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QUESTION 1
QUESTION 2
QUESTION 3
QUESTION 4
QUESTION 5
QUESTION 6
QUESTION 7
1. Sulfur is needed for the production of sulfuric acid. Two of the major sources of
sulfur are
● underground deposits of the element sulfur,
● sulfur compounds from natural gas and petroleum.
(a) Explain why sulfur and its compounds are removed from these fuels before they
are burned.
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(b) Sulfur dioxide is made by spraying molten sulfur into air. The sulfur ignites and
sulfur dioxide is formed. (i) Suggest why molten sulfur is used in the form of a fi ne
spray.
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(ii) Explain why traces of sulfur dioxide act as a preservative in fruit juices.
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(c) Describe how sulfur dioxide is changed into sulfur trioxide. Give the reaction
conditions and an equation.
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(d) Complete the following equations for the formation of sulfuric acid from sulfur
trioxide.
SO3 + ............... → H2S2O7
H2S2O7 + ………. → ..........H2 SO4 [2]
2. Sulfuric acid is a strong acid. Hexanesulfonic acid is also a strong acid. It has similar
properties to sulfuric acid.
(a) Sulfonic acids are made from alkanes and oleum, H2S2O7.
C6H14 + H2S2O7 → C6H13SO3H + H2SO4
(i) Describe how oleum is made from sulfur by the Contact process. Give equations
and reaction conditions.
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(b) Calcium hydroxide, slaked lime, is made from calcium oxide. Write an equation
for this reaction.
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(c) Calculate the maximum mass of calcium oxide which could be made from 12.5
tonnes of calcium carbonate. 1 tonne = 1 × 106 g.
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(d) Limestone is used in agriculture to reduce the acidity of soil and for the
desulfurisation of fl ue gases in power stations. (i) Most crops thrive in soils whose
pH is close to 7. Calcium carbonate, which is insoluble in water, and calcium oxide,
which is slightly soluble in water, are both used to reduce the acidity of soils.
Suggest two advantages of using calcium carbonate for this purpose.
1. ..................................................................................................................................
2. ............................................................................................................................. [2]
(ii) Sulfur is used to make sulfuric acid. Give one source of sulfur.
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(iii) Sulfur is oxidised by air to form sulfur dioxide. Give one use of sulfur dioxide.
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(a) Sulfur is a common starting material for the Contact process. Name a source of
sulfur.
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(b) Describe step 2, giving reaction conditions and a chemical equation. Reference
to reaction rate and yield is not required
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……………………………………………………………………………………………….[5]
(c) Step 3 involves adding sulfur trioxide to concentrated sulfuric acid to form oleum.
Complete the chemical equation for this reaction.
H2SO4 + SO3 → ................................ [1]
(d) Dilute sulfuric acid is a typical acid. A student adds excess dilute sulfuric acid to
a sample of solid copper(II) carbonate in a test-tube. (i) Give three observations the
student would make.
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● the letter W to show where waste gases exit the furnace. [2]
(ii) How do you know from the information in the diagram that slag is less dense than
molten iron?
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(b) Limestone (calcium carbonate) is one of the raw materials added to the blast
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(ii) Complete the chemical equation for this reaction. CaCO3 →CaO + ............... [1]
a) (i) Complete the box to give the chemical name and formula of lime. [2]
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MgCO3. Write a chemical equation for the reaction between magnesium carbonate
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