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1
Which of the following crystals does not exhibit Frenkel defect?

A AgBr

B AgCl

C KBr

D ZnS
1
Which of the following crystals does not exhibit Frenkel defect?

A AgBr

B AgCl

C KBr

D ZnS
● Frenkel defect is occurred in those ionic crystals in which sizes of ions
(anions and cations) show large differences.
● Compounds such as KBr show Schottky defect.
2
Which of the following statement is not true about amorphous solids?

A On heating they may become crystalline at certain temperature.

B They may become crystalline on keeping for long time.

C Amorphous solids can be moulded by heating.

D They are anisotropic in nature.


2
Which of the following statement is not true about amorphous solids?

A On heating they may become crystalline at certain temperature.

B They may become crystalline on keeping for long time.

C Amorphous solids can be moulded by heating.

D They are anisotropic in nature.


● The amorphous solids are isotropic.
● They have the same physical properties in all directions due to
irregular arrangement
3
Which one of the following is a covalent crystal?

A Rock salt

B Ice

C Quartz

D Dry ice
3
Which one of the following is a covalent crystal?

A Rock salt

B Ice

C Quartz

D Dry ice
(SiO2) Quartz is a covalent crystal
4
For tetrahedral arrangement, the radius ratio r+/r- is

A 0.732 - 1.0

B 0.225 - 0.414

C 0.414 - 0.732

D 0.155 - 0.225
4
For tetrahedral arrangement, the radius ratio r+/r- is

A 0.732 - 1.0

B 0.225 - 0.414

C 0.414 - 0.732

D 0.155 - 0.225
Radius Ratio Coordination No. Structure Example
0.225 – 0.414 4 Tetrahedral ZnS
5 A given metal crystallises out with a cubic structure having edge length
of 361 pm. If there are four metal atoms in one unit cell, then the radius
of one atom is

A 80 pm

B 108 pm

C 40 pm

D 128 pm
5 A given metal crystallises out with a cubic structure having edge length
of 361 pm. If there are four metal atoms in one unit cell, then the radius
of one atom is

A 80 pm

B 108 pm

C 40 pm

D 128 pm
6
The crystal system of a compound with unit cell dimensions a = 0.387,
b = 0.387 and c = 0.504 nm and α = β = 90o and 𝝲 = 120o is

A Cubic

B Hexagonal

C Orthorhombic

D Rhombohedral
6
The crystal system of a compound with unit cell dimensions a = 0.387,
b = 0.387 and c = 0.504 nm and α = β = 90o and 𝝲 = 120o is

A Cubic

B Hexagonal

C Orthorhombic

D Rhombohedral
7 If NaCl is doped with 10-4 mol % of SrCl2, the concentration of cation
vacancies will be
(NA = 6.02 x 1023 mol-1)

A 6.02 x 1016 mol-1

B 6.02 x 1017 mol-1

C 6.02 x 1014 mol-1

D 6.02 x 1015 mol-1


7 If NaCl is doped with 10-4 mol % of SrCl2, the concentration of cation
vacancies will be
(NA = 6.02 x 1023 mol-1)

A 6.02 x 1016 mol-1

B 6.02 x 1017 mol-1

C 6.02 x 1014 mol-1

D 6.02 x 1015 mol-1


8 If Z is the number of atoms in the unit cell that represents the closest
packing sequence ….ABC ABC….., the number of tetrahedral voids in
the unit cell is equal to

A Z

B 2Z

C Z/2

D Z/4
8 If Z is the number of atoms in the unit cell that represents the closest
packing sequence ….ABC ABC….., the number of tetrahedral voids in
the unit cell is equal to

A Z

B 2Z

C Z/2

D Z/4
9 Assertion: bcc and hcp has same packing efficiency.
Reason: Both have same number of atoms per unit cell and same
arrangement.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


9 Assertion: bcc and hcp has same packing efficiency.
Reason: Both have same number of atoms per unit cell and same
arrangement.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


10
The number of atoms in 100 g of an fcc crystal with density d = 10 gcm-3
and cell edge as 200 pm is equal to

A 3 × 1025

B 5 × 1024

C 1 × 1025

D 2 × 1025
10
The number of atoms in 100 g of an fcc crystal with density d = 10 gcm-3
and cell edge as 200 pm is equal to

A 3 × 1025

B 5 × 1024

C 1 × 1025

D 2 × 1025
11
A solid AB has NaCl type structure. The radius of A+ is 100 pm. What is
the radius of B-?

A 190.47

B 540.13

C 525

D 78.12
11
A solid AB has NaCl type structure. The radius of A+ is 100 pm. What is
the radius of B-?

A 190.47

B 540.13

C 525

D 78.12
12 Assertion: Due to Frenkel defect, density of the crystalline solid
decreases.
Reason: In Frenkel defect, a cation or an anion leaves the crystal.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


12 Assertion: Due to Frenkel defect, density of the crystalline solid
decreases.
Reason: In Frenkel defect, a cation or an anion leaves the crystal.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


13 Formula of metal oxide with metal deficiency defect in its crystal is
A0.8O. The crystal contains A2+ and A3+ions. The fraction of metal existing
as A2+ ions in the crystal is

A 0.96

B 0.04

C 0.50

D 0.31
13 Formula of metal oxide with metal deficiency defect in its crystal is
A0.8O. The crystal contains A2+ and A3+ions. The fraction of metal existing
as A2+ ions in the crystal is

A 0.96

B 0.04

C 0.50

D 0.31
14 Assertion: Monoclinic sulphur is an example of monoclinic crystal
system.
Reason: For a monoclinic system, a ≠ b ≠ c and 𝝰 = 𝛄 = 90o, 𝛃 ≠ 90o.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


14 Assertion: Monoclinic sulphur is an example of monoclinic crystal
system.
Reason: For a monoclinic system, a ≠ b ≠ c and 𝝰 = 𝛄 = 90o, 𝛃 ≠ 90o.

Both A and R are true and R is the


A correct explanation of A

Both A and R are true but R is not the


B correct explanation of A

C A is true but R is false

Both A and R are false


D
Crystal Systems Axial Lengths Axial Angles Example
Monoclinic a ≠ b ≠c ⍺ = 𝝲 =90°, ꞵ ≠ 90° Monoclinic sulphur
15 An ionic compound made up of atoms X and Y has a fcc arrangement in
which atoms X are at the corner and atoms Y are at the face- centres. If one
of the atoms is missing from the corner, what is the simplest formula of the
compound ?

A XY

B X 2Y 3

C X7Y24

D X 3Y 5
15 An ionic compound made up of atoms X and Y has a fcc arrangement in
which atoms X are at the corner and atoms Y are at the face- centres. If one
of the atoms is missing from the corner, what is the simplest formula of the
compound ?

A XY

B X 2Y 3

C X7Y24

D X 3Y 5
CASE1: Read the passage given below and answer the following questions 16-18

In hexagonal system of crystals, a frequently encountered arrangement of atoms


is described as a hexagonal prism. Hexagonal close packed (hcp), is constituted of
a sphere on a flat surface surrounded in the same plane by six identical spheres
as closely as possible. There spheres are then placed over the first layer so that
they touch each other and represent the second layer. Each one of these three
spheres touches three spheres of the bottom layer. Finally, the second layer is
covered with a third layer that is identical to the bottom layer in relative position.
16
Which of the following describes the hexagonal close packed
arrangement of spheres ?

A ABC ABA

B ABC ABC

C ABABA

D ABBABB
16
Which of the following describes the hexagonal close packed
arrangement of spheres ?

A ABC ABA

B ABC ABC

C ABABA

D ABBABB
17
The empty space in this hcp unit cell is

A 74%

B 47.6%

C 32%

D 26%
17
The empty space in this hcp unit cell is

A 74%

B 47.6%

C 32%

D 26%
● Packing efficiency of hcp unit cell = 74%
● The empty space in hcp unit cell = 100 − 74 = 26%.
18
Which of the following statements is correct about hexagonal close
packing?

A In this arrangement, third layer is


identical to the first layer.

B The coordination number in this


arrangement is 6.

C It is as closely packed as body


centered cubic packing.

D It has 32% empty space.


18
Which of the following statements is correct about hexagonal close
packing?

A In this arrangement, third layer is


identical to the first layer.

B The coordination number in this


arrangement is 6.

C It is as closely packed as body


centered cubic packing.

D It has 32% empty space.


19
One kilogram of sea water sample contains 6 mg of dissolved O2. The
concentration of O2 in ppm in the sample is

A 0.06

B 60

C 6

D 0.6
19
One kilogram of sea water sample contains 6 mg of dissolved O2. The
concentration of O2 in ppm in the sample is

A 0.06

B 60

C 6

D 0.6
20
At a given temperature, osmotic pressure of a concentrated solution of a
substance ________.

A Is higher than that of a dilute solution

B Is lower than that of a dilute solution

C Is same as that of a dilute solution

D Cannot be compared with osmotic pressure of dilute solution


20
At a given temperature, osmotic pressure of a concentrated solution of a
substance ________.

A Is higher than that of a dilute solution

B Is lower than that of a dilute solution

C Is same as that of a dilute solution

D Cannot be compared with osmotic pressure of dilute solution


21
If 18 g glucose is present in 1000 g of a solvent, the solution will be

A 1 molar

B 0.1 molar

C 0.5 molal

D 0.1 molal
21
If 18 g glucose is present in 1000 g of a solvent, the solution will be

A 1 molar

B 0.1 molar

C 0.5 molal

D 0.1 molal
22
What happen to freezing point of benzene when naphthalene is added?

A Increases

B Decreases

C Remains unchanged

D First decreases and then increases


22
What happen to freezing point of benzene when naphthalene is added?

A Increases

B Decreases

C Remains unchanged

D First decreases and then increases


23 1 g of a non-volatile, non - electrolyte solute is dissolved in 100 g of two
different solvents A and B, whose ebullioscopic constants are in the
ratio of 1 : 5. The ratio of the elevation in their boiling points, is

A 5:1

B 10 : 1

C 1:5

D 1 : 0.2
23 1 g of a non-volatile, non - electrolyte solute is dissolved in 100 g of two
different solvents A and B, whose ebullioscopic constants are in the
ratio of 1 : 5. The ratio of the elevation in their boiling points, is

A 5:1

B 10 : 1

C 1:5

D 1 : 0.2
24
Which one of the following statements regarding Henry’s law is not
correct?

A Different gases have different KH (Henry’s law constant)


values at the same temperature

B Higher the value of KH at a given pressure, higher is the


solubility of the gas in the liquids

C The value of KH increases with increase of temperature


and KH is function of the nature of the gas

D The partial pressure of the gas in vapour phase is


proportional to the mole fraction of the gas in the solution
24
Which one of the following statements regarding Henry’s law is not
correct?

A Different gases have different KH (Henry’s law constant)


values at the same temperature

B Higher the value of KH at a given pressure, higher is the


solubility of the gas in the liquids

C The value of KH increases with increase of temperature


and KH is function of the nature of the gas

D The partial pressure of the gas in vapour phase is


proportional to the mole fraction of the gas in the solution
25 A mixture of ethyl alcohol and propyl alcohol has vapour pressure of 290
mm Hg at 300 K. The vapour pressure of propyl alcohol is 200 mm Hg. If the
mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm Hg) at the
same temperature will be

A 360

B 350

C 300

D 700
25 A mixture of ethyl alcohol and propyl alcohol has vapour pressure of 290
mm Hg at 300 K. The vapour pressure of propyl alcohol is 200 mm Hg. If the
mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm Hg) at the
same temperature will be

A 360

B 350

C 300

D 700
Hg
26
Which of the following liquid pairs shows a positive deviation from
Raoult’s law?

A Water - hydrochloric acid

B Benzene - methanol

C Water - nitric acid

D Acetone - chloroform
26
Which of the following liquid pairs shows a positive deviation from
Raoult’s law?

A Water - hydrochloric acid

B Benzene - methanol

C Water - nitric acid

D Acetone - chloroform
Benzene in methanol breaks the H - bonding of the alcohol making
its boiling point decrease & there by its vapour pressure increases
leading two +ve deviation.
27
Which of the following mixture will form maximum boiling azeotrope?

A Conc. HNO3 and water.

B Acetone and benzene

C Ethyl alcohol and water

D Acetone and CS2


27
Which of the following mixture will form maximum boiling azeotrope?

A Conc. HNO3 and water.

B Acetone and benzene

C Ethyl alcohol and water

D Acetone and CS2


Water + Nitric acid. Solution showing negative deviation from Raoult's law
form maximum boiling azeotrope
28 Assertion: 0.1 M solution of glucose has same depression in the freezing
point as 0.1 M solution of urea.
Reason: Kf for both has same value.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


28 Assertion: 0.1 M solution of glucose has same depression in the freezing
point as 0.1 M solution of urea.
Reason: Kf for both has same value.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


29 Elevation in the boiling point for 1 molal solution of glucose is 2K. The
depression in the freezing point for 2 molal solution of glucose in the
same solvent is 2 K. The relation between Kb and Kf is

A Kb = 1.5 Kf

B Kb = 0.5 Kf

C Kb = Kf

D Kb = 2 K f
29 Elevation in the boiling point for 1 molal solution of glucose is 2K. The
depression in the freezing point for 2 molal solution of glucose in the
same solvent is 2 K. The relation between Kb and Kf is

A Kb = 1.5 Kf

B Kb = 0.5 Kf

C Kb = Kf

D Kb = 2 K f
30 pA and pB are the vapour pressure of pure liquid components, A and B,
respectively of an ideal binary solution. If χA represents the mole
fraction of component A, the total pressure of the solution will be

A pA + χA(pB - pA)

B pA + χA(pA - pB)

C pB + χA(pB - pA)

D pB + χA(pA - pB)
30 pA and pB are the vapour pressure of pure liquid components, A and B,
respectively of an ideal binary solution. If χA represents the mole
fraction of component A, the total pressure of the solution will be

A pA + χA(pB - pA)

B pA + χA(pA - pB)

C pB + χA(pB - pA)

D pB + χA(pA - pB)
31 Assertion: An ideal solution obeys Raoult’s law.
Reason: In an ideal solution, solute-solute as well as solvent-solvent
interactions are similar to solute-solvent interactions.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


31 Assertion: An ideal solution obeys Raoult’s law.
Reason: In an ideal solution, solute-solute as well as solvent-solvent
interactions are similar to solute-solvent interactions.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Ideal solution
32 Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0 kg of
water, then how many grams of ethylene glycol (C2H6O2) must you add
to get the freezing point of the solution lowered to -2.8oC?

A 72 g

B 93 g

C 39 g

D 27 g
32 Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0 kg of
water, then how many grams of ethylene glycol (C2H6O2) must you add
to get the freezing point of the solution lowered to -2.8oC?

A 72 g

B 93 g

C 39 g

D 27 g
33
Assertion: Solubility of gases increases with increasing in pressure.
Reason: Dissolution of gas in liquid is exothermic.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


33
Assertion: Solubility of gases increases with increasing in pressure.
Reason: Dissolution of gas in liquid is exothermic.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Correct Explanation : By increasing pressure, more gas molecules condense
and dissolve in the liquid.
CASE1: Read the passage given below and answer the following questions 34-36
34
What will happen if blood cells are kept in hypertonic solution?

A They swell

B They shrink

C They remain same

D They die
34
What will happen if blood cells are kept in hypertonic solution?

A They swell

B They shrink

C They remain same

D They die
If we place the blood cells in a hypertonic solution water will flow out of
the cells and they would shrink.
35 When solvent and solution are separated by semi-permeable
membrane, and the pressure applied on the solution side is more than
the osmotic pressure, the process which takes place is :

A Diffusion

B Osmosis

C Reverse osmosis

D Disintegration
35 When solvent and solution are separated by semi-permeable
membrane, and the pressure applied on the solution side is more than
the osmotic pressure, the process which takes place is :

A Diffusion

B Osmosis

C Reverse osmosis

D Disintegration
❖ If external pressure greater than osmotic pressure is applied, the flow of
solvent molecules can be made to proceed from solution towards pure
solvent, i.e., in reverse direction of the ordinary osmosis.
36
Calculate the molarity of 30 g of Co(NO3)2. 6H2O in 4.3 litre of solution.
(molar mass of solute = 290.7g/mol)

A 0.103 M

B 0.024 M

C 0.48 M

D 30 M
36
Calculate the molarity of 30 g of Co(NO3)2. 6H2O in 4.3 litre of solution.
(molar mass of solute = 290.7g/mol)

A 0.103 M

B 0.024 M

C 0.48 M

D 30 M
0.024 M
37
Rhombic sulphur is of _____________ colour .

A Red

B Black

C White

D Yellow
37
Rhombic sulphur is of _____________ colour .

A Red

B Black

C White

D Yellow
Rhombic Sulphur
38 Elements of group 15 form compounds in +5 oxidation state. However ,
bismuth forms only one well characterised compound in +5 oxidation
state. The compound is ……….. .

A Bi2O5

B BiF5

C BiCl5

D Bi2S5
38 Elements of group 15 form compounds in +5 oxidation state. However ,
bismuth forms only one well characterised compound in +5 oxidation
state. The compound is ……….. .

A Bi2O5

B BiF5

C BiCl5

D Bi2S5
The stability of +5 oxidation state decreases down the group due to inert
pair effect. The only well characterised Bi(V) compound is BiF5
39
Which of the following elements can be involved in p𝞹 - d𝞹 bonding ?

A Carbon

B Nitrogen

C Phosphorus

D Boron
39
Which of the following elements can be involved in p𝞹 - d𝞹 bonding ?

A Carbon

B Nitrogen

C Phosphorus

D Boron
40
The industrial preparation of SO2 is

A S(s) + O2 (g) →SO2 (g)

B SO32-(aq) + 2H+ (aq) →H2O(I) +SO2 (g)

C 4FeS2(s) + 11O2 (g) →2Fe2O3(s) + 8SO2 (g)

D All of the above


40
The industrial preparation of SO2 is

A S(s) + O2 (g) →SO2 (g)

B SO32-(aq) + 2H+ (aq) →H2O(I) +SO2 (g)

C 4FeS2(s) + 11O2 (g) →2Fe2O3(s) + 8SO2 (g)

D All of the above


Industrial Method
4FeS2 (s) + 11O2 (g) 2Fe2O3 (s) + 8SO2 (g)
Iron disulphide/ Ferric oxide
Iron Pyrite
41 The type of hybridisation and number of lone pair(s) of electrons of Xe
in XeOF4, respectively, are

A sp3d2 and 1

B sp3d and 2

C sp3d and 1

D sp3d2 and 2
41 The type of hybridisation and number of lone pair(s) of electrons of Xe
in XeOF4, respectively, are

A sp3d2 and 1

B sp3d and 2

C sp3d and 1

D sp3d2 and 2
Hybridisation- sp3d2
Lone pair = 1
42
Ammonia is used in detection of Cu2+ ion because

A aqueous solution of NH3 reacts with Cu2+ ion to


form deep blue coloured complex

B NH3 reacts with Cu2+ ion to give


blue precipitate of CuO

aqueous solution of NH3 reacts with Cu2+ to form


C white coloured complex

D NH3 reacts with Cu2+ ion to give


green precipitate
42
Ammonia is used in detection of Cu2+ ion because

A aqueous solution of NH3 reacts with Cu2+ ion to


form deep blue coloured complex

B NH3 reacts with Cu2+ ion to give


blue precipitate of CuO

aqueous solution of NH3 reacts with Cu2+ to form


C white coloured complex

D NH3 reacts with Cu2+ ion to give


green precipitate
Cu2+(aq) + 4NH3(aq) ⇌ [Cu(NH3)4]2+ (aq)
43
The catalyst used in contact process for the production of H2SO4 is

A Al2O3

B Cr2O3

C V 2 O5

D MnO2
43
The catalyst used in contact process for the production of H2SO4 is

A Al2O3

B Cr2O3

C V 2 O5

D MnO2
Step 1: 2SO2(g) + O2(g) V2 O5
2SO3(g)↑
Sulphur dioxide Sulphur trioxide

Step 2: SO3(g) + H2SO4(l) H2S2O7(g)


Oleum

Step 3: H2S2O7(g) + H2O(l) H2SO4(l)


Sulphuric acid
44
Correct order of electron affinity for halogen is

A F > Cl > Br > I

B F < Cl < Br < I

C F < Cl > Br > I

D F > Cl < Br > I


44
Correct order of electron affinity for halogen is

A F > Cl > Br > I

B F < Cl < Br < I

C F < Cl > Br > I

D F > Cl < Br > I


The correct order of Electron gain enthalpy of Fluorine family is,
Cl > F > Br > I
45 Assertion : Bond energy of F2 is lesser than Cl2
Reason : F - atom is smaller in size than Cl.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


45 Assertion : Bond energy of F2 is lesser than Cl2
Reason : F - atom is smaller in size than Cl.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Bond dissociation energy of F2 molecule is less than that of Cl2 molecule
because F has smaller radius and due to smaller size repulsion is high.
46
How is ammonia generally manufactured in large scale ?

A By heating a mixture of NH4Cl and slaked lime


Ca(OH)2 .

B By passing an electric discharge in the mixture of


N2 and H2.

C By reducing the by-product of nitric acid .

D By passing a mixture of N2 and H2 under high


pressure and moderate temperature over a
catalyst
46
How is ammonia generally manufactured in large scale ?

A By heating a mixture of NH4Cl and slaked lime


Ca(OH)2 .

B By passing an electric discharge in the mixture of


N2 and H2.

C By reducing the by-product of nitric acid .

D By passing a mixture of N2 and H2 under high


pressure and moderate temperature over a
catalyst
Large Scale Synthesis :

Fe

700K,
200 atm

● High Pressure ≈ 200 atm


● Temp. ≈ 700 K
● Catalysts such as iron or iron oxide with small amount of
K2O & Al2O3
47 Match the species given in Column I with the shape given in Column II
and mark the correct option.

Column I Column II

A SF4 1. Tetrahedral
A A - 3, B - 2, C - 1, D - 4 B BrF3 2. Pyramidal

C BrO3- 3. See-saw shaped


B A -3, B - 4, C - 2, D - 1
D NH4+ 4. Bent T-shaped

C A -1, B - 2, C - 3, D - 4

D A -1, B - 4, C - 3, D - 2
47 Match the species given in Column I with the shape given in Column II
and mark the correct option.

Column I Column II

A SF4 1. Tetrahedral
A A - 3, B - 2, C - 1, D - 4 B BrF3 2. Pyramidal

C BrO3- 3. See-saw shaped


B A -3, B - 4, C - 2, D - 1
D NH4+ 4. Bent T-shaped

C A -1, B - 2, C - 3, D - 4

D A -1, B - 4, C - 3, D - 2
48
Which of the following compounds does not give N2 on heating?

A NH4NO2

B NH4NO3

C NaN3

D Both A & B
48
Which of the following compounds does not give N2 on heating?

A NH4NO2

B NH4NO3

C NaN3

D Both A & B
49
The element which forms oxides in all oxidation states +1 to +5 is

A N

B P

C As

D Sb
49
The element which forms oxides in all oxidation states +1 to +5 is

A N

B P

C As

D Sb
50 Assertion : HClO4 is a stronger acid than HClO3
Reason : Oxidation state of Cl in HClO4 is + 8 and in HClO3 is + 5.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


50 Assertion : HClO4 is a stronger acid than HClO3
Reason : Oxidation state of Cl in HClO4 is + 8 and in HClO3 is +4.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


+1 +3 +5 +7
HClO < HClO2 < HClO3 < HClO4
51
For which of the following elements it is difficult to disproportionate in
+3 oxidation

A N

B As

C Sb

D Bi
51
For which of the following elements it is difficult to disproportionate in
+3 oxidation

A N

B As

C Sb

D Bi
52
Zinc on reaction with dilute HNO3 gives x and zinc on reaction with
concentrated HNO3 gives y. Identify x and y.

A x = NO2 , y = N2O

B x = N2O , y = NO

C x = NO , y = NO2

D x = N2O , y = NO2
52
Zinc on reaction with dilute HNO3 gives x and zinc on reaction with
concentrated HNO3 gives y. Identify x and y.

A x = NO2 , y = N2O

B x = N2O , y = NO

C x = NO , y = NO2

D x = N2O , y = NO2
4Zn(s) + 10HNO3(dil.) 4Zn(NO3)2(s) + N2O(g) + 5H2O(l)
Zinc Nitrous oxide/
Nitrate Laughing gas

Zn + 4HNO3(conc.) Zn(NO3)2(s) + 2NO2(g) + 2H2O(l)


Nitrogen
dioxide
53
XeF₆ on complete hydrolysis produces

A XeOF₄

B XeO₂F₂

C XeO₃

D XeO₂
53
XeF₆ on complete hydrolysis produces

A XeOF₄

B XeO₂F₂

C XeO₃

D XeO₂
54
Which one has the highest boiling point?

A He

B Ne

C Kr

D Xe
54
Which one has the highest boiling point?

A He

B Ne

C Kr

D Xe
55
The IUPAC name of the compound is

A 4 - fluoro-1-methyl-3-nitrobenzene

B 1-fluoro-4-methyl-2-nitrobenzene

C 2-fluoro-5-methyl-1-nitrobenzene

D 4-methyl-1-fluoro-2-nitrobenzene
55
The IUPAC name of the compound is

A 4 - fluoro-1-methyl-3-nitrobenzene

B 1-fluoro-4-methyl-2-nitrobenzene

C 2-fluoro-5-methyl-1-nitrobenzene

D 4-methyl-1-fluoro-2-nitrobenzene
1-fluoro-4-methyl-2-nitrobenzene
56
Arrange the following compounds in the increasing order of their
densities.

A (i) < (ii) < (iii) < (iv)


B (i) < (iii) < (iv) < (ii)

C (iv) < (iii) < (ii) < (i) D (ii) < (iv) < (iii) < (i)
56
Arrange the following compounds in the increasing order of their
densities.

A (i) < (ii) < (iii) < (iv)


B (i) < (iii) < (iv) < (ii)

C (iv) < (iii) < (ii) < (i) D (ii) < (iv) < (iii) < (i)
57
Chlorination of toluene in presence of sunlight and heat and followed by
treatment with aqueous NaOH gives

A o-cresol

B p-cresol

C 2, 4-dihydroxytoluene

D Benzoic acid
57
Chlorination of toluene in presence of sunlight and heat and followed by
treatment with aqueous NaOH gives

A o-cresol

B p-cresol

C 2, 4-dihydroxytoluene

D Benzoic acid
58
The compound which reacts with HBr obeying Markovnikov’s rule is

A CH2 = CH2

B cis-but2-ene

C trans-but-2-ene

D (CH3)2C = CH2
58
The compound which reacts with HBr obeying Markovnikov’s rule is

A CH2 = CH2

B cis-but2-ene

C trans-but-2-ene

D (CH3)2C = CH2
All others are symmetrical alkenes
59
The following reaction is described as

A SE2 reaction B SNI reaction

C SN2 reaction D SN0 reaction


59
The following reaction is described as

A SE2 reaction B SNI reaction

C SN2 reaction D SN0 reaction


Inversion of configuration is taking place so it is SN2 reaction
60
(CH3)3 CMgCl on reaction with D2O produces

A (CH3)3 CD

B (CH3)3COD

C (CD3)3 CD

D (CD)3 COD
60
(CH3)3 CMgCl on reaction with D2O produces

A (CH3)3 CD

B (CH3)3COD

C (CD3)3 CD

D (CD)3 COD
61 The replacement of chlorine of chlorobenzene to give phenol requires
drastic conditions but chlorine of 2, 4-dinitrochlorobenzene is readily
replaced since

A NO2 makes the ring electron rich at o-and ρ

B NO2 withdraws electrons from the m-position

C NO2 donates electrons at m-position

D NO2 withdraws electrons from o-and ρ-positions.


61 The replacement of chlorine of chlorobenzene to give phenol requires
drastic conditions but chlorine of 2, 4-dinitrochlorobenzene is readily
replaced since

A NO2 makes the ring electron rich at o-and ρ

B NO2 withdraws electrons from the m-position

C NO2 donates electrons at m-position

D NO2 withdraws electrons from o-and ρ-positions.


NO2 group shows −M effect due to which electrons are withdrawn from
ortho and para position which makes the benzene ring more prone to
electrophilic substitution reaction and hence replacement of Cl can be
done easily.
62
Which of the following is known as Sandmeyer Reaction?

D
62
Which of the following is known as Sandmeyer Reaction?

D
Sandmeyer's reaction
63
Which of the following compounds has the highest boiling point ?

A CH3CH2CH2Cl

B CH3CH2CH2CH2Cl

C CH3CH(CH3)CH2Cl

D (CH3)3CCl
63
Which of the following compounds has the highest boiling point ?

A CH3CH2CH2Cl

B CH3CH2CH2CH2Cl

C CH3CH(CH3)CH2Cl

D (CH3)3CCl
64
The decreasing order of reactivity of the following compound towards
electrophilic substitution is

A III > I > II > IV B IV > I > II > III

C I > II > III > IV D II > I > III > IV


64
The decreasing order of reactivity of the following compound towards
electrophilic substitution is

A III > I > II > IV B IV > I > II > III

C I > II > III > IV D II > I > III > IV


+M +I -I
65
Major product (P) will be

A B

C D
65
Major product (P) will be

A B

C D
para product is the major product
66
Which of the following reaction involves both aryl and alkyl halide?

A Wurtz reaction

B Wurtz fittig reaction

C Fittig Reaction

D Friedel-Crafts reaction
66
Which of the following reaction involves both aryl and alkyl halide?

A Wurtz reaction

B Wurtz fittig reaction

C Fittig Reaction

D Friedel-Crafts reaction
Wurtz-Fittig Reaction
67
Which of the following compounds is not chiral?

A 1-Chloropentane

B 2-Chloropentane

C 1-Chloro-2-methylpentane

D 3-Chloro-2-methylpentane
67
Which of the following compounds is not chiral?

A 1-Chloropentane

B 2-Chloropentane

C 1-Chloro-2-methylpentane

D 3-Chloro-2-methylpentane
68 An aromatic compound C7H6Cl2(A), gives AgCl on boiling with alcoholic
AgNO2 solution and yields C7H7OCl on treatment with sodium hydroxide. (A)
on oxidation gives monochlorobenzoic acid. The compound (A) is

A B

C D
68 An aromatic compound C7H6Cl2(A), gives AgCl on boiling with alcoholic
AgNO2 solution and yields C7H7OCl on treatment with sodium hydroxide. (A)
on oxidation gives monochlorobenzoic acid. The compound (A) is

A B

C D
69 Assertion (A) : Rate of hydrolysis of methyl chloride to methanol is higher in
DMF than in water.
Reason (R) : Hydrolysis of methyl chloride follows second order kinetics.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


69 Assertion (A) : Rate of hydrolysis of methyl chloride to methanol is higher in
DMF than in water.
Reason (R) : Hydrolysis of methyl chloride follows second order kinetics.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


SN2 reactions are favoured by polar aprotic solvents such as DMF
70

The product ‘A’ is

A Cumene

B n-butyl benzene

C CH3CH2CH(CH3)2

D t-butyl benzene
70

The product ‘A’ is

A Cumene

B n-butyl benzene

C CH3CH2CH(CH3)2

D t-butyl benzene
71 In the following replacement reaction,the reaction will be most
favourable if M happens to be

A K

B Rb

C Li

D Na
71 In the following replacement reaction,the reaction will be most
favourable if M happens to be

A K

B Rb

C Li

D Na
● Reaction is faster with Rb because lattice
energy of RbF is less than LiF, NaF, KF
● Hence will give the nucleophile F- easily
72 Assertion (A) : Hydrolysis of n-bromobutane proceeds with inversion of
configuration.
Reason (R) : This reaction proceeds through the formation of a
carbocation.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


72 Assertion (A) : Hydrolysis of n-bromobutane proceeds with inversion of
configuration.
Reason (R) : This reaction proceeds through the formation of a
carbocation.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Correct reason: the reaction proceeds through the formation of the
transition state by following SN2 mechanism.
73
IUPAC name of the compound is

A 1-methoxy-1-methylethane

B 2-methoxy-2-methylethane

C 2-methoxypropane

D isopropylmethyl ether
73
IUPAC name of the compound is

A 1-methoxy-1-methylethane

B 2-methoxy-2-methylethane

C 2-methoxypropane

D isopropylmethyl ether
2-methoxypropane
74
In the reaction given below, X is :

A 2-methylpent-2-ene

B 2-methylpentane

C 2-methylbut-2-ene

D Neopentane
74
In the reaction given below, X is :

A 2-methylpent-2-ene

B 2-methylpentane

C 2-methylbut-2-ene

D Neopentane
75
Which of the following compounds will react with sodium hydroxide
solution in water ?

A C6H5OH

B C6H5CH2OH

C (CH3)3 COH

D C2H5OH
75
Which of the following compounds will react with sodium hydroxide
solution in water ?

A C6H5OH

B C6H5CH2OH

C (CH3)3 COH

D C2H5OH
Only phenol will react NaOH. All other compounds are alcohols and are
only weakly acidic in nature and phenol is more acidic than them.
76
Which of these when passed over heated Cu at 573 K forms an alkene ?

A An alkane

B An alkyne

C Secondary alcohol

D Tertiary alcohol
76
Which of these when passed over heated Cu at 573 K forms an alkene ?

A An alkane

B An alkyne

C Secondary alcohol

D Tertiary alcohol
3° Alcohol Alkene
77
The general molecular formula, which represents the homologous series
of alkanols is

A CnH2n+2O

B CnH2nO2

C CnH2nO

D CnH2n + 1O
77
The general molecular formula, which represents the homologous series
of alkanols is

A CnH2n+2O

B CnH2nO2

C CnH2nO

D CnH2n + 1O
78
Phenylmagnesium bromide reacts with methanol to give

A A mixture of anisole + Mg(OH)Br

B A mixture of benzene + Mg(OMe)Br

C A mixture of toluene + Mg(OH)Br

D A mixture of phenol + Mg(OH)Br


78
Phenylmagnesium bromide reacts with methanol to give

A A mixture of anisole + Mg(OH)Br

B A mixture of benzene + Mg(OMe)Br

C A mixture of toluene + Mg(OH)Br

D A mixture of phenol + Mg(OH)Br


79
Ethylene oxide when treated with Grignard reagent yield

A secondary alcohol

B tertiary alcohol

C cyclopropyl alcohol

D primary alcohol
79
Ethylene oxide when treated with Grignard reagent yield

A secondary alcohol

B tertiary alcohol

C cyclopropyl alcohol

D primary alcohol
80
Diethyl ether on heating with HI gives two moles of

A Ethanol

B Iodoform

C Ethyl iodide

D Methyl iodide
80
Diethyl ether on heating with HI gives two moles of

A Ethanol

B Iodoform

C Ethyl iodide

D Methyl iodide
81
Diethyl ether and ethanol are isomeric but ether boils at a much lower
temperature because

A Density of ether is less than that


of alcohol.

B Alcohol mixes with water but


ether does not.

C There is lack of hydrogen bonding


in ether.

D There are two methyl groups in


ether.
81
Diethyl ether and ethanol are isomeric but ether boils at a much lower
temperature because

A Density of ether is less than that


of alcohol.

B Alcohol mixes with water but


ether does not.

C There is lack of hydrogen bonding


in ether.

D There are two methyl groups in


ether.
Ethers have lower boiling points than their corresponding isomeric
alcohols because of hydrogen bonding in alcohols that is absent in ethers
82
Preparation of ethers by reacting sodium alkoxide with alkyl halide is
called

A Kolbe’s synthesis

B Williamson’s synthesis

C Wurtz reaction

D Cannizzaro’s reaction
82
Preparation of ethers by reacting sodium alkoxide with alkyl halide is
called

A Kolbe’s synthesis

B Williamson’s synthesis

C Wurtz reaction

D Cannizzaro’s reaction
Williamson Synthesis

SN2
83
Formation of diethyl ether from ethanol in presence of H2SO4 is based
on

A Dehydrogenation reaction

B Hydrogenation reaction

C Dehydration reaction

D Heterolytic fission reaction


83
Formation of diethyl ether from ethanol in presence of H2SO4 is based
on

A Dehydrogenation reaction

B Hydrogenation reaction

C Dehydration reaction

D Heterolytic fission reaction


By dehydration of Alcohol
Conc. H2SO4
2CH3CH2-OH CH2CH2-O-CH2CH3 + H 2O
413K
84
Phenol when first treated with concentrated sulphuric acid and then
with concentrated nitric acid, gives

A Nitrobenzene

B 2,4,6-trinitrophenol

C o-nitrophenol

D p-nitrophenol
84
Phenol when first treated with concentrated sulphuric acid and then
with concentrated nitric acid, gives

A Nitrobenzene

B 2,4,6-trinitrophenol

C o-nitrophenol

D p-nitrophenol
85
Lucas reagent is

A conc. HCl and anhydrous ZnCl2

B conc. HNO3 and hydrous ZnCl2

C conc. HCl and hydrous ZnCl2

D conc. HNO3 and anhydrous ZnCl2


85
Lucas reagent is

A conc. HCl and anhydrous ZnCl2

B conc. HNO3 and hydrous ZnCl2

C conc. HCl and hydrous ZnCl2

D conc. HNO3 and anhydrous ZnCl2


conc. HCl + anhydrous ZnCl2 is
Lucas Reagent
86
Assertion (A) : Hydroquinone is more acidic than resorcinol.
Reason (R) : -OH group shows +I effect.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


86
Assertion (A) : Hydroquinone is more acidic than resorcinol.
Reason (R) : -OH group shows +I effect.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Resorcinol is more acidic than hydroquinone.
OH− shows weak −I effect but strong +R effect.
87 Assertion (A) : Phenol reacts with CH3I in presence of NaOH to form
methoxybenzene.
Reason (R) : Phenoxide is better nucleophile than phenol.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


87 Assertion (A) : Phenol reacts with CH3I in presence of NaOH to form
methoxybenzene.
Reason (R) : Phenoxide is better nucleophile than phenol.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


88
Cumene process is the most important commercial method for the
manufacture of phenol. Cumene is

A Iso-propyl benzene

B Ethyl benzene

C Vinyl benzene

D Propyl benzene
88
Cumene process is the most important commercial method for the
manufacture of phenol. Cumene is

A Iso-propyl benzene

B Ethyl benzene

C Vinyl benzene

D Propyl benzene
89
For the reaction of phenol with CHCl3 in presence of KOH, the
electrophile is


A CHCl2

B ∶CCl2


C CHCl2

D None of these
89
For the reaction of phenol with CHCl3 in presence of KOH, the
electrophile is


A CHCl2

B ∶CCl2


C CHCl2

D None of these
90 Assertion (A) : o-Nitrophenol is less soluble in water than the
m- and p-isomers.
Reason (R) : m- and p- Nitrophenols exist as associated molecules.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


90 Assertion (A) : o-Nitrophenol is less soluble in water than the
m- and p-isomers.
Reason (R) : m- and p- Nitrophenols exist as associated molecules.

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D Both A and R are false


Correct Explanation : Due to the presence of intramolecular hydrogen
bonding, o-nitrophenol does not form hydrogen bonds with H2O but
m and p-nitrophenol form hydrogen bonds with water.
91
Which of the following is a polysaccharide?

A Glucose

B Maltose

C Glycogen

D Lactose
91
Which of the following is a polysaccharide?

A Glucose

B Maltose

C Glycogen

D Lactose
Glycogen is a polysachharide
92
Glucose is prepared from

A Sucrose

B Maltose

C Lactose

D Cellulose
92
Glucose is prepared from

A Sucrose

B Maltose

C Lactose

D Cellulose
93
Which one given below is a non reducing sugar?

A Glucose

B Sucrose

C Maltose

D Lactose
93
Which one given below is a non reducing sugar?

A Glucose

B Sucrose

C Maltose

D Lactose
Since the reducing groups of glucose and fructose are
involved in glycosidic bond formation, sucrose is a
non-reducing sugar.
94
Which of the following is a basic amino acid?

A Tyrosine

B Lysine

C Serine

D Alanine
94
Which of the following is a basic amino acid?

A Tyrosine

B Lysine

C Serine

D Alanine
95
Assertion: Glucose does not form the hydrogen bisulphite addition product
Reason: Glucose is not so reactive to form the product with NaHSO3

Both A and R are true and R is the correct


A explanation of A

Both A and R are true but R is not the


B correct explanation of A

C A is true but R is false

A is false but R is true


D
95
Assertion: Glucose does not form the hydrogen bisulphite addition product
Reason: Glucose is not so reactive to form the product with NaHSO3

Both A and R are true and R is the correct


A explanation of A

Both A and R are true but R is not the


B correct explanation of A

C A is true but R is false

A is false but R is true


D
96
Assertion : The two strands of DNA are complementary to each other.
Reason : The hydrogen bonds are formed between specific pairs of bases

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D A is false but R is true


96
Assertion : The two strands of DNA are complementary to each other.
Reason : The hydrogen bonds are formed between specific pairs of bases

A Both A and R are true and R is the


correct explanation of A

B Both A and R are true but R is not the


correct explanation of A

C A is true but R is false

D A is false but R is true


97 Assertion: ⍺-amino acids exist as dipolar ions or zwitter ions in aqueous
solution
Reason: ⍺-amino acids are the building blocks of protein

Both A and R are true and R is the correct


A explanation of A

Both A and R are true but R is not the


B correct explanation of A

C A is true but R is false

A is false but R is true


D
97 Assertion: ⍺-amino acids exist as dipolar ions or zwitter ions in aqueous
solution
Reason: ⍺-amino acids are the building blocks of protein

Both A and R are true and R is the correct


A explanation of A

Both A and R are true but R is not the


B correct explanation of A

C A is true but R is false

A is false but R is true


D
❖ ⍺-amino acids exist as dipolar ions or zwitter ions because In aqueous
solution, the carboxyl group can lose a proton and amino group can accept a
proton, giving rise to a dipolar ion known as zwitter ion.
CASE: Read the passage given below and answer the following questions 98-100

When a protein in its native form, is subjected to physical changes like


change in temperature or chemical changes like change in pH, the hydrogen
bonds are disturbed. Due to this, globules unfold and helix get uncoiled and
protein loses its biological activity. This is called denaturation of protein. The
denaturation causes change in secondary and tertiary structures but primary
structures remains intact.
Examples of denaturation of protein are coagulation of egg white on boiling,
curdling of milk, formation of cheese when an acid is added to milk.
98
Denaturation of protein leads to loss of its biological activity by

A Formation of amino acid

B Loss of primary structure

C Loss of both primary and secondary


structure

D Loss of both secondary and tertiary


structure
98
Denaturation of protein leads to loss of its biological activity by

A Formation of amino acid

B Loss of primary structure

C Loss of both primary and secondary


structure

D Loss of both secondary and tertiary


structure
❖ During denaturation secondary and tertiary structures are destroyed but
primary structure remains intact.
99
α-helix and β-pleated structures of proteins are classified as

A primary structure

B secondary structures

C tertiary structure

D quaternary structure
99
α-helix and β-pleated structures of proteins are classified as

A primary structure

B secondary structures

C tertiary structure

D quaternary structure
In proteins the α-helix and β-pleated sheet are classified as:
Secondary structure.
100
Which of the following is/are example(s) of denaturation of protein?

A Coagulation of egg white

B Clotting of blood

C Curdling of milk

D Both (a) and (c)


100
Which of the following is/are example(s) of denaturation of protein?

A Coagulation of egg white

B Clotting of blood

C Curdling of milk

D Both (a) and (c)


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