~
,\ I' " ,
1 I 1\ I'" ,I ,.,dl
~.
~l))\\ll;:: ~ \\ \\f
I, ,1 111' 1 1
l
e
1\1)'
r'/'/I ,,' 11
1 I'jl' I,
111[ 'I 'I
' I111I
.
~i::' /1,\ \
iI
11(1\
1'1 i:
IL L: 11
I Ii 1I1
I
Cane cuttings or portions of the staik. As Two kinds of growth rings. Left, the growth
planting material the cuttings are usually selccted ring is bent upward at the bud side of the stalk j
from the growing-point reg ion of the cane staik. right, it is more or less horizontal and thus passes
Af ter ]. P. MARTJl"J behind the budo After ]ESWIET.
~
o
.- , '- 3· 1 Sligar cane
11
VasculM bundies
Cor cracks
Bud furrc'N
Growth ring
Root band
Wax ring
Roet primordia
Bud
Corky patch
Growth crack
J
I
,.' ',-,
- I
,I
- 1
1
SCLERENCHYMA
A cross section of a portion of an H 109 ca ne leaf. After J. P. MARTIN
PHLDEM {~:~~~D;'NI6~~fll
Magnification, X 274.
PAQENCHYMA OR STORAGE CELLS
INTERCEL LULAQ. SPACES
....
Fig. 3-2 Structure of sugar cane N
__
·. . .. _- - ~ - ---_._... ~- .- - - -- _ ._ - --
TERTIARY STALKS
·~v
,~ • ~ U\I
,/ I POINT Of AnACHMEN T
TO ORIGINAl CUnlNG
\Vhen a eane eutting is planted , ncw shoots The underg round portion of a eane stool,
devclop from the lateral buds and roots develop showin g the primary staIk, seeonda ry stalks, and
from the root band. Later, staiks of thc various tertiary staIks from which staIks of thc fourth
orders and shoot roots develop from the primary anc! sueceed ing orders devclop . Af ter J. P.
shoot. After J. P. MARTIN
l MARTIN
~
w
50
.,~
40
Petiole
30
Crown
Leaf scars
20
Root
\
\
\ , 10-
Rootlets 'I
\
:.
( '.
I \ o
Rübt-nwurulkörpPf
Schwanz
CANE BEET
I
I
I
I MOLASSES
I
I
I ~
I I
RAW SUGAR. RAW SUGAR
L ___ _ __ .J
REFINERY
CONSUMER
" Can~ s~cd rlac~d 'cnd !O end' in m>rrnal planting at Victmias \Iilling Co"
Philirrincs, !'laflling g o(" l '1u a lity sc'cd in this rnanncr \\'ith ade'lu:lt~ suil m"isture
or \I' ith \\'ater for irrigati" n rc s ults in ade4uar~ stands and in sun stanti:d sa\' ings "f
secd,
.",
21
5.1. Gene r a Z
Sugar eane
Transport
Size reduction
Pressing
Evaporation
open batch
Storage in
forms
Fig 5-1
I SIMPLE MANUFACTORING PROCESS I
24 a
Bactas$'e Fi ! fr Q I ion Mud
.---------------------------- - -------
f 1
~cjQr t prep-aratJonHMil! station :J~~ef' Eval2.orar/on C;'ris/a/fizallón
Cone Shredder PUf! tca Ion
r--
Raw Ju/ce Tnin Jl/iC'e ,' I t
~qQr
DÎEF-usion chrisf:at ..,-
L----....-il Proce s Separa t ion
1'10!Qm?S
BQ9'-Q sse
~------
cokes:---:---f P{Qné
t
~--------------------
Lime ~ Mi/koLLime Ca (ollh
__ CO 2 gases __
-1---
--.-J
I
...
8agasse Smoke
Exhausfanc!
qj
Fuef . Power station QSES
Multt:llt-elle tl ha por al or
I /' 1 I1 ~II
A
hrsl Secend
I
I
n 1II : : ~ I II
~,a y bO ~1 I I 11 1 1
I 1 11 : 1
I t :t i l
I
f j~
ti
11 ' 7 11
P
11 -, 1 1
1 :.J 1 1
1 1 1
Va cuu m / Va ~1J um : Vatuum I I
/
pan ( pan pan I
I I
1 I I I I
-1-+ _~_J ; _+_ .LJ
Syrup
I juice , 60 ?~ Sollds '5
~' .~
Scums 112-16%
~ SG i'~fl'ir'i
ff) t· • 'd11 j
L-----~r' ---- r i
.:;
:<
Pre~s juice I
L-----rA~~ Ba&asse la boders
/
//,r- ----~------------------
/,/ !,'~P:' -
-_-_-~I 1\I
r-
__
Frnal molasses
M,ngl"
~
---
\\
5.3. By pr oduet s o f Ca n e
and a beet
There are resem blanc es betw een a cane facto ry
wher eas
facto ry. Both extr act the suga r from a plan t but
r beet
suga r cane is a tough , intra ctab le mate rial, suga
oyed by
is relat ively soft and its cells could be destr
cane .
crush ing. It has to be treat ed diffe rent ly from
ined from
There are also diffe renc es in the raw juice s obta
isely the
the two plan ts altho ugh the end prod uct is prec
same . Comp are page 24 a and page 30.
ry does
It shou ld be emph asize d that a beet suga r facto
esize d
not reall y manu factu re suga r; the sucro se is synth
alled
by proc ess of natu re in beet roots and the so-c
ratin g
manu factu ring proc ess is esse ntial ly one of sepa
vario us
the suga r, even tuall y in a pure form , from the
root s.
mate rials with whic h it is asso ciate d in the beet
es Fig.6 -1,
The proc ess may be desc ribed by the block schem
6-2 and the flow shee t illus trate d in Fig. 6-3.
comp lex
From this flow shee t one can see that a long and
r from
proc essin g is requ ired for the prod uctio n of suga
t, from
beet s. The actu al "seas on" or "cam paign " is shor
d of
mid Septe mber unti l the end of Dece mber , a perio
usly
abou t 80 days. Beet suga r facto ries work cont inuo
and
durin g this perio d, the proc essin g going on day
nigh t.
a boil er
Altho ugh not show n in the flow shee t, there is
es.
hous e, powe r hous e and its atten dant auxi liari
and
Much stearn is used as weIl as plen ty of wate r
and
large supp lies of coal, oil or natu ral gas, coke
WATER
PROCESS CONNECTION
- - - - DISCONNECTION POSSIBlE
POWER
_._. - ' - VAPOUR OR CON DENSWATER
'"
L--_ _ _ __
Deunp
J
Brandstof.
Dror;1erlj DrCX)? pulp
Na/Ie
pulp
, -- SchUimaarde.
Wa'Ssen D if'fuS ie
1
Sap-
Do.rnp
• 1
-
kri~tQ.L
Bieten - en
Snijden
r-- ,oroce~
I - - Zuivering' r--- Yerdamping' ~
r-
proces
5njdseL I Dun-
Ruw- .n,-k-
sap I Sap Sap
Slib Water ~ eentriT'
+-
Su/ker
I .Dro9'en !'1efa.5se
j
Wa ter- Na./er I ........,
Co,.,densor
Na ter - beho.nol. I
I I
I -SLib
Ca.Or~O= ka.lleme!k
/(a!ksleen I
kalKollen
cokes - r----- ~
C02
------ g'as ~
Hele g'a55en
r ./'
. Sit>OrnkeleL .
Bron cis 101. - +
een/rede
~
k0
stoom
-
Fig, 6-2 FLOWSHEET BEET SUGAR FACTORY,
31
BEET SUGAR
Beets
I
ScaJes
I
Recelving
.
statI ion
To factory
bins, or
long· term
storage
,
Stone and trash
removers
CaO WJ~her
or Sli~ers
sacchJrate I Pulp flrcss water
ca Ke Water _ _ D i f l u s e r - - - - - - - - - - - - - - - - - ,
J
Ddf~slon I
JUlce IW"~'" !
Screens Presses
I
First _CO.
carbonation . fvlolasses.
I
I +-conc Steffen
Clarifier L---r--~: fdtrate
I
Driers
Standard liquor I
I F irst I
I Mo lasses a I
IC.Jrbonatlon I and second
carbonat Ion i dried pulp
I Juree : press cakes
I
Second
Storage .
CO, - - carbonation
I use,
Filters sale
·To lime or
saccharate or
milk recaJcine(1
Filters
Evaporators Intermediate
and raw
Thick jUi~e sugars
filter aid
Melter
Fil:ers Cake, to .first
-"7"-.J==~- carbonatlon
~ ~____._S_lu,dge ~H~i~gh~~~----~~L~o~w~ Low
High green ~ wash green
Drier
I
Granulators To melter To melter Storage
Condit'ioning 1
To · pressed
Scre~ning pulp,
Storaq'c bins Stetten
process
~ or sale
To spec ialty
manufJcturing,
packJgrng, or
bulk sa Je
6.2.2.1. Beet pumps pick up the beets and drop the roots
into a washer. This washer consists of an open, perforated
trough with revolving arms. Earth, small rocks, stones etc.
are removed. Af ter washing, beets are lifted by bucket
elevators to the top of the building, where they are deposi-
ted in supply hoppers over the beet-slicing mechnisms.
juice.
is pumped.
Schaumzerstörung
ohne Schaumöl
interz:"ular~---~
~-----
~
l' Zulührung von entgastem
PreBwasser (BW-PreBwasser-
entgasung)
~ -- -------- -- -- ------
~,"
Abgeschiedene ,
Gase verdrängen luft-
'.
sauerstoff aus den Schnitzeln ",
-~ ''''-, Beste PreBwasserverteilung
durch rotierende Rührarme
Schnitzeleinlührung
oh ne Schaumerzeugung
.. _~
""~ .~
G1eichmäBige Gegenstrom-
".
". führung von Schnitzel und Saft.
Höchste Schnitzelfü"ung
erzwingt schne"sten Saltdurchlauf
BW-AUSLAUGER
lultabschluB durch
hohen Flüssigkeitsstand Für 200 bis 5000 tato Einze"eistung
im Schnitzelschacht
---"~- "
'-"
leitflügel von absoluter
Betriebssicherheit,
'",Keine Schnitzelstauungen
Abspülung der anhal-
tenden Erdbakterien
~_ _ __ S_i_e_b.:..p_a_ra_I_lele Schnitzelaulgabe
Ul
)..1
Q)
~
o
+J
~
o
.~
Ul
:::l
4-1
4-1
.~
Cl
37
•
'~/'tsleen Coke S .
~-
~ J;e6ranc/e ia/k -
-- Water
- la!kme!k
I
r _____~~c~'O~2._ :- - ~.. :. .
/"Car60na. -
-Ia.fle
-
Ala-fillra~e
Ontharde"
Fig. 6-8 JUICE PURIFICATION.
JJunsab
38
6.2.5.4. 8ulfitation.
of non-sugar.
of non-sugar.
40
condensor
l -,
I
steaffi 1I
I I
I I
L----r-~ 1 I 1I
I I I
I I I I I
i I ~ L ___ ._-.-JI 1...
thin juice
.- -+- .-JL
-~
I
condensate
-'-
t
Ithick juice
__+
+
Fig. 6-9 Four effect evaporator
41
6.2.7. Crystallization.
6.2:8. Centrifuges.
D/~SQ.é
---~
kook.pan
~9~mollen ju/ier
of siroop
110.1Q. X eu r
( koel. trog' )
Centrifuge
sIroop
suiker
H.A.Syrup 3t/75
Remelted sugar 15,6t/65
vapour to
condensor 1 3 , 7 t . . - - - - - Massecuite 31,9t/90
1n1i te sugar
13,1 ti 100
H.B.syrup 3,3t/75 A-syrup 17,7t/75
vapour to
condensor 3,5t
.-----
mixer
Hassecuite 17,5t/91
lvater I, 3t
- - - B-su a r 7 6t 9
5,4 t
water
r-___~~~B--~s~v~ru~n~~5t/75
6,4t/75
vapour to
condensor 1 ,55t'-- - - -
lIassecuite 6,151 3
Molasses 3,8t/84...~_ _ __
~ I----~ C-sugar 3,36t/98
gas or coal.
t"'"" ""
f-'o
.
l.Q INT(RN LO !.!> fS I
I
0\
.....I
';=-
a
M I UUlIM[
MllK OF lIME CO 2 G .~
.......,
l
H AT lOS SES
lAANSPQRTATION
""U
% ~ PAESS WA TEA
:u
'"~ '"~ () 0
0 0 ()
Hl z 0z z
0
..
'"
z rrl
g: '":: ~"
'" . 0
'"~ O[NSEA (f)
(f)
(!) ~
rt
C) Cl' .... 0 t.J
Hl ~A" OU H
r-' ~ C ~ ~ ~ ~ ~ ~ ~ ""U
n- ~ ~
~
m I r 0 r •
• ~ ~ • - ~ m ~
0 Ilif AT IN nOCK lUIer
!o ~~ ~~ 0; ~ ~
: ~ 2
p:
D
~
~ ~
C,pNOENSE A
S:~N Of.NS AT(
Ul a : ~ ~! ~
s '"
z
o.. "..
;
z
.,.
(J
c
~
'"'
~
0
(f)
~
~ " '"..
" .." -i
-
Hl
Pl ..'z" 0 TRAHSPORT.'ION I ~
WARM WATER
.."
0
Z
~f-'o
(!) ~
Ul ex>
r -,-
19 ST 13
--- -,
I 5+9 ,·----1- .(ë1l I
~
BPn
liP Ir I
~-~J:
., P
E. houst
9 cues RJn I RJn
BPl!l
AIR
OJn RJm
1
OJ
u RJ
ru I I
1
-TJn OJm TS OJ
FuEl N ru
_ ___J ~ :
FCJ
n RJ
cr 1
SCJn
Fej::- Hl
Fe)
sCJ I
lJ., LJ
~~ I I
~:
! POWER I
- ~ STATION I
I
I
~
1
)
STEM"B OILER. GENERAT ION
r - - ~lURRY
I
I
EVAPORA TOR
-I
I
I
I1 I
I
r- T-
r
1 7 WET OlrFU~ION
PULP
1
8 19 P
POWER STATION
1 BEET TRANSPOR T
l
1 COKE
2 WATER TRANSPOR T
VAPOUR 1 1 SLICING , OIFFuSION
I LIME STONE
1 4
• JUICE TRAN!)PQH T
EVAPQAAt lON
I ~C02G .. S
~ BOIllP4G PANS .VACUUM
AIA 1---,.-- ---,,.--. -- OR I EO PUL P
I 6 SUGAR HOUSE
7 PULP DRY ING
I rUEl WATER
• TRANSPOR T
I 8 II ME KlU'\!
I ~--'--_ PELLETS 11 STEAM BOilERS
I I • GENERATO RS
I BURNEO
UME STONE
I
L PULP ORYING
1 LlME KILN 1 __ _ _ __ JI
*"\.0
Fig. 6-15 The divis ion of the heat sehem e.
50
By-Products of Beet
The chief by-product is beet pulp, which is dried Fig.
6-16and mixed ' with beet molasses into pulp nuts, which
have a wide scale as animal feed.
Molasses, another important by-product, is used in many
industrial processes. The leaves and crowns of the beet,
which are cutt of during harvesting, provide valuable
animal feed for many farmers.
6.4. Off-campaign
Ir
Pz.rSen
Pe~JvateÎ naa.r
dif/L1S'/e t DÎen
8rano/slof - Q7en
'20.
./)rood - .lJa.rnh
LtJcl~t -- frommel
I
çc~ooicle
~
pull:>
!3raK{es
é.ersen
•
0É.slaq' ~
q'w-~e
pul;.,
~ ~
The outer layers are softened with warm syrup and the
less.
d,
crys tals by scree ning befo re pack ing as gran ulate
by
fine st gran ulate d or cast er. Icing suga r is made
by comp res-
pulv erisi ng crys tals in a mill and cube suga r
g.
sing mois t suga r crys tals in moul ds and then dryin
55
distributed.
delivery.
8.2. Consumption
crude oil, but the rise in price of oil may make it less
that they do not break down af ter use and, when dis-
industries
possibility.