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ACID AND BASE:

A. Definitions
 In chemistry, acids and bases have been defined differently by three sets of
theories:
 Arrhenius Acids and Bases
The Arrhenius definition of acid-base reactions is a development of the
"hydrogen theory of acids". It was used to provide a modern definition of
acids and bases, and followed from Arrhenius's work with Friedrich
Wilhelm Ostwald in establishing the presence of ions in aqueous solution
in 1884.
a. An Arrhenius acid is a compound that increases the concentration
of H+H+ ions that are present when added to water.
Example:
HCl(g)→H+(aq)+Cl−(aq)

Explanation:

In this reaction, hydrochloric acid (HCl) gas dissociates


into hydrogen (H+) and chloride (Cl−) ions when dissolved in
water, thereby releasing H+H+ ions into solution. These H+ ions
form the hydronium ion (H3O+) when they combine with water
molecules. Both processes can be represented in a chemical
equation by adding H2O to the reactants side of Equation and
switching hydronium ions for free protons.

Example:

HCl(g)+H2O(l)→H3O+(aq)+Cl−(aq)

b. An Arrhenius base is a compound that dissociates to yield


hydroxide ions (OH−OH−) in aqueous solution.

Common examples of Arrhenius bases include Sodium hydroxide


(NaOH), Potassium hydroxide (KOH), Magnesium hydroxide Mg
(OH)2, and Calcium hydroxide Ca (OH)2. All of these bases are
solids at room temperature and when dissolved in water, will
generate a metal cation and the hydroxide ion ((OH−) for
example, Sodium hydroxide
Example:

NaOH(s)⟶Na+(aq)+OH−(aq)
All Arrhenius acids have easily detachable hydrogen that leave to form hydronium ions in
solution and all Arrhenius bases have easily detachable OH groups that form hydroxide ions in
solution.

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