Anglo−Chinese School (Independent)

Year 5 (2022) IBDP Chemistry HL

Topic 1: Stoichiometric Relationships

Assignment 1a (Stoichiometry calculations involving solids and liquids)

Name : Jeremy Kek ( 10 ) Mark :

Class : 5.13 Date : 5 / 3 /2022

Section A: MCQ
Fill in your answers for MCQ in the squares provided

Question 1 2 3 4 5 6 7 8 9 10
Answer A D A B C B D A A B
Question 11 12 13 14 15
Answer B D D D A

1. Which statement about one mole of a metal is always correct?

A. It contains the same number of atoms as 1 mol of hydrogen atoms.

B. It contains the same number of atoms as 1/12 mol of 12C.
C. It has the same mass as 1 mol of hydrogen atoms.
D. It is liberated by 1 mol of electrons.

2. How many atoms of hydrogen are in 0.500 mol of CH3OH molecules?

A. 1.20×1023
B. 3.01×1023
C. 6.02×1023
D. 1.20×1024

3. Which of the following has the greatest mass?

A. 6.02 x 1025 atoms of helium gas

B. 10 moles of oxygen molecules
C. 1.2 x 1024 atoms of copper
D. 1 mole of gold atoms

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 4. What is the mass of hydrogen in a sample of glucose, C6H12O6, which contains 24.0 g of
carbon?

A. 2.0
B. 4.0
C. 6.0
D. 12.0

5. Tartaric acid, which occur in many fruits has a relative molecular mass of 150.1 and
contains 63.96 % oxygen by mass. The number of oxygen atoms in each tartaric acid
molecule is

A. 3
B. 4
C. 6
D. 8

6. When 8.00 g of hydrogen gas reacts with 32.0 g of oxygen gas in an explosion, (relative
atomic masses are H = 1.01 and O = 16.00), the final gas mixture at SATP will contain:

A. H2, H2O, and O2.

B. H2.
C. O2, H2O.
D. H2, H2O.

7. An unknown element M combines with O2 to form the compound MO2. If 24.0 g of element
M combines exactly with 16.0 g of oxygen gas, what is the atomic mass M in g mol−1?

A. 12 .0
B. 16.0
C. 24.0
D. 48.0

8. Calcium carbonate reacts with hydrochloric acid according to the following equation.

CaCO3 (s) + 2HCl (aq) → CaCl2 (aq) + CO2 (g) + H2O (l)

What is the theoretical yield, in mol, of calcium chloride if 0.10 mol CaCO3 is added to
100 cm3 of 1.0 mol dm−3 HCl?

A. 0.050
B. 0.10
C. 0.20
D. 0.50

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 9. BaO2, barium peroxide, decomposes when heated to give BaO and O2. If 0.500 mol of
BaO2 is decomposed, the number of moles of O2 formed is

A. 0.250
B. 0.500
C. 1.00
D. 4.00

10. 5.00 g of calcium carbonate, when heated, produced 2.40 g of calcium oxide. Which is
the correct expression for the percentage yield of calcium oxide? (Mr (CaCO3) = 100;
Mr (CaO) = 56.)

CaCO3 (s) → CaO(s) + CO2 (g)

A. 56×5.00×100
2.40
B. 2.40×100×100
56×5.00
C. 56×5.00×100
2.40×100
D. 2.40×100
56×5.00
11. Which one of the following compounds has the highest percentage by mass of iron?

A. FeCO3
B. FeO
C. Fe3O4
D. Fe2O3

12. The crystalline solid sodium ethanoate, CH3COONa.3H2O, may be converted to the
anhydrous form by heating. What mass of anhydrous salt could be obtained from 6.25 g
of the original hydrate? Molar mass of CH3COONa.3H2O = 136.08 g mol−1.

A. 10.7 g
B. 6.25 g
C. 5.42 g
D. 3.77 g

13. Nitroglycerine, C3H5N3O9, can be used in the manufacture of explosives. What is the
coefficient of C3H5N3O9 (l) when the equation for its decomposition reaction is balanced
using the lowest whole numbers?

___ C3H5N3O9 (l) → ___ CO2 (g) + ___ H2O (l) + ___ N2 (g) + ___ O2 (g)

A. 1
B. 2
C. 3
D. 4

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 14. A compound with the empirical formula CH3Li has a relative molecular mass of 87.92.
How many moles of hydrogen atoms will be present in each mole of the compound?

A. 3
B. 6
C. 9
D. 12

15. Which type(s) of formula can be determined by using only the percent composition data
for an unknown compound?
I. empirical formula
II. molecular formula

A. I only
B. II only
C. Both I and II
D. Neither I nor II

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Section B: Structured Questions

1. Two IB students carried out a project on the chemistry of bleach. The bleach contained a
solution of sodium hypochlorite, NaClO (aq). The students determined experimentally the
concentration of hypochlorite ions, ClO−, in the bleach:

Experimental procedure:
• The bleach solution was first diluted by adding 25.00 cm3 of the bleach to a 250 cm3
volumetric flask. The solution was filled to the graduation mark with deionised water.
• 25.00 cm3 of this solution was then reacted with excess iodide in acid.
ClO− (aq) + 2I− (aq) + 2H+ (aq)  Cl− (aq) + I2 (aq) + H2O (l)
• The iodine formed was titrated with 0.100 mol dm–3 sodium thiosulfate solution,
Na2S2O3 (aq), using starch indicator.
I2 (aq) + 2S2O32− (aq)  2I− (aq) + S4O62− (aq)

The following data were recorded for the titration:

First titre Second titre Third titre
Final burette reading of 0.100 mol dm−3 23.95 46.00 22.15
3
Na2S2O3 (aq) (in cm )
Initial burette reading of 0.100 mol dm−3 0.00 23.95 0.00
Na2S2O3 (aq) (in cm3)

(a) Calculate the volume, in cm3, of 0.100 mol dm−3 Na2S2O3 (aq) required to react with the
iodine to reach the end point.

(b) Calculate the amount, in mol, of Na2S2O3 (aq) that reacts with the iodine.

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(c) Calculate the concentration, in mol dm−3, of hypochlorite ions in the diluted bleach solution.

(d) Calculate the concentration, in mol dm−3, of hypochlorite ions in the undiluted bleach
solution.

2. Strontium hydroxide is isolated as a hydrate, Sr(OH)2.xH2O. When 6.85 g of the hydrate is

dried in an oven, 3.13 g of anhydrous Sr(OH)2 is formed. What is the value for x?

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3. Maleic acid is a diprotic carboxylic acid used in dyeing and as a preservative of fats. In a
combustion analysis, it is found that complete combustion of 0.0899 g maleic acid yields
0.1364 g CO2 and 0.0279 g H2O. Calculate the empirical formula of maleic acid.

4. A 10.0 g mixture of CaCO3 and MgCO3 was decomposed to form the metal oxide and carbon
dioxide, till a constant mass. The mass of the residue remaining was 5.1 g. Calculate the
percentage of MgCO3 in the mixture.

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