Worksheet@Organic 15 To 18

Organic Chemistry Work Sheet - 15
Topic- Preparation of Alkanes & Ozonolysis Reaction
S.No. Reaction Product
Pd
1. CH3–CC–CH3 + 2H2 

2H / Ni
2. CH2=CH–CH=CH2 
2

Ni
3. + H2 
Zn  Hg / conc.HCl
4. CH3CH2CHO      


O Zn  Hg / conc.HCl
5.      


NH NH / KOH
6. CH3–COCH3  
2
2  


Na
7. CH3 – CH2 – Br 

dry ether
CH CH Cl
8. (CH3CH2)2CuLi 
3
2
Anhy d. AlCl
9. CH3CH2CH2CH2CH3    
3

HCl
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Page No. - 1
ANSWER KEY
1. CH3–CH2–CH2–CH3 2. CH3–CH2–CH2–CH3 3.
4. CH3CH2CH3 5. 6. CH3CH2CH3
CH3
7. CH3 – CH2 – CH2 – CH3 8. CH3CH2CH2CH3 9. CH3CHCH2CH3 + CH3CCH3
CH3 CH3
Page No. - 2
Topic- Preparation & Chemical reaction of Alkenes
S. No. Reaction Products
KOH(alc)
1. CH3–CH2–CH2–CH2
Br
OH
2. 60%H SO
CH3–CH2–CH–CH3 
2 4

100C
CH3
3. Al2O3
CH3–CH–CH2–OH 
H SO , 
CH3–CH–CH3 2 
4

4.
OH
5. CH3–CH=CH–CH3 + HBr
6. H O / H
CH3–CH=CH–CH3 2  

HBr
7. CH3–CH=CH2 
R2O2 / h
CCl
8. CH3–CHCH2 + Br2 
4

CH3
9. CH3–C–CH=CH2 Hg(OAc)2 ,H2O
NaBH4
CH3
CH3
10. (BH3)2 H2O2, OH
–
CH3–C=CH2
Page No. - 3
ANSWER KEY
KOH(alc)
1. CH3–CH2–CH2–CH2 CH3–CH2–CH=CH2
Br
OH
 CH3–CH=CH–CH3
60%H2SO4
2. CH3–CH2–CH–CH3 
100C
CH3 CH3
Al2O3
3. CH3–CH–CH2–OH  CH3–C=CH2
Zn dust, Alcohol 
4. CH3–CH–CH3 
 CH3–CH=CH2
OH
5. CH3–CH=CH–CH3 + HBr CH3–CH–CH2–CH3

Br
+
H2O/H
6. CH3–CH2=CH2–CH3 CH3–CH–CH2–CH3
OH
HBr
7. CH3–CH=CH2  CH3–CH2–CH2
R O / h
2 2
Br
CCl
8. CH3–CHCH2 + Br2 

4
 CH3–CH–CH2
Br Br
CH3 CH3
Hg(OAc)2 ,H2O
9. CH3–C–CH2=CH2 NaBH4 CH3 C CH CH3
CH3 CH3 OH
CH3 CH3
–
(BH3)2 H2O2, OH
CH3–C=CH2
10. CH3–CH–CH2–OH
Page No. - 4
Topic- Preparation & Chemical reaction of Alkynes
H H
2NaNH
1. CH3–CH2–C–C–CH2–CH3 
2

Br Br
Br Br
2. CH3–CH2–C–C–CH2–CH3 

Br Br
3. 2Ph–CCl3 + Ag 
CCl
4. CH3–CCH + Cl2 
4

5. C2H5–CC–C2H5 + HBr 
( excess )
6. Hg2 / H SO
CH3CCCH3 + H2O   2
4

7. B H / H O – OH–
CH3–CCH 2 
6
22 
HgSO , H SO
8. Ph–CC–Ph + H2O  
4 2 4

conc. HNO
9. 
3

conc. H2SO 4
Page No. - 5
ANSWER KEY
H H
2NaNH
1. CH3–CH2–C–C–CH2–CH3 
2
 CH3–CH2–CC–CH2–CH3
Br Br
Br Br
2. CH3–CH2–C–C–CH2–CH3 
 CH3–CH2–CC–CH2–CH3
Br Br
3. 2Ph–CCl3 + Ag  Ph–CC–Ph + AgCl
CCl
4. CH3–CCH + Cl2 

4
 CH3–CCl2–CHCl2
Br
5. C2H5–CC–C2H5 + HBr C2H5–CH2–CC2H5
( excess)
Br
O
CH3CCCH3 + H2O  CH3–C–CH2–CH3
H2SO 4
6.
B H / H O – OH –
7. CH3–CCH 2 6
22  CH3CH2–CHO
HgSO , H SO
8. Ph–CC–Ph + H2O 
4

2

4
 Ph–C–CH2–Ph
O
NO2
conc. HNO
9. 
3

conc. H2SO 4
Page No. - 6
Topic- Preparation & Chemical reaction of Benzene
+ HC
HC CH Re d hot tube
1.    
HC CH 1500 – 2000 º C
+ HC
OH
2. Distillation
+ Zn 
COONa
3. CaO
+NaOH 
Heat
4. + Br2 / AlCl3 
5. + CH3Cl / AlCl3 
CH3
6. H SO (Conc .)
+ HNO3 2  
4
 
( Conc .) 50 º C
AlCl
7. + Cl2 
3

or FeCl3
AlCl
8. + CH3–CH2–Cl 
3

O
AlCl
9. + CH3–C–Cl 
3

Acetyl chloride
Benzene
Page No. - 7
ANSWER KEY
+ HC
HC CH Re d hot tube
1.    
HC CH 1500 – 2000 º C
+ HC
OH
Distillation
2. + Zn  + ZnO
Benzene
COONa
CaO
3. +NaOH  + Na2CO3
Heat
Br
4. + Br2 / AlCl3 

CH3
5. + CH3Cl / AlCl3 

CH3 CH3 CH3
NO2
H SO (Conc .)
6. + HNO3 2  
4
  + + H2O
( Conc .) 50 º C
NO2
Cl
AlCl
7. + Cl2 
3

or FeCl3
Chlorobenzene
CH2–CH3
AlCl
8. + CH3–CH2–Cl 
3
 + HCl
O
O C
AlCl CH3
9. + CH3–C–Cl 
3
 + HCl
Acetyl chloride
Benzene
Page No. - 8

Worksheet@Organic 15 To 18

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Worksheet@Organic 15 To 18

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Organic Chemistry Work Sheet - 15

Topic- Preparation of Alkanes & Ozonolysis Reaction

S.No. Reaction Product

S. No. Reaction Products

5. CH3–CH=CH–CH3 + HBr CH3–CH–CH2–CH3

S.No. Reaction Product

3. 2Ph–CCl3 + Ag  Ph–CC–Ph + AgCl

S.No. Reaction Product

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