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1
Which of the following crystals does not exhibit Frenkel defect?
A AgBr
B AgCl
C KBr
D ZnS
1
Which of the following crystals does not exhibit Frenkel defect?
A AgBr
B AgCl
C KBr
D ZnS
● Frenkel defect is occurred in those ionic crystals in which sizes of ions
(anions and cations) show large differences.
● Compounds such as KBr show Schottky defect.
2
Which of the following statement is not true about amorphous solids?
A Rock salt
B Ice
C Quartz
D Dry ice
3
Which one of the following is a covalent crystal?
A Rock salt
B Ice
C Quartz
D Dry ice
(SiO2) Quartz is a covalent crystal
4
For tetrahedral arrangement, the radius ratio r+/r- is
A 0.732 - 1.0
B 0.225 - 0.414
C 0.414 - 0.732
D 0.155 - 0.225
4
For tetrahedral arrangement, the radius ratio r+/r- is
A 0.732 - 1.0
B 0.225 - 0.414
C 0.414 - 0.732
D 0.155 - 0.225
Radius Ratio Coordination No. Structure Example
0.225 – 0.414 4 Tetrahedral ZnS
5 A given metal crystallises out with a cubic structure having edge length
of 361 pm. If there are four metal atoms in one unit cell, then the radius
of one atom is
A 80 pm
B 108 pm
C 40 pm
D 128 pm
5 A given metal crystallises out with a cubic structure having edge length
of 361 pm. If there are four metal atoms in one unit cell, then the radius
of one atom is
A 80 pm
B 108 pm
C 40 pm
D 128 pm
6
The crystal system of a compound with unit cell dimensions a = 0.387,
b = 0.387 and c = 0.504 nm and α = β = 90o and 𝝲 = 120o is
A Cubic
B Hexagonal
C Orthorhombic
D Rhombohedral
6
The crystal system of a compound with unit cell dimensions a = 0.387,
b = 0.387 and c = 0.504 nm and α = β = 90o and 𝝲 = 120o is
A Cubic
B Hexagonal
C Orthorhombic
D Rhombohedral
7 If NaCl is doped with 10-4 mol % of SrCl2, the concentration of cation
vacancies will be
(NA = 6.02 x 1023 mol-1)
A Z
B 2Z
C Z/2
D Z/4
8 If Z is the number of atoms in the unit cell that represents the closest
packing sequence ….ABC ABC….., the number of tetrahedral voids in
the unit cell is equal to
A Z
B 2Z
C Z/2
D Z/4
9 Assertion: bcc and hcp has same packing efficiency.
Reason: Both have same number of atoms per unit cell and same
arrangement.
A 3 × 1025
B 5 × 1024
C 1 × 1025
D 2 × 1025
10
The number of atoms in 100 g of an fcc crystal with density d = 10 gcm-3
and cell edge as 200 pm is equal to
A 3 × 1025
B 5 × 1024
C 1 × 1025
D 2 × 1025
11
A solid AB has NaCl type structure. The radius of A+ is 100 pm. What is
the radius of B-?
A 190.47
B 540.13
C 525
D 78.12
11
A solid AB has NaCl type structure. The radius of A+ is 100 pm. What is
the radius of B-?
A 190.47
B 540.13
C 525
D 78.12
12 Assertion: Due to Frenkel defect, density of the crystalline solid
decreases.
Reason: In Frenkel defect, a cation or an anion leaves the crystal.
A 0.96
B 0.04
C 0.50
D 0.31
13 Formula of metal oxide with metal deficiency defect in its crystal is
A0.8O. The crystal contains A2+ and A3+ions. The fraction of metal existing
as A2+ ions in the crystal is
A 0.96
B 0.04
C 0.50
D 0.31
14 Assertion: Monoclinic sulphur is an example of monoclinic crystal
system.
Reason: For a monoclinic system, a ≠ b ≠ c and 𝝰 = 𝛄 = 90o, 𝛃 ≠ 90o.
A XY
B X 2Y 3
C X7Y24
D X 3Y 5
15 An ionic compound made up of atoms X and Y has a fcc arrangement in
which atoms X are at the corner and atoms Y are at the face- centres. If one
of the atoms is missing from the corner, what is the simplest formula of the
compound ?
A XY
B X 2Y 3
C X7Y24
D X 3Y 5
CASE1: Read the passage given below and answer the following questions 16-18
A ABC ABA
B ABC ABC
C ABABA
D ABBABB
16
Which of the following describes the hexagonal close packed
arrangement of spheres ?
A ABC ABA
B ABC ABC
C ABABA
D ABBABB
17
The empty space in this hcp unit cell is
A 74%
B 47.6%
C 32%
D 26%
17
The empty space in this hcp unit cell is
A 74%
B 47.6%
C 32%
D 26%
● Packing efficiency of hcp unit cell = 74%
● The empty space in hcp unit cell = 100 − 74 = 26%.
18
Which of the following statements is correct about hexagonal close
packing?
A 0.06
B 60
C 6
D 0.6
19
One kilogram of sea water sample contains 6 mg of dissolved O2. The
concentration of O2 in ppm in the sample is
A 0.06
B 60
C 6
D 0.6
20
At a given temperature, osmotic pressure of a concentrated solution of a
substance ________.
A 1 molar
B 0.1 molar
C 0.5 molal
D 0.1 molal
21
If 18 g glucose is present in 1000 g of a solvent, the solution will be
A 1 molar
B 0.1 molar
C 0.5 molal
D 0.1 molal
22
What happen to freezing point of benzene when naphthalene is added?
A Increases
B Decreases
C Remains unchanged
A Increases
B Decreases
C Remains unchanged
A 5:1
B 10 : 1
C 1:5
D 1 : 0.2
23 1 g of a non-volatile, non - electrolyte solute is dissolved in 100 g of two
different solvents A and B, whose ebullioscopic constants are in the
ratio of 1 : 5. The ratio of the elevation in their boiling points, is
A 5:1
B 10 : 1
C 1:5
D 1 : 0.2
24
Which one of the following statements regarding Henry’s law is not
correct?
A 360
B 350
C 300
D 700
25 A mixture of ethyl alcohol and propyl alcohol has vapour pressure of 290
mm Hg at 300 K. The vapour pressure of propyl alcohol is 200 mm Hg. If the
mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm Hg) at the
same temperature will be
A 360
B 350
C 300
D 700
Hg
26
Which of the following liquid pairs shows a positive deviation from
Raoult’s law?
B Benzene - methanol
D Acetone - chloroform
26
Which of the following liquid pairs shows a positive deviation from
Raoult’s law?
B Benzene - methanol
D Acetone - chloroform
Benzene in methanol breaks the H - bonding of the alcohol making
its boiling point decrease & there by its vapour pressure increases
leading two +ve deviation.
27
Which of the following mixture will form maximum boiling azeotrope?
A Kb = 1.5 Kf
B Kb = 0.5 Kf
C Kb = Kf
D Kb = 2 K f
29 Elevation in the boiling point for 1 molal solution of glucose is 2K. The
depression in the freezing point for 2 molal solution of glucose in the
same solvent is 2 K. The relation between Kb and Kf is
A Kb = 1.5 Kf
B Kb = 0.5 Kf
C Kb = Kf
D Kb = 2 K f
30 pA and pB are the vapour pressure of pure liquid components, A and B,
respectively of an ideal binary solution. If χA represents the mole
fraction of component A, the total pressure of the solution will be
A pA + χA(pB - pA)
B pA + χA(pA - pB)
C pB + χA(pB - pA)
D pB + χA(pA - pB)
30 pA and pB are the vapour pressure of pure liquid components, A and B,
respectively of an ideal binary solution. If χA represents the mole
fraction of component A, the total pressure of the solution will be
A pA + χA(pB - pA)
B pA + χA(pA - pB)
C pB + χA(pB - pA)
D pB + χA(pA - pB)
31 Assertion: An ideal solution obeys Raoult’s law.
Reason: In an ideal solution, solute-solute as well as solvent-solvent
interactions are similar to solute-solvent interactions.
A 72 g
B 93 g
C 39 g
D 27 g
32 Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0 kg of
water, then how many grams of ethylene glycol (C2H6O2) must you add
to get the freezing point of the solution lowered to -2.8oC?
A 72 g
B 93 g
C 39 g
D 27 g
33
Assertion: Solubility of gases increases with increasing in pressure.
Reason: Dissolution of gas in liquid is exothermic.
A They swell
B They shrink
D They die
34
What will happen if blood cells are kept in hypertonic solution?
A They swell
B They shrink
D They die
If we place the blood cells in a hypertonic solution water will flow out of
the cells and they would shrink.
35 When solvent and solution are separated by semi-permeable
membrane, and the pressure applied on the solution side is more than
the osmotic pressure, the process which takes place is :
A Diffusion
B Osmosis
C Reverse osmosis
D Disintegration
35 When solvent and solution are separated by semi-permeable
membrane, and the pressure applied on the solution side is more than
the osmotic pressure, the process which takes place is :
A Diffusion
B Osmosis
C Reverse osmosis
D Disintegration
❖ If external pressure greater than osmotic pressure is applied, the flow of
solvent molecules can be made to proceed from solution towards pure
solvent, i.e., in reverse direction of the ordinary osmosis.
36
Calculate the molarity of 30 g of Co(NO3)2. 6H2O in 4.3 litre of solution.
(molar mass of solute = 290.7g/mol)
A 0.103 M
B 0.024 M
C 0.48 M
D 30 M
36
Calculate the molarity of 30 g of Co(NO3)2. 6H2O in 4.3 litre of solution.
(molar mass of solute = 290.7g/mol)
A 0.103 M
B 0.024 M
C 0.48 M
D 30 M
0.024 M
37
Rhombic sulphur is of _____________ colour .
A Red
B Black
C White
D Yellow
37
Rhombic sulphur is of _____________ colour .
A Red
B Black
C White
D Yellow
Rhombic Sulphur
38 Elements of group 15 form compounds in +5 oxidation state. However ,
bismuth forms only one well characterised compound in +5 oxidation
state. The compound is ……….. .
A Bi2O5
B BiF5
C BiCl5
D Bi2S5
38 Elements of group 15 form compounds in +5 oxidation state. However ,
bismuth forms only one well characterised compound in +5 oxidation
state. The compound is ……….. .
A Bi2O5
B BiF5
C BiCl5
D Bi2S5
The stability of +5 oxidation state decreases down the group due to inert
pair effect. The only well characterised Bi(V) compound is BiF5
39
Which of the following elements can be involved in p𝞹 - d𝞹 bonding ?
A Carbon
B Nitrogen
C Phosphorus
D Boron
39
Which of the following elements can be involved in p𝞹 - d𝞹 bonding ?
A Carbon
B Nitrogen
C Phosphorus
D Boron
40
The industrial preparation of SO2 is
A sp3d2 and 1
B sp3d and 2
C sp3d and 1
D sp3d2 and 2
41 The type of hybridisation and number of lone pair(s) of electrons of Xe
in XeOF4, respectively, are
A sp3d2 and 1
B sp3d and 2
C sp3d and 1
D sp3d2 and 2
Hybridisation- sp3d2
Lone pair = 1
42
Ammonia is used in detection of Cu2+ ion because
A Al2O3
B Cr2O3
C V 2 O5
D MnO2
43
The catalyst used in contact process for the production of H2SO4 is
A Al2O3
B Cr2O3
C V 2 O5
D MnO2
Step 1: 2SO2(g) + O2(g) V2 O5
2SO3(g)↑
Sulphur dioxide Sulphur trioxide
Fe
700K,
200 atm
Column I Column II
A SF4 1. Tetrahedral
A A - 3, B - 2, C - 1, D - 4 B BrF3 2. Pyramidal
C A -1, B - 2, C - 3, D - 4
D A -1, B - 4, C - 3, D - 2
47 Match the species given in Column I with the shape given in Column II
and mark the correct option.
Column I Column II
A SF4 1. Tetrahedral
A A - 3, B - 2, C - 1, D - 4 B BrF3 2. Pyramidal
C A -1, B - 2, C - 3, D - 4
D A -1, B - 4, C - 3, D - 2
48
Which of the following compounds does not give N2 on heating?
A NH4NO2
B NH4NO3
C NaN3
D Both A & B
48
Which of the following compounds does not give N2 on heating?
A NH4NO2
B NH4NO3
C NaN3
D Both A & B
49
The element which forms oxides in all oxidation states +1 to +5 is
A N
B P
C As
D Sb
49
The element which forms oxides in all oxidation states +1 to +5 is
A N
B P
C As
D Sb
50 Assertion : HClO4 is a stronger acid than HClO3
Reason : Oxidation state of Cl in HClO4 is + 8 and in HClO3 is + 5.
A N
B As
C Sb
D Bi
51
For which of the following elements it is difficult to disproportionate in
+3 oxidation
A N
B As
C Sb
D Bi
52
Zinc on reaction with dilute HNO3 gives x and zinc on reaction with
concentrated HNO3 gives y. Identify x and y.
A x = NO2 , y = N2O
B x = N2O , y = NO
C x = NO , y = NO2
D x = N2O , y = NO2
52
Zinc on reaction with dilute HNO3 gives x and zinc on reaction with
concentrated HNO3 gives y. Identify x and y.
A x = NO2 , y = N2O
B x = N2O , y = NO
C x = NO , y = NO2
D x = N2O , y = NO2
4Zn(s) + 10HNO3(dil.) 4Zn(NO3)2(s) + N2O(g) + 5H2O(l)
Zinc Nitrous oxide/
Nitrate Laughing gas
A XeOF₄
B XeO₂F₂
C XeO₃
D XeO₂
53
XeF₆ on complete hydrolysis produces
A XeOF₄
B XeO₂F₂
C XeO₃
D XeO₂
54
Which one has the highest boiling point?
A He
B Ne
C Kr
D Xe
54
Which one has the highest boiling point?
A He
B Ne
C Kr
D Xe
55
The IUPAC name of the compound is
A 4 - fluoro-1-methyl-3-nitrobenzene
B 1-fluoro-4-methyl-2-nitrobenzene
C 2-fluoro-5-methyl-1-nitrobenzene
D 4-methyl-1-fluoro-2-nitrobenzene
55
The IUPAC name of the compound is
A 4 - fluoro-1-methyl-3-nitrobenzene
B 1-fluoro-4-methyl-2-nitrobenzene
C 2-fluoro-5-methyl-1-nitrobenzene
D 4-methyl-1-fluoro-2-nitrobenzene
1-fluoro-4-methyl-2-nitrobenzene
56
Arrange the following compounds in the increasing order of their
densities.
C (iv) < (iii) < (ii) < (i) D (ii) < (iv) < (iii) < (i)
56
Arrange the following compounds in the increasing order of their
densities.
C (iv) < (iii) < (ii) < (i) D (ii) < (iv) < (iii) < (i)
57
Chlorination of toluene in presence of sunlight and heat and followed by
treatment with aqueous NaOH gives
A o-cresol
B p-cresol
C 2, 4-dihydroxytoluene
D Benzoic acid
57
Chlorination of toluene in presence of sunlight and heat and followed by
treatment with aqueous NaOH gives
A o-cresol
B p-cresol
C 2, 4-dihydroxytoluene
D Benzoic acid
58
The compound which reacts with HBr obeying Markovnikov’s rule is
A CH2 = CH2
B cis-but2-ene
C trans-but-2-ene
D (CH3)2C = CH2
58
The compound which reacts with HBr obeying Markovnikov’s rule is
A CH2 = CH2
B cis-but2-ene
C trans-but-2-ene
D (CH3)2C = CH2
All others are symmetrical alkenes
59
The following reaction is described as
A (CH3)3 CD
B (CH3)3COD
C (CD3)3 CD
D (CD)3 COD
60
(CH3)3 CMgCl on reaction with D2O produces
A (CH3)3 CD
B (CH3)3COD
C (CD3)3 CD
D (CD)3 COD
61 The replacement of chlorine of chlorobenzene to give phenol requires
drastic conditions but chlorine of 2, 4-dinitrochlorobenzene is readily
replaced since
D
62
Which of the following is known as Sandmeyer Reaction?
D
Sandmeyer's reaction
63
Which of the following compounds has the highest boiling point ?
A CH3CH2CH2Cl
B CH3CH2CH2CH2Cl
C CH3CH(CH3)CH2Cl
D (CH3)3CCl
63
Which of the following compounds has the highest boiling point ?
A CH3CH2CH2Cl
B CH3CH2CH2CH2Cl
C CH3CH(CH3)CH2Cl
D (CH3)3CCl
64
The decreasing order of reactivity of the following compound towards
electrophilic substitution is
A B
C D
65
Major product (P) will be
A B
C D
para product is the major product
66
Which of the following reaction involves both aryl and alkyl halide?
A Wurtz reaction
C Fittig Reaction
D Friedel-Crafts reaction
66
Which of the following reaction involves both aryl and alkyl halide?
A Wurtz reaction
C Fittig Reaction
D Friedel-Crafts reaction
Wurtz-Fittig Reaction
67
Which of the following compounds is not chiral?
A 1-Chloropentane
B 2-Chloropentane
C 1-Chloro-2-methylpentane
D 3-Chloro-2-methylpentane
67
Which of the following compounds is not chiral?
A 1-Chloropentane
B 2-Chloropentane
C 1-Chloro-2-methylpentane
D 3-Chloro-2-methylpentane
68 An aromatic compound C7H6Cl2(A), gives AgCl on boiling with alcoholic
AgNO2 solution and yields C7H7OCl on treatment with sodium hydroxide. (A)
on oxidation gives monochlorobenzoic acid. The compound (A) is
A B
C D
68 An aromatic compound C7H6Cl2(A), gives AgCl on boiling with alcoholic
AgNO2 solution and yields C7H7OCl on treatment with sodium hydroxide. (A)
on oxidation gives monochlorobenzoic acid. The compound (A) is
A B
C D
69 Assertion (A) : Rate of hydrolysis of methyl chloride to methanol is higher in
DMF than in water.
Reason (R) : Hydrolysis of methyl chloride follows second order kinetics.
A Cumene
B n-butyl benzene
C CH3CH2CH(CH3)2
D t-butyl benzene
70
A Cumene
B n-butyl benzene
C CH3CH2CH(CH3)2
D t-butyl benzene
71 In the following replacement reaction,the reaction will be most
favourable if M happens to be
A K
B Rb
C Li
D Na
71 In the following replacement reaction,the reaction will be most
favourable if M happens to be
A K
B Rb
C Li
D Na
● Reaction is faster with Rb because lattice
energy of RbF is less than LiF, NaF, KF
● Hence will give the nucleophile F- easily
72 Assertion (A) : Hydrolysis of n-bromobutane proceeds with inversion of
configuration.
Reason (R) : This reaction proceeds through the formation of a
carbocation.
A 1-methoxy-1-methylethane
B 2-methoxy-2-methylethane
C 2-methoxypropane
D isopropylmethyl ether
73
IUPAC name of the compound is
A 1-methoxy-1-methylethane
B 2-methoxy-2-methylethane
C 2-methoxypropane
D isopropylmethyl ether
2-methoxypropane
74
In the reaction given below, X is :
A 2-methylpent-2-ene
B 2-methylpentane
C 2-methylbut-2-ene
D Neopentane
74
In the reaction given below, X is :
A 2-methylpent-2-ene
B 2-methylpentane
C 2-methylbut-2-ene
D Neopentane
75
Which of the following compounds will react with sodium hydroxide
solution in water ?
A C6H5OH
B C6H5CH2OH
C (CH3)3 COH
D C2H5OH
75
Which of the following compounds will react with sodium hydroxide
solution in water ?
A C6H5OH
B C6H5CH2OH
C (CH3)3 COH
D C2H5OH
Only phenol will react NaOH. All other compounds are alcohols and are
only weakly acidic in nature and phenol is more acidic than them.
76
Which of these when passed over heated Cu at 573 K forms an alkene ?
A An alkane
B An alkyne
C Secondary alcohol
D Tertiary alcohol
76
Which of these when passed over heated Cu at 573 K forms an alkene ?
A An alkane
B An alkyne
C Secondary alcohol
D Tertiary alcohol
3° Alcohol Alkene
77
The general molecular formula, which represents the homologous series
of alkanols is
A CnH2n+2O
B CnH2nO2
C CnH2nO
D CnH2n + 1O
77
The general molecular formula, which represents the homologous series
of alkanols is
A CnH2n+2O
B CnH2nO2
C CnH2nO
D CnH2n + 1O
78
Phenylmagnesium bromide reacts with methanol to give
A secondary alcohol
B tertiary alcohol
C cyclopropyl alcohol
D primary alcohol
79
Ethylene oxide when treated with Grignard reagent yield
A secondary alcohol
B tertiary alcohol
C cyclopropyl alcohol
D primary alcohol
80
Diethyl ether on heating with HI gives two moles of
A Ethanol
B Iodoform
C Ethyl iodide
D Methyl iodide
80
Diethyl ether on heating with HI gives two moles of
A Ethanol
B Iodoform
C Ethyl iodide
D Methyl iodide
81
Diethyl ether and ethanol are isomeric but ether boils at a much lower
temperature because
A Kolbe’s synthesis
B Williamson’s synthesis
C Wurtz reaction
D Cannizzaro’s reaction
82
Preparation of ethers by reacting sodium alkoxide with alkyl halide is
called
A Kolbe’s synthesis
B Williamson’s synthesis
C Wurtz reaction
D Cannizzaro’s reaction
Williamson Synthesis
SN2
83
Formation of diethyl ether from ethanol in presence of H2SO4 is based
on
A Dehydrogenation reaction
B Hydrogenation reaction
C Dehydration reaction
A Dehydrogenation reaction
B Hydrogenation reaction
C Dehydration reaction
A Nitrobenzene
B 2,4,6-trinitrophenol
C o-nitrophenol
D p-nitrophenol
84
Phenol when first treated with concentrated sulphuric acid and then
with concentrated nitric acid, gives
A Nitrobenzene
B 2,4,6-trinitrophenol
C o-nitrophenol
D p-nitrophenol
85
Lucas reagent is
A Iso-propyl benzene
B Ethyl benzene
C Vinyl benzene
D Propyl benzene
88
Cumene process is the most important commercial method for the
manufacture of phenol. Cumene is
A Iso-propyl benzene
B Ethyl benzene
C Vinyl benzene
D Propyl benzene
89
For the reaction of phenol with CHCl3 in presence of KOH, the
electrophile is
⊕
A CHCl2
B ∶CCl2
⊝
C CHCl2
D None of these
89
For the reaction of phenol with CHCl3 in presence of KOH, the
electrophile is
⊕
A CHCl2
B ∶CCl2
⊝
C CHCl2
D None of these
90 Assertion (A) : o-Nitrophenol is less soluble in water than the
m- and p-isomers.
Reason (R) : m- and p- Nitrophenols exist as associated molecules.
A Glucose
B Maltose
C Glycogen
D Lactose
91
Which of the following is a polysaccharide?
A Glucose
B Maltose
C Glycogen
D Lactose
Glycogen is a polysachharide
92
Glucose is prepared from
A Sucrose
B Maltose
C Lactose
D Cellulose
92
Glucose is prepared from
A Sucrose
B Maltose
C Lactose
D Cellulose
93
Which one given below is a non reducing sugar?
A Glucose
B Sucrose
C Maltose
D Lactose
93
Which one given below is a non reducing sugar?
A Glucose
B Sucrose
C Maltose
D Lactose
Since the reducing groups of glucose and fructose are
involved in glycosidic bond formation, sucrose is a
non-reducing sugar.
94
Which of the following is a basic amino acid?
A Tyrosine
B Lysine
C Serine
D Alanine
94
Which of the following is a basic amino acid?
A Tyrosine
B Lysine
C Serine
D Alanine
95
Assertion: Glucose does not form the hydrogen bisulphite addition product
Reason: Glucose is not so reactive to form the product with NaHSO3
A primary structure
B secondary structures
C tertiary structure
D quaternary structure
99
α-helix and β-pleated structures of proteins are classified as
A primary structure
B secondary structures
C tertiary structure
D quaternary structure
In proteins the α-helix and β-pleated sheet are classified as:
Secondary structure.
100
Which of the following is/are example(s) of denaturation of protein?
B Clotting of blood
C Curdling of milk
B Clotting of blood
C Curdling of milk