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Fouling Mitigation Using Helixchanger
Fouling Mitigation Using Helixchanger
heat exchangers
300-500°F
Refinery applications
Generally, the fouling deposits occur as high molecular To Reformer
75 - Or Product
weight polymers are formed in the crude preheat sys- Naphtha Feed 300°F Blending
From Storage
tems. Products of corrosion and inorganic salts mix with Or Crude Unit Feed/Effluent Exchangers
the polymers and increase the volume of the fouling
Fig. 2 Schematic of a Naphtha Hydrotreater Unit
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deposits.
Most of the heat input in a refinery takes place in the
Crude Unit where the crude oil is preheated in heat ex- maintenance and cleaning costs of heat exchangers could
changer trains prior to further heating to elevated tem- significantly affect the plant operating costs. Anti-fouling
perature in a fired heater (furnace). See Fig. 1. The total agents are often added to the process streams to reduce the
refinery output is relying on the uniform operation of fouling tendencies and improve the plant economics.
the crude unit with consistent outlet temperatures at The total fouling related expenses in the major refining units in
desired flow rates. Preheat exchanger performance is, the USA alone is estimated to be approximately US$ 1.4 billion
therefore, vital in reducing the fuel consumption in the a year. The total fouling related costs for major industrialized
downstream furnace and supplying the uniform crude nations is estimated to exceed US$4.4 billion annually.
flow to the furnace over a desired run cycle. Considering that the Refinery fouling related costs
The second most important process unit in the refinery is represent a minor portion of the fouling related costs in
the Hydrotreater. The process stream in a Hydrotreater all industries, the fouling mitigation technology deserves
reacts with hydrogen in presence of a catalyst at elevated a greater attention.
temperature and pressure to remove sulfur and nitrogen.
The major fouling in this unit occurs in the feed/effluent Fouling mitigation technology
heat exchangers. In these exchangers, the cold Naphtha feed The Tubular Heat Exchanger Manufacturers Association
is preheated using the hot product effluent. See Fig. 2. (TEMA) standards suggest fouling factors for several
Fouling in the Feed/Effluent heat exchangers can decrease fluids based upon the asymptotic fouling model as
the outlet preheat temperature of Naphtha causing more described by Kern and Seaton (1959). In this model the
fuel consumption in the furnace and/or reduce the Naphtha competing fouling mechanisms lead to an asymptotic
flow rate. fouling resistance beyond which no further increase in
The last refinery process where heat exchangers are em- fouling occurs. The asymptotic values are, therefore,
ployed as Feed/Effluent heat exchangers is the Reformer recommended as the design fouling factors in the TEMA
Unit. See Fig. 3 for a schematic of this unit. Reforming standards. This approach does not particularly address
is a catalytic process designed to increase the antiknock the fouling phenomenon such as that at the “hot” end
quality of the naphtha streams. The dehydrogenation in of a crude preheat train, since fouling there does not
this unit converts the naphthenes to aromatics. Fouling exhibit the asymptotic behavior.
in the preheat exchangers play a vital role in reducing Ebert and Panchal (1997) have presented a fouling model
the heat transfer coefficient, often by 25-30% in three(3) that is expressed as the average (linear) fouling rate un-
months and as low as 50% in six(6) months after startup. der given conditions as a result of two competing terms,
Added fuel costs in the downstream furnace as well as namely, a deposition term and a mitigation term.
REACTORS
880-960°F 880-960°F
Ambient
880-960°F
225-300°F
Desalter
225-300°F
Crude Storage
Gas
3,000 Bbi/SD
Heat Exchangers
Naphtha
D
23,000 Bbi/SD I
Middle Distillate
S
T 700- 450-
24,000 Bbi/SD I 750°F 550°F
L Reheat Furnace Reheat Furnace
Gas Oil L 500°F
A
40,000 Bbi/SD T Furnace 300-500°F
Residuum
I
O
N
10,000 Bbi/SD Preheat Exchanger Train
Naphtha Feed From
Hydrotreater Preheat Furnace
200-300°F Feed/Effluent Exchangers
Fig. 1 Schematic of a Crude Unit
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Effectiveness, E
C–Segmental
0.5 D Baffle
where α, β, γ, and δ are parameters determined by regres- D–Pe=0
sion, τw in the shear stress at the tube wall and Tfilm is the 0.4
Helixchanger feedback
8000
7000
6000 S Segment
5000 Helix 17 deg.
Helix 40 deg.
4000
Helix 44 deg.
3000
Helix 35 deg.
2000 Helix 24 deg.
1000
0
0 2 4 6 8 10 12 14 16 18 20
Pressure Drop
Fig. 5 Measured heat transfer coefficient v/s pressure drop on shellside for various baffle systems
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37
25
35
33
20
31
15 29
27
10 25
7/24/98 9/12/98 11/1/98 12/21/98 2/9/99 3/31/99 5/20/99 7/9/99 8/28/99 3/15/00 5/4/00 6/23/00 8/12/00 10/1/00
Time Time
Fig. 7(a) Case 1: Performance of Segmental Bundles Fig. 7(b) Case 1: Performance of HELIX Bundles
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in these exchangers varied from about 24 MMBtu/hr Replacement HELIX bundles were offered targeting the
to 17 MMBtu/hr in mid-1999. The first set of HELIX original heat duty in the fourteen(14) crude preheat
bundles were installed in mid-1999. Fig 7 (b) shows the exchangers. The earlier segmental bundles required clean-
performance of these bundles after more than 6 months in ing once every year. As of Mar-2003, the HELIX bundles
operation. Between Mar-2000 and Sep-2000, the heat duty have demonstrated more than 2 years of continuous
achieved in these bundles varied from 37 MMBtu/hr. to 33 enhanced heat transfer performance. Fig 8 (a) & (b) shows
MMBtu/hr. In mid-2001, the average heat duty achieved sample data as variation of overall heat transfer coefficient
in the HELIX bundles was 29MMBtu/hr. As evident, the with time between the segmental and the HELIX bundles,
HELIX bundles achieved, on average, more than 50% in the hottest four of the crude preheat exchangers. In this
higher duty than the earlier segmental bundles. This was set of exchangers, crude is preheated from 370°F to about
a result of the significantly reduced fouling accumulation 475°F using 540°F heavy vacuum gas oil (HVGO). It is
on the heat transfer surface and the enhanced heat transfer limited by temperature cross. The helical data in Fig 8 (b)
performance achieved in the HELIX design. Evaluation after Dec 1 is to be excluded as it corresponds to a sudden
of typical mid-2001 data on the HELIX bundles showed 25% drop in crude flow rates combined with a 25°F drop
the total fouling resistance to be around 0.022 hr ft2 °F/ in HVGO inlet temperature. Although it may be observed
Btu, which was less than 50% of the fouling resistance from the graphs that the HELIX bundles show marginal
observed in the segmental bundles. The higher average improvement in the drop in overall heat transfer coef-
heat transfer performance of the HELIX bundles resulted ficient with time in the initial stages, it has since achieved
in valuable savings in fuel cost in the downstream fired and sustained an asymptotic level of performance much
heater. Inspection of these bundles in early 2002 showed higher than the performance level achieved in the earlier
little fouling on the heat transfer surface. In summary, the segmental bundles. The HELIX bundles are reportedly
HELIX bundles achieved 2-3 times longer operation run- expected to achieve more than 3 years of continuous op-
lengths between cleaning than the earlier segmental bun- eration, thus increasing the run-length by 3 times.
dles while achieving enhanced heat transfer performance. The crude overhead condenser application consists of
The feedback on the application has led to the specification four parallel trains of two shells in series. 50% capacity
of HELIX bundles in many crude preheat trains at differ- upgrade was offered for this service using helical baffles
ent facilities of this processor. in low-finned tube bundles within limited shellside pres-
sure drop. The plant has confirmed achieving the capacity
Case 2: Crude Unit, Refinery in Canada upgrade and has reported, as of Mar-2003, more than
Twenty-two(22) HELIX units are in service at this refin- two(2) years of successful continuous operation with
ery – fourteen(14) in crude preheat service and eight(8) these HELIX bundles. Earlier segmental bundles required
in crude overhead condenser service. 2-3 times cleaning in this time period. The HELIX bun-
90.0 90.0
2 Months after Start-up
80.0 80.0 Slope is 0.148 if data after
Dec.1 is excluded
Btu/hr ft2 F
Btu/hr ft2 F
70.0 70.0
60.0 60.0
50.0 50.0
40.0 40.0
Y = -0.1744x + 5491.7 Y = 0.1984x + 7388.5
30.0 30.0
8/17/01
8/24/01
8/31/01
9/7/01
9/14/01
9/21/01
9/28/01
10/5/01
10/12/01
10/19/01
10/26/01
11/2/01
11/9/01
11/16/01
11/23/01
11/30/01
12/7/01
12/14/01
12/21/01
12/28/01
9/16/00
9/30/00
10/14/00
10/28/00
11/11/00
11/28/00
12/3/00
12/23/00
1/6/01
1/20/01
2/3/01
2/17/01
3/3/01
3/17/01
3/31/01
4/14/01
4/28/01
Fig. 8(a) Case 2: Performance of Segmental Bundles Fig. 8(b) Case 2: Performance of HELIX Bundles
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(a) and (b) show photographs of the hottest and coldest
HELIX bundles after one year in operation. Insignificant
fouling was observed in the COLD bundle while uniform
scale type of fouling was observed on the heat transfer
surface in the HOT bundle. The processor has reported
extending the runlength of this unit by 3-4 times with
the application of the HELIX bundles. These bundles have
achieved 25% larger throughput within limiting hydraulic
constraints. It was also reported that the significantly
enhanced heat transfer performance
of the HELIX bundles have provided substantial additional
savings by not requiring downstream heater modifications.
Fig. 10(b) Case 4: HELIX Bundle with Uniform Fouling
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Nomenclature
E activation energy, J/mol K
Pr Prandtl number
R gas constant, J/mol K
Re Reynolds number
Rf fouling resistance, m2 K/kW
t time, s
T temperature, K
α, β, γ, δ constants in Eq. (1)
Fig. 9(b) Case 3: Hottest HELIX Bundle τw Wall shear stress, Pa
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van der Ploeg, H. J., and Master, B. I., 1996, Helically Baf-
ABOUT BERT BOXMA fled Heat Exchangers – Design Option for Reactor Feed/
Effluent Heat Exchange, Advances in Industrial Heat
Mr Bert Boxma is CEO of Heat (NLAHX) was presided over Transfer, IChemE, UK.
Transfer ABC B.V. and has by Bert for eleven years.
more than thirty-five years of After starting his career in
experience, specialised in heat Engineering, he moved into
Storey, D., and van der Ploeg, H. J., 1997, Compact ex-
exchangers. His company the Business Development changer to reduce refinery fouling, Petroleum Technology
is member of Heat Transfer of Helixchanger, an advanced Quarterly, Autumn 1997, pp. 88-89.
Research Inc. (HTRI) USA shell & tube type of heat ex-
and he has been familiar with changer. This product started van der Ploeg, H. J., and Master, B. I., 1997, A new shell-
HTRI’s software products with almost no Western and-tube option for refineries, Petroleum Technology
since 1982. references and is now globally
He holds a B.Sc. in Chemical accepted. Quarterly, Autumn 1997, pp. 91-95.
Engineering from the High He started his Company in
Technical School in Gronin- 2006. Technology Transfer Chunangad, K., and Master, B., 1998, Helixchanger:
gen The Netherlands. He was through courses is his driving malfunctioning heat exchang- Performance Enhancement with Greater Reliability,
a member of the Task Force force to teach the ABC of Heat ers using fouling mitigation First Int. Symp. on Innovative Approaches For Improv-
of ISO 16812 and ESDU’s Transfer in a mix of theory technologies. His advice is used ing Heat Exchanger Reliability, 1998, Materials Tech.
Crude Oil Fouling Working and practical aspects through to help deal with fluid induced
Party. Additionally, he was the workshops and detailed pres- vibration when the exchanger Inst. of the Chemical Process Industries, Houston, Texas,
first Chairman and founder of entations. To date more than is suffering from fluid elastic- pp. 12-21.
HTRI’s Communication Com- 1000 engineeers, representing or acoustic vibration.
mittee: CC-Holland. 250 companies have followed He has published many Chunangad, K. S., Master, B. I., Thome, J. R., and Tolba,
Bert is a guest lecturer his courses in Europe, and the articles explaining the use of M. B., 1999, Helixchanger Heat Exchanger: Single-
at three Dutch Universi- Far and Middle East countries. advanced type heat exchang-
Phase and Two-Phase Enhancement, Proceedings of the
ties (Twente, Delft, and In addition to courses, Bert ers in combination with the
Eindhoven). The Dutch Heat has provided many main end subject Total Life Cycle Cost International Conference on Compact Heat Exchangers
Exchanger Action Group users with solutions for their Analysis. and Enhancement Technology for the Process Industries,
1999, Begell House, New York, pp. 471-477.