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ABSTRACT: The fertiliser mineral potash is completely imported in India. But, it has been
identified the deep seated vast reserves of potash mineralisation in Nagaur-Ganganagar basin in
Northwest part of the Rajasthan state about three decades ago. The current requirement and the
technology encourages for its mining after detailed exploration with estimation of in-situ grades
for atleast one of the prospective locations in Kalu, Jaitpura, Satipura, Bharusari and Lakhasar sub-
basins. The source of potash has also been found in Glauconite deposits at surface to sub-surface
locations in various states of India. These deposits are still not taken up for the mining. This paper
is an attempt to highlight the international status of potash and the latest emerging opportunities
for its mining in India as an import substitute mineral with details of innovative techno-economic
mining technology including solution mining technique for deep seated potassium deposits.
19
basin to a depth between 300 and 900 m. 3. GEOLOGICAL AND EXPLORATION
Potash deposits have been identified based on DETAILS
the drilling data in Satipura, Bharusari, Jaitpura
GSI has identified a thick marine evaporite
and Lakhasar sub-basins. Exploration work has
sequence developed in the subsurface in Nagaur-
been completed in Satipura-Bharusari sub-
Ganganagar basin by drilling (70 boreholes and
basins and 175.95 million tonnes containing 60,000 m) in Churu, Bikaner, Hanumangarh and
5.15% K2O have been estimated in Satipura, Sriganganagar districts during 1974–83.
and 150.85 million tonnes reserves containing
The Nagaur-Ganganagar basin contains
4.68% K2O in Bharusari by the GSI in year marine sediments of Marwar Supergroup (Late
1982. Proterozoic to Early Cambrian) lying uncon-
The exploration and grade estimation of formably over the basement rocks of the Malani
potash deposits is a difficult task as it occurs Igneous suite and/or Delhi metamorphites. The
mostly in the form of highly soluble minerals. Marwar Supergroup comprising Jodhpur,
In this vast deposit, there are possibilities of Hanseran Evaporite Group and its homotaxial
availability of high grade potash deposit at time equivalent lateral facies variants Bilara
shallow depth of 350 m in Kalu and Jaitpura Group and Birmania formation exposed in the
areas. The Jaitpura area could not be worked Southern parts of the basin and Nagaur Group.
out properly for want of water supply and The Marwar Supergroup is unconformably
inaccessible terrain condition at the time of overlain by rock formations of diverse ages at
exploration. different places as described by Sinha.[4]
The potash reserves are also found in Saltpe- The Hanseran Evaporite Group (HEG)
tre and Glauconite deposits in Rajasthan, which contains the host rock halite for potash
Gujarat and other states. The latest conventional mineralisation is subcroping in the northern
and solution mining technology are described parts of the basin falling in parts of Churu,
for large scale potash mining at depth. Bikaner, Hanumangarh and Sriganganagar
districts. HEG lies unconformably above the
2. MODE OF ORIGIN OF POTASH predominantly arenaceous Jodhpur Group and
DEPOSITS is underlain by predominantly red argillites of
Nagaur Group of rocks, the upper and lower
Evaporites are deposited in marine basins contacts being gradational. The HEG comprises
which get separated from the open sea by some cyclic deposits of halite (most dominant)
barrier. The restricted sea water, on evaporation, containing potash minerals (localised at places),
progressively gets concentrated in marine salts alternating with clay, marl, limestone, dolomite,
which precipitate out of it in order of their anhydrite, magnesite, occasionally glauberite,
solubility in water at atmospheric temperature. glauconite, rarely vanthofite etc. Potash minerals
Under ideal conditions, the first to precipitate hosted within the halite include polyhalite
is calcium carbonate, followed by calcium [K2MgCa2(SO4)4.2H2O], sylvinite (KCl, NaCl),
sulphate, sodium chloride accompanied by sylvite (KCl), Langbeinite (K2SO4. Mg SO4)
magnesium sulphate, and lastly the potassites and carnallite (KCl.MgCl2) in decreasing order
which include potassium chloride and magne- of abundance. The thickness of HEG ranges
sium chloride. For appreciable concentrations from 103 m to more than 652 m containing
and final precipitation of potash salts, it is halite zones with a maximum cumulative
imperative that the basin must remain in steady thickness of 488 m. A maximum of seven halite
equilibrium with the barrier for a considerable cycles numbered H1, H2 ……H7 (from bottom
span of time. The potassic layer is also required to top) have been identified. The basin deepens
to be covered up by an impervious layer of towards the center and northwest direction due
clastics or non-clastics, for its preservation as to step like NNE-SSW gravity faults with their
per GSI Report.[3] down thrown sides towards west causing
20
progressive deepening. The thickness of HEG sylvinite mineralisation as mentioned by
as well as the number of halite cycle increases Kumar.[5]
from the margins towards the center of the basin. In Kalu, where -44 mg gravity closure has
Amongst the potash minerals, polyhalite is been indicated by the ONGC, halite has been
more frequently noticed than sylvite/sylvinite. encountered at a depth of 320 m and continued
Thickness of polyhalite bearing zones varies up to 824.93 m including various sequences of
from 0.05 m to 27.27 m containing 0.1% to anhydrite, dolomite, fetid dolomite and clay. In
10.20% K. Thickness of sylvite/sylvinite bearing this borehole No. P-8, total 6 major halite cycles
zones varies from 0.10 m to 4.34 m containing (H1 to H6) have been recorded.
0.20 to 22.75% K. Langbeinite mineralisation The potash in the form of sylvite (KCl) and
occurs in association with sylvite and polyhalite sylvinite (KCl + NaCl) have been intersected
and is intersected in Bharusari sub-basin only. only in H2 halite zone at depths between 592 m
Amongst all the halite cycles, H2 halite cycle to 681 m for borehole Nos. P-21 (Satipura), P-29
appears to be most prospective with respect to (Jandewali), P-32 (Mukkasar) and P-35
sylvite mineralisation. (Khunja). The thickness of sylvite or sylvinite
On the basis of exploration based on drilling zones varies from 0.10 m to 1.05 m with 2.5% to
eight sub-basins/depocentres/areas for potash 19.2% K (wt. average).
mineralisation containing over 2% K have been The drilling operation for potash exploration
identified viz. Bikaner, Hanseran, Arjunsar, in Rajasthan is shown in Figure 1. Summarised
Gharsisar, Jaitpura, Satipura, Bharusari and logs of the evaporite sequence, encountered in
Lakhasar. Out of these the last four were different boreholes, are presented in Table 1 as
considered to be most prospective for sylvite/ reported by GSI.[3]
21
Table 2. Potash reserves estimated by boreholes in
sub-basins
Potash reserves in
Ganganagar Area million tonnes Grade
P-30 Sub-basin
sq. km Prob- K%
P-29 P-21 Possible
Satipura P-27
able
P-33
Hanumangarh
Satipura 245.61 202.30 1429.95 4.80
P-42
Suratgarh
Bharusari 71.0 88.16 300.15 4.68
Anupgarh
Lakhasar 29.50 113.73 342.29 4.39
P-19 P-18
Bharusari
P-17 Source: GSI Report.[3]
P20
RAJASTHAN
Jaitpura Total reserves (probable + possible) in the
P-16
Chattargarh
Malkisor
P-14 three sub-basins are of the order 2476 million
Pugal
P-12 tonnes with 4.70% K or 5.26% K2O. It is,
P-44
P-13 P-8 however, important to note that the in-situ grade
Kalu
of potash mineralisation is likely to be much
P-7
Lakhasar
P-10
more than what has been reported above based
P-9
P-11
P-6
P-5
P-4
Dungargarh on the assay values of the core samples. It is
P-15 Bikaner
Naguar because during the process of drilling and
P-22 retrieval of the core from the borehole, the
sylvite crystals from the surface of the core gets
INDEX
dissolved due to leaching and leaving behind
BOREHOLES
cavities on the surface of mineralised core.[5]
Fig. 1. Map showing potash exploration in Northwest The international economic grades are ranging
Rajasthan. from 8% to 24%. Germany is mining potash
from grades of 8 to 16%, but most of the other
4. RESERVES AND GRADES mines are mining this mineral for 22–24%
grades deposits as per report of Asia Pacific
The total probable and possible reserves of Potash.[7] In the vast deposit of India, the
potash resources computed over an area of international economic grades may be estab-
approx. 5,000 sq. km in Northwest Rajasthan, lished if proper in-situ grades are worked out
lying between Nagaur, Bikaner, Lakhasar, with latest techniques using sonic tools and
Gusainsar, Hanseran, Kalu, Jaitpura, Suratgarh, radioactive methods like gamma ray and
Hanumangarh, Satipura and Ganganagar, is of neutron logs, etc. The available grades of
the order of 20397 million tonnes as per Indian Indian potash deposits are based on core
Minerals Yearbook.[6] The reserves of halite in recovery and not the actual in-situ grades.
areas covered by 1.0 km radius around the
boreholes drilled so far are of the order of 7,900
5. OTHER POSSIBLE SOURCES OF
million tonnes. If the mining depth is restricted POTASH IN INDIA
to 350 m, the halite reserves in Kalu and
Hanseran areas would be estimated at 322 5.1 Saltpetre (KNO3) deposits
million tones.[3] Potassium nitrate (saltpetre), commonly known
Ten boreholes in Satipura, six in Bharusari as ‘shora’ occurs as salt encrustations in the
and four in Lakhasar areas/sub-basins/depo- form of efflorescence on the soil surface as
centres intersected potash mineralisation pockets in Dholpur, Bharatpur, Bhilwara,
containing over 3% K at 1.5 m minimum stoping Sriganganagar and Hanumangarh districts of
width and accordingly following reserves were Rajasthan. These are being regularly extracted
estimated, as given in Table 2. by local persons under state control. A good
22
quantity of crude salt (50–70% KNO3) is of 500m and occurs at depth between 73 m and
obtained from such sources as mentioned by 78 m below surface. Its thickness varies from
Ghevariya.[8] 0.60 cm to 5.30 m with K2O average grade with
an ore/overburden ratio as 1.19.
5.2 Glauconite deposits Around village Giral in Barmer district,
Glauconite is a hydrous silicate of iron and glauconitic sandstone horizon has been inter-
potassium with variable quantities of aluminum sected between 35.20 m and 160 m; 90.70 m
and magnesium. It contains 2 to 8% K2O. Green and 172.4 m; and 85 m respectively in three
sand containing good quantity of glauconite boreholes drilled for lignite investigation.
had been used as slow acting potash fertilizer in 24 drill core samples analysed from these
England, France, Belgium, USA and Western horizons contain K2O varying from 1.0% to
Australia during pre-world War-II times. 2.05% and XRD analysis indicate presence of
Glauconitic shale, clays and sands are asso- glauconite with quartz as major constituents. In
ciated with various Mesozoic horizons in Kapurdi area of Barmer district, glauconitic
different parts of Kachchh area in Gujarat clay in eight patches, 1.0 m to 36.10 m were
State. A systematic study revealed various intersected in boreholes by GSI.
glauconite bands with K2O percentage varies At the instance of GSI, some of the agricul-
from 2.5 to 5.40. The glauconitic shales and tural institutes conducted field experimentation
clays occur in the surface with overburden on the applicability of glauconitic sandstone to
ranging from few cm. to about 0.5 m and occur the crops of wheat and paddy and have
in several repetitive bands at several localities. indicated quite encouraging results. The results
Aggregate thickness may be more than 5 to of the experiments indicate that glauconite is an
7 m. with a considerable strike length. These ideal slow acting potash fertilizer and it has
glauconite horizons may form good source for an advantage over the traditional chemical
potash. This can be used directly after pulveris- fertilizer. Thus, the application of glauconite
ing and suitable beneficiation treatments to may not only be effective slow acting potash
break the complex silicate structures to increase fertilizer but is also very cheap, easily available
water solubility. This can be directly used as and has tremendous indigenous resources (over
potash fertiliser. Gujarat has very large reserves 2000 million tonnes). Glauconitic sand is
of glauconite in various geological horizons applicable only in acidic soil as described by
ranging from Mesozoic to Tertiary. A systematic Kumar.[5]
evaluation may indicate detail reserves.
In Rajasthan, glauconite occurrences are 5.2.1 Feasibility of glauconite as source of potash
reported from Vindhyans of Chittorgarh and The glauconite is feasible as source of import
Kota districts with K2O content upto 5.50%. substitute potash in India in view of following.
• Glauconite is a complex hydrous silicate of
Reserves of these occurrences, however, have
not yet been estimated. Deposits of glauconite iron and potassium with average potash
occurring in Sanu Formation (Lower Palaeocene content of 2–7% in India
• Glauconite found as green coloured sand
age) located near village Mashuriyan in Sam
tehsil of Jaisalmer district have been investigated
size particles but does not behave like sand
• The porous structure of glauconite enhances
by GSI. This glauconitic sand deposit covers an
area of about 1.5 sq. km. and occurs in the
massive argillaceous member of Sanu Forma- the water storage ability for the soil for the
growth of crops
• Glauconite is used as fertiliser for acidic
tion. It is successively overlain by Khuiala
Formation (Eocene) and desert sand (Sub-
pyritiferous at places and contains intercalation soils and soil conditioner for hard water area
of fossiliferous shales. The glauconitic horizon • Source of potassium is essential for the
extends for about 3 km with an average width growth of plants, yield and nutrition values
23
for crops such as tea, coffee, banana, coco- Deposits are located mainly in Canada (31%),
nut, oil palm, black pepper, rubber, etc. Belarus (21%), Russia (17%), China and USA
(6% each), Chile and Germany (4% each) as
5.2.2 Present status of glauconite mining in India per Indian Minerals Year Book-2014.[9]
Presently, there is no mining of glauconite The world production of potash in 2013 was
mineral in India. The glauconite as source of 34.3 million tonnes in terms of K2O content as
potash is a sedimentary deposit found at surface against 36.3 million tonnes in 2012. Canada
in the form of sandstone/shale/limestone and as remained the leading producer of potash with
greensands. It is available in the following 30% share in total production in 2013, followed
states with locations.[2]
• Rajasthan: Jaisalmer, Barmer, Chittorgarh,
by Russia (17%), Belarus (12%), China (10%),
Germany (9%), Israel (6%), Chile and Jordan
Kota, Karauli
• U.P.: Chitrakoot (7% K), Mirzapur, Banda,
(3% each) as shown in Table 3.
Sonbhadra
• M.P.: Sidhi (4–11% K) and Satna
7. FOREIGN TRADE OF POTASH
(Vindhyan sandstone) BY INDIA
• Gujarat: Guneri in Kachchh district
• Kerala: Occurrence in Quilon Limestone
7.1 Exports
and sea bed sediments of Trivandrum coast. The exports of potash fertilizer increased
considerably to 19753 tonnes in 2013–14 as
The detailed exploration work is under against 13972 tonnes in the previous year.
progress to assess the quantity, quality, depth Exports were mainly to Sri Lanka (48%), UAE
and size of the glauconite deposits as source of
(19%) and Mozambique (9%). Exports of
Potash.[2]
potassium nitrate increased marginally to 1,144
tonnes in 2013–14 from 1,061 tonnes in the
6. WORLD SCENARIO OF POTASH previous year. Exports were mainly to Thailand
The world reserves are estimated at approxi- (36%), Turkey (13%), Malaysia (12%) and
mately 3500 million tonnes of K2O content. UAE (10%).
24
Table 4. Import of potash fertilizer in India (by countries)
2012–13 2013–14
Country Quantity Value Quantity Value
(t) ` ’000 (t) ` ’000
All Countries 2122718 57194141 3394833 81826455
Russia 579407 15463618 898673 21447423
Canada 236330 6735209 828718 20070241
Israel 521217 13774506 576773 13786229
Jordan 217051 6170509 352043 8706090
Belarus 352953 9246885 280412 6681302
Latvia 27061 733748 181983 4186537
Germany 66076 1737843 153293 3791005
Lithuania 57456 1473700 92985 2180279
Chinese Taipei/Taiwan 12837 452268 7258 280543
Iceland – – 10000 232158
Other countries 52330 1405855 12695 464648
[9]
Source: Indian minerals year book-2014.
25
over halite (NaCl) in high temperature brines. • Residue remains in the cavern, therefore
Solar evaporation of brines that naturally eco-friendly
contain potassium is the method of obtaining • Less surface area is disturbed
potash ore. Halite and Carnallite are precipitated • The demand of manpower is low
•
in a succession of ponds, and the Carnallite is
The first step of the potash mill (hot
transferred in slurry form to the beneficiation
leaching) is in the underground, and it
facilities.
contribute for clean technology.
8.3 Beneficiation
The steps in the processing of potash ore are
usually size reduction-de-sliming-separation,
drying, then compaction or granulation. The
following series of steps: crushing and grinding;
de-sliming; separation; drying; and compaction
and granulation. The specific processes used
depend upon characteristics and composition of
the potash ore and market requirements. A
system of crushing and grinding is used to
separate crystalline minerals and disperse clay
slime. Fine materials such as clays and sand are
separated from the potash ore in the de-sliming
step, which involves intense agitation followed
by either flotation or hydro-cyclone. Four
separation processes are used to concentrate the
potash: flotation, electrostatic separation,
Fig. 2. A typical diagram showing solution mining thermal dissolution-crystallization, and heavy
layout.[12] media separation. Drying is usually carried out
in a rotary or fluid bed dryer. Dried potash is
Advantage of solution mining: then either granulated or compacted through
• Reduced development costs, timeline and high-pressure rollers and screened to specific
mining risks particle sizes.
• The investment costs are low, as we do not
need a mine
• Reduced CAPEX, shorter payback period
and higher IRR
• The drilling of the bore holes are running
costs
• No underground workings, access or
personnel needed
• Development and production is easily
scalable
• Ability to mine deep and irregularly shaped
deposits
• Faster timeline to production compared to
conventional
• Reduced environmental impact compare to Fig. 3. Schematic block diagram of a conventional
conventional potash flotation plant.[13]
26
About 70% of the total potash, and almost benefits of reduced development costs, timeline
90% of fertilizer grade potassium chloride is and mining risks because only bore holes are
produced by conventional froth flotation, required for mine production.
sometimes supplemented by heavy media
separation. Crystallization is used mainly to REFERENCES
produce industrial grade and specially fertilizer
grade (white muriate) potash. Figure 3 shows [1] Mohnot, J. K., Prasad, V.V.R. and Verma,
the conventional flotation route to obtain H.K., “Investment Opportunities for Potash
fertilizer grade potassium chloride as described Mining in India as an Import Substitute Min-
eral”, First Indian Mineral Congress and Tech-
by Perucca.[13]
nological Exhibition on Showcasing the Min-
eral Industry in 21st Century, organised by ISM
9. CONCLUSIONS Alumni Association, CMRI and DGMS, Dhan-
bad, pp. 421–34, Feb.28–March 1, 2005.
This may be concluded that huge potash
[2] Indian Minerals Yearbook-2015, Published by
reserves are available in the forms of marine Indian Bureau of Mines, Nagpur, pp. 40, Nov.,
evaporite deposits at depth of 300–900 m, 2016.
saltpetre and glauconite as surface deposits in [3] GSI Report, “Exploration of Potash in
Northwest Rajasthan and other states of India. Rajasthan”, J. Indian Minerals, Calcutta, Vol.
The indigenous production may be undertaken 36, No. 4, pp. 1–5, 1982.
after detailed exploration of the identified
[4] Sinha-Roy, S., Malhotra, G. and Mohanty, M.,
deposits. During detailed exploration, the Geology of Rajasthan, Published by GSI, Ban-
correct in-situ grades can be established using glore, pp. 167–176, 1998.
gamma ray, neutron logs and other latest
[5] Kumar, Virendra and Rasik, Ravindra,
techniques. The in-situ grades should be more “Rajasthan—The Leading Indian State in Fertil-
than the reported grades based on the core iser Mineral Resources”, Conf. on Indian In-
recovery. It is because the mineral is water dustrial Minerals, org. by Federation of Indian
soluble and it gets dissolved from the surface of Mineral Industries, New Delhi, Vol. I, pp. 278–
core during the process of drilling. 80, 1998.
The market of potash is expected to increase [6] Indian Minerals Yearbook, Published by Indian
year-by-year globally. Over half of the forecast Bureau of Mines, Nagpur, 1991 to 2003.
is accounted for Asian markets which will [7] Report on Asia Pacific Potash Corporation,
further consolidate the region’s position as the Thailand, Published by Asia Pacific Resources
world’s largest importer of potash. There is also Ltd., Canada, pp. 1–5, 1999.
good potential for export of this mineral to [8] Ghevariya, Z.G., “Industrial Minerals of
neighbouring Asian countries. Therefore, the Gujarat—Certain Issues Related to Exploration,
investment opportunities for potash mining in Upgradation and Utilisation”, Conf. on Indian
India as an import substitute mineral may be Industrial Minerals, FIMI, New Delhi, pp. 100,
utilised for the development of mineral wealth. 1998.
The domestic demand of this fertiliser mineral [9] Indian Minerals Yearbook–2014, Published by
and entire supply by import encourages for Indian Bureau of Mines, Nagpur, pp. 40, July,
mining of potash in India. 2016.
The conventional mining with special boring [10] BGS Report, “World Mineral Production 2009-
machine is economical for large scale production 2013”, British Geological Survey, London,
from underground. In some cases a combina- pp. 59, 2015.
tion of conventional and solution mining can be [11] Mohnot, J.K., “Formulation of Optimun
practiced in order to recover the left over ore. Investment Decision Model for Economic
The solution mining technique for potash is Evaluation of Mining Venture”, Ph.D. Thesis,
an innovative mining technology for deep Guide Dr. U.K. Singh, ISM, Dhanbad”,
seated deposits as eco-friendly method with pp. 133–40, 2002.
27
[12] PotashCorp Report, “The Potash Journey”, [14] Fuzesy, Anne, “Potash in Saskatchewan”,
published by PotashCorp, Canada, Aug., 2013. Saskatchewan Geological Survey, Canada,
[13] Perucca, C.F., “Potash processing in Saska- Report No. 181, pp. 2, 1982.
tchewan—a review of process technologies”,
CIM Bulletin, Vol. 96, No. 1070, 2003.
28