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  • Phenolic: Phenols Group With System

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    Armaan Garg
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    Phenols have an OH group directly attached to an aromatic system. There are different types based on the number of OH groups: monohydric phenols have one OH group, dihydric phenols have two OH groups, and trihydric phenols have three OH groups. Phenols can be prepared through several methods including Dow's process using NaOH, from benzene sulphonic acid via ipso attack, from catechol via fusion, and the cymene hydroperoxide method which involves a peroxide shift.

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    lec 10 (16 sep)

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    Phenols have an OH group directly attached to an aromatic system. There are different types based on the number of OH groups: monohydric phenols have one OH group, dihydric phenols have two OH groups, and trihydric phenols have three OH groups. Phenols can be prepared through several methods including Dow's process using NaOH, from benzene sulphonic acid via ipso attack, from catechol via fusion, and the cymene hydroperoxide method which involves a peroxide shift.

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    © All Rights Reserved
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    12 views4 pages

    Phenolic: Phenols Group With System

    Uploaded by

    Armaan Garg
    Phenols have an OH group directly attached to an aromatic system. There are different types based on the number of OH groups: monohydric phenols have one OH group, dihydric phenols have two OH groups, and trihydric phenols have three OH groups. Phenols can be prepared through several methods including Dow's process using NaOH, from benzene sulphonic acid via ipso attack, from catechol via fusion, and the cymene hydroperoxide method which involves a peroxide shift.

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    © All Rights Reserved
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    of 4

    Phenols

    In phenolic compounds oh group has


    direct attachment with Aromatic system

    Types of Phenol
    based on number of OH group

    i Monohydric phenol
    one OH
    in 9
    B
    phenol cresol to m p

    ii Dihydric phenol
    has two OH

    9 on it in
    OH
    catechol Resorcinol 8h Quinol

    iii Trihydric Phenol


    has 3 OH group

    9 OH 9 OH 9
    OH
    pyrogallol on Hydrony
    quinol
    8 of Phloroslucinol
    Methods of Preparation
    1 Dow's process
    By
    it NaOH in
    300atom 823K

    Follow benzyne mechanism

    Mechanism
    2
    By Arsm2

    02M
    T MOZ UM
    I MOZ
    may
    high T P
    02 102
    picric acid

    Picryl chloride
    strong Elma at o p promote the reaction

    3 From benzene sulphonic acid

    is
    moon at
    fusion
    It follow Ipso attack
    HI
    1 Me
    NaOH
    P
    Fuston
    OH
    2 Y NaOH
    P2
    Fuston

    OH

    501

    4 From GR
    PbM8X Oz Photagx Hot Phon

    5 From diazo salt

    pad in

    Via Ars i reaction

    6
    By sodalime process

    9 cook in
    maon ca
    T
    A MazCOg

    salicylic acid
    7 Cymene hydroperoxide method
    CB ÉB
    t CHCH cha H Oz AIR
    95 13506
    9 c
    got
    t
    Ctycock

    mechanism
    Cb in cha
    0 0
    c
    f CB on
    Cb ÉO O H

    95 13506
    cymene hydroperoxide

    oph Cb H
    cuz
    112 e
    got
    PDshift
    HI
    Ctb
    f oph Chzcocty t Phon

    Hemiketal

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