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Zinc Zn
69
Valency of elements
Magnesium Mg2
Magnesium ion
Sulphur Sulphide
Cuprous/ Cu /Cu2
Copper Cupric
Oxygen Oxide 0
Zinc Zinc ion Zn2
An 1on having more than one atoms is called polyatomic ion. The valencies of polyatomic
Sulphate SO2
Carbonate CO,2
Nitrate NO
Sulphite S0
Phosphate PO
+1
Ammonium NH
1
Hydrogen carbonate HCO
1
Hydroxide (or Hydroxyl) OH
Qprestions
Write T for True and F for False.
Step 3: C,0
Representation of Compounds
A molecule of a compound can be Step 4: Since the
valencies are divisible bv 2
would be CO,
represented by a chemical formula. It is the simplified formula
derived on the basis of the following rules.
Example 2 Derivation of iron sulphide.
Step 1 Write down the symbols of the
elements that make up the compound. Step 1: Write the symbols Fe and S
valencies +2 and-2
Step 2: Write the
Step 2 Write down the valency of each of the
Step 3: Interchange the valencies Fe, and S
elements below their respective symbols. and write as subscripts
alcium
and nydroxide, a polyatonmic ion the right-hand side. A plus sign is written
of oxygen and hydrogen). between the reactants (between products
made up
too, if nmore than one are formed) and an
Write the symbols Ca and OH arrow points towards the products.
Step 1:
Write the valencies +2 and -1
step 2: The conditions necessary for the reaction
step 3: interchange the valences Ca and
are usually written on top of (or below)
and write as subscripts (OH) the arrow. When a chemical reaction is
Step4: Divide the valencies bya Not
Common factor divisible represented using only the names of the
chemicals involved, then it is called a word
Chemical formula of calcium
hydroxide
Ca(OH) equation.
ne
representation of a chemical reacton
Mg +
O
0 MgO
LStrng symbols and formulae is known as a Even this equation is not correct. It violates
chemical equation. very important law of matter - the law of
N
= 0 =
1
of Mg
RHS: No. of atoms
of this magnesium
atoms is
equation number of
The
balanced
the
of oxygen atoms is
equation.
Here,
number
the
reaction is: balanced but
Heat 2MgO not.
2Mg+
to balance the
coniorms
Multiply the R S by 2
equation 2.
balanced
chemical
o atoms on both sides.
A and the law number of oxygen
atomic theory
to both the Heat
conservation ot mass.
+ 2MgO
Mg
of Mg =l 0 =2
BALANCING SIMPLE LHS: No. of atoms
CHEMICAL EQUATIONS 2 0 2
No. of atoms of Mg =
the RHS:
balanced on
be
equation
can
atoms is
A chemical law of number of oxygen
laws: atomic
theory and Here, the
basis of two of magnesium
balanced but the number
conservation of mass.
atoms is not.
of Mg =
2
forming newer
RHS: No. of atoms
of atoms of each
Example1
1. Count the number Wite the word and the chemical
equations
element on the LHS and that of each product the
for the burning of carbon and balance
on the RHS.
chemical equation.
So, in the equation
Heat Solution
Mg + 0,
MgO Word equation:
Carbon + Oxygen Carbon dioxide
LHS: No. of atoms of Mg 1 0 2
chemical e q u a t i o n :
Solution
C+ 0, Co, Word equation:
Hydrogen + Chlorine Hydrogen chloride
No. of atoms of C =
1 OO =
2
IHS:
Chemical equation: H, + Cl HCI
No. of atoms of C
=
1 O 2
RHS: LHS: No. of atoms of H = 2
Example 2
Multiply RHS by 2 to balance the number of
Write the word and chemical equations for a
hydrogen and chlorine atoms on both sides.
reaction between hydrogen and oxygen and
balance the chemical equation.
H +Cl 2HCI
LHS: No. of atoms of H = 2
Solution
Word equation: Hydrogen + Oxygen -Water No. of atoms of Cl = 2
C 1 O 3 O H 2 RHS: No. o f a t o m s of H = 2 0= 2
Qrestions.
Balance the following equations.
ron (catalyst)
1. H + N NH
2. Fe H,O Fe,O+ H
3. Al+ NaOH + H,O NaAlO, + H,
HH
Therefore,the molecular mass The information that be
(average mass
can
gathered from
of a molecule) of this equation are:
reactants and products
becomes 1. Name of reactants: Calcium and
Ca+ HCI
40 CaCl, +H, Hydrochloric acid
40
+35.5) 40+(35.5x2) (1x2) 2.
5 111
Name of the products: Calcium chloride
2
Total Mass and Hydrogen
(of reactants) on
LAS 40 + 36.5 =
76.5
3. The number of molecules of each
reactant: 1 molecule of Calcium
lotal Mass and 2
(of products) molecules of
RIHS 1 + 2
on Hydrochloric acid
113 4. The number of molecules of
each
erence of mass 113 product: molecule of Calcium chloride
1
=
76.5 =
36.5
Mass of one and 1 molecule of
should be addedmolecule of HCl, which Hydrogen
5.
to the LHS. Therefore, the Proportion of reactants: Calcium
Dalanced equation is Hydrochloric
and
acid react in the ratio
Ca 1:2
4040 2HCI
2x (1+35.5) CaCl,
6.
Proportion products: Calcium chloride
of
+H,
40+(35.5 x 2) (1 x 2) and hydrogen in the
73 ratio 1:1
111 2
Answer: Thus,
28 8 of lime will he
7. Mas of the reactants: Calcium 40g and
heating 50 8 OI calcium carbonate
obtained
on
Hydrochloric acid 73g
Example2
8. Mass of the products: Calcium chloride Calculate the amount of lime (Ca
when 75 g of calcium carbonate is heated
formed
111g and Hydrogen 28
Example 1 CThe atomic masses of the elements are:
formed 12, and O
of lime (Ca0) 16.)
=
equation.
Solution
Write the balanced
chemical When calcium
carbonate (limestone) is
Step one:
heated, carbon dioxide
is liberated.
equation.
CaO +
CO,
When calcium carbonate (limestone)
is CaCO Calcium oxide Carbon dioxide
Calcium carbonate
liberated.
heated, carbon dioxide is
two: Calculate the molecular masses of
CaCO Ca0 CO Step
Calcium oxide Carbon dioxide compounds using atomic masses given.
Calcium carbonate
of
Step two: Calculate the molecular masses
CaCO Ca0 CO
compounds using atomic masses given. 40+16 12+2/16)
40+12+3(16)
CaCO Ca0 CO 100 56 44
78
Example 3
56+32
56 32 takes place. However, it silver nitrate is
sodium iodide is in
56 32 88 in the solid state and
solution state, then the reaction does not
three: Write the molecular masses of
Step take place. Therefore, the equation must
the compounds.
mention this intormation as shown in the
Fe S FeS
88g
following equation.
56 g 32g
AgNO, (aq) + Nal(aq) NaNO,(aq) + Agl
Using the unitary method,
iron sulphide A solution in water is mentioned as (ag)
S6g of iron is converted into
using 32 8 of sulphur. next to the solution in a chemical equation.
It reads 'aqueous' meaning watery.
Tg ofiron is converted into iron sulphide
using 32/56 g of sulphur.
Heat and temperature
Hence, 112 g of iron is converted into iron Certain chemical reactions take place at
sulphide using (32/56) x 112 g of sulphur.
high temperatures, whereas some take place
Answer: Thus, 64 g of sulphur is required to at low temperatures. The necessity ot heat
Convert 112 g of iron into iron sulphide. must be stated in the chemical equation.
80
chlorate, when
tassium
heated, produces
notassium chlorid and alters the
oxygen. speed of reaction ithout itself
a
2KCIO
Heat undergong any chemical
2KCI+ 30, is specilic in nature change. A catalyst
Cannot be used for The same catalyst
all
Light
For
reactions.
Certain hemical
reactions take place in example, iron is used as
catalyst
1manufacturing process of ammonia.
a
in the
thepresence sunlight For example
of.
photosynthesis in green plants takes
place N2 Iron as catalyst
in he presence of sunlight. The 3H
oht must be stated in the
necessity of A 2NH,
light chemical equation. catalyst can be a positive or a
Catalyst
A
Mg+ H,SO, MgSO +H
catalyst is a chemical substance that
81
Endothermic or exothermic
heat
WRAP UP
r the element itself.
representation of an atom of an element, or
A chemical symbol is a
Compound.
of element. Most elements have variable
Valency represents the combining capacity of an atom an
valency. catiOn
when of atoms gains or loses electrons. A
atom or a group
lons are charged particles formed an
is formed by the loss of electrons and an anion formed is by the gain of electrons.
A chemical equation is a representation ofa chemical reaction using symbols and formulae
side.
In a chemical equation reactants are shown on the left-hand side and products on the right-hand
The number ofatoms of reactants should be equal to number of atoms of products.
The total mass of the reactants should be equal to the total mass of the products.
A chemical equation is said to be balanced if the atoms of each element on either side are equal in
number.
A chemical equation carries only a limited information about a chemical reaction.
A chemical reaction can be influenced by reactant state, heat or temperature, light, electricity, pressule
or presence of a catalyst.
82
Exercises, es
SECTION I
4. CO, + H,0
5. H, + Cl, ****
6. Fe + S.
83
SECTION II
A. Give reasons for the
following
1. Chemical formula of sodi suiphate is Na 50, and not Naso
0
2. The
valency of carbon is 4
3 A downward arrow is placed n the folowing teactio0
AgNo, aCl NaN0, AgCl
-
B.
Explain the foliowing terms.
1Valency
2 ions
3 Balanced chermical equation
C.
Distinguish between the following
.Cation and anion
2 Chemical
symbol and chemical formula
D. Short answer
1. What do
questions5.
you understand by valency of element:
an
2
2 Nane any two elements that have variable valences.
3 Write the symbols, atomic
number, mass number. and valency of any ive
4. Write the nane, chemical
iormula, and valency of three ions.
elements
any
E. Long answer
1.
questions.
What is a chemical
symbol? List the rules to write a chemical
2. Cive the
step-by-step procedure to derive the chemical formulasymbol
of
hydroxide. water and calcium
3 What is a chemical equation? Why does a chemical equation need be
F Numerical questions
to balanced?
(The atomic masses of a few elements
are: Ca =
40, C =
12. O
1. Calculate the =
16, Fe =
56. S 32, and
amount of calcium ozide
formed when 500
=
Mg=
g of calcium carbonate is heatea
2. What amount of iron
CaCO,Ca0 co
sulphide is formed when 11.2 g of iron is
Fe S Fes heated with sulphur:
3 What anount of iron
sulphide is formed when 224 of iron
g is heated with
FeS Fes suiphur
4 How much magnesium oxide will be formed
when 96 g of
of air? magnesium is bunt in the
esu
5. What is the amount of
magnesium required to form 160 g of
magnesium in air? magnesium oxide by burn
2MgO: >2MgO
84
CTURE-BASED QUESTIONS
PICTURE
a. Name any two anions that can be formed using the combinations of the elements
85
Mytearming comer
A. Think about
Make a table having seven negative polyatomic ions and seven cations. Now
ow write chem
formula using these anions and cations. [You will be able to write 49 tormula.|
B. Picture study
Carbonate
Co
Nitrate 1
NO
Sulphite -2
S0
Phosphate PO, 3
Ammonium
NH +1
Hydrogen carbonate HCO -1
Hydroxide (or Hydroxyl) OH -1
a. Identify the
polyatomic ion of sulphur.
b. Name any two
negative polyatomic ions having -2 charge.
c. What is the difference
between sulphite and sulphate ions?
d. Write formula for ammonium
phosphate.
e. Which polyatomic anion has two atoms only? What is its charge? Write its formula with
Potassium cation.
C. Try out
86