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    Coordinate Obj

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    ES EQ)-CEEELENE ACADEYIW Chemistry Coaching for XI, XIl, IIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit Tim 3. 5. 2 10. TEST- COORDINATION COMPOUNDS J Hrs. MM. 30 aurea onan, ae : (@) diamminechloro(tethylamine)platinum(t) co oe chloride Which of the following ligand can not act (©) (dimethylamine)chlorodiamminoplatinam(t1) as flexidentate ligand ? chloride @so, (b) CH; - coo" (©) Isothiocynate (d) Carbonate Neutral and symmetrical bidentate ligand is : (@) Oxalate (b) dien 14. (©) propylene diamine _(d) dipyridyl Incorrect statement is : (@) Hydrazine can act as bidentate ligand. (b) In urea, donar atom is oxygen (©) All bidentate ligands are chelating ligands (d) Number of Chelate rings = denticit Which of the following ias five donof>\S (coordinating) sites? ~\)\ Sere (©) Ethylene diamine triacetate ion © So) (@) Diethylene triamine ion How many EDTA‘ PENA acetate) molecules are required to make an 43, octahedral complex tha Ca eh? (a Six (8) Three (c) One (a). TW0> The m-acid ligand which uses its d-orbital during synergic. bonding» in its complex compound?" @NO'C AAA PR (©) CoHe ) \™ (dco Incorrect statement for addition compound (@) Triethylene tetramine (©) Ethylene diamine tetra acetate ion ow (@) Simple salf8’do not lose their identity in 14, double sat. (b) Complex compounds retain their identity in aqueous solution, (©) Simple salts lose their identity in complex ‘compound (d) Double salts retain their identity in aqueous solution ‘ TUPAC name of Hi [PtCld is + (a) hydrogen hexachloroplatinate (IV) (b) dihydrogen hexachloroplatinate (IV) (©) hydrogen hexachloroplatinic (IV) acid 415: (d) hexachloroplatinic (IV) acid. ‘The IUPAC name for [P(C1(NH;CH;) (NH3):] Cl is: ».@) Sodium amminebromochloronitro-N- © bis(ammine)ehforo(methylamine)platinate(Il) chloride SA ~ © diaminechiosdtinehylamine)platinum(tIeloride The IUPAC. nomenclature for the complex.Na [PtBrC\(NO3) (NHS)] is: (@ Sodium amminethlorobromonitro-N- platinum(tt)— SOx “Sodium nitrochlorobromoammine-N-platinate sl) ~ (a SSouiuts amminebromochloronitro-N-patinate i) atinurn(t) The IUPAC name of Xe [Pt Fe] is: (a) Hexafluoroplatinate(VI)xenon (b) Xenonhexafluoroplatinate (V) (c) Xenonhexafluoroplatinate (VI) (d) Xenoniumhexafluoroplatinum(V) The coordination number of a central metal atom in.a complex is determined by : (@ the number of only anionic ligands bonded to the metal ion (the number of monodentate ligands around a metal ion bonded by pi-bonds (©)the number of monodentate ligands around a ‘metal ion bonded .by a and pi-bonds both (@the number of monodentate ligands aroui ‘metal ion bonded by a-bonds Which statement about coordination number cation is true? (a)Most metal ions exhibit only a s characteristic coordination number (b) The coordination number is equal to the nui of ligands bonded to the metal atom (c) The coordination number is determined sole the tendency to surround the metal atom the same number of electrons as one of the gases (d)For most cations, the coordination nu] depends on the size, and charge of the cation What is the oxidation number of Fe in [Fe(H0)(No) ?* ion ? (+2 (b) +3 + (0 'ADD- 54, HANUMAN NAGAR, cHANKYA PURI (NEAR PUSPANJALI BUILDING) AGRA. Ph : - 9412425629 BIO-CHENM ACADENVWY 7 it Chemistry Coaching for XI, XIl, lIT/ AIEEE/ CBSE/ Medical Entrance Exow By: Dr. Mohit Dixit Wh ‘h_ of the following complexes have a ‘maximum number of unpaired electrons ? (@) [Ni(CO).) (b) [Co(NH)«(NO2)2]" © LAgKCNT (4) (CuBr The degeneracy of d-orbitals is lost under : (D Strong field ligand (11) Weak field ligand (1) Mixed fieldigand (IV) Chelated ligand field Choose the coftect.code (@)|, Hand IV (b) Land 11 (©), Mylll and TV. ~—~(4) I, Mand IL The complex.ion (Fe(CN),\* contains : (@) total 6£36;lestzons on Fe* cation (). sp'd’ hybrid orbitals with octahedral structure EN] total of 104 electrons \ Adio clement forms octahedral complex but its magnetic moment remains same either in Strong field or in weak field ligand, Which of the following is/are correct ? (@) Element always forms colourless compound (b) Number of electrons in fa orbitals are less than ine,orbitals (©) Itcan have either dor d* configuration (@ It can have d’ or d configuration Select the correct statement about the erystal filed theory (@) Metal ligand bond in coordination compounds arises purely form electrostatic interation between the metal ion and the ligand, (b) Metal-ligand bond in coordination compound is purely a covalent bond, (©) The patter of splitting of the d-orbitals depends upon the nature ofthe erystal field (@) (@)and (©) both 16. The oxidation state of iron in Nag [Fe(CN)s 25, (N05) is (@)+1 (b) 42 +3 (a) zeroo 17. Which of the following cannot act as electrolyte a 26. @CoC1; 6NH, (@) CoC, SNH, (©)COC1; ANH, (@) CoCl INH; ‘ 18. A complex of platinum, ammonia and chlorine produces four ions per molecule in the aqueous solution. The structure pertaining to above observation 97, is: (a) Hexaammineplatinum (IV) chloride (b) Pentaamminechloroplatinum (IV) chloride (©) Diamminetetrachloroplatinum (IV) chloride elf (d) Tetraamminedichloroplatinum (IV) chloride ¢C~* \(@), Six sigma bonds 19. The oxidation number and co-ordin: number of cobalt in K[Co(CO)4] @+,4 04 O-+8 @14 . 20. In complex K, [FeF] the possible vilue-dt and QRS. 3 and g=3.87 BM i 1.73BM S , (©) x=4 and g= 4.90BM (OS (@ x=2 and g=3.87 BMAX \) \ eS 21. The oxidation state\gf"Mo, Sits-dx-complex species MO: (O)s (Calla Jz ]*is) (+5 (by els ee d) +2 22. For the

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