Safety data sheet AkzoNobel a Accor ing to Regulation (EC) No. 1907/2006 BUTANOX M-60 ‘IDENTIFIGATION OF THE SUBSTANCE OR PREPARATION AND THE COMPANY/UNDERTAKING Product Identifier Methyl ethy! ketone peroxide, solution in dimethyl phthalate [Supplier [Akzo Nobel Functional Chemicals BV. Stationsstraat 77, PO Box 247 NL-3800 AE Amersfoort The Netherlands HT +31 334676767 | wwww.akzonobel.com/polymer [E-mail address of person responsible for safety data sheet RegulatoryPC@akzonobel.com ‘Emergency telephone ‘AkzoNobel Chemicals-Deventer-NL T +31 570 678211 F +31 670 679801 Relevant identified uses of the substance or mixture Curing agent Date of last iseue / Revision number 2013/05/14 13.45 ‘Chemical family peroxides REACH Registration number [01-2119514691-43 2, HAZARDS IDENTIFICATION May cause fre. Harmful if swallowed. Causes burs, [GHS classification [Description [Applicable (Organic peroxide Type D [Acute toxicity (inhalation) category 4 [Acute toxicity (oral) category 4 Eye irritation [category 7 [Skin corrosion! tation [category 18 Pictogram(s) (GHS) Product code 654291 Dae fet ine 012866 Paget - 11 me tpt iepnanted 2140119 GB.GermanySafety data sheet __AkzoNobel J,” According to Regulation (EC) No. 1907/2008, Signal word/Hazard statomont(s) GHS (Code Description ‘Signal word DANGER F243. Heating may cause a fre. 1302, Harmful f swallowed, Hata. Causes severe skin burns and eye damage. 1332, Harmful inhaled, Precautionary statements) (GHS) (Code Description F210. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources, No smoking, P2200 Keep away from din, rust, chemicals in particular. F284, ‘Keep only in original container. P2606, Do not breathe vapours. P2648, [Wash hands and contaminated skin thoroughly after handing, P270, Do not eat, drink or smoke when using this product. Part Use only outdoors or in a well-ventilated area P2606. Wear protective gloves, eyelface protection and protective clothing, P301+PS30°PS3T, TF SWALLOWED: Rinse mouth, Do NOT induce voriting, PA0S"P361+PSSS. TF ON SKIN (or hain): Take off immediately all contaminated clothing. Rinse skin with water. Pad P40, TF INHALED: Remove vicin to fresh air and Keep at rest in a positon comfortable for breathing PO05+P51+ POSE. TF IN EYES: Rince cautiously with water for soveral minutos, Remove contact, lenses, if present and easy to do. Continue rinsing. P30, Tmmediately call a POISON CENTER or doctoriphysican, P3784 Use waterspray, foam, sand, dry chemical powder or CO2 for extinction. P403+P235, ‘Sore in a well-ventilated place. Keep cool PAO, Protect from sunlight. P5Dta Dispose of contents and container according to local regulation, 3, COMPOSITION/INEORMATION ON INGREDIENTS This product is to be Considered as a preparation in conformance to EC directives. Information on hazardous ingredients ‘Chemical description Methyl ethy ketone peroxide, solution in dimethy! phthalate [Composition / information on ingredients Number _[%wiw CAS-numbor Chomical namo i 55-70 Dons ATS Dimethy! phthalate 2 [30-39 (001336284 Methyl ethyl ketone peroxide a 1-5 joo078-93:3 Methyl ethyl Ketone Product code 654291 Date ot st nue ZH 4 Page 2 - 11 batt pining ie gerented 204003 GB.GermanySafety data sheet AkzoNobel iL” According to Regulation (EC) No. 1907/2006 REACH — | ECmumber | Glasafeaton according to Registra ‘arate oe amended 7 praties [ROS0TT6 | GHS cassTicaon Tone 37220.96 2 for-zttes |zisest2 [orancperoase TypeD | HaazrsozHsi2 [COROT RIZRS 14891-43 HBI4 HS3t Rate Tox (raaton) [category 3 este text (oral) category 4 Acute txt (dermal) category Eye ration catego [Skin coresion/ tation | eatogory 78 a 201630 | Flammabie nauis catepoy2 | Ha2s HaTOHGSG | FXIRTI ASG ROG R67 Eye tation category Target ogan. single exposure [categorys ‘Other information Balance: non-hazardous ingredients. 4. FIRST AID MEASURES Most important symptoms and effects Harmful if swallowed. Causes burns. Causes injury tothe cornea and eyelids. Risk of serious damage to eyes. Description of first aid measures General Call a physician immediately. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Oxygen may additionally be given, by trained personnel, ifitis available, Get medical attention immediatoy, ‘Skin Immediately start continuous flushing of skin with water for at least 16 minutes, while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse, Thoroughly clean or destroy contaminated shoes. Eye Immediately start continuous fushing of eyes with water for at least 15 minutes. If easy to do, contact lenses should be removed during the flushing, by trained personnel. Hold the eyelids apart during the fushing to [ensure rinsing the entre surface of the aye and lids with water. Get mecical attention immediately. ingestion 'DO NOT induce vomiting. Get medical attention immediately by calling a physician or a poison control center. If Victim is conscious and alert, give a cupful of water. Never give anything by mouth to an unconscious or Convuising person. If vomiting occurs, the patient should lie on their left side while voriting to reduce the risk of aspiration Indication of any immediate medical attontion and special treatment needed Persons with pre-existing skin, respiratory, andlor central nervous system disease may be at increased risk if exposed to this material. This material is severely corrosive to the eyes and may cause delayed keratitis. The normally prescribed 15 minute eye irrigation after exposure may be diffcult because of the severe pain, The prior installation of a topical ocular anesthetic is essential to facilitate a comprehensive ocular lavage. If swallowed, do not induce vomiting. Give patient plenty of water to drink. Ingestion ofthis corrosive material may result in severe ulceration, inflammation, and possible perforation ofthe upper alimentary trac, with hemorrhage and fluid loss. Aspiration ofthis material during induced lemesis can result in severe lung injury. Contact @ Poison Control Center for addtional treatment information. Treat any additional effects symptomatically. 5. FIRE-FIGHTING MEASURES Product code 654291 Dae ans 2000544 Pages - 11 ate otptotegpat te series 24033 GB.Germany.Safety data sheet AkzoNobel ¥,/” According to Regulation (EC) No. 1907/2008 Extinguishing media ]waterspray, alcohol resistant foam, sand, dry chemical powder, CO2, Unsuitable extinguishing medi halones. [Hazardous decomposition / combustion products ‘C02, Carson monoxide ‘Acetic acid, Formic acid, Propanoic acid, Methy! ethyl ketone, Protective equipment Firefighters must wear fire resistant protective equipment. Wear approved respirator and protective gloves. Other information Evacuate all non-essential personnel. Extinguish a small fire with powder or carbon dioxide then apply water to prevent re-ignition. Cool closed containers with water. Water used to extinguish a fre should not be allowed to enter the Jorainage system or water courses. After a fre, ventiiate thoroughly the area and soak with water, clean the walls and metalic suraces. Fire and explosion hazard ‘CAUTION: reigntion may occur. Decomposition under effect of heating (See also Section Hazardous decomposition Products). If involved in a fire, it will support combustion. Vapours may form explosive mixtures with ar. In case of fre andlor explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Do not breathe fumestvapour. Avid contact with skin and eyes. For personal protection see Section & Environmental precautions 1 not alow to enter drains or water courses. ‘Methods and materia for containment and cleaning up Stop leakage if possible. Eliminate all sources of ignition, and do not generate flames or sparks. Transfer remaining produc fom leaking container to clean and suitable container. Cover the remainder with inert absorbent (e.g vermiculte) for disposal. Keep contents moist. The waste should NOT be confined. lush surroundings with arge [amounts of water [Other information ‘CAUTION: reigniton may occur. Vapours are heavier than air and may spread along foors. Vapoure may travel to a source ofigniion and fash back. Evacuate personnel to safe area 7. HANDLING AND STORAGE, Precautions for safe handling Never weigh out in the storage room. When using do not eat, drink or smoke. Do not pipet by mouth. Do not breathe umesivapour. Handle in wal ventilated areas. Eliminate all sources of ignition, and do not generate flames or sparks, Keep away from reducing agents (e.g. amines), acids, akalies and heavy metal compounds (e.g. accelerators, driers, /metal soaps). Keep product and emptied container away from heat and sources of ignition. Confinement must be avoided. Avoid contact with skin and eyes. Avoid Incompatible materials (See Section 10). Fire and explosion prevention Use explosion protected equipment. Keep away fom sources of ignition - No smoking, Vapours are heavier than air [and may spread along floors. Use non-sparking toois in area's where exolosive vapor air mixtures may occur. Do nat [cut or weld on or near this container even when empty. [Conditions for safe storage Store in accordance with localinational regulations. Keep away from food, drink and animal feedingstutfs. Store in @ dry well ventilated place away from sources of heat and direct sunlight, Store separate from other chemicals. Keep only inthe original container. Keep container upright to prevent leakage, ‘Storage recommendations Lagerklasso 5.2 - Organische Poroxide und selbstzersetzliche Getahretoffe (TRGS 510), [Storage For maximum quality store below. 25 [Other information It is recommended to use electrical equipment of temperature group 3. However, autcignition can never be excluded, \Wash hands thoroughly ater handling or contact. Keep working clothing separately and do not take them home, 8, EXPOSURE CONTROLS/PERSONAL PROTECTION Product code 654201 De fa nse 2086 Paged = 11 Dae opiate peated 01400" GB.GermanySafety data sheet AkzoNobel ¥,/” According to Regulation (EC) No. 1907/2006 [Control paramotors Ensure good ventilation and local exhaustion ofthe working area. Explosion proof ventlation recommended. Personal protection Respiratory In case of insufficient ventilation wear suitable respiratory equipment (respirator with Filter A) Hand Wear suitable protective gloves of neoprene or synthetic rubber. Eye Wear eyerface protection ‘Skin and body Wear suitable protective clothing ‘Other information Emergency-shower and facilis for rinsing eyes must be accessible. Launder clothes before reuse. ‘Methyl ethyl Ketone peroxide ‘Arbeitsplatagrenzwert (AGW) vgl Abschnitt, Via DNEL [Worker DNEL long term inhalation systemic (mgim3): 7.0 Worker DNEL long term dermal systemic (mg/kg bwiday): 1.08 General population DNEL long term inhalation systemic (mgim3): 0.41, General population DNEL long term dermal systemic (mg/kg bwiday): 0.54 General population DNEL long term oral systemic (mghkg bw/day) 0.27 PNEC NEC fresh water (mall 0.0056 PNEC marine water (mgf}: 0.00056 NEC intermittent release (mil): 0.056 PNEC Sewage Treatment Plant (mg/): 1.2. PNEC sediment fresh water (mg/kg): 0.019 PNEC sediment marine (mafxg): 0.0019 PNEC soil (mg/kg): 0.00231 Methyl ethyl ketone Emfehlung Arbeltsplatzgrenzwert 200 ppm (AGW) Emfehlung Arbelisplaizgrenzwert 600 maim" (AGW) TRGS 800 Arbeltsplatzgrenzwert 200 ppm (AGW) TRGS 800 Arbellsplatzgrenzwert 600 - maim (acm) Limit Values: Skin designation Potential for cutaneous absorption Emfehlung Arbelisplatzgrenzwer, 200 ppm Spitzenbegrenzung Emfehlung Arbelisplatzgrenzwer, 600 main" [Spltzenbegrenzung 9. PHYSICAL AND CHEMICAL PROPERTIES [Appearance feloar liquid [colour colourless [Odour aint Product code 654291 Date ttt eee sore Pages - 11 ano pking egret 204013 GB-GermanySafety data sheet ‘According to Regulation (EC) No. 1907/2006 AkzoNobel ad Boiling pointrango not applicable (Decomposes) ‘Melting pointfroezing point Soliiies at or below 10°C / 14°F Flash point [Above the SADT value Flammability Decomposition products may be flammable. Explosive properties Ro Oxidising properties ot applicable Vapour pressure ot determined Density 1170 kglm (20°C /68°F) Specific gravity = 1.17 (20°C / 68°F) Bulk density ‘not applicable ‘Solubility in water Party miscible with water (20°C / 68°F) [Solubility in other solvents Miscible with phthalates (20°C / 68°F) [pH value slightly acidic Partition coefficient n-octanoliwater not determined Relative vapour density (air=1) ot determined Viscosity [25 mPa.s (20°C / 68°F) [Active oxygen content 9.8 -10.0% Peroxide content 36.% [Autoignition temperature Test method not applicable (See Section 7) SADT 160 °C. See also Section 10. Upperilower flammability or explosive limits not determined Volatile % Not determined 40. STABILITY AND REACTIVITY [Chemical stability ‘SADT - (Seif accelerating decomposition temperature) Is the lowest temperature at which self accelerating Jdecompositon may occur with a substance in the packaging as used in transport. [A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion o fre can be caused by thermal decomposition at and above the following temperature: 60 °C. Contact with incompatible substances can cause decomposition at or below the SADT 60 °C. Product code 654291 ate of printing pt le erated 18013 GB-GermanySafety data sheet AkzoNob cle According to Regulation (EC) No. 1907/2006 Conditions to avoid To maintain quaily store in orginal Closed container below. 25°C. Confinement must be avoided. [incompatible materials ‘Avoid contact with rus, iron and Copper. Contact with incompatible materials such as acids, alkalies, heavy metals, ‘and reducing agents wil result in hazardous decomposition. Do not mix with peroxide accelerators. Use only Stainless stee! 316, PP, polyethylene or glass-lined equipment. Contact Akzo Nobel for more information. Possibility of hazardous reactions. Polymerization does not occur. Hazardous decomposition products Hazardous decomposition preducts; Acetic acid, Formic acid, Propanoie acid, Methyl ethyl Ketone, (Other information [Emergency procedures wil vary depending on conditions. The customer must have an emergency response plan in place. Contact Akzo Nobel for assistance with developing an emergency response plan. 41, TOXICOLOGICAL INFORMATION. ‘No experimental toxicological data on the preparation as auch avaliable. The folowing data are applicable to the ingredients) listed below. Dimethyl phthalate [Acute toxicity (Oral LDSO rat >2400 mg/kg Dermal LOSO rabbit: 10,000 malkg Inhalation LC50 9300 mg/m? (6.5 hours ) Irritation ‘Skin Milly iitating Eyo Minimally iitating [Methy! ethyl ketone peroxide, 40 % in Dimethyl phthalate [Acute toxicity (Oral LDS0 rat-1017 mag Dermal LD50 rat4000 mg/kg Inhalation LC5O rat'17 mall 4 hours exposure time iritation ‘Skin Corrosive Bye [Corrosive ‘Sensitization Not sensitizing ‘Genotoxicity ‘Ames test: Not mutagenic [Methyl ethyl ketone Product code 654291 ake fat nae 200514 Page? - 11 Date erpsntagpat ie ynentes 214043 GB.GermanySafety data sheet a ___AlzoNobel J,” According to Regulation (EC) No. 1907/2008 BUT, ‘Acute toxicity ‘Oral LDSO rat: 2737 mgikg Dermal LD5O rabbit 6480 moka Inhalation LC50 Fat 23.5000 mgien® Irritation ‘Skin Moderately initating Eye Moderately iritating 412. ECOLOGICAL INFORMATION [No experimental ecological data are avallable on the preparation as such, The following dati are apalicable fo the ingredients) listed below. Dimethyl phthalate Ecotoxicity Tish Lepomis macrochirus: 96h-LC50: 420 ppm algae Selenastrum capricornutum: 38.8 mg/l ( 96h-IC50 ) Fate Degradation Biotic Readily biodegradable, (Other information| Bio Concentration Factor (BCF) fish 5.4 (24 hours ) Methyl ethyl Ketone peroxide, 40 % in Dimethyl phthalate [Ecotoxicity fish Acute toxicity, 96h-LO5t bacteria Activated siudge respiration inhibition test EC50 = 48.0 maf Fate Degradation Biotic Readily biodegradable ( Closed bottie test). [Methyl ethyl ketone Ecotoxicity fish Lepomis macrochirus: 96h-LC50: 3.22 gf Fate Degradation Biotic Readly biodegradabie, [Other information [Naturally occuring substance 14.2 mg/l. ( Poesia reticulata.) 13, DISPOSAL CONSIDERATIONS Product [Due tothe high risk of contamination recycting/recovery is not recommended. Waste disposal in accordance with regulations (most probably controled incineration). Product code 654201 ue tise are Pages - 11 Dae opine preted 2010009 GB.GermanySafety data sheet AkzoNobel 7 ‘According to Regulation (EC) No. 1907/2008 Contaminated packaging According to local regulations. Emptied container might retain product residues. Follow all wamings even after the Container Is emptied. Other information For further advice contact manufacturer “14, TRANSPORT INFORMATION [Lend transport Transport hazard class 52. (Classification Code PA RID lass 52 ‘Substance Identification No. 3105 UN number 3105 Proper Shipping Name ORGANIC PEROXIDE, TYPE D, LIQUID ( Methyl ethyl Ketone peroxide ) Tunnel code D Required labels 52 ‘Sea transport (IMO IMDG-code) Transport hazard class. 52. [UN number: 3105 EMS Fx, SR Marine pollutant Proper Shipping Name Organic peroxide type 4, iquid_( Methyl ethyl Ketone peroxide ) [Other information Labels): 5.2 [Air transport ((CAO-T17ATA-DGR) UN number 3105, Transport hazard class 52. Proper Shipping Name (Organic peroxide type 4, quid (Methyl ethyl ketone peroxide ) (Other information| Labels): 5.2 415, REGULATORY INFORMATION Product code 654291 Diet et ieve corr Pago - 11 Dae ot pring gerarted 008. GB.GermanySafety data sheet AkzoNobel ¥,/” According to Regulation (EC) No. Product labo! nat Methyl ethy! ketone peroxide, solution in dimethyl phthalate 1907/2006 Labelling according to EC directives EG-number ot applicable [R(isk) phrase(s) (EU classification) (Code Description ROT. Nay cause fre. R22. Harmful if swallowed, RGA Causes burns: S(afety) phrase(s) (EU classification) Code Description 503/07. Keep container tighty closed in a cool place: S148, Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds (2-9. accelerators, driers, metal soaps). 326. Tn case of contact with eyes, rinse immediately wih plenty of water and seck medical advice. S36/37/98, [Wear suitable protective clothing, gloves and eye/face protection. 345. Tn case of accident or if you Teel unwell, sesk medical advice immediately (show the label where possible), $500. Do not mix with peroxide-accelerators or reducing agents, (Classification according to 67/648/EC as ammended = id CORROSIVE (C)__ OXIDISING (0) [Other information Substance and/or product listed in Directive 96/82/EC. 1 (Vin\iwS Anhang 4 Nr. 3) [German Water Hazard Class (WGK) [Hinweise zur Beschaftigungsbeschrankungen Jugendarbeitschutzgesetz Paragraph 22 beachten. Klassifiziorung nach Betriebssicherheltsverordnung Nicht untorstel gema Paragraph 2 (1) Zi 3b. Technische Anloitung Luft 5.2.5 Organic compounds : max. 0,50 kglh or 50 mg/m* Product code 654291 bat oat sue 01 GB-Germany Page 10 - 11Safety data sheet __AkzoNobel J,” ‘According to Regulation (EC) No. 1907/2006 GV 84 Gefahrgruppe lb (UW, BGV 84). 48. OTHER INFORMATION [Relevant hazard statements (Chemical name Hazard statoment(s) (GHS-classifeat on) Methyl ethyl Ketone peroxide 242, Heating may cause a fre 7302. Harmful if swallowed. 7312, Harmful in contact with skin. 314, Causes severe skin bums and eye damage, E31 Tox if innaled Methyl ethyl Ketone 1225, Highly flammable liquid and vapour 1318, (Causes serious eye iitation, Ha6, May cause drowsiness or dizziness, [R-phrase information ‘Chemical name Risk) phrase(s) (eu classification) Dimethyl phihalate [none Tone Methyl ethyl Ketone peroxide: RO May cause fre R22 Harmful f swallowed Raa [Causes burns [Methyl ethyl ketone Rit [Highly flammable R36 ritating to eyes R85 [Repeated exposure may cause skin dryness or cracking Re? ‘Vapours may cause drowsiness and dizziness, History [Date of printing? af file generated 201410113 Revision 3.45 [Composed by Regulatory Affairs - Europe. [Changes were made in section [Annex (EU) "retin oy Sa Si TES GA wd Tran Db aT nega SSSR ona RRS Te RESINS POT ntaape nro escort an por ngoos sures mara. vas ean som egotism setae ae ‘Si he pees ne spe Product code 654291 Dae fst noe ote Page tt - 11 Dt ot pte gerartes 204003 GB.Germany