Adsorbent adsorbate T Kl = Kd Qmax

polymer antibiotic imprinted 298.15 0.4006 2.892

308.15 0.3005 3.231
318.15 0.4901 1.594
non-imprinted 298.15 0.1703 1.935
308.15 0.2124 2.114
318.15 0.2375 2.225

polymer-antibiotic removal polymer-antibiotic removal prop

0.6 1400
imprinted
0.5 Linear (imprinted) 1200
Linear (imprinted) f(x) = − 18.86579 x + 6783.71655516667
1000 R² = 0.999989905462666
0.4 f(x) = 0.004475 x − 0.981904583333337
R² = 0.222595900361663 Linear (imprinted) 800
0.3 non-imprinted
Linear (non-imprinted) 600
0.2 f(x) = 0.00336 x − 0.828650666666668
Linear (non-imprinted) 400 f(x) = 9.94535000000001 x − 2628.99906916667
R² = 0.979113245237964 R² = 0.986660156165557
0.1
200
0 0
295 300 305 310 315 320 295 300 305 310 315 32
Adsorbent adsorbate T Kl = Kd Qmax
antibiotic 288 0.6 279.01
Tetracycline
glucose-base hydrochloride 298 1.26 283.75
mesoporous carbon (TC) 308 1.38 297.91
288 0.45 304.54
ciprofloxanin
(CIP) 298 0.66 342
308 0.69 369.85
288 0.72 214.36
sulfadiazine 298 0.75 232.31
(SDZ) 308 0.88 246.73

mesoporous carbon - antibiotic paper mesoporous car

TC
1.6
Linear (TC) 450000
1.4 f(x) = 0.039 x − 10.542 400000 f(x) = 12185.49 x − 33
Linear (TC)
1.2 R² = 0.862244897959184 350000 R² = 0.905296046089
CIP
1 300000
Linear (CIP)
250000
0.8 Linear (CIP) f(x) = 5907.67500000
f(x) = 0.008 x − 1.60066666666667 200000 R²
0.6 R² ==0.884792626728111
f(x) 0.012 x − 2.976 SDZ f(x)==0.922779230713
3139.16 x − 753
150000 R² = 0.957192638273
0.4 R² = 0.842105263157895 Linear (SDZ) 100000
0.2 Linear (SDZ) 50000
0
0 285 290 295
285 290 295 300 305 310

Adsorbent adsorbate T Kd = (qe(W/V))/ Ce Qmax

CIP 303 0.012418085546788 108.74
microporous fluoroquinolon 313 0.010320765686333 118.05
activated carbon es antibiotics 323 0.007578815396753 131.14
NOR 303 0.006713731097691 166.99
313 0.009453208872726 160.9
 323 0.013937088515275 153.99

micropore actv carbon - fluoro antibiotic (paper) micropore actv carbon - fl

0.016
(propose)
0.014 1000000
f(x) = 0.000361167870879 x − 0.103010867423288 CIP 900000
0.012 f(x)
R² ==0.980930820706362
− 0.000241963507502 x + 0.085840466724665 Linear (CIP) 800000 f(x) = − 15733.7312000001 x
0.01 R² = 0.994119971729637 700000 R² = 0.973385084654075
NOR
0.008 600000
Linear (NOR)
500000
0.006 Linear (NOR) 400000
0.004 300000 f(x) = 3006.84460000003 x −
200000 R² = 0.539710221828373
0.002 100000
0 0
300 305 310 315 320 325 300 305 310 315 320

𝐾𝑑=𝑎𝑠/𝑎𝑒= (𝛾_𝑠 𝑞𝑒)/(𝛾_𝑒 𝑐𝑒)

Adsorbent adsorbate T Qmax
298 0.998049871905419 26.46
triazine 308 0.998365425175567 24.51
p doped biochar pesticides 318 0.998759626296067 24.3

triazine pesticide (paper data) triazine pesticide (propos

0.999 2500000
0.9988
2000000
0.9986 f(x) = 3.54877195323741E-05 x + 0.987461423509713
0.9984 R² = 0.99592373541298 1500000 f(x) = − 99191.5200000005 x + 31271
R² = 0.798299155107799
0.9982 1000000
0.998
500000
0.9978
0.9976 0
295 300 305 310 315 320 295 300 305 310

T 𝐾𝑑=𝑞𝑒/𝑐𝑒 Qmax
Adsorbent adsorbate

bentazon 293 0.993192412653618 169.491

activated carbon 303 0.994695245724937 104.166
313 0.995116261342537 89.956

Paper data bentazon propose

0.9955 70000
0.995 f(x) = 9.61924344459524E-05 x + 0.965188332269907 60000 f(x) = 1471.67895 x − 3
R² = 0.90464905062358 R² = 0.93976281900260
0.9945 50000
0.994 40000
0.9935 30000
0.993 20000

0.9925 10000

0.992 0
290 295 300 305 310 315 290 295 300
 0.993
0.9925
0.992
290 295 300 305 310 315

Adsorbent adsorbate T𝐾𝑑=𝑎𝑠/𝑎𝑒= (𝑣_𝑠 𝑞𝑒)/(𝑣_𝑒 𝑐𝑒)

Qmax

chitosan pentachlorophe CHT 293 0.999828471339606 21.29

nol 303 1.00032179623227 18.58
313 1.00078381934322 13.13
CHTA 293 0.99882548189221 39.11
303 0.999335506459015 31.91
313 0.999813177595232 25.46
CHTAC 293 0.998835408684175 36.85
303 0.999190290288659 32.19
313 0.999522610011522 22.35

Pentachlorophenol - paper Pentach

CHT
1.001 2500
Linear (CHT)
1.0005 f(x) = 4.77674001808142E-05 x + 0.985837840050246 Linear (CHT)
R² = 0.999642284071098 2000 f(x) = − 54.67500000000
1 CHTA f(x)
R² ==0.86341671404207
− 59.58500000000
0.9995 f(x) = 4.93847851510809E-05 x + 0.984361132081375 Linear (CHTA) 1500 R² = 0.99353517771403
f(x)==0.999642465636639
R² 3.4360066367365E-05 x + 0.988771669552141 Linear (CHTA)
0.999 R² = 0.999640825593446 1000
CHTAC
0.9985 Linear (CHTAC) f(x) = − 22.885 x + 7535
Linear (CHTAC) 500 R² = 0.97353809856135
0.998
0.9975 0
290 295 300 305 310 315 290 295 300

Adsorbent adsorbate T 𝐾𝑑=𝑞𝑒/𝑐𝑒 Qmax

carbofuran 303 1.00218964642597 160

borassus aethiopum
shell-based 313 1.00207725628977 156
activated carbon 323 1.00200914896994 152

carbofuran paper carbofuran propose

1.00225 60000
1.0022 50000
1.00215 f(x) = − 9.02487280157559E-06 x + 1.00491680241545
R² = 0.980331111053238 40000 f(x) = − 1592.40000000001 x + 527642.533
1.0021 R² = 0.765065381477074
30000
1.00205
20000
1.002
1.00195 10000

1.0019 0
300 305 310 315 320 325 300 305 310 315 320

Adsorbent adsorbate T Kd = Fe/1-Fe Qmax

atrazine MOP 298 1.00037543795608 0.692
moringa oleirfera 308 1.000437474018 0.786
pods 318 1.00043885002428 0.946
MOPC 298 1.0007792919516 1.58
 308 1.00093767867634 1.614
318 1.00108991319864 1.887
MOPT 298 1.00424295988999 7.47
308 1.00443043097537 7.99
318 1.00465554157227 8.24

Atrazine paper Atrazine propose

MOP
1.005 60
Linear (MOP)
1.004 f(x) = 2.06290841143088E-05 x + 0.998089219572003
Linear (MOP)
R² = 0.997233417400629 55
MOPC f(x) = 0.618500000000005 x − 141.279333333335
1.003 f(x)
R² ==0.897566261542835
− 0.734100000000004 x + 272.263466666668
50
1.002 Linear (MOPC) R² = 0.838752849342762
Linear (MOPC) 45
1.001
MOPT
f(x) = 1.5531062352456E-05 x + 0.996152060737637 40
1 R² ==0.999869256268015
f(x) 3.17060341001147E-06 x + 0.999440708149173
Linear (MOPT)
0.999 R² = 0.766266749586558 Linear (MOPT) 35

0.998 30
295 300 305 310 315 320 295 300 305 310 315 320
 gibbs s h Kd = qmax*kl*1000 gibbs reff
-2267.60352455858 1158.5352 2871799
-3080.26270468984 970.9155 2487446 Xu, L., Pan, J., Dai, J., Li, X., Hanga, H., Cao
-1886.34138534271 781.2194 2066403 Preparation of thermal-responsive magneti
-4387.98993272739 329.5305 816846.5 polymers for selective removal of antibiotics
Journal of Hazardous Materia
-3969.2022156768 449.0136 1150354
-3802.56181375384 528.4375 1397770

lymer-antibiotic removal propose

imprinted
) = − 18.86579 x + 6783.71655516667 Linear (imprinted)
= 0.999989905462666 Linear (imprinted)
non-imprinted
Linear (non-imprinted)
) = 9.94535000000001 x − 2628.99906916667 Linear (non-imprinted)
= 0.986660156165557

00 305 310 315 320

gibbs s h Kd = qmax*kl*1000 gibbs reff
-10.89 167406
-12.2 166.08 37.05 357525
-14.22 411115.8 Wang, B., Xu, X., Tang, H., Mao, Y., Chen, H
efficient adsorption of three antibiotics from
-10.9 137043 glucose-based mesoporous carbon. Applied
-12.35 139.41 29.23 225720
-13.69 255196.5
-10.01 154339.2
-10.96 104.72 20.18 174232.5
-12.11 217122.4

mesoporous carbon-antibiotic propose

450000
400000 f(x) = 12185.49 x − 3319260.42 TC
350000 R² = 0.905296046089568 Linear
300000 (TC)
250000 Linear
f(x) = 5907.67500000001 x − 1554500.65 (TC)
200000 R²
f(x)==0.922779230713422
3139.16 x − 753571.646666667 CIP
150000 R² = 0.957192638273781
100000 Linear
(CIP)
50000 Linear
0 (CIP)
285 290 295 300 305 310
SDZ

gibbs s h Kd = qmax*kl*1000 gibbs reff

-11055.51 104.06 20527.27 355721.162 32199.43
Ahmed, Muthanna J.; Theyda
-11901.79 337693.83 33126.78
-13111.3 415858.054 34744.26 (2014). Fluoroquinolones antibiotic
-12604.78 -58.53 -30362.73 862186.069 34429.68 microporous activated carbon from lign
-12130.28 659786.54 34869.72 microwave pyrolysis. Journal of the
Chemical Engineers, 45(1),
 Ahmed, Muthanna J.; Theyda
(2014). Fluoroquinolones antibiotic
microporous activated carbon from lign
microwave pyrolysis. Journal of the
-11475.35 547511.445 35482.85 Chemical Engineers, 45(1),

micropore actv carbon - fluorocarbon antibiotic nilai KL nya ga karuan, that's why de fitting kita ga masuk
(propose)
1000000 CIP
900000
Linear (CIP)
800000 f(x) = − 15733.7312000001 x + 5614485.88360004 Linear (CIP)
700000 R² = 0.973385084654075
600000 NOR
500000 Linear (NOR)
400000 Linear (NOR)
300000 f(x) = 3006.84460000003 x − 571384.677800009
200000 R² = 0.539710221828373
100000
0
300 305 310 315 320 325

gibbs s h Kd = qmax*kl*1000 gibbs reff

-4.8363 2000111.4 -35946.38
Suo, Fengyue; You, Xiangwei; Ma, Yongqiang;
-4.1891 144609 -30425.84 removal of triazine pesticide by P doped bio
-3.2814 16281 -25639.43 mechanism. Chemosphere.

triazine pesticide (propose)

f(x) = − 99191.5200000005 x + 31271321.9600002

R² = 0.798299155107799

95 300 305 310 315 320

gibbs s h Kd = qmax*kl*1000 gibbs reff

-16.64 31016.853 -25193.83 Omri, Abdessalem; Wali, Ahmed; Benzina, Mou

bentazon on activated carbon prepared from
-13.399 -0.207 -77.233 52187.166 -27364.41 Equilibrium, kinetic and thermodynamic stu
-12.74 60450.432 -28650 Chemistry (S1729-S173

propose data bentazon

70000
60000 f(x) = 1471.67895 x − 398033.90485
50000 R² = 0.939762819002601
40000
30000
20000
10000
0
290 295 300 305 310 315
 reff
gibbs s h Kd = qmax*kl*1000 gibbs

-0.417879999999997 851.6
0.810520000000004 -0.12284 -36.41 557.4
2.03892 393.9 Shankar,Aparajita; Kongot, Manasa; Saini, Vi
(2020). Removal of pentachlorophenol pesticid
-2.86281 1955.5 using modified chitosan. Arabian Journal of
-1.67451 -0.11883 -37.68 1276.4
-0.48621 763.8
-2.8386 2211
-2.0406 -0.0798 -26.22 1287.6
-1.2426 1117.5

Pentachlorophenol - propose
CHT
2500
Linear (CHT)
2000 Linear (CHT)
f(x) = − 54.6750000000001 x + 18105.225 CHTA
f(x)
R² ==0.86341671404207
− 59.5850000000001 x + 19386.155
1500 R² = 0.993535177714035 Linear (CHTA)
Linear (CHTA)
1000 CHTAC
f(x) = − 22.885 x + 7535.12166666668 Linear (CHTAC)
500 R² = 0.973538098561357 Linear (CHTAC)
0
290 295 300 305 310 315

gibbs s h Kd = qmax*kl*1000 gibbs reff

-5.51 50240 -27268.62 N. Garba, Z.; Tanimu, A.; U. Zango, Z. (20

-5.4 44.1 -0.084 19032 -25642.57 shell-based activated carbon as efficient ad
-5.39 18392 -26370 Bulletin of the Chemical Society of Ethi

carbofuran propose

f(x) = − 1592.40000000001 x + 527642.533333336

R² = 0.765065381477074

305 310 315 320 325

gibbs s h Kd = qmax*kl*1000 gibbs reff

-0.93 55.36
-1.12 0.036 9.91 42.444
-1.16 40.678
-1.93 44.24 Coldebella, Priscila Ferri; Fagundes-Klen, Mar
Valverde, Karina Cardoso; Cavalvanti, Eliane Be
Onelia Aparecida; Bergamasco, Rosangela. (2
chemical and thermal treatment on the Kin
thermodynamic studies for atrazine biosorptio
pods. The Canadian Journal of Chemical Eng
 Coldebella, Priscila Ferri; Fagundes-Klen, Mar
-2.4 0.048 12.3 46.806 Valverde, Karina Cardoso; Cavalvanti, Eliane Be
-2.88 56.61 Onelia Aparecida; Bergamasco, Rosangela. (2
chemical and thermal treatment on the Kin
-10.49 25995.6 thermodynamic studies for atrazine biosorptio
-11.32 0.089 16.14 26494.84 pods. The Canadian Journal of Chemical Eng
-12.28 27551.264

Atrazine propose cuman MOP tok yang hasil e bagus

MOP
0.618500000000005 x − 141.279333333335 Linear (MOP)
−897566261542835
0.734100000000004 x + 272.263466666668 Linear (MOP)
838752849342762
MOPC
Linear (MOPC)
Linear (MOPC)

305 310 315 320

 reff

Dai, J., Li, X., Hanga, H., Cao, Z., & Yan, Y. (2021).
hermal-responsive magnetic molecularly imprinted
ective removal of antibiotics from aqueous solution.
ournal of Hazardous Material, 48-56.

reff

., Tang, H., Mao, Y., Chen, H., & Ji, F. (2020). Highly
on of three antibiotics from aqueous solutions using
mesoporous carbon. Applied Surface Science, 1-10.

reff

ed, Muthanna J.; Theydan, Samar K.

oroquinolones antibiotics adsorption onto
tivated carbon from lignocellulosic biomass by
pyrolysis. Journal of the Taiwan Institute of
emical Engineers, 45(1), 219–226.
ed, Muthanna J.; Theydan, Samar K.
oroquinolones antibiotics adsorption onto
tivated carbon from lignocellulosic biomass by
pyrolysis. Journal of the Taiwan Institute of
emical Engineers, 45(1), 219–226.

why de fitting kita ga masuk

reff
u, Xiangwei; Ma, Yongqiang; Li, Yiqiang. (2019). Rapid
ne pesticide by P doped biochar and the adsorption
mechanism. Chemosphere. 918-925

reff

Wali, Ahmed; Benzina, Mourad. (2016). Adsorption of

vated carbon prepared from Lawsonia inermis wood:
etic and thermodynamic studies. Arabian Journal of
Chemistry (S1729-S1739).
 reff

a; Kongot, Manasa; Saini, Vipin Kumar; Kumar, Amit.

f pentachlorophenol pesticide from aqueous solutions
chitosan. Arabian Journal of Chemistry. 1821-1830.

reff

imu, A.; U. Zango, Z. (2019). Borassus aethiopum

ated carbon as efficient adsorbent for carbofuran.
Chemical Society of Ethiopia, 33(3), 425–436.

reff

la Ferri; Fagundes-Klen, Marcia Regina; Nishi, Leticia;

ardoso; Cavalvanti, Eliane Bezerra; Andreo dos Santos,
a; Bergamasco, Rosangela. (2017). Potential effect of
hermal treatment on the Kinetics, equilibrium, and
udies for atrazine biosorption by the Moringa oleifera
ian Journal of Chemical Engineering, 95(5), 961-973.