methanol(1)+water(2)

R T(K) P1sat 84.562

1 333.15 P2sat 19.953
r 1.4311 0.92
q 1.432 1.4
Binary interactions 0 0 It is common to report UNIQUAC binary interaction parameters as a12/R
0 0 In this case, use R=1 in the spreadsheet; otherwise use units compatible

Experimental data for the mixture. These 2 columns were calculated

with array function uniquac.
x1exp x2exp y1exp y2exp Pexp(kPa) lngama1
0 1 0 1 19.953
0.1686 0.8314 0.5714 0.4286 39.223
0.2167 0.7833 0.6268 0.3732 42.984
0.3039 0.6961 0.6943 0.3057 48.852
0.3681 0.6319 0.7345 0.2655 52.784
0.4461 0.5539 0.7742 0.2258 56.652
0.5282 0.4718 0.8085 0.1915 60.614
0.6044 0.3956 0.8383 0.1617 63.998
0.6804 0.3196 0.8733 0.1267 67.924
0.7255 0.2745 0.8922 0.1078 70.229
0.7776 0.2224 0.9141 0.0859 72.832
1 0 1 0 84.562
 AC binary interaction parameters as a12/R, a21/R, etc… in Kelvin.
preadsheet; otherwise use units compatible with the aij values.

2 columns were calculated These final columns were calculated with spreadsheet formulas.
rray function uniquac.
lngama2 gama1 gama2 Pcalc(kPa) deltaP deltaP^2 y1calc y2calc

Objective: Sum(deltaP^2)

Hint: use Solver to minimize the objective function cell

changing the two cells that correspond to the binary
interaction parameters of the UNIQUAC model.
ve function cell
to the binary