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5/14/13 CHLORIDE ATTACK ON CONCRETE STRUCTURES

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Chloride Attack on Concrete Structures:


CONSTRUCTION EQUIPMENT
Chloride attack is one of the most important aspects for consideration when we deal with
the durability of concrete. Chloride attack is particularly important because it primarily
CONSTRUCTION MANAGEMENT
causes corrosion of reinforcement. Statistics have indicated that over 40 per cent of failure
of structures is due to corrosion of reinforcement.
GENERAL CONTRACTORS
Due to high alkalinity of concrete a protective oxide film is present on the surface of steel
reinforcement. The protective passivity layer can be lost due to carbonation. This protective MECHANICAL ENGINEERING
layer also can be lost due to the presence of chloride in the presence of water and oxygen.
In reality the action of chloride in inducing corrosion of reinforcement is more serious than ENGINEERING DESIGN
any other reasons. One may understand that Sulphates attack the concrete whereas the
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chloride attacks steel reinforcements.

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Chloride enters the concrete from cement, water, and aggregate and sometimes from
admixtures. The present day admixtures are generally containing negligible quantity of
chloride or what they call chloride free. Chloride can enter the concrete by diffusion from
environment. The Bureau of Indian Standard earlier specified the maximum chloride content
in cement as 0.05 percent. But it is now increased the allowable chloride content in cement
to 0.1 per cent. I S 456 of 2000 limits the chloride content as (Cl) in the concrete at the
time of placing is shown in table-1.

theconstructor.org/concrete/chloride-attack-on-concrete-structures/7802/ 1/2
5/14/13 CHLORIDE ATTACK ON CONCRETE STRUCTURES
Table-1: Limits of Chloride Content of Concrete (IS 456 of 2000)

Maximum Total acid


soluble chloride
S.No. Type of Use of Concrete content. Expressed
as
kg/m3 of concrete
1 Concrete containing metal and steam cured at
elevated temperature and prestressed 0.4
concrete.
2 Reinforced concrete or plain concrete
containing embedded metal. 0.6

3 Concrete not containing embedded metal or


any material requiring protection from chloride. 3.0

The amount of chloride required for initiating corrosion is partly dependent on the pH value
of the pore water in concrete. At a pH value less than 11.5 corrosion may occur without the
presence of chloride. At pH value greater than 11.5 a good amount of chloride is required.

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