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SCIENCE (52)

CHEMISTRY
SCIENCE Paper - 2

CLASS X

There will be one paper of two hours duration of 2. Chemical Bonding


80 marks and Internal Assessment of practical work Electrovalent, covalent and co-ordinate
carrying 20 marks. bonding, structures of various compounds,
The paper will be divided into two sections, Electron dot structure.
Section I (40 marks) and Section II (40 marks). (a) Electrovalent bonding:
Section I (compulsory) will contain short answer • Electron dot structure of Electrovalent
questions on the entire syllabus. compounds NaCl, MgCl2, CaO.
Section II will contain six questions. Candidates • Characteristic properties of
will be required to answer any four of these six electrovalent compounds – state of
questions. existence, melting and boiling points,
conductivity (heat and electricity),
Note: All chemical process/reactions should be dissociation in solution and in molten
studied with reference to the reactants, products, state to be linked with electrolysis.
conditions, observation, the (balanced) equations (b) Covalent Bonding:
and diagrams.
• Electron dot structure of non-polar
1. Periodic Properties and variations of covalent molecules on the basis of
Properties duplet and octet of electrons (example:
hydrogen, chlorine, oxygen, nitrogen,
(i) Periodic properties and their variations in carbon tetrachloride and methane.
groups and periods.
• Polar Covalent compounds – based on
Definitions and trends of the following difference in electronegativity:
periodic properties in groups and periods
Examples – HCl, NH3 and H2O
should be studied:
including electron dot structures.
• atomic size
• Characteristic properties of Covalent
• metallic character compounds – state of existence, melting
• non-metallic character and boiling points, conductivity (heat
• ionisation potential and electricity), ionisation in solution.
Comparison of Electrovalent and
• electron affinity
Covalent compounds.
• electronegativity
(c) Coordinate Bonding:
(ii) Periodicity on the basis of atomic number for • Definition
elements.
• The lone pair effect of the oxygen atom
• The study of modern periodic table up to of the water molecule and the nitrogen
period 4 and Group 2 [IIA] (students to atom of the ammonia molecule to
be exposed to the complete modern explain the formation of H3O+ and OH-
periodic table but no questions will be ions in water and NH4+ ion.
asked on elements beyond period 4 –
Calcium) The meaning of lone pair; the formation of
hydronium ion and ammonium ion must
• Periodicity and other related properties be explained with help of electron dot
to be explained on the basis of nuclear diagrams.
charge and shells (not orbitals).
(Special reference to the alkali metals, alkaline 3. Study of Acids, Bases and Salts
earth metals, halogen groups and inert gases). (i) Simple definitions in terms of the
molecules, their classification and
characteristic properties.

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(ii) Ions present in mineral acids, alkalis and (ii) Action of caustic alkalis (NaOH, KOH)
salts and their solutions; use of common on aluminium their oxides and
acid - base indicators and universal hydroxides.
indicator, pH paper to test for acidity and Self explanatory.
alkalinity.
• Examples with equation for the 5. Mole Concept and Stoichiometry
ionisation/dissociation of ions of acids, Vapour Density and its relation to relative
bases and salts. molecular mass:
• Acids form hydronium ions (only • Molecular mass = 2×vapour density (formal
positive ions) and alkalis form hydroxyl proof not required)
ions (only negative ions) with water and • Deduction of simple (empirical) and
their effect on indicators. molecular formula from:
• Definitions - Salts are formed by partial (a) the percentage composition of a
or complete replacement of the hydrogen compound.
ion of an acid by a metal or Ionic (b) the masses of combining elements.
definition of salt (To be explained with
suitable examples). 6. Electrolysis
• Introduction to pH scale to test for (i) Electrolytes and non-electrolytes.
acidity, neutrality and alkalinity by using Definitions and examples.
pH paper or Universal indicator.
(ii) Substances containing molecules only, ions
• Types of salts: normal salts, acid salt, only, both molecules and ions.
basic salt, definition and examples.
• Substances containing molecules only
4. Analytical Chemistry ions only, both molecules and ions.
(i) Action of Ammonium Hydroxide and • Examples; relating their composition
Sodium Hydroxide on solution of salts: with their behaviour as strong and weak
colour of salt and its solution; formation electrolytes as well as non-electrolytes.
and colour of hydroxide precipitated (iii) Definition and explanation of electrolysis,
from salt solutions of Ca, Fe, Cu, Zn and electrolyte, electrode, anode, cathode,
Pb; special action of ammonium anion, cation, oxidation and reduction (on
hydroxide on solutions of copper salt the basis of loss and gain of electrons).
and sodium hydroxide on ammonium
salts. (iv) An elementary study of the migration of
ions, with reference to the factors
On solution of salts: influencing selective discharge of ions
• Colour of salt and its solution. (reference should be made to the activity
series as indicating the tendency of metals,
• Action on addition of Sodium
e.g. Na, Mg, Fe, Cu, to form ions) illustrated
Hydroxide to solution of Ca, Fe, Cu,
Zn, and Pb salts drop by drop in by the electrolysis of:
excess. Formation and colour of • Molten lead bromide
hydroxide precipitated to be
highlighted with the help of • acidified water with platinum electrodes
equations. • Aqueous copper (II) sulphate with active
and inert electrodes; electron transfer at
• Action on addition of Ammonium
Hydroxide to solution of Ca, Fe, Cu, the electrodes.
Zn, and Pb salts drop by drop in The above electrolytic processes can be
excess. Formation and colour of studied in terms of electrolyte used,
hydroxide precipitated to be electrodes used, ionization reaction, anode
highlighted with the help of reaction, cathode reaction, use of selective
equations. discharge theory, wherever applicable.
• Special action of Ammonium (v) Applications of electrolysis.
Hydroxide on solutions of copper • Electroplating with nickel and silver,
salts and sodium hydroxide on choice of electrolyte for electroplating.
ammonium salts.
• Electro refining of copper.

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Reasons and conditions for electroplating; mechanism by which the back suction is
names of the electrolytes and the electrodes avoided should be learnt.
used should be given. Equations for the • Reaction with ammonia
reactions at the electrodes should be given
for electroplating, refining of copper. • Acidic properties of its solution -
reaction with metals, their oxides,
7. Metallurgy hydroxides and carbonates to give their
chlorides; decomposition of carbonates,
(i) Occurrence of metals in nature: hydrogen carbonates, sulphides,
• Mineral and ore - Meaning only. sulphites.
• Common ores of iron, aluminium and • Precipitation reactions with silver
zinc. nitrate solution and lead nitrate
(ii) Extraction of Aluminium. solution.
(a) Chemical method for purifying bauxite B. Ammonia
by using NaOH – Baeyer’s Process.
Ammonia: its laboratory preparation from
(b) Electrolytic extraction – Hall Heroult’s
ammonium chloride and collection;
process:
ammonium salts. Manufacture by Haber’s
Structure of electrolytic cell - the Process; density and solubility of ammonia
various components as part of the (fountain experiment); aqueous solution of
electrolyte, electrodes and electrode ammonia; its reactions with hydrogen
reactions. chloride and with hot copper (II) oxide; lead
Description of the changes occurring, monoxide (PbO) and chlorine; the burning
purpose of the substances used and the of ammonia in oxygen; uses of ammonia.
main reactions with their equations. • Laboratory preparation from
(iii) Alloys ammonium chloride and collection; (the
preparation to be studied in terms of,
Definition, alloys of Aluminium (only setting of the apparatus and diagram,
constituent elements), properties and uses. procedure, observation, collection and
identification (Tests).
8. Study of Compounds
Ammonia from ammonium salts using
A. Hydrogen Chloride
alkalies.
Hydrogen chloride: preparation of hydrogen
chloride from sodium chloride; refer to the The reactions to be studied in terms of
density and solubility of hydrogen chloride reactants, products, conditions and
(fountain experiment); reaction with equations.
ammonia; acidic properties of its solution. • Manufacture by Haber’s Process.
• Preparation of hydrogen chloride from • Density and solubility of ammonia
sodium chloride; the laboratory method (fountain experiment).
of preparation can be learnt in terms of
• The burning of ammonia in oxygen.
reactants, product, condition, equation,
diagram or setting of the apparatus, • The catalytic oxidation of ammonia
procedure, observation, precaution, (with conditions and reaction)
collection of the gas and identification • Its reactions with hydrogen chloride
(Tests). and with hot copper (II) oxide, lead
• Simple experiment to show the density monoxide (PbO) and chlorine (both
of the gas (Hydrogen Chloride) – chlorine in excess and ammonia in
heavier than air. excess).
• Solubility of hydrogen chloride All these reactions may be studied in terms
(fountain experiment); setting of the of reactants, products, conditions,
apparatus, procedure, observation, equations and observations.
inference.
• Aqueous solution of ammonia - reaction
• Method of preparation of hydrochloric with sulphuric acid, nitric acid,
acid by dissolving the gas in water- the hydrochloric acid and solutions of
special arrangement and the iron(III) chloride, iron(II) sulphate,
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lead nitrate, zinc nitrate and copper 9. Organic Chemistry
sulphate. (i) Introduction to Organic compounds.
C. Nitric Acid • Unique nature of Carbon atom – tetra
Nitric Acid: one laboratory method of valency, catenation.
preparation of nitric acid from potassium • Formation of single, double and triple
nitrate or sodium nitrate. Large scale bonds, straight chain, branched chain,
preparation. Nitric acid as an oxidizing cyclic compounds (only benzene).
agent. (ii) Structure and Isomerism.
• Laboratory preparation of nitric acid • Structure of compounds with single,
from potassium nitrate or sodium double and triple bonds.
nitrate; the laboratory method to be • Structural formulae of hydrocarbons.
studied in terms of reactants, products, Structural formula must be given for:
conditions, equations, setting up of alkanes, alkenes, alkynes up to 5 carbon
apparatus, diagram, precautions,
atoms.
collection and identification. (Tests)
• Isomerism – structural (chain, position)
• Manufacture of Nitric acid by
(iii) Homologous series – characteristics with
Ostwald’s process (Only equations with
examples.
conditions where applicable).
Alkane, alkene, alkyne series and their
• As an oxidising agent: its reaction with gradation in properties and the relationship
copper, carbon, sulphur. with the molecular mass or molecular
formula.
D. Sulphuric Acid
(iv) Simple nomenclature.
Large scale preparation, its behaviour as an Simple nomenclature of the hydrocarbons
acid when dilute, as an oxidizing agent when with simple functional groups – (double
concentrated - oxidation of carbon and bond, triple bond, alcoholic, aldehydic,
sulphur; as a dehydrating agent - carboxylic group) longest chain rule and
dehydration of sugar and copper (II) smallest number for functional groups rule
sulphate crystals; its non-volatile nature. – trivial and IUPAC names (compounds
• Manufacture by Contact Process with only one functional group).
Equations with conditions where (v) Hydrocarbons: alkanes, alkenes, alkynes.
applicable).
• Alkanes - general formula; methane
• Its behaviour as an acid when dilute - (greenhouse gas). Complete combustion
reaction with metal, metal oxide, metal of methane and ethane, reaction of
hydroxide, metal carbonate, metal methane and ethane with chlorine
bicarbonate, metal sulphite, metal through substitution.
sulphide.
• Alkenes – (unsaturated hydrocarbons
• Concentrated sulphuric acid as an with a double bond); ethene as an
oxidizing agent - the oxidation of carbon
example.
and sulphur.
• Concentrated sulphuric acid as a • Alkynes - (unsaturated hydrocarbons
dehydrating agent- (a) the dehydration with a triple bond); ethyne as an
of sugar (b) Copper (II) sulphate example of alkyne.
crystals. Only main properties, particularly addition
• Non-volatile nature of sulphuric acid - products with hydrogen and halogen
reaction with sodium or potassium namely Cl2, Br2 and I2 pertaining to alkenes
chloride and sodium or potassium and alkynes.
nitrate.
• Identification and Tests for both dilute
and concentrated sulphuric acid.

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INTERNAL ASSESSMENT OF hydroxide solution, make observations and
PRACTICAL WORK give your deduction. Warming the mixture may
be needed. Choose from substances containing
Candidates will be asked to observe the effect of
Ca2+, Cu2+, Fe2+, Fe3+, Pb2+, Zn2+, NH4+.
reagents and/or of heat on substances supplied to
them. The exercises will be simple and may include 3. Supply a solution of a dilute acid and alkali.
the recognition and identification of certain gases Determine which is acidic and which is basic,
and ions listed below. The examiners will not, giving two tests for each.
however, be restricted in their choice to substances 4. Add concentrated hydrochloric acid to each of
containing the listed ions. the given substances, warm, make
observations, identify any product and make
Gases: Hydrogen, Oxygen, Carbon dioxide, deductions: (a) copper oxide (b) manganese
Chlorine, Hydrogen chloride, Sulphur dioxide, dioxide.
Hydrogen sulphide, Ammonia, Water vapour,
Nitrogen dioxide. EVALUATION
Ions: Calcium, Copper, Iron, Lead, Zinc and The assignments/project work are to be evaluated by
Ammonium, Carbonate, Chloride, Nitrate, Sulphide, the subject teacher and by an External Examiner.
Sulphite and Sulphate. (The External Examiner may be a teacher nominated
Knowledge of a formal scheme of analysis is not by the Head of the school, who could be from the
required. Semi-micro techniques are acceptable but faculty, but not teaching the subject in the
candidates using such techniques may need to adapt section/class. For example, a teacher of Chemistry
the instructions given to suit the size of the apparatus of Class VIII may be deputed to be an External
being used. Examiner for Class X Chemistry projects.)
Candidates are expected to have completed the The Internal Examiner and the External Examiner
following minimum practical work:
will assess the assignments independently.
1. Action of heat on the following substances:
(a) Copper carbonate, zinc carbonate Award of Marks (20 Marks)
(b) Zinc nitrate, copper nitrate, lead nitrate Subject Teacher (Internal Examiner) 10 marks
(c) Hydrated copper sulphate External Examiner 10 marks
Make observations, identify the products and The total marks obtained out of 20 are to be sent to
make deductions where possible (equations not the Council by the Head of the school.
required).
The Head of the school will be responsible for the
2. Make a solution of the unknown substance: add online entry of marks on the Council’s CAREERS
sodium hydroxide solution or ammonium portal by the due date.

NOTE: According to the recommendation of International Union of Pure and Applied Chemistry
(IUPAC), the groups are numbered from 1 to 18 replacing the older notation of groups IA …. VIIA, VIII,
IB …… VIIB and 0. However, for the examination both notations will be accepted.
Old IA IIA IIIB IVB VB VIB VIIB VIII IB IIB IIIA IVA VA VIA VIIA 0
notation
New 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
notation

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