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Aga Khan Academy, Nairobi

IB DP 1 Chemistry
Stoichiometric Relationships – SL & HL
September 2020
Name:
________________________________________________________________________________
For questions 1 to 20, work a side then choose the correct answer.
For questions 21-23, show all your workings in logical steps.
1. What amount of atoms, in mol, is present in 128 g of sulfur dioxide? (Avogadro’s constant = 6 x
1023 mol-1)
A. 1.2 x 1024
B. 3.6 x 1024
C. 2
D. 6

2. Which is the correct expression for converting the mass of a substance in grams to the
amount in moles?

A.

B.
C. mass x molar mass

D.

3. Which sample of fluorine gas, F2, contains the greatest number of fluorine molecules? (Avogadro’s
constant = 6 x 1023 mol-1)
A. 1.9 x 1023 F2 molecules
B. 1.9 dm3 of F2 at 273 K and 1.00 x 105 Pa pressure
C. 1.9 g F2
D. 1.9 mol F2

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4. What is the total number of ions present in the formula Na2SO4?
A. 2
B. 3
C. 4
D. 6

5. Which sample contains the least number of atoms?


A. 2 mol of NaCl
B. 2 mol of NH3
C. 1 mol of CH3COOH
D. 1 mol of H2O

6. Which has the same value as Avogadro’s constant?


A. Number of electrons in 1 mol of hydrogen gas
B. Number of ions in 1 mol of molten sodium chloride
C. Number of atoms in 1 mole of helium gas
D. Number of protons in 1 mol of argon gas

7. A compound has a molar mass of approximately 56 g mol-1. Which compound might this be?
A. AlP
B. AgOH
C. F2O
D. MgS

8. Which statement defines molecular formula?


A. The number of atoms present in one molecule of a compound
B. The number of elements present in one molecule of a compound
C. The number of atoms of each element in one molecule of a compound
D. The simplest ratio of the numbers of atoms of each element in a molecule of a compound

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9. Which sample has the greatest mass? (Avogadro’s constant = 6 x 1023 mol-1)
A. 1 mole of Na2S
B. 3.0 x 1024 molecules of O2
C. 8.8 x 101 g of NaCl
D. 1.2 x 1024 atoms of K

10. What would be the empirical formula of a hypothetical compound that contains 60% by mass
of element A (Ar = 10 ) and 40% by mass of element B (Ar = 20)?
A. A3B2
B. AB3
C. AB2
D. A3B

11. A compound has a relative molecular mass of 74. Which are possible formulas for the
compound?
I. CH3CH2CH2CH2OH
II. CH3CH2CH(OH)CH3
III. (CH3)3COH
A. I and II only
B. I and III only
C. II and III only
D. I, II and III

12. What is the sum of all the coefficients when the equation for the reaction of 1 mol of
potassium metal with water is balanced?
K(s) + __ H2O(l) → __ KOH(aq) + __ H2(g)
A. 2.5
B. 3.5
C. 5
D. 7

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13. Which change does not involve the gaseous state?
A. subliming
B. melting
C. condensing
D. evaporating

14. When calcium carbonate is heated it decomposes according to the equation:


CaCO3(s) → CaO(s) + CO2(g)
When 60 g of calcium carbonate is heated, 16.8 g of calcium oxide are formed. What is
the percentage yield?
A. 16.8%
B. 25%
C. 50%
D. 60%

15. Assuming that all volume are measured at the same temperature and pressure and the reaction
goes to completion what volume of ammonia, in cm3, can be prepared by reacting 20 cm3
of nitrogen gas with 30 cm3 of hydrogen gas?
N2(g) + 3H2(g) → 2NH3(g)
A. 20
B. 30
C. 40
D. 50

16. The equation for the complete combustion of methylpropane is


2CH3CH(CH3)CH3(g) + 13O2(g) → 8CO2(g) + 10H2O(l)
What amount, in mol, of carbon dioxide will be formed when three moles of
methylpropane are combusted completely?
A. 4
B. 8
C. 12
D. 16

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17. 10 cm3 of carbon monoxide and 10 cm3 of oxygen are mixed together at the same temperature
and pressure. What will be the total volume of gas present, in cm3, after they have reacted,
assuming that the volume is measured at the same temperature and pressure?
2CO(g) + O2(g) → 2CO2(g)
A. 10
B. 15
C. 20
D. 25

18. Which solution contains 0.2 mol of potassium hydroxide, KOH?


A. 1 cm3 of 0.2 mol dm-3 KOH(aq)
B. 10 cm3 of 0.2 mol dm-3 KOH(aq)
C. 100 cm3 of 2.0 mol dm-3 KOH(aq)
D. 1 dm3 of 2.0 mol dm-3 KOH(aq)

19. What volume, in cm3, of 0.200 mol dm-3 sodium hydroxide solution, NaOH(aq), is required
to neutralise exactly 25.0 cm3 of 0.100 mol dm-3 sulfuric acid solution, H2SO4(aq)?
A. 12.5
B. 25.0
C. 50.0
D. 100

20. What will be the concentration, in mol dm-3, of the resulting solution when 200 cm3 of
0.200 mol dm-3 hydrochloric acid, HCl(aq) are mixed with 300 cm3 of 0.100 mol dm-3 HCl(aq)?
A. 0.140
B. 0.300
C. 0.070
D. 0.150

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Show all your working in logical steps.

21. Nitrogen can be prepared in the laboratory by the following reaction:


2NH3(g) + 3CuO(s) → N2(g) + 3H2O(l) + 3Cu(s)

If 227 cm3 of ammonia, when reacted with excess copper oxide, produce 85 cm3 of nitrogen,
calculate the percentage yield of nitrogen. All gas volumes are measured at STP. [2]

22. A hydrocarbon contains 88.8% C. 0.201 g of the hydrocarbon occupied a volume of 98.9
cm3 at 320 K and 1.00 × 105Pa.
a Determine the empirical formula of the hydrocarbon. [2]
b Determine the molecular formula of the hydrocarbon. [2]

23. 25.0 cm3 of 0.100 mol dm−3 copper(II) nitrate solution is added to 15.0 cm3 of 0.500 mol
dm−3 potassium iodide. The ionic equation for the reaction that occurs is:
2Cu2+(aq) + 4I−(aq) → 2CuI(s) + I2(aq)
a Determine which reactant is present in excess. [2]
b Determine the mass of iodine produced. [2]

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