You are on page 1of 8

Silicon (2018) 10:1653–1660

https://doi.org/10.1007/s12633-017-9649-3

ORIGINAL PAPER

Study of the Enhancement of the Efficiency


of the Monocrystalline Silicon Solar Cell by Optimizing
Effective Parameters Using PC1D Simulation
Galib Hashmi1 · Abdur Rafique Akand2 · Mahbubul Hoq2 · Habibur Rahman1

Received: 16 December 2016 / Accepted: 2 October 2017 / Published online: 4 January 2018
© Springer Science+Business Media B.V., part of Springer Nature 2018

Abstract In this paper, simulation of a monocrystalline sil- 1 Introduction


icon solar cell was done using PC1D software. The impact
of different solar cell parameters, with their effects on The total power consumption of the world in 2015 was more
power and efficiency, has been investigated. For a p-type than 20,000 TWh [1], moreover, the statistics show that the
monocrystalline silicon wafer, with an area of 10 × 10 cm2 demand for energy is increasing all over the world. To cope
and a thickness of 300 μm, initial simulation shows a with this demand, one of the possible solutions is to utilize
12.10% efficient solar cell. To optimize the simulation energy efficient solar cells. It is expected that energy effi-
experimentally obtained data has been used in the textur- cient solar cells will contribute a significant portion of the
energy investment in the future.
ization process. It is seen that the textured surface reduces
Solar cells have come a lot further since 1839, when
reflection and increases the efficiency of the solar cell at
French experimental physicist Antoine-César Becquerel
least 1–2%. From the simulation it is seen that the optimum
discovered the photovoltaic effect [2]. Still, efficiency of the
value of p-type doping concentration is 1 × 1017 cm−3 and
solar cell is limited, and commercially available solar panel
n-type doping concentration is 1 × 1018 cm−3 . 200.3 μm
efficiency is about 13%. In all the cases of solar cell fab-
diffusion length is considered as optimum. Both sides tex-
rication, the experimental procedure proves to be difficult
tured wafer with pyramid height of 2–3 μm and equal angles for understanding, sometimes phenomena are not observ-
of 54.74 degrees produces the best result in simulation. An able or measurements are impractical. Furthermore, even
anti-reflection coating with 2.019 refractive index and a a little change in the solar cell fabrication process can be
thickness of 74 nm is considered as optimum. By optimiz- too expensive. Because change in any aspect of the fabri-
ing the effective parameters, a 20.35% efficient solar cell cation process is a difficult task, for this reason simulation
has been achieved by simulation. has gained importance over the past few years and allowed
the designers to change different parameters of the system
Keywords Solar cell · Doping concentration · thus enabling them to fabricate and observe the behavior of
Anti-reflection coating (ARC) · Diffusion length · the system [3]. Not only that, simulation has also enabled
Texturing the researchers to study and observe their theoretical inves-
tigations [4]. Last but not the least, it has vastly extended
the range and depth of application with minimum cost, and
provided better understanding of how the devices operate.
PC1D is a commercially available software most com-
 Galib Hashmi monly used for solar cell modeling [5]. This software is cur-
galib 90@yahoo.com rently used by many companies and universities such as the
University of New South Wales, Australia. Here the PC1D
1 Department of Electrical and Electronic Engineering, version 5.9 has been used to simulate an energy efficient
University of Dhaka, Dhaka, Bangladesh
monocrystalline silicon solar cell. The simulation also gives
2 Institute of Electronics, AERE, Bangladesh Atomic Energy insight about the range and impact of doping concentration,
Commission, Savar, Dhaka, Bangladesh diffusion length, texturing and anti-reflection coating.
1654 Silicon (2018) 10:1653–1660

2 Simulation of Monocrystalline Solar Cell In Fig. 2, the blue line shows the I-V curve and the red
line shows the P-V curve of the 12.10% efficient solar cell.
Efficient and accurate modeling requires all the parame- The current (I) versus voltage (V) curve of a solar cell shows
ters of the solar cell to be involved, but for simplicity and all the possible combinations of its current and voltage
to understand the impact of the parameters, some of the outputs, whereas, the power (W) versus voltage (V) curve
parameters like texturing and anti-reflection coating are not shows all the possible combinations of its power and voltage
considered at first. Typically a solar cell thickness varies outputs. The point in the I-V curve where voltage and cur-
from 100 to 500 nm and normally the area is of 10 × 10 cm2 rent is maximum is called the maximum power point (MPP).
or 12.5 × 12.5 cm2 [6]. So, a p-type silicon wafer, with an In the P-V curve MPP is the point where power has the high-
area of 10 × 10 cm2 and thickness of 300 μm was selected est value. In both I-V and P-V curves the maximum power
for solar cell simulation. The doping concentration of a point is represented as Pm. Also the maximum voltage and
monocrystalline silicon wafer varies from 1 × 1012 cm−3 to maximum current is designated as Vm and Im. The val-
1 × 1020 cm−3 as shown in Fig. 1 [7]. High doping concen- ues of short circuit current (Isc), open circuit voltage (Voc),
tration in a p-type wafer increases Voc (open circuit voltage) Im, Vm, Pm, efficiency and fill factor are shown in Table 1.
but at the cost of damaging the crystal [8]. So, moderate
doping is generally used in a p-type silicon wafer. Thus the
doping concentration of the p-type silicon wafer has been 3 Impact of Doping Concentration
randomly adjusted to 5 × 1016 cm−3 at first.
By using a four point probe instrument it is seen that The doping concentration of the p-type silicon wafer was
normally p-type wafer sheet resistivity varies from 0.01 to changed to find out the optimum doping concentration and its
10 .cm. Because of variation in doping concentration, the impact on the efficiency of the solar cell. At first, doping
sheet resistivity varies. The sheet resistivity decreases with concentration of the emitter (n-type) was kept fixed at 1 ×
the increase of doping concentration. For doping concen- 1019 cm−3 . Then the p-type silicon wafer doping concentration
tration 5 × 1016 cm−3 , the p-type wafer sheet resistivity was changed in the simulation. After completion of the simu-
is 0.3441 .cm [9]. So 0.3441 .cm was considered at lation, data was tabulated in Table 2 and the I-V curve due to
first for simulation. The doping level of the emitter (n- different doping concentrations was drawn and is shown in
type) has been randomly adjusted to 1 × 1019 cm−3 to Fig. 3. In Fig. 3, blue, red, green, violet, yellow, brown and
form a p-n junction. For 1 × 1019 cm−3 the emitter (n-type) black color respectively represents the following doping con-
sheet resistance is 26.11 / (ohms/square). 26.11 / centrations, 1 × 1014 cm−3 , 1 × 1015 cm−3 , 1 × 1016 cm−3 ,
was considered as the sheet resistance of the emitter. Nor- 1 × 1017 cm−3 , 1 × 1018 cm−3 and 5 × 1016 cm−3 .
mally the thickness of the emitter (n-type) varies from From the simulated data, in Table 2 and from Fig. 3,
1–2 μm. So in this simulation, the thickness of the emitter it is seen that increasing doping concentration does not
was adjusted to 2 μm and uniform doping profile condi- always increases efficiency. Especially when, the p-type sil-
tion has been assumed. Diffusion length must be less than icon wafer doping concentration is more than or closer to
the thickness of the p-type material. The thickness of the the doping concentration of the n-type wafer, efficiency
p-type wafer is selected as 300 μm and, at first, diffusion drastically decreases. Because of excessive doping, excess
length was randomly considered, 144.3 μm. To observe the minority carrier lifetime is reduced, thus the minority carrier
impact of the antireflection coating (ARC), ARC was not diffusion length is also reduced [10]. Also, carrier mobil-
applied at first. To emulate the sun, AM (Air Mass) −1.5 G ity decreases with increasing total dopant concentration thus
condition was selected. Also, to see the time progression, reducing efficiency [11]. Low p-type doping concentration
the number of time steps was selected as 100. After running
the simulation, it is seen that the efficiency of the solar cell
is 12.10%.
I-V and P-V Curve
2.5

2
Low doping Moderate doping Heavy doping 1.5
(A)
1 (W)
0.5
12 14 16 18 20
10 10 10 10 10 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
-3
Dopant Concentration [cm ] Voltage(V)

Fig. 1 Range of doping concentration Fig. 2 I-V and P-V curve of 12.10% efficient solar cell
Silicon (2018) 10:1653–1660 1655

Table 1 Data of 12.10 % efficient solar cell I-V curve with various p-type doping concentration

3
Isc Voc Vm Im Pm FF Efficiency doping
1x10^14
2.5 doping
2.28 A 0.636 V 0.56 V 2.16 A 1.21 W 0.835 12.10% 1x10^15
2 doping

Current (A)
1x10^16
doping
1.5 1x10^17
doping
1 1x10^18
also shows an unfruitful result. Here, from the simulation, doping
1x10^19
optimum p-type doping concentration has been found to be 0.5 doping

1 × 1017 cm−3 . As p-type doping concentration varies from


5x10^16
0
1 × 1012 cm−3 to 1 × 1020 cm−3 [7], the optimum p-type 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Volatge (V)
doping concentration falls in this range.
Next, by keeping p-type doping concentration fixed at Fig. 3 I-V curve with various p-type doping concentration (n-type
5 × 1016 cm−3 , n-type doping concentration has been var- doping concentration fixed at 1 × 1019 cm−3 )
ied in the PC1D simulation. After that both p-type and
n-type doping concentration were varied. The results are 4 Impact of Diffusion Length
tabulated in Table 3 and I-V curves drawn as shown in
Figs. 4 and 5. In Fig. 4, black, red, green, brown, yel- The key in improving the efficiency of solar cells lies in
low and blue color represents n-type doping concentrations increasing the minority-carrier lifetime [13]. Moreover, the
1×1019 cm−3 , 1×1020 cm−3 , 1×1018 cm−3 , 1×1017 cm−3 , relationship between minority carrier lifetime and diffusion
5 × 1018 cm−3 and 5 × 1017 cm−3 , respectively. In addition, length is
in Fig. 5 black, blue and red color respectively represents √
L = Dτ [14].
n-type doping concentration as 5 × 1017 cm−3 , 1 ×
1018 cm−3 and 1 × 1019 cm−3 and p-type doping concentra- Where L is the diffusion length in meters, D is the diffu-
tion as 5 × 1016 cm−3 , 1 × 1017 cm−3 and 1 × 1017 cm−3 . sivity in m2 /s and τ is the lifetime in seconds. If diffusion
It is seen from Table 3, Figs. 4 and 5 that optimum dop- length is increased, minority carrier lifetime is increased,
ing concentration of the p-type wafer is 1 × 1017 cm−3 and thus the efficiency of the solar cell is increased. However,
n-type is 1 × 1018 cm−3 . At that doping concentration max- for a monocrystalline silicon solar cell, typically the diffusion
imum efficiency is 12.94% with fill factor value 0.8395. length is 100–300 μm [14]. Moreover, the diffusion length
Note that, for n-type doping concentration 1 × 1021 cm−3 must be less than the thickness of the p-type material [15].
and p-type doping concentration 5 × 1016 cm−3 transient As p-type wafer thickness is 300 μm, the maximum value of
convergence failure occurs as shown in Table 3. The tran- diffusion length is considered to be 200.3 μm. By observing
sient convergence failure indicates error in the result [12] some actual wafer specifications it is seen that the minimum
i.e. convergence for a transient simulation cannot provide a minority carrier lifetime is 10 μs [16] (equivalent to diffu-
solution using the PC1D simulation. This can be caused by sion length 130.5 μm). So, a diffusion length of 130.5 μm
numerous factors like time steps, non-linearity etc. Mainly is also used in the simulation. Lastly, the lowest value of dif-
because the solar cell is a non-linear model for those param- fusion length 100 μm is used in the simulation. It is seen
eters it is unable to provide a result and for that transient from Table 4 that with optimum doping concentration and
convergence failure occurs. having 200.3 μm diffusion length the efficiency of the solar

Table 2 Data of solar cell with various p-type doping concentration

Material Doping concentration Short circuit current (Isc) Open circuit voltage (Voc) Max power (W) Fill factor (FF) Efficiency

P-type 5 × 1016 cm−3 2.275 A 0.6364 V 1.210 W 0.835745022 12.10%


P-type 1 × 1016 cm−3 2.311 A 0.5953 V 1.138 W 0.827192207 11.38%
P-type 1 × 1014 cm−3 2.439 A 0.4891 V 0.7964 W 0.667608394 7.964%
P-type 1 × 1015 cm−3 2.343 A 0.5363 V 1.006 W 0.800604257 10.06%
P-type 1 × 1017 cm−3 2.258 A 0.6526 V 1.236 W 0.838778836 12.36%
P-type 5 × 1017 cm−3 2.184 A 0.6597 V 1.208 W 0.838431943 12.08%
P-type 1 × 1018 cm−3 2.116 A 0.6543 V 1.160 W 0.837848325 11.60%
P-type 1 × 1019 cm−3 1.592 A 0.5952 V 0.6917 W 0.729981392 6.917%
P-type 1 × 1020 cm−3 −9.166e-5 A 2.196e-10 V – – –
1656 Silicon (2018) 10:1653–1660

Table 3 Data of solar cell with various n-type and p-type doping concentration

Doping concentration Doping concentration Short circuit Open circuit Max power Fill factor Efficiency
(n-type) (p-type) current (Isc) voltage (Voc) (W) (FF)

1 × 1019 cm−3 5 × 1016 cm−3 2.275 A 0.6364 V 1.210 W 0.835745022 12.10%


1 × 1020 cm−3 5 × 1016 cm−3 1.433 A 0.6079 V 0.7232 W 0.830194943 7.232%
1 × 1021 cm−3 5 × 1016 cm−3 1.058 A – 0.5046 W Transient convergence failure
1 × 1018 cm−3 5 × 1016 cm−3 2.335 A 0.6412 V 1.263 W 0.843573546 12.63%
1 × 1017 cm−3 5 × 1016 cm−3 2.356 A 0.6410 V 1.263 W 0.836315286 12.63%
5 × 1018 cm−3 5 × 1016 cm−3 2.334 A 0.6395 V 1.248 W 0.836128804 12.48%
5 × 1017 cm−3 5 × 1016 cm−3 2.356 A 0.6412 V 1.263 W 0.836054427 12.63%
1 × 1018 cm−3 1 × 1017 cm−3 2.334 A 0.6604 V 1.294 W 0.839510940 12.94%
1 × 1019 cm−3 1 × 1017 cm−3 2.258 A 0.6526 V 1.236 W 0.838778836 12.36%

cell is 13.75%. It should be noted that if diffusion length is 54.74◦ . Pyramids having equal angles of 48◦ have also been
increased more the efficiency will increase but for a realistic found as shown in Fig. 7.
approach the diffusion length is considered to be 200.3 μm. Taking the value from the practically obtained data tex-
turization was done in the simulation. Both front surface and
back surface texturization, only front surface texturization,
5 Texturization and its Impact on the Solar Cell and only back surface texturization procedures were done.
Also, pyramid heights and angles were changed in the sim-
Texturization on the solar cell is done to reduce reflection ulation. Simulation shows that the front and back surface
and enhance light absorption. Texturization normally cre- textured wafer, having pyramids with height 2–3 μm and
ates an uneven surface, that is pyramid-like structures form having an equal angle of 54.74◦ has the maximum efficiency
on the surface of the p-type wafer as shown in Fig. 6. of 14.02%. Similar results have also been found for only
Texturization is normally done using a wet chemical front surface texturing, but as only one-sided texturing is a
recipe. Here, a cleaned p-type wafer was textured using difficult and costly procedure and after the diffusion process
0.763 wt% KOH–4 wt% IPA solution. Generally pyramid it is difficult to identify the textured surface, both surface
height varies from 1–6 μm. By using a stylus surface pro- texturing is considered optimum. All the results from the
filometer the height of the peak of the pyramids was mea- simulation are tabulated in Table 5. It suffices to say textur-
sured. The result shows pyramid height lies in the range of ization increases at least 1% to 2% efficiency of the solar
1–3.5 μm. Also from the SEM image, pyramid angles were cell.
measured using triangle maker software. Although pyramid
angle being equilateral is theoretically possible but practi-
cally isosceles pyramid structures are formed. Measurement 6 Impact of Anti-reflection Coating
shows isosceles pyramids having equal angles of maximum
The anti-reflection coating (ARC) shows the most signif-
Various Ntype Doping Concentration with fixed icant change in efficiency in this simulation. To design
5x10^16 cm-3 ptype doping concentration
doping
2.5
ntype
1x10^19 OPTIMUM DOPING CONCENTRATION
doping doping ntype
2 2.5
ntype 5x10^17
1x10^20 doping ptype
doping 5x10^16
Current (A)

1.5 2
ntype
CURRENT (A)

1x10^18 doping ntype


1.5
1 doping 1x10^18
ntype doping ptype
1x10^17 1 1x10^17
0.5 doping
ntype
0.5 doping ntype
5x10^18
1x10^19
0 doping doping ptype
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 ntype 0 1x10^17
Voltage(V) 5x10^17 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
VOLTAGE (V)
Fig. 4 I-V curve with various n-type doping concentration (p-type
doping concentration fixed at 5 × 1016 cm−3 ) Fig. 5 I-V curve of solar cell with optimum doping concentration
Silicon (2018) 10:1653–1660 1657

the ARC layer the following equations [15] were used to

Efficiency

12.94%
13.75%
12.45%
determine, the thickness and refractive index of the ARC
layer.

Refractive index of ARC is ηAR = ηair ∗ ηsi (λ0 )

0.839510940

0.857172718
λ0

0.84249973
And the thickness of ARC is d =
Fill factor
4 ∗ ηAR
(FF) Using both equations, thickness and refractive index of
the ARC layer are tabulated in Table 6.
Varying the refractive index and thickness the simulation
Max power

efficiency of the solar cell was calculated and tabulated as


1.294 W
1.375 W
1.245 W
shown in Table 7. It is seen that if the thickness of the ARC
(W)

layer is 74 nm then the maximum efficiency of 20.35% can


be achieved. If the thickness of the ARC layer is higher (e.g.
100 nm) than or lower than (e.g. 68 nm) 74 nm then the
voltage (Voc)
Open circuit

efficiency decreases. That is for 74 nm thickness the solar


0.6604 V
0.6744 V
0.6522 V

spectrum is absorbed more effectively.

7 Result and Discussion


Short circuit
current (Isc)

The result shows that with p-type doping concentration


2.334 A
2.420 A
2.227 A

1 × 1017 cm−3 , n-type doping concentration 1 × 1018 cm−3 ,


diffusion length 200.3 μm, both sides textured wafer (pyra-
mid height 2–3 μm and equal angle of 54.74◦ ) and with
anti-reflection coating thickness of 74 nm and refractive
Minority carrier

index 2.019, maximum efficiency of 20.357% was achieved.


lifetime (μs)

These optimum parameters are compared with published


literature and it is found that the values are feasible as
24.18
5.822

shown in Table 8. In Fig. 8, the blue curve represents the


10

I-V curve of the solar cell with no ARC and texturing. The
red curve represents the I-V curve of the solar cell with no
ARC but with texturing. Last but not least the green curve
Diffusion length
(Micrometer)

represents I-V of the solar cell with ARC and texturing. The
130.5
200.3
Table 4 Data of solar cell with different diffusion (DL ) length

100
Doping concentration

1 × 1017 cm−3
1 × 1017 cm−3
1 × 1017 cm−3
(p-type)
Doping concentration

1 × 1018 cm−3
1 × 1018 cm−3
1 × 1018 cm−3
(n-type)

Fig. 6 Textured wafer


1658 Silicon (2018) 10:1653–1660

(a) 54.74° (b) 48°


Fig. 7 Isosceles pyramid angles

Table 5 Data of textured solar cell

Doping concentration 1 × 1018 cm−3 Short circuit Open circuit Max power Fill factor Efficiency Efficiency increased
(n-type), 1 × 1017 cm−3 current (Isc) voltage (Voc) (W) (FF)
(p-type) DL = 200.3
(1.402−1.375)
Not textured 2.420 A 0.6744 V 1.375 W 0.84250 13.75% 1.375 ∗ 100 = 1.96364%
Textured 2.466 A 0.6748 V 1.402 W 0.84252 14.02%
Front and back surface textured
Angle 54.74◦
Depth 3 μm
(1.402−1.375)
Textured 2.466 A 0.6748 V 1.402 W 0.84252 14.02% 1.375 ∗ 100 = 1.96364%
Front and back surface textured
Angle 54.74◦
Depth 2 μm
(1.402−1.375)
Textured 2.466 A 0.6748 V 1.402 W 0.84252 14.02% 1.375 ∗ 100 = 1.96364%
Front and back surface textured
Angle 54.74◦
Depth 1 μm
(1.401−1.375)
Textured 2.465 A 0.6747 V 1.401 W 0.84238 14.01% 1.375 ∗ 100 = 1.8909%
Front and back surface textured
Angle 54.74◦
Depth 5 μm
(1.395−1.375)
Textured 2.454 A 0.6747 V 1.395 W 0.84254 13.95% 1.375 ∗ 100 = 1.454545%
Front and back surface textured
Angle 48◦
Depth 3 μm
(1.402−1.375)
Textured 2.466 A 0.6748 V 1.402 W 0.84252 14.02% 1.375 ∗ 100 = 1.96364%
Front surface textured
Angle 54.74◦
Depth 2 μm
(1.395−1.375)
Textured 2.420 A 0.6744 V 1.374 W 0.84189 13.74% 1.375 ∗ 100 = 1.454545%
Back surface textured
Angle 54.74◦
Depth 2 μm
Silicon (2018) 10:1653–1660 1659

Table 6 Thickness and


refractive index of ARC layer Wavelength Refractive index of silicon Refractive index of Thickness
(nm) [17] ARC (nm)

25 1.69 1.301538 48.02013


30 5.05 2.248333 33.35805
40 5.58 2.363684 42.30685
50 4.29 2.071956 60.32948
55 4.07 2.019158 68.09768
60 3.93 1.984691 75.578
65 3.84 1.960612 82.88228
70 3.77 1.942679 90.08181
75 3.72 1.929508 97.17505
80 3.68 1.918593 104.24
90 3.62 1.9026 118.2574
1000 3.57 1.889444 132.31

Table 7 Data of anti-reflection layer coated solar cell

Doping concentration 1 × 1018 cm−3 Short circuit Open circuit Max power Fill factor Efficiency
(n-type), 1 × 1017 cm−3 (p-type) current (Isc) voltage (Voc) (W) (FF)
DL = 200.3 (Textured)

No ARC 2.466 A 0.6747 V 1.402 W 0.8426441910261158 14.02%


Thickness 750 nm, RI = 2 3.059 A 0.6801 V 1.756 W 0.844057940251561 17.56%
Thickness 118 nm, RI = 1.9 3.232 A 0.6816 V 1.860 W 0.8443295914098452 18.60%
Thickness 60 nm, RI = 2.071 3.461 A 0.6837 V 1.997 W 0.8439386672539161 19.97%
Thickness 68 nm, RI = 2.019 3.511 A 0.6841 V 2.027 W 0.8439239825584603 20.27%
Thickness 74 nm, RI = 2.019 3.524 A 0.6843 V 2.035 W 0.8438824864402391 20.35%
Thickness 100 nm, RI = 2.019 3.347 A 0.6827 V 1.929 W 0.844202458217777 19.29%

Table 8 Comparison table

Parameters of solar cell Published literature/experimental value Simulated optimum value Remark

P-type doping concentration range 1 × 1012 cm−3 to 1 × 1020 cm−3 [7] 1 × 1017 cm−3 Optimum value is within the range
N-type doping concentration range 1 × 1012 cm−3 to 1 × 1020 cm−3 [7] 1 × 1018 cm−3 Optimum value is within the range
Diffusion length 100–300 μm [14] 200.3 μm Optimum value is within the range
Textured wafer pyramid height 1–6 μm [18] 1–3.5 μm (Experimental) 2–3 μm Optimum value is within the range
Textured wafer pyramid angle 60◦ (Theoretical) 54.78◦ (Experimental) 54.78◦ Optimum value is within the range
ARC layer thickness 30–135 nm [19] 74 nm Optimum value is within the range
1660 Silicon (2018) 10:1653–1660

SOLAR CELL EFFICIENCY References


4 12.1%
3.5 No ARC,
No
1. World power consumption | Electricity consumption | Enerdata,
3 Texturing Yearbook.enerdata.net (2017) [Online]. Available: https://yearbook.
CURRENT (A)

2.5 14.02%
enerdata.net/electricity-domestic-consumption-data-by-region.html.
No ARC, Accessed date: 07 July 2017
2
Textured 2. Quiebras J (2013) Wet chemical textures for crystalline silicon
1.5 solar cells, Ph.D. thesis, Department of Physics, University of
1 20.35%, Konstanz, Germany
ARC,
0.5 Textured 3. Hosseinpour F, Hajihosseini H (2009) Importance of simulation
0
in manufacturing. Int J Sociol Behav Educ Econ Bus Indus Eng
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 3(3):229–232
VOLTAGE (V) 4. Research and development in simulation-based engineering and
science, Wtec.org (2017) [Online]. Available: http://www.wtec.
Fig. 8 20.35% efficient solar cell I-V curve org/sbes/. Accessed date: 07 July 2017
5. PC1D, PVEducation (2017) [Online]. Available: http://www.
pveducation.org/pvcdrom/characterisation/pc1d. Accessed date:
blue curve also represents the initial simulation showing a 07 July 2017
12.10% efficient solar cell. This solar cell has been opti- 6. Silicon solar cell parameters | PVEducation, Pveducation.org
(2017) [Online]. Available: http://www.pveducation.org/pvcdrom/
mized by proper application of the ARC and texturization
design/solar-cell-parameters. Accessed date: 07 July 2017
process thus making a 20.35% efficient solar cell (green 7. Reading 3: semiconductor materials for solar cells - TU Delft
curve). OCW, TU Delft OCW (2017) [Online]. Available: https://ocw.
tudelft.nl/course-readings/solar-cells-r3-semicon-materials/.
Accessed date: 07 July 2017
8. Ruge I, Graul J (eds.) (1971) Ion implantation in semiconductors.
8 Conclusion In: Proceedings of the 2nd international conference on ion implan-
tation in semiconductors, physics and technology, fundamental
Simulation of a monocrystalline silicon solar cell has been and applied aspects May 24–28, 1971, Garmisch-Partenkirchen,
Bavaria, Germany, 1st edn., p. XIV, 508. Springer, Berlin
done by PC1D software. All the optimum solar cell param- Heidelberg. ISBN: 978-3-642-80662-9. https://doi.org/10.1007/
eters used in the simulation are compared with published 978-3-642-80660-5
literature and it is found that the values are feasible. With 9. Geerligs L, Macdonald D (2004) Base doping and recombina-
the assist of experimentally obtained values, the texturiza- tion activity of impurities in crystalline silicon solar cells. Prog
Photovolt Res Appl 12(4):309–316
tion process has been thoroughly investigated in the PC1D 10. Brendel R (2011) Thin-film crystalline silicon solar cells. Wiley,
simulation. It is adequate to say that by applying the tex- Weinheim
turing effect on the solar cell at least 1–2% increase in 11. Zeghbroeck B (2011) Principles of semiconductor devices,
efficiency is to be expected in a real world solar cell fabrica- Ecee.colorado.edu. [Online]. Available: http://ecee.colorado.edu/
∼bart/book/. Accessed date: 07 July 2017
tion scenario. It can be claimed that the key accomplishment 12. Quarles T (1989) Analysis of performance and convergence issues
is by thoroughly investigating a different process, espe- for circuit simulation
cially texturization, and optimizing different parameters in 13. Dimitriadis C (1986) Effect of doping concentration on the per-
formance of large-grain polycrystalline silicon solar cell. J Appl
the PC1D simulation, a more than 20% efficient solar cell
Phys 59(6):2259–2261
has been obtained. Simulation facilitates us by making bet- 14. Hashmi G, Akand M, Basher M, Hoq M, Rahman M (2016) Fab-
ter decisions, thus it is one of the cost saving strategies rication of crystalline silicon solar cell in Bangladesh: limitations
for engineering [20]. Promoting simulation of the solar cell and remedies. Int J Scientific Eng Res 7(5):581–586
15. Luque A, Sala G, Palz W, Santos G, Helm P (1991) Tenth E.C.
before actual fabrication may minimize a lot of the cost and photovoltaic solar energy conference. Springer, Dordrecht
gives an in-depth reason of what to expect by changing the 16. Solar wafers for solar cell manufacturing | Targray, Targray (2017)
parameters. [Online]. Available: http://www.targray.com/solar/crystalline-cell-
materials/solar-wafers. Accessed date: 07 July 2017
17. Green M, Keevers M (1995) Optical properties of intrinsic silicon
Acknowledgments The authors express their thanks to the Univer- at 300 K. Prog Photovolt Res Appl 3(3):189–192
sity of New South Wales, Australia for providing the PC1D software. 18. Wang X, Alam M (2013) Estimating pyramid density of a random-
This work has been supported by the scholarship program of the ICT textured surface by capacitance-voltage measurement of c-Si solar
Division, Ministry of Posts, Telecommunications and IT, Government cells. In: 2013 IEEE 39th photovoltaic specialists conference
of Bangladesh. The authors also thank Bangladesh Atomic Energy (PVSC)
Commission, for giving access to the solar cell fabrication laboratory 19. Dzhafarov T (2013) Silicon solar cells with nanoporous silicon
for texturization process and Glass and Ceramic Engineering Depart- layer. INTECH Open Access Publisher
ment, Bangladesh University of Engineering Technology for allowing 20. Aberdeen group white paper: cost saving strategies for engineer-
the use of their laboratory for measurement. Finally, the authors also ing - using simulation to make better decisions, IDGA (2017)
express their gratitude to the Faculty of Engineering and Technology [Online]. Available: https://www.idga.org/intelligence/white-papers/
and Department of Electrical and Electronic Engineering, University aberdeen-group-white-paper-cost-saving-strategies. Accessed date:
of Dhaka for contributing to this kind of research. 07 July 2017

You might also like