Riits +2 reap batch chemistry descriptive examination

Solid state and solution

total mark : 40 time : 1 hr

General Instructions
(a) All questions are compulsory.
(b) Section A: Q.no. 1 to 10 are very short answer questions and carry 1 mark each.
(c) Section B: Q.no. 11 to 14 are short answer questions and carry 2 marks each.
(d) Section C: Q.no. 15 to 18 are long answer questions and carry 3 marks each.
(e) Section D: Q.no. 19 to 20 are also long answer questions and carry 5 marks each.
(f) There is no overall choice.
(g) Use log tables if necessary, the use of calculators is not allowed

SECTION- A
Read the given passage and answer the questions 1 to 5 that follow:
A colligative property is a property of a solution that is dependent on the ratio between
the total number of solute particles (in the solution) to the total number of solvent particles.
Colligative properties are not dependent on the chemical nature of the solution’s components.
Thus, colligative properties can be linked to several quantities that express the concentration
of a solution, such as molarity, normality, and molality.

1. What is meant by elevation in boiling point?

2. Write the colligative property which is used to find the molecular mass of
macromolecules.
3. How is the osmotic pressure related to the concentration of a solute in solution?
4. Define the term molal depression constant.
5. Addition of 1 mol glucose to 1 L water, the boiling point of water increases. Why?
Questions 6 to 10 are one-word answers:

6. Which point defect in crystals does not alter the density of the relevant solid?
7. What is the number of atoms in a unit cell of a face-centred cubic crystal?
8. What type of defect can arise when a solid is heated?
9. What change occurs when AgCl is dopped with CdCl2 ?
10. Packing efficiency of hexagonal close packing is ……………….

SECTION B
11. Write two differences between ideal and non ideal solutions
12. Define the following
a) F-centre
b) Doping
13. Write any two applications of Henry’s law
14. An element crystallizes in a bcc lattice with cell edge of 500 pm. The density of the
element is 7.5g /cm3. How many atoms are present in 300g of the element?
SECTION C
15. Calculate the freezing point of a solution containing 0.5 g KCl (Molar mass = 74.5
g/mol) dissolved in 100 g water, assuming KCl to be 92% ionized.
Kf of water = 1.86 K kg / mol.
16. Explain how you can determine the atomic mass of an unknown metal if you know its
mass density and the dimensions of unit cell of its crystal
17. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour
pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this solution. The new
vapour pressure becomes 2.9 kPa at 298 K.
a) Calculate the molecular mass of solute and
b) Vapour pressure of water at 298 K.
18. Account for the following:
a) Schottky defects lower the density of related solids.
b) Conductivity of silicon increases on doping it with phosphorus.
 SECTION D

19.
a) State the following:
(i) Henry’s law about partial pressure of a gas in a mixture.
(ii) Raoult’s law in its general form in reference to solutions.
b) A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 mL of water
has an osmotic pressure of 0.335 torr at 25°C. Assuming the gene fragment is a
non-electrolyte, determine its molar mass
20.
(a) Based on the nature of intermolecular forces, classify the following solids:
Sodium sulphate, Hydrogen
(b) What happens when CdCl2 is doped with AgCl?
(c) Why do ferrimagnetic substances show better magnetism than antiferromagnetic
substances? An element crystallises in bcc lattice with cell edge of 400 pm.
Calculate its density if 500 g of this element contains 2.5 × 10 24 atoms

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