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Kenneth Iheme CH 126-01

Trial # 0.05M [0.10M]            


Moles
KIO3
Needed Theoretical Actual g
To React g of Solid of
With Sr(IO3)2 Sr(IO3)2
Volume Sr(NO3)2 Volume KIO3 Moles Moles Moles of Limiting Ppt. Ppt.
  (mL) (mL) Sr(NO3)2 KIO3 Sr(NO3)2 Reagent formed formed
Sr(NO3)
1 6.00 12.00 0.0003 0.0012 0.0006 2 0.13128 0.12
Sr(NO3)
2 7.00 12.00 0.00035 0.0012 0.0007 2 0.15316 0.145
Sr(NO3)
3 8.00 12.00 0.0004 0.0012 0.0008 2 0.17504 0.168
Sr(NO3)
4 9.00 12.00 0.00045 0.0012 0.0009 2 0.19692 0.197
Sr(NO3)
5 10.00 12.00 0.0005 0.0012 0.001 2 0.2188 0.21
Sr(NO3)
6 10.10 12.00 0.000505 0.0012 0.00101 2 0.220988 0.22
Sr(NO3)
7 11.00 12.00 0.00055 0.0012 0.0011 2 0.24068 0.25
8 12.00 12.00 0.0006 0.0012 0.0012 Neither 0.26256 0.26
9 12.50 12.00 0.000625 0.0012 0.00125 KIO3 0.26256 0.265
10 13.00 12.00 0.00065 0.0012 0.0013 KIO3 0.26256 0.26
11 14.00 12.00 0.0007 0.0012 0.0014 KIO3 0.26256 0.266
12 16.00 12.00 0.0008 0.0012 0.0016 KIO3 0.26256 0.262

Sr(NO3)2(aq)+2KIO3(aq)→Sr(IO3)2(s)+2KNO3(aq) 

Data Formula Explanation


Moles Sr(NO3)2 0.05*(Volume Calculating the moles of Sr(NO3)2 by
Sr(NO3)2/1000)L multiplying concentration and volume in
litres
Moles of KIO3 needed to Moles of Sr(NO3)2*2 Stochiometric relationship of Sr(NO3)2
react with Sr(NO3)2 and KIO3 is 1:2
Theoretical g of solid -Moles of Sr(NO3)2*437.6—(i) Equation (i) is used where Sr(NO3)2 is the
Sr(IO3)2 -Moles of KIO3*437.6/2 –(ii) limiting reagent and (ii) is used when
KIO3 is the limiting reagent. Either
equation works where neither is the
limiting reagent
Kenneth Iheme CH 126-01

Limiting Strontium Nitrate and Potassium Iodate in the production of Strontium Iodate

Theoretical yield
with strontium
nitrate limitng
theoretical yield of
0.28 strontium iodate
with strontium
nitrate limiting
0.26 R² Theoretical yield
R² == 0.99
1 0.02
R² = 0
with potassium
iodate limiting
Mass of strontium iodate in g

0.24
theoretical yield of
strontium iodate
0.22 with potassium
nitrate limiting
0.2 Linear (Theoretical
yield with potassium
iodate limiting)
0.18 Actual yield with
strontium nitrate
0.16 limiting

0.14

0.12
0 0 0
Number 0
of moles 0
of reactants0 0 0

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