Vidyamandir Classes: Innovating For Your Success

General Instructions
1. The question paper consists of 3 Subject (Subject I: Physics, Subject II: Chemistry, Subject III: Mathematics).
Each Part has two sections (Section 1 & Section 2).
2. Section 1 contains 2 types of questions [Type A and Type B].
Type A contains SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B),(C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.
Type B contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
3. Section 2 contains 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero
in the decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative values,
Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.
Vidyamandir Classes: Innovating For Your Success
MARKING SCHEME
SECTION-1 | Type A
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is
(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers,
then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
SECTION-1 | Type B
 This section contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme;
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
SECTION - 2
 This section contains 6 Integer Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not
add zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However, for
negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct Integer value is entered. There is NO negative marking.
Zero Marks: 0 In all other cases.
VMC | JEE-2023 | Paper-2 2 JEE Advanced-3 | Gen 1 & 2

SUBJECT I : PHYSICS 60 MARKS
SECTION-1 | Type A
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
k
1. The displacement x of a particle varies with time according to the relation x 
l
 
1  e lt , then :
1  2  k 
(A) At t  , the displacement of the particle is nearly   
l  3  l 
(B) The velocity and acceleration of the particle at t = 0 are k and –kl respectively
k
(C) The particle cannot reach a point at a distance x' from its starting position if x' 
l
(D) The particle will come back to its starting point at t  
2. A uniform rod of mass m and length 4R is joined with a uniform ring of mass 2 m and radius R to form a
rigid body as shown. The body is in x-y plane with the origin at one end of rod as shown. Choose correct
options.
(A) Coordinates of centre of mass of the body is (2.5 R, 0)

(B) Coordinates of centre of mass of the body is (4R, 0)
(C) Moment of inertia of the body about an axis passing through its centre of mass and perpendicular to
28
x-y plane is mR 2
3
(D) Moment of inertia of the body about z-axis is 48mR 2
3. Three identical balls are kept in a line on a frictionless surface. Now, the balls are suddenly given velocities
as shown. All collisions between the balls are elastic. Choose correct options.
(A) Total number of collisions will be 3
(B) Total number of collisions will be 2
(C) After all collisions have taken place, ball A moves
at 2v
(D) After all collisions have taken place, ball C moves
at 3v

4. There is no friction anywhere and the system is released from rest. Choose correct options
mg
(A) Acceleration of the hemisphere towards left is a 
M tan  m cot 
mg
(B) Acceleration of the hemisphere towards left is a 
M cot   mtan
(C) Acceleration of the rod is atan
(D) Acceleration of the rod is a cot 
5. A uniform disc  m, R  is kept on a rough horizontal surface with coefficient of friction   0.1 . The disc is
hit with a stick horizontally providing it an impulse J. In the subsequent motion :
R
(A) If h  , the disc starts rolling immediately after it is hit.
2
R J2
(B) If h  , work done by friction over a long period of time is .
2 3m
2J
(C) If h  R, velocity of center of disc long time after it is hit is
3m
(D) If h  R, work done by friction in the frame attached to center of disc over a long time is positive
6. A bucket in the shape of the frustum of a cone of radii a and b and height h
is filled completely with water of density . Neglect the effects of
atmospheric pressure. Which of these statements are correct?
(A) The pressure force on the flat circular base of the bucket is gha 2
(B) The pressure force on the flat circular base of the bucket is equal to the weight of the water in the
bucket
(C) The pressure force on the curved surface of the bucket is gh(b 2  a 2 )
(D) The net force on the bucket due to the water is equal to the weight of the water in the bucket
SECTION-1 | Type B
This section consists of THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
Paragraph for Questions 7 - 8
A uniform disc of radius R is mounted on a frictionless vertical axle and made to rotate about
it at angular velocity  . Now another uniform disc of the same material with half the radius
and half the thickness is placed coaxially on top of the first disc. The two discs are uniformly
rough over their surface (coefficient of friction =  ), so friction acts between them for a time
duration t until both discs are rotating with common angular velocity   .
7. Find the value of   .

4 8 16 32
(A) (B) (C) (D)
5 9 17 33
8. Find the value of t. [g is acceleration due to gravity]

R 6 R 4 R 3R
(A) (B) (C) (D)
3 g 17  g 11 g 10 g
Two uniform solid spherical balls of radius r and 2r and of same density  are
welded together and released in a very long viscous liquid column of lesser
density  and viscosity  .
9. What is the initial acceleration of the spheres?

      
(A) g (B) 1   g (C) 1   g (D)   1 g
      
10. What is the terminal velocity acquired by the spheres?

2 (   ) gr 2 2 (   ) gr 2 4 (   ) gr 2 4 (   ) gr 2
(A) (B) (C) (D)
3  9  3  9 
A uniform chain of length '  ' and mass ‘m’ lies on the surface of a smooth fixed
hemisphere of radius R  , with one end of the chain tied to the top of the
hemisphere, as shown in the figure.
11. Find the gravitational potential energy of the chain with reference level at the centre of the
hemisphere.
mgR mgR 2  mgR 2  mgR 2
(A) (B) sin   (C) cos   (D)
2  R  R 
12. Suppose the chain is released and it slides down the hemisphere. Find the tangential acceleration of the chain
(rate of change of speed of any part), when the chain starts sliding down.
 Rg  Rg     Rg    
(A) g sin   (B) sin   (C) 1  sin    (D) 1  cos   
R  R    R     R 
SECTION-2
This section consists of 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-
off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be bubbled. (Example:
6, 81, 1.50, 3.25, 0.08)
1. A large tank is filled with water to a height H. A small hole is made at the base of the tank. It takes T1 time to
H T
decrease the height of water to and it takes T2 time to take out the rest of water. Then the ratio 1 is
9 T2
____.
2. A block tied between two springs is in equilibrium. If upper spring is cut then the
acceleration of block just after cut is 6 m/s2 downwards. Now, if instead of the
upper spring, lower spring is cut then the acceleration of block just after cut will be
__________ m/s2. (g = 10 m/s2)
3. A ball A is projected vertically upwards at velocity 6 m / s. At the same instant an

identical ball B is released from a point directly above A at a height 1.6 m. The
balls collide mid-air, and stick together. The combination of the balls returns to the floor
with speed v. Find the value of v. [ g  10 m / s 2 ]
4. A satellite is moving with constant speed v in a circular orbit around earth. An object of mass m is ejected
from the satellite such that it just escapes the gravitational pull of earth. At the time of its ejection, the kinetic
n
energy of the object is mv 2 . The value of n is __________.
2
5. A long, thin glass capillary is dipped just below the surface of water filled in a beaker to a height h1 12cm .
Now, oil is poured gently into the beaker to a height h2 10cm . It is now observed that the surface of water
in the capillary is at the same level as the surface of oil in the beaker. If the radius of the capillary is
  104 m , find  .
[Given:  water 103 kg m 3 oil  7.14  102 kgm 3 , g = 9.8 m/s2,
Surface Tension of water = 0.07 N/m
Angle of contact of water with glass = 0°,
the oil and water are immiscible]
6. A particle is projected from ground with initial speed v  30m / s and projection angle   60 from
horizontal. If R is the radius of curvature of the trajectory of the particle when during flight particle’s velocity

make an angle with horizontal, then find the value of R 3 (Take g = 10).
2

SUBJECT II : CHEMISTRY 60 MARKS
SECTION-1 | Type A
3
1. A sample of NaOH has some M 2 (CO3 )3 as impurity. Also the metal ion M is inert to HCl. 2.0 g of the
above sample was dissolved to make 100 mL of solution which required 350 mL of a 0.10 M HCl solution to
reach the phenolphthalein end point. At the phenolphthalein end point, some methyl orange indicator were
added and a further 150 mL of same HCl was required to reach second end point. Which of the following
is(are) correct as per given information?
(A) M 2 (CO3 )3 is 60% by weight
(B) Atomic weight of metal M is 40
(C) Molecular weight of
M 2 (CO3 )3  240 (D) Percentage weight of NaOH is 40%
2. Consider the reaction  2CO 2 (g)  heat. Under what conditions shift is
2CO(g)  O2 (g) 
undeterminable or no change.
(A) Addition of O 2 and decrease in volume
(B) Addition of Ar at constant pressure

(C) Addition of CO and increase in temperature
(D) Increase in temperature and decrease in volume
3. Choose the correct statement(s) regarding PCl5 molecule.
(A) Phosphorus uses 3d-orbital in hybridization

(B) Three different bond angles are observed in the molecule
(C) In solid state it contains ion-pairs
(D) All P  Cl bonds are equal in length
4. Select the correct statement(s).
(A) The value of electron gain enthalpy of an element can be negative or positive
(B) In the periodic table, metallic character of the elements increases down the group and decreases
across the period
(C) Ionization enthalpy of an atom is equal to magnitude of electron gain enthalpy of its cation
(D) Cl and Ca 2 are isoelectronic species but first one is bigger in size than the second

5. If intermolecular force of attraction between the particles of a real gas is zero, which of the following graphs
is/are correct regarding that gas (Z = compressibility factor, V = Potential energy, r = intermolecular
distance between gas particle)
(A) (B)
(C) (D)
6. For a system at equilibrium, which of the following are correct ?

(A) Equilibrium constant of an exothermic reaction decreases with increase of temperature
(B) The plot of ln K p vs 1 / T of an exothermic reaction can be represented as
(C) K p is always greater then K c

1  0 H 0 
(D) ln K p   S  
R  T 

SECTION-1 | Type B
Paragraph for Question Nos. 7 and 8

 2SO 2 (g)  O2 (g), the degree of dissociation of SO3 can be
For dissociation reactions, like 2SO3 (g) 
determined by vapour density measurement of the reacting species through the following relation.
Dd

(n  1)d
Where D is initial vapour density, d is equilibrium vapour density and n is number of mole of products formed from
one mole of reactant.
The molecular mass of the reaction mixture at equilibrium is 60. Initially only SO3 was taken for the reaction.
Answer the following questions on the basis of above write up.
7. What is the value of ‘D’ in the reaction ?
(A) 60 (B) 30 (C) 40 (D) 80
8. What is the value of '  ' for the reaction ?

(A) 0.22 (B) 0.44 (C) 0.66 (D) 0.88

A fixed mass ‘m’ of a gas is subjected to transformation of state ‘A’ to state ‘B’ as shown.
9. If length AC = CB then select correct statement regarding the P-V diagram.

(A) H  q p for path A  C (B) SAB  SA CB
(C) WA B  WACB (D) W   ve for path A  C  B
10. The pair of isochoric and isobaric processes among the transformation of states is:
(A) A to C and C to B (B) C to B and A to B
(C) A to C and A to B (D) C to B and A to B
A quantity of 1.9145 g of brass containing Cu and Zn reacts with 3 M  HNO3 solution, the following reactions
(unbalanced) take place.
Cu(s)  HNO3 (aq)  Cu 2 (aq)  NO 2 (g)  H 2O(l)
Zn(s)  H  (aq)  NO3 (aq)  NH 4 (aq)  Zn 2 (aq)  H 2O(l)
The liberated NO 2 (g) was found to be 1.23 L at 27°C and 1 atm. (At. wt Zn = 65.4, Cu = 63.5)
11. What is the percentage of copper in brass?

(A) 17.08% (B) 82.92% (C) 41.46% (D) 62.19%

12. How many millilitres of 3 M  HNO3 will be required for complete reaction with brass?
(A) 33.33 ml (B) 37.5 ml (C) 4.17 ml (D) 18.75 ml
SECTION-2
6, 81, 1.50, 3.25, 0.08)
1. A gas present in a cylinder fitted with a frictionless piston expands against a constant pressure of 1 atm from
a volume of 3 lit. to a volume of 7 lit. In doing so, it absorbs 750 J heat from surroundings. Determine
increase in internal energy of the gas (in J). [Take 1 L atm = 101.3 J]
2. Total energy of electron in the 1st orbit of hydrogen atom is –13.6 eV/atom. Kinetic energy of electron (in eV)
2
in the 1st excited state of Li ion is:
3. The equilibrium constant (K P ) for a homogeneous gaseous reaction at 27°C is 102 . The standard free
energy change (G ) in calorie for the reaction is (R = 2 cal K 1 mol1 .)
4. At what temperature (in K) is the average velocity of O 2 molecules equal to the root mean square velocity at
27°C? (Use   3.14 )
5. For the reaction; FeCO3 (s) 

 FeO(s)  CO2 (g); H  82.8kJ at 25°C, what is (E or U) in kJ
at 25°C ?
6. Total number of compounds in which central atom have only two lone pairs is x, then x is:
ClF4 , SeF2 , XeOF2 , XeO3 , ClF2 , SNF3 , I3 , SOCl2 , SO32

SUBJECT III : MATHEMATICS 60 MARKS
SECTION-1 | Type A
x2
The equation 2 2  1 x   2
   2  x  2 x 1  2 for real number x has
x 2
1.
 
(A) Number of real solutions 4 (B) Number of real solutions  3
(C) Sum of real solutions  0 (D) Sum of real solutions 2
n
2. The coefficient of 
x n in the expansion of 1 – 2 x  3 x 2 – 4 x 3  ..  is p then
(A) p  20 if n  3 (B) p  10 if n  3
(C) p  70 if n  4 (D) p  35 if n  4
10
 1 
3. The value of the constant term in the binomial  x 2  2  2  is also equal to
 x 
10
(A) number of different dissimilar terms in  x1  x 2  ....  x10 
2 2 2
(B)  10
C0   10
C1   ....   10
C10 
20
(C) Coefficient of x 10 in 1  x 
(D) number of linear arrangements of 20 things of which 10 alike to one kind and rest all are different, taken all
at a times.
4. The number of ways in which five different books to be distributed among 3 persons, so that each person gets at
least one book, is equal to the number of ways in which
(A) 5 persons are allotted 3 different residential flats, so that each person is allotted at most one flat and no two
persons are allotted the same flat.
(B) Number of parallelograms formed by one set of 6 parallel lines and other set of 5 parallel lines that goes
in other direction.
(C) 5 different toys are to be distributed among 3 children , so that each child get at least one toy.
(D) 3 mathematics professors are assigned five different lectures to be delivered , so that each professor gets at
least one lecture
5. Let Pn denotes the number of ways of selecting 3 people out of ' n ' sitting in a row, if no two of them are
consecutive and Qn is the corresponding figure when they are in a circle, then
(A) Pn   n  1C (B) Pn   n  2 C
3 3
(C) Qn  nC3  n  n  1 (D) Qn  nC3  n  n  3
6. If S 
12  1  1 1!  22  2  1  2!
 2  ..... 
 n 2  n  1  n !
. Then
n
12  3 1  2 2  32  2  n2  3n  2 
1433 1259 1437 39
(A) S5  (B) S6  (C) S5  (D) S4 
14 2 2 2
SECTION-1 | Type B
Paragraph for Question 7 - 8

2
Consider a quadratic equation az  bz  c  0, where a, b and c are complex numbers
7. The condition that the equation has one purely imaginary root, is
(A)  ab  ab  bc  bc    ca  ca 2  0
(B)  ab  ab  bc  bc    ca  ca 2  0
(C)  ab  ab  bc  bc    ca  ca 2  0
(D)  ab  ab  bc  bc    ca  ca 2  0
8. The condition that the equation has two purely imaginary roots, is
a b c a b c
(A)   (B)   
a b c a b c
a b c a b c
(C)   (D)  
a b c a b c
Paragraph for Question 9 - 10

Paragraph -2 (Single Correct)
Consider the following curves given in parametric forms:
S1 : x  at 2  bt  c1, y  at and
 
S 2 : x   at 2  bt  c2 , y  at , a  0
9. S1 and S2 intersect if
(A) b 2  4a  c1  c2  (B) b 2  2a  c1  c2 
(C) b 2  a  c1  c2  (D) b 2  2a  c1  c2   0
10. If the curves S1 and S2 intersect orthogonally then in addition to the condition obtained in previous question ,
coefficients must satisfy the condition
(A) a 2  b 2  2a  c1  c2   0
(B) a 2  b2  2a  c1  c2   0
(C) a 2  b 2  2a  c1  c2   0
(D) a 2  b2  2a  c1  c2   0

Paragraph for Question 11-12

Paragraph -3 (single correct)
Complex numbers can be used for finding out the sums of the two series of the form
C  a0 cos   a1 cos       a2 cos    2   ........ and
S  a0 sin   a1 sin       a2 sin    2   ........
Provided the sum of the series
f ( x )  a0  a1 x  a2 x 2  .......... is known
Suppose that series from C and S are infinite, then we have
C  iS  a0  cos   i sin    a1 cos       i sin       .......
 a0ei  a1e 
i  
 a2 e 
i  2 
 ...........
 ei  a0  a1ei  a2e 2i  .........  ei  a0  a1 x  a2 x 2  ......

   
 
 ei f ei , then we can equate real & imaginary part.
Similarly C  iS  e  
 i
f ei
1
 C   ei f  ei   e i f  e i  
2 
1  i
S
2i 
 
e f ei  e i f e i 
  
 
11. If     then
2 2
1 1 1.3
1  cos 2  cos 4  cos 6  ........ to inf is equal to
2 2.4 2.4.6

(A) cos  1  cos   (B) cos  cos
2
 
(C) 2cos  cos (D) 2 cos  sin
2 2
a n  n  1 a 2
12. If a  c in a ABC, then the sum to infinity terms of the series n. sin B  sin 2 B  ....... is
c 2! c 2
cn an
(A) sin nA (B) sin nA
bn bn
bn
(C) sin nA (D) sin nA
cn

SECTION-2
6, 81, 1.50, 3.25, 0.08)
200
1. The value of C0 200 C1  200 C2 200 C3  .......  200 C148 is equal to xC y then least value of x + y is….
2. The number of rational numbers lying in the interval  2021, 2022  all whose digits after the decimal points are non-
zero and are in decreasing order, is ______.
3.
2
If the equation x  nx  n  0, n  I , has integral roots, then the number integral values n2  4n can assume
4. The absolute value of sec 610 cos ec160   cot 380  tan 470  is

1 
 1k 1 s
5. If S   2
and t   2
, then the value of
t
is equal to
k 1 k k 1 k
p
6. If k  k  z
2
 z
2
 k  R  then principal argument of z is
q
(H.C.F.  p, q   1). The value of
p  q is ….
   End of JEE Advanced – 2 | Paper - 3 |JEE -2023 (GEN 1 & 2)  

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General Instructions

2. Section 1 contains 2 types of questions [Type A and Type B].

VMC | JEE-2023 | Paper-2 2 JEE Advanced-3 | Gen 1 & 2

SUBJECT I : PHYSICS 60 MARKS

(A) Coordinates of centre of mass of the body is (2.5 R, 0)

VMC | JEE-2023 | Paper-2 3 JEE Advanced-3 | Gen 1 & 2

atmospheric pressure. Which of these statements are correct?

Paragraph for Questions 7 - 8

7. Find the value of   .

8. Find the value of t. [g is acceleration due to gravity]

Paragraph for Questions 9 - 10

9. What is the initial acceleration of the spheres?

10. What is the terminal velocity acquired by the spheres?

3. A ball A is projected vertically upwards at velocity 6 m / s. At the same instant an

VMC | JEE-2023 | Paper-2 6 JEE Advanced-3 | Gen 1 & 2

SUBJECT II : CHEMISTRY 60 MARKS

(B) Addition of Ar at constant pressure

3. Choose the correct statement(s) regarding PCl5 molecule.

(A) Phosphorus uses 3d-orbital in hybridization

VMC | JEE-2023 | Paper-2 7 JEE Advanced-3 | Gen 1 & 2

6. For a system at equilibrium, which of the following are correct ?

(C) K p is always greater then K c

VMC | JEE-2023 | Paper-2 8 JEE Advanced-3 | Gen 1 & 2

Paragraph for Question Nos. 7 and 8

8. What is the value of '  ' for the reaction ?

Paragraph for Question Nos. 9 and 10

9. If length AC = CB then select correct statement regarding the P-V diagram.

VMC | JEE-2023 | Paper-2 9 JEE Advanced-3 | Gen 1 & 2

(A) 17.08% (B) 82.92% (C) 41.46% (D) 62.19%

energy change (G ) in calorie for the reaction is (R = 2 cal K 1 mol1 .)

5. For the reaction; FeCO3 (s) 

VMC | JEE-2023 | Paper-2 10 JEE Advanced-3 | Gen 1 & 2

SUBJECT III : MATHEMATICS 60 MARKS

(C) Qn  nC3  n  n  1 (D) Qn  nC3  n  n  3

Paragraph for Question 7 - 8

Paragraph for Question 9 - 10

VMC | JEE-2023 | Paper-2 12 JEE Advanced-3 | Gen 1 & 2

Paragraph for Question 11-12

 ei  a0  a1ei  a2e 2i  .........  ei  a0  a1 x  a2 x 2  ......

VMC | JEE-2023 | Paper-2 13 JEE Advanced-3 | Gen 1 & 2

   End of JEE Advanced – 2 | Paper - 3 |JEE -2023 (GEN 1 & 2)  

VMC | JEE-2023 | Paper-2 14 JEE Advanced-3 | Gen 1 & 2

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