AMINES

CONCEPTS &
APPLICATIONS

SIR
KRISNU
Application &
concepts
A Case Study
figure 1
Exercise 1a
Exercise 1b
Exercise 1c (Past Papers)
exercise 2a

Isoelectric Point (pI)

exercise 2b
Amide is neutral

exercise 3
 strecker reaction

figure 2
synthesis of amino acids
 .......
x
exercise 4

Predict the initial aldehyde x

 .......
z
exercise 5

Predict the initial aldehyde z

 exercise 6a

Medical Application
exercise 6b
 dative
bond
Figure 3

Ammonia is neutralized by H+
Acid-base Reaction
exercise 7 :

Proline is mixed
with excess HCl. Draw the structure
of the product
 :

:
exercise 8

Epibatidine is mixed
with excess HCl. Draw the structure
of the product
 :

:
exercise 9

Tryptophan is mixed
with excess HCl. Draw the structure
of the product
FIGURE 4

:
Problem with Sn, HCl
(the product is a salt)
FIGURE 5
:

Problem with AlCl3

& Aniline (Acid-base Reaction)
ACID can be a:
1. Proton donor
2. Lonepair Acceptor
 Polymers
long chain
repeating units
(monomers)
figure 6
Condensation Polymerisation
Polyamide (Page 413)
figure 7
Condensation Polymerisation
nylon 6,6
Exercise 10a

1. Cut the first bond and the end.

2. Locate any amide or ester group. Cut the C-O or C-N
bonds
3. Connect the fragments with -OH and -H 
 Exercise 10b

Predict the initial monomers

of the polyamide
Exercise 10c
 Figure 8

Similar reaction & observation with phenol.

2,4,6-tribromoaniline is also a white ppt
 Ultimate Question 1

What is reagent to differentiate

phenol from aniline?
Ultimate Question 2
THANK
YOU!