Fiitjee: - JEE (Main)

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

QP Code: SET: A
BATCHES – CTY 2022 (PHASE – III)
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) contains Twenty (20) multiple choice objective questions which have four (4) options each
and only one correct option. Each question carries +4 marks which will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.
(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4
marks for correct answer and there will be no negative marking.
Name of the Candidate :_____________________________________________________
Batch :_____________________________ Date of Examination : ___________________
Enrolment Number :________________________________________________________
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-JEEM-PCM-SET-A - P2
USEFUL DATA
PHYSICS CHEMISTRY
2
Acceleration due to gravity : g = 10 m/s 1 1
Gas Constant R = 8.314 J K mol
34
Planck constant : h = 6.6  10 J  s = 0.0821 Lit atm
19 1 1
Charge of electron : e = 1.6  10 C K mol
Mass of electron : me  9.1  10
31
kg
= 1.987  2 Cal
1 1
12 2 2 K mol
Permittivity of free space :  0  8.85  10 C /N m
Avogadro’s Number Na = 6.023  1023
: water  10 kg / m
3 3
Density of water
34
5 2 Planck’s constant h = 6.625 10 J .s
Atmospheric pressure : Pa  10 N / m 27
Gas constant : R = 8.314 J = 6.625 10 erg .s
1 Faraday = 96500 coulomb
K 1 mol 1 1 calorie = 4.2 joule
27
1 amu = 1.66 10 kg
19
1 eV = 1.6  10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.
Section – I Physics
PART – A
(Single Correct Answer Type)
This part contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1.
@QS
If U is the potential energy of an oscillating particle (SHM) and F is the force acting on it at a given
instant, then which of the following is true? (Take x be the displacement of particle from mean position)
U 2U
(A)  x  0 (B) x0
F F
F F
(C)  x  0 (D) x0
U 2U
@QE
@TagS
QT:SCO,
CA:B,
CC:P111103,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
2.
@QS
A uniform rod of mass M and length L is hanging from its one end free to rotate in a vertical plane. A
small ball of equal mass is attached to the lower end as shown. Time period of small oscillations of the
rod is
M, L
8L 2L
(A) 2 (B) 2
9g 3g
8L L
(C) 2 (D) 2
3g g
@QE
@TagS
QT:SCO,
CA:A,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
3.
@QS
A light rigid rod of length L with a point mass m at its end has spring of force constant k connected to it
at a distance h below its point of suspension. The frequency of vibrations of the system for small value
of amplitude is
1 mL2 mgL  kh2

(A) (B) 2
2 mgL  kh2 mL2
mgL  kh2 1 mgL  kh2
(C) (D)
mL2 2 mL2
@QE
@TagS
QT:SCO,
CA:D,
CC:P111107,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
4.
@QS
Figure is a representation of a simple harmonic progressive wave, progressing in the negative X-axis, at
a given instant. The direction of the velocity of the particle at P in the figure is best represented by the
arrow.
y
Displacement
x
D
P
C
B
 
(A) PA (B) PB
 
(C) PC (D) PD
@QE
@TagS
QT:SCO,
CA:A,
CC:P111305,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
5.
@QS
A wave represented by the equation y1  A cos kx  t  is superimposed with another wave to form a
stationary wave such that the point x = 0 is a node. The equation of the other wave is
(A) y 2   A sin  kx  t  (B) y 2   A cos(kx  t)
(C) y 2  A sin  kx  t  (D) y 2  A cos(kx  t)
@QE
@TagS
QT:SCO,
CA:B,
CC:P111307,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
6.
@QS
2
Find the stress in CD. Area of CD = 2 m .
C D
40 N 10 N 30 N
A B E F
2 2
(A) 15 N/m (B) 5 N/m
2
(C) 20 N/m (D) None of these
@QE
@TagS
QT:SCO,
CA:A,
CC:P111101,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
7.
@QS
An object of specific gravity  is hung from a thin steel wire. The fundamental frequency for transverse
standing waves in the wire is 300 Hz. The object is immersed in water, so that one half of its volume is
submerged. The new fundamental frequency (in Hz) is
1/ 2 1/ 2
 2  1   2 
(A) 300   (B) 300  
 2   2  1 
 2   2  1 
(C) 300   (D) 300  
 2  1   2 
@QE
@TagS
QT:SCO,
CA:A,
CC:P111303,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
8.
@QS
In the resonance tube experiment, the first resonance is heard when length of air column is  1 and
second resonance is heard when length of air column is  2 . What should be the minimum length of the
tube such that third resonance can also be heard
(A) 2 2  1 (B) 71
(C) 51 (D) 21
@QE
@TagS
QT:SCO,
CA:A,
CC:P111309,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
9.
@QS
Two pipes have equal length of 2 m. One is closed at one end and the other is open at both ends. The
speed of sound in air is 340 m/s. the frequency at which both can resonate is.
(A) 340 Hz (B) 510 Hz
(C) 425 Hz (D) None of these
@QE
@TagS
QT:SCO,
CA:D,
CC:P111309,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
10.
@QS
A closed organ pipe has length '  ' . The air in it is vibrating in 3 overtone with maximum amplitude ‘a’.
rd
the amplitude at a distance of  / 7 from closed end of the pipe is equal to

(A) a (B) a/2
a 3
(C) (D) zero
2
@QE
@TagS
QT:SCO,
CA:A,
CC:P111309,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
11.
@QS
A 2 m long light metal rod AB is suspended from the ceiling horizontally by means of two vertical wires
–4 2
of equal length, tied to its ends. One wire is of brass and has cross-section of 0.2 x 10 m and the
–4 2
other is of steel with 0.1 x 10 m cross-section. In order to have equal stresses in the two wires, a
weight should be hung from the rod from end A at a distance of
Brass Steel
C B
A
W
(A) 66.6 cm (B) 133 cm
(C) 44.4 cm (D) 155.6 cm
@QE
@TagS
QT:SCO,
CA:A,
CC:P111101,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
12.
@QS
A liquid of mass m and specific heat S is heated to a temperature 2T. Another liquid of mass (m/2) and
specific heat 2S is heated to a temperature T. If these two liquids are mixed, the resulting temperature
of the mixture is
(A) (2/3) T (B) (8/5) T
(C) (3/5) T (D) (3/2) T
@QE
@TagS
QT:SCO,
CA:D,
CC:P111223,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
13.
@QS
Three rods of the same dimensions have thermal conductivities 3k, 2k and k. They are arranged as
o o o
shown, with their ends at 100 C, 50 C and 0 C. The temperature of their junction is
50oC
2k
100oC
3k
k
0oC
o o
(A) (100/3) C (B) (200/3) C
o o
(C) 40 C (D) 75 C
@QE
@TagS
QT:SCO,
CA:B,
CC:P111221,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
14.
@QS
The coefficient of linear expansion  of the material of a rod of length L0 varies with absolute
2
temperature as  = aT – bT where a and b are constants. The linear expansion of the rod when heated
from T1 to T2 = 2 T1 is
3 7b 3   7b 
(A)  aT12  T1  L0 (B)  4a   T1L 0
 2 3   3 
 7b 3 
(C)  2aT12  T1  L0 (D) None of these
 3 
@QE
@TagS
QT:SCO,
CA:A,
CC:P111204,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
15.
@QS
A container shown in figure contains a liquid to a depth H, and of density p. The gauge pressure at
point P is
P0
P
H
  H/2
pgH pgH
(A) (B)
2  P0 2
pgH pgH cos 
(C) (D)
2 cos  2
@QE
@TagS
QT:SCO,
CA:B,
CC:P111014,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
16.
@QS
The spring block system as shown in the figure is in equilibrium. The string connecting blocks A and B
is cut. The mass of all the three blocks is m and spring constant of both the spring is k. The amplitude
of resulting oscillation of block A is:
A m
B m
C m
mg 2mg
(A) (B)
k k
3mg 4mg
(C) (D)
k k
@QE
@TagS
QT:SCO,
CA:B,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
17.
@QS
A thread is tied slightly loose to a wire frame as in the figure and the frame is dipped into a soap
solution and taken out. The frame is completely covered with the film. When the portion A is punctured
with a pin, the thread
A Frame
Thread
(A) becomes concave toward A

(B) becomes convex towards A
(C) remains in the initial position
(D) either (A) or (B) depending on the size of A w.r.t. B
@QE
@TagS
QT:SCO,
CA:A,
CC:P111013,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
18.
@QS
3 p0
The densities at points A and B are p0 and . Find the value of x on P-axis.
2
P
x B
P0
T
T0 2T0
3
(A) 2P0 (B) P0
2
(C) 3P0 (D) 4P0
@QE
@TagS
QT:SCO,
CA:C,
CC:P111213,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
19.
@QS
A uniform slender rod of length L, cross-sectional area A and Young’s modulus Y is acted upon by the
forces shown in the figure. The elongation of the rod is
L /3
3F 2F
F
3FL 2FL
(A) (B)
5AY 5AY
3FL 8FL
(C) (D)
8AY 3AY
@QE
@TagS
QT:SCO,
CA:D,
CC:P111101,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
20.
@QS
An ideal gas undergoes a quasi-static, reversible process in which its molar heat capacity C remains
n
constant. If during this process the relation of pressure P and volume V is given by PV = constant,
then n is given by (Here CP and CV are molar specific heat at constant pressure and constant volume,
respectively):
C C  CP
(A) n  P (B) n 
CV C  CV
CP  C C  CV
(C) n  (D) n 
C  CV C  CP
@QE
@TagS
QT:SCO,
CA:B,
CC:P111212,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
PART – B
(Numerical Based)
This part contains 5 numerical based questions, the answer of which may be positive or negative numbers or
decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).
1.
@QS
A long uniform rod of length L = 50 cm and mass m = 300 g is free to rotate in a horizontal plane about
a vertical axis through its center. A spring with force constant k = 10 N/m is connected horizontally
between one end of the rod and a fixed wall, as shown in the overhead view of figure. When the rod is
in equilibrium, it is parallel to the wall. The period of the small oscillations that results when the rod is
rotated slightly and released is N/10 seconds. Then the value of N is
Wall
Rotation axis
@QE
@TagS
QT:NUR,
CA:6.28,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
2.
@QS
A certain 120 Hz wave on a string has an amplitude of 0.16 mm. The energy that exists in an 80 g
length of the string is  mJ. Find the value of .
@QE
@TagS
QT:NUR,
CA:0.58,
CC:P111304,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
3.
@QS
A large spherical mass M is fixed at one position and two identical point masses m are kept on a line
passing through the center of M (sec figure). The point masses are connected by a rigid massless rod
of length l and this assembly is free to move along the line connecting them. All three masses interact
only through their mutual gravitational interaction. When the point mass nearer to M is at a distance
 M 
r  3l from M, the tension in the rod is zero for m  k   . The value of k is
 288 
m m
r l
@QE
@TagS
QT:NUR,
CA:7,
CC:P110905,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
4.
@QS
o o
The arrangement as shown, temperatures of end P and R are 200 C and 0 C. The lengths of rods are
shown. The length of rod RS is IL, if no heat flows through QS where I is an integer. Find the value of I.
Cross section area and thermal conductivity of each rod is same.
Q
L 3L
P
o R 0o C 
200 C
2L
S
@QE
@TagS
QT:NUR,
CA:6,
CC:P111221,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
5.
@QS
Force acting on a particle is F  8x in SHM. The amplitude of oscillations is 2 (in m) and mass of the
particle is 0.5 kg. The total mechanical energy of the particle is 20.3 J. Find the potential energy of the
particle in mean position (in J).
@QE
@TagS
QT:NUR,
CA:4.30,
CC:P111106,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
Section – II Chemistry
PART – A
1.
@QS
Which of the following dienes is expected to have least value of enthalpy of hydrogenation?
H2C
CH2
(A) H2C CH2 (B)
CH3
CH2
(C) (D) H2C C CH2
H2C
@QE
@TagS
QT:SCO,
CA:B,
CC:C111709,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
2.
@QS
Among the following compounds, the strongest base is
O NH
(A) (B)
H2N NH2 H2N NH2
(C) H2N (D) H3C NH CH3
@QE
@TagS
QT:SCO,
CA:B,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
3.
@QS
The most stable carbanion among the following is
(A) (B) CH2

CH2
H3C
(C) O CH2 (D) NO2 CH2
@QE
@TagS
QT:SCO,
CA:D,
CC:C111303,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
4.
@QS
In the following compounds order of acidic strength is
OH OH OH OH
NO2
CH3 NO2
(I) (II) (III) (IV)
(A) III > IV > I > II (B) I > IV > III > II
(C) II > I > III > IV (D) IV > III > I > II
@QE
@TagS
QT:SCO,
CA:D,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
5.
@QS
Which of the following has least pKb value?
H3 C CH3 H 3C CH3
N N
(A) (B)
H3 C CH3
H 3C CH3
H3 C CH3 N
N
H 3C CH3
(C) (D)
CH3
@QE
@TagS
QT:SCO,
CA:C,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
6.
@QS
trans-2 butene on reacting with Br2 in CCl4 forms mainly
(A) () 2,3-dibromobutane (B) (+) 2, 3-dibromobutane
(C) (-) 2, 3-dibromobutane (D) Meso-2, 3-dibromobutane
@QE
@TagS
QT:SCO,
CA:D,
CC:C111707,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
7.
@QS
A hydrocarbon of formula C6H10 absorbs only one molecule of H2 upon catalytic hydrogenation. Upon
ozonolysis, the hydrocarbon yields a compound of the following structure,
O
H
H
O
The hydrocarbon is:
(A) cyclohexane (B) cyclohexyne
(C) cyclohexene (D) cyclobutane
@QE
@TagS
QT:SCO,
CA:C,
CC:C111709,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
8.
@QS
H3C
CH2 
HOCl
 major product
H3C
H3C H3C
(A) OH (B) Cl
H3C H3C
Cl OH
H 3C H3C
(C) Cl (D) OH
H 3C H3C
H H
@QE
@TagS
QT:SCO,
CA:B,
CC:C111709,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
9.
@QS
Which of the following compound forms enol in aqueous state?
O
(A) CH3 – O – CH2CH3 (B)

CH - C - CH
3 3
(C) CH3 – CH2 – NH2 (D) CH3 – CH2 – OH
@QE
@TagS
QT:SCO,
CA:B,
CC:C111402,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
10.
@QS
Which of the following substance is most basic in gaseous state?
(A) CH3CH2CH2NH2 (B) CH3CH2NHCH3
(C) CH3 - N - CH3 (D) CH3CONH2
CH3
@QE
@TagS
QT:SCO,
CA:C,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
11.
@QS
Which of the following property of trans-2-butene is higher than that of cis-2-butene?
(A) Dipole moment (B) Boiling point
(C) Solubility in water (D) Melting point
@QE
@TagS
QT:SCO,
CA:D,
CC:C111403,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
12.
@QS
OH
Conc.H2SO4
  Pr oduct

The organic product of above reaction is:
(A) (B)
(C) (D)
@QE
@TagS
QT:SCO,
CA:B,
CC:C111705,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
13.
@QS
Which of the following free radical is most stable?
CH2
(A) (B)
H3C CH3
CH3
CH2CH2
C2 H 5
(C) (D)
@QE
@TagS
QT:SCO,
CA:B,
CC:C111301,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
14.
@QS
Which of the following compound has the most acidic strength?
(A) ClCH2CH2COOH (B) FCH2CH2COOH
(C) CH3CHCOOH (D) CH3CHCOOH
F Cl
@QE
@TagS
QT:SCO,
CA:C,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
15.
@QS
The most unstable cycloalkane C6H12 is:
(A) (B)
(C) (D)
@QE
@TagS
QT:SCO,
CA:A,
CC:C111704,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
16.
@QS
Which of the following compounds will exhibit geometrical isomerism?
(A) 1-Phenyl-2-butene (B) 3-Phenyl-1-butene
(C) 2-Phenyl-1-butene (D) 1,1-Diphenyl-1-propene
@QE
@TagS
QT:SCO,
CA:A,
CC:C111403,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
17.
@QS
Correct configuration of the following is:
CH3
1
H OH
2
H 3C OH
H
(A) lS, 2S (B) lS, 2R
(C) lR, 2S (D) lR, 2R
@QE
@TagS
QT:SCO,
CA:A,
CC:C111404,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
18.
@QS
Acetylene contains same degrees of unsaturation as:
(A) (B)
(C) (D)
@QE
@TagS
QT:SCO,
CA:B,
CC:C111713,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
19.
@QS
The reaction of propene with HOCl proceeds via the addition of:
+ +
(A) H in the first step (B) Cl in the first step
- + -
(C) OH in the first step (D) Cl and OH in the single step
@QE
@TagS
QT:SCO,
CA:B,
CC:C111707,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
20.
@QS
Which of the following is the strongest base?
(A) (B)
N N
H
NH 2
(C ) (D)
N
H
@QE
@TagS
QT:SCO,
CA:A,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
PART – B
(Numerical Based)
decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).
1.
@QS
Number of chiral carbon atom in
Br
is
Br
@QE
@TagS
QT:NUR,
CA:2,
CC:C111404,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
2.
@QS
The number of geometrical isomers in CH 3 CH CHCH 2CH CH2 is
@QE
@TagS
QT:NUR,
CA:2,
CC:C111403,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
3.
@QS
2
1 NH
3
4
6
5
O
Identify the position where the nitration takes place.
@QE
@TagS
QT:NUR,
CA:4,
CC:C111804,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
4.
@QS
If M is the molecular mass of smallest chiral alkane (CnH2n+2) in which isotope/s of hydrogen will not be
used, the numerical value of M/15 is
@QE
@TagS
QT:NUR,
CA:6.67,
CC:C111404,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
5.
@QS
Total number of cyclic structural isomers corresponding to the molecular formula C4H6 is
@QE
@TagS
QT:NUR,
CA:5,
CC:C111401,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
Section – III Mathematics

PART – A
1.
@QS
If z be complex number such that equation z  a 2  z  4a  3 always represents an ellipse, then
range of a (where “a” is real number) is
(A) 2  7,3  (B)  2  7, 2  7 
(C) (1, 3) (D)  3, 2  7 
@QE
@TagS
QT:SCO,
CA:D,
CC:M110304,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
2.
@QS
The number of ways in which the letters of the word ARTICLE can be rearranged so that even places
are always occupied by consonants is
(A) 576 (B)
4
C3  4
(C) 2. 4 (D) None of these
@QE
@TagS
QT:SCO,
CA:A,
CC:M111206,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
3.
@QS
a 2  b2  c2
In triangle ABC, is always

(A) 6 3 (B) 4 3
(C)  8 3 (D)  12 3
@QE
@TagS
QT:SCO,
CA:B,
CC:M111506,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
4.
@QS
xa , xb , and x c represents
“P” is an interior point of an equilateral triangle ABC of side length 2 units. If
the distance of ‘P’ from the sides BC, CA and AB respectively. Then xa  xb  xc is equal to
(A) 6 (B) 3
(C) 3/2 (D) 2 3
@QE
@TagS
QT:SCO,
CA:B,
CC:M113535,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
5.
@QS
1 1 1
If z1  z2  z3  1, then ,  is always equal to
z1 z2 z3
z1
(A) z1 z2 z3 (B)
z2 z3
(C) z1  z2  z3 (D) 3
@QE
@TagS
QT:SCO,
CA:C,
CC:M110306,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
6.
@QS
 2017 
754
The last digit of is
(A) 3 (B) 1
(C) 7 (D) 9
@QE
@TagS
QT:SCO,
CA:D,
CC:M110414,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
7.
@QS
x
Total number of solutions of sin x  is equal to
10
(A) 9 (B) 19
(C) 10 (D) 20
@QE
@TagS
QT:SCO,
CA:B,
CC:M113526,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
8.
@QS
 2x 
Range of tan 1  2 
is
 1 x 
       
(A)  , (B)  , 
 4 4   2 2
     
(C)  , (D)  , 
 2 4  4 2
@QE
@TagS
QT:SCO,
CA:A,
CC:M113553,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
9.
@QS
If x  y  z  , then sin x  sin 2 y  sin 2 z is equal to
2
(A) 2 sin x sin y sin z (B) 2 cos x cos y cos z

(C) 2 sin x cos y cos z (D) 2 sin x sin y cos z
@QE
@TagS
QT:SCO,
CA:D,
CC:M113513,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
10.
@QS
Among the 8 permutations of the digits 1, 2,3,...........8, consider those arrangements which have the
following property, if we take any five consecutive positions, the product of the corresponding digits is
divided by 5. The number of such arrangement will be equal to
(A) 7 (B) 2. 7
7
(C) C4 (D) None of these
@QE
@TagS
QT:SCO,
CA:B,
CC:M111206,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
11.
@QS
In a triangle ABC. sin A,sin B and sin C are in A.P, then
(A) Altitudes are in H.P (B) Altitudes are in A.P
(C) Altitudes are in G.P (D) None of these
@QE
@TagS
QT:SCO,
CA:A,
CC:M111501,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
12.
@QS
n  N  1, then sum of real part of roots of z n   z  1 is equal to
n
If
n n 1
(A) (B)
2 2
n 1 n
(C) (D)
2 2
@QE
@TagS
QT:SCO,
CA:D,
CC:M110331,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
13.
@QS
The number of solution of the equation x3  x 2  4 x  2sin x  0, in 0  x  2 is
(A) zero (B) one
(C) two (D) four
@QE
@TagS
QT:SCO,
CA:B,
CC:M113529,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
14.
@QS
The general solution of the equation sin 2020 x  cos 2020 x  1 is
 
(A) 2 n  , n  I (B) n  , n  I
3 2
 
(C) n  , n  I (D) 2n  , n  I
4 3
@QE
@TagS
QT:SCO,
CA:B,
CC:M113526,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
15.
@QS
The coefficient of x50in 1  x 
41
1  x  x 
2 40
is
(A) 1 (B) 2
(C) 3 (D) 0
@QE
@TagS
QT:SCO,
CA:D,
CC:M110410,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
16.
@QS
The number of permutations of the letter of the word INEFFECTIVE taken four at a time must be
(A) 2214 (B) 1422
(C) 5424 (D) 2454
@QE
@TagS
QT:SCO,
CA:B,
CC:M111206,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
17.
@QS
The rank of the word SUCCESS in the dictionary
(A) 328 (B) 329
(C) 330 (D) 331
@QE
@TagS
QT:SCO,
CA:D,
CC:M111206,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
18.
@QS
If a complex number z lies on a circle of radius 1/2, then the complex number  1  4z  lies on a circle
of radius
(A) 1/2 (B) 1
(C) 2 (D) 4
@QE
@TagS
QT:SCO,
CA:C,
CC:M110310,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
19.
@QS
If n is a positive integer but not a multiple of 3 and 
z  1  i 3, where i  1 , then 
z 2n
 2 n z n  2 2 n  is equal to
(A) 0 (B) – 1
(C) 1 (D) 3  2n
@QE
@TagS
QT:SCO,
CA:A,
CC:M110403,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
20.
@QS
The number of positive integral solutions of ordered pair  x, y  of tan 1 x  cot 1 y  tan 1 3 is
(A) one (B) two
(C) three (D) four
@QE
@TagS
QT:SCO,
CA:B,
CC:M113555,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:-1,
@TagE
PART – B
(Numerical Based)
decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).
1.
@QS
Two sides of a triangle are given by the roots of the equation x 2  2 3 x  2  0 . The angle between

the sides is
3

. Find the perimeter of  . Use 2  1.4, 3  1.7, 5  2.2 
@QE
@TagS
QT:NUR,
CA:5.78,
CC:M111507,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
2.
@QS
Total number of complex numbers ‘z’ satisfying Re  z 2   0, z  3, is equal to
@QE
@TagS
QT:NUR,
CA:4,
CC:M110302,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
3.
@QS
A convex polygon has 44 diagonals. The number of its sides is equal to
@QE
@TagS
QT:NUR,
CA:11,
CC:M111221,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
4.
@QS
2  31/10  is
1/5 55
The number of irrational terms in the expansion of
@QE
@TagS
QT:NUR,
CA:50,
CC:M110414,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
5.
@QS
The sum of the roots of equation cos 4 x  6  7 cos 2 x over the interval [0, 314] is  . Then the
numerical quantity  must be
@QE
@TagS
QT:NUR,
CA:4950,
CC:M113524,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4,WM:0,
@TagE
TWO YEAR CRP (CTY - 2022)

BATCHES: B – LOT (PHASE – III)
PCM (JEE MAIN)
PAPER CODE: XXXX.X DATE: DD.MM.YYYY
ANSWER KEYS [SET – A]
SECTION – I (PHYSICS) SECTION – II (CHEMISTRY) SECTION– III (MATHS)

PART - A PART - A PART - A
1. B P111103 1. B C111709 1. D M110304
2. A P111105 2. B C111302 2. A M111206
3. D P111107 3. D C111303 3. B M111506
4. A P111305 4. D C111302 4. B M113535
5. B P111307 5. C C111302 5. C M110306
6. A P111101 6. D C111707 6. D M110414
7. A P111303 7. C C111709 7. B M113526
8. A P111309 8. B C111709 8. A M113553
9. D P111309 9. B C111402 9. D M113513
10. A P111309 10. C C111302 10. B M111206
11. A P111101 11. D C111403 11. A M111501
12. D P111223 12. B C111705 12. D M110331
13. B P111221 13. B C111301 13. B M113529
14. A P111204 14. C C111302 14. B M113526
15. B P111014 15. A C111704 15. D M110410
16. B P111105 16. A C111403 16. B M111206
17. A P111013 17. A C111404 17. D M111206
18. C P111213 18. B C111713 18. C M110310
19. D P111101 19. B C111707 19. A M110403
20. B P111212 20. A C111302 20. B M113555
PART - B PART - B PART - B
1. 6.28 P111105 1. 2.00 C111404 1. 5.78 M111507
2. 0.58 P111304 2. 2.00 C111403 2. 4.00 M110302
3. 7.00 P110905 3. 4.00 C111804 3. 11.00 M111221
4. 6.00 P111221 4. 6.67 C111404 4. 50.00 M110414
5. 4.30 P111106 5. 5.00 C111401 5. 4950.00 M113524

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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_____________________________________________________

Batch :___________ Date of Examination : _

Enrolment Number :________________________________________________________

Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

1 mL2 mgL  kh2

the amplitude at a distance of  / 7 from closed end of the pipe is equal to

(A) becomes concave toward A

(C) H2N (D) H3C NH CH3

(A) (B) CH2

(C) O CH2 (D) NO2 CH2

(A) CH3 – O – CH2CH3 (B)

The organic product of above reaction is:

Section – III Mathematics

(A) 2 sin x sin y sin z (B) 2 cos x cos y cos z

TWO YEAR CRP (CTY - 2022)

SECTION – I (PHYSICS) SECTION – II (CHEMISTRY) SECTION– III (MATHS)

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