Jee Advanced 2 Paper 2

General Instructions
1. The question paper consists of 3 Subject (Subject I: Physics, Subject II: Chemistry, Subject III: Mathematics).
Each Part has two sections (Section 1 & Section 2).
2. Section 1 contains 2 types of questions [Type A and Type B].
Type A contains SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B),(C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.
Type B contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
3. Section 2 contains 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value,
then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the
decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign
should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.
Vidyamandir Classes: Innovating For Your Success
MARKING SCHEME
SECTION-1 | Type A
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get marks.
SECTION-1 | Type B
 This section contains THREE (03) paragraphs. Based on each paragraph, there are TWO (02)
questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme;
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : In all other cases.
SECTION - 2
 This section contains 6 Integer Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add
zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However, for
negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct Integer value is entered. There is NO negative marking.
Zero Marks: 0 In all other cases.
VMC | JEE-2023 | Paper-2 2 JEE Advanced-2 | Gen 1 & 2

SUBJECT I : PHYSICS 60 MARKS
SECTION-1 | Type A
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
1. A thin uniform rod of length L and mass m is pivoted at a point at a distance L /3 from one of its ends such
that it can rotate freely in the vertical plane. The rod is released from rest in the horizontal position as
shown. Which of these options is/are correct?
3g
(A) The initial acceleration of the centre of mass of the rod is
4
3mg
(B) The force applied by the pivot on the rod just after it is released is
4
3g
(C) As it rotates, the maximum angular velocity the rod attains is
L
(D) At the instant the angular velocity of the rod is maximum, the acceleration of its centre of mass
g
is
2
2. A double pulley of smaller radius R and larger radius 2R , and mass m, is arranged with two massless
strings and a block of mass M as shown. Both strings are wound tightly on the pulley. The moment of
inertia of the pulley about its central axis is 3mR 2 /2 . The system is released with both bodies at rest and
 
both strings tight. Let the acceleration of the centre of the pulley and the block be aC and A respectively.
Which of these options is/are correct?
 
(A) aC   A
 
(B) aC  2 A
(C) If M  2m , the acceleration of the block is g /9 downwards
(D) If M  m /2 , the acceleration of the block is g /6 upwards

3. A small ball is thrown horizontally from a 20 m high window of a building with velocity 10 m/s. The ball
collides with the smooth horizontal ground and immediately after the first rebound, its velocity vector
makes a 45o angle with the horizontal. Let the maximum height reached by the ball between its first and
second rebound be H and let the angle that its velocity vector makes with the horizontal after the second
rebound be  . Which of these options is/are correct?  g  10 m/s2 
(A) H = 10 m (B) H=5m
 1  1
(C)   tan 1   (D)   tan 1  
 2 2
4. The acceleration a  t  of a particle moving on the X-axis varies with time as:
a  t   3t  t 2 for 0  t  2
a  t   4  5t  t 2 for 2  t  4
At t  0 , the particle is at rest at x  0 . Which of these options is/are correct?
7
(A) The velocity of the particle at t  1 is
6
(B) The displacement of the particle between t  1 and t  3 is 6.66
13
(C) The velocity of the particle at t  3 is
2
(D) The position of the particle at t  4 is x  13.33
5. A point mass m is fixed rigidly to the rim of a thin circular disc of radius R. The disc is pivoted at its centre
so that it can rotate in the vertical plane. Using a motor, the disc is rotated with a constant angular
g
velocity   in the clockwise direction. Let the instantaneous angular position of the point mass
2R
be  , with its bottom-most position shown in the figure on the right being   0 . Let the force exerted by
the disc on the point mass be denoted by F    , and let the instantaneous power being delivered by the disc
to the point mass be denoted by P    . Which of these options is/are correct?
 2  3 mg
(A) F   mg (B) F   
 3  2 2
   mgR  3  mgR
(C) P   (D) P   
4 2  4  2
6. Two blocks A and B of mass 1.9 kg and 2.1 kg are suspended using an ideal, massless pulley and string as
shown. Initially, both blocks are at a height 40 cm from the ground. The system is released from rest
at t  0 . At t  1.0 s , the string suddenly breaks at the point it is attached to block B. At t  1.1 s , the
velocity of the blocks A and B are v A and v B respectively and their height above the ground is h A and hB
respectively. Which of these options is/are correct?
 g  10 m/s 
2
(A) v A  0.5 m/s , downward

(B) vB  1.5 m/s , downward
(C) hA  25 cm
(D) hB  5 cm

SECTION-1 | Type B
This section consists of THREE (03) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
Paragraph for Question 7 - 8

A thin uniform rod of mass 2m and length L, hinged at its upper end, hangs in equilibrium. A small bullet of mass
m is fired horizontally with velocity v. The bullet hits the rod very close to its bottom end and gets embedded in it.
7. The angular velocity of the combined system just afterwards is:

3v 3v 4v 6v
(A) (B) (C) (D)
4L 5L 5L 5L
8. If after the collision, the rod comes to rest in the horizontal position, then the correct relation is:
16 gL 20 gL
(A) v2  (B) v2 
3 3
32 gL 75gL
(C) v2  (D) v2 
5 8
A block of mass M is attached to an ideal spring of spring constant k and natural length L and placed on a horizontal
frictionless surface with the other end of the spring attached to a fixed support. Initially, the block is at rest, and the
spring is vertical and unstretched. Now, the block is suddenly given a horizontal velocity v towards the right. The
block moves a distance 3L /4 along the surface and then comes to rest.
9. The correct relation between v and the other quantities is:

5L k 3L k
(A) v (B) v
4 M 4 M
L k 3L k
(C) v (D) v
4 M 2 M
10. The acceleration of the block at the instant it comes to rest is:
3k L kL 7k L kL
(A) (B) (C) (D)
20 M 16 M 120 M 18 M

Paragraph for Question 11-12

A thin uniform rod of length L and mass M is moving on a smooth horizontal surface (which is taken to be the X-Y
plane). Two men A and B of mass M each are at the two ends of the rod. At the instant shown  t  0  , the ends of
the rod are at the origin and the point  L,0  , the rod has an angular velocity 0 clockwise, the mid-point of the rod
is at rest, and the men are at rest relative to the rod. Immediately after t  0 , the man A starts walking along the rod
towards its mid-point. Let t  t1 be the instant the rod is parallel to the Y-axis for the first time after t  0 . At the
instant t  t1 , the man A is at the mid-point of the rod and at rest relative to the rod.
11. The coordinates of the man B at the instant t  t1 are:

L L L L L L L L
(A)  ,  (B)  ,  (C)  ,  (D)  , 
2 6 4 6 2 3 4 3
12. The velocity of the man A (relative to the ground) at the instant t  t1 is:
7 7 5 5
(A) L 0 (B) L 0 (C) L 0 (D) L 0
48 18 36 12
SECTION-2
This section consists of 6 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-
off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be bubbled. (Example: 6,
81, 1.50, 3.25, 0.08)
1. A particle is moving in the X-Y plane. Its position as a function of time is given by:

r  cos  3t  iˆ  2 sin  3t  ˆj . Let t  t0 be the first instant after t = 0 when the force acting on the particle
is perpendicular to its velocity. The distance of the particle from the origin at t  t0 is ________.
2. A particle is projected vertically from a point on the ground at t  0 . The particle crosses a point P
at t  1 s , and again at t  4 s . The height (in metres) of the point P from the ground

is _______. g  10 m/s2 
3. A particle moves on the curve y  4 x at a constant speed 4 2 m/s , with x and y being in metres. At the
instant the X-coordinate of the particle is 4 m, its Y-component of velocity
(in m/s) is _________.
4. A sphere of radius 5 cm and mass 4 kg rests on two point supports

as shown, such that the points A, B and the centre of the sphere
are in the same vertical plane. Friction is absent. The height
difference between the supports and the centre of the sphere is
shown in the figure. The force (in Newton) acting on the sphere
from the support A is _______.  g  10 m/s2 

5. A particle of mass 1 kg is moving with constant velocity 20 m/s along a straight line. At t  0 , a
force F  t   At starts acting on the particle, where t is time in seconds, F is in Newton, and A  2.0 N/s .
The direction of the force is always perpendicular to the velocity of the particle. If the velocity of the
   
particle at t  0 and at t  5 s is v0 and v5 respectively, the angle (in radians) between v0 and v5 is _________.
6. Starting from rest, a cylindrical body of uniform density and mass m is allowed to roll down from the top of
a fixed inclined plane of total height h. The upper half of the inclined plane is rough (and the friction
coefficient is high enough to allow pure rolling), and the lower half of the inclined plane is frictionless. The
14 gh
velocity of the centre of the body upon arriving at the bottom of the plane is . If the moment of
9
inertia of the body about its central axis is mk 2 , the ratio k 2 /R 2 is ________.

SUBJECT II : CHEMISTRY 60 MARKS
SECTION-1 | Type A
1. At 300 K, the standard enthalpies of formation of C6 H5COOH(s), CO 2 (g) and H 2O() are –410, –390
and –285 kJ/mol, respectively. The heat of combustion of benzoic acid (s) at 300 K is:
 J 
 R  8.314 mol  K 
(A) –3201 kJ/mol, at constant pressure (B) –3175 kJ/mol, at constant pressure
(C) –3173.75 kJ/mol, at constant volume (D) –3199.76 kJ/mol, at constant volume
2. A quantity of 900 g water is added in 138 g ethanol at a certain temperature to get 1 L of solution. Which of
the following is/are correct regarding the solution formed?
(A) The density of solution is 950 kg / m3 (B) The mole fraction of ethanol is (3/53)
(C) The molarity of solution is 5 M (D) The molality of solution is (10/3) mol/kg
3. Select incorrect statement(s) among the following :
(A) The value of compressibility factor ‘Z’ for H 2 gas is greater than one at room temperature and
pressure
(B) The real gas behaves as an ideal gas at critical temperature
(C) For a real gas following van der Waals’ equation of state, the expression of boyle’s temperature is
8a
27R.b
a
(D) At low pressure, the compressibility factor ' Z ' 1  for 2 moles of vander waals’ gas
VRT
4. When photons of energy 4.25 eV strike the surface of a metal ‘A’, the ejected photoelectrons have
maximum kinetic energy TA (in eV) and de-Broglie wavelength  A . The maximum kinetic energy of
photoelectrons liberated from another metal ‘B’ (of same mass) by photons of energy 4.20 eV is
TB ( TA  2.5eV) . If the de-Broglie wavelength of these photoelectrons is  B ( 2 A ) , then
(A) The work function of ‘A’ is 2.25 eV (B) The work function of ‘B’ is 3.37 eV
10 5
(C) TA  eV (D) TB  eV
3 3
5. Which pair of compounds is/are not isostructural but possess same number of lone pairs on the central
atom?
(A) SF4 and SO32 (B) CO 2 and SO 2 (C) XeF2 and BeH 2 (D) CIF3 and XeF4
6. Which of the following order is/are incorrect :
(A) NaCl  MgO (Lattice enthalpy)
(B) O 2  Na   F  Mg 2 (Ionic radii)
(C) Li  Be  B  C ( IE1 )
(D) Cl  F  Br  I (Electron Affinity)

SECTION-1 | Type B

According to molecular orbital theory atomic orbitals of nearly same energy of different atoms are combined and
form molecule, In homodiatomic molecule two atomic orbitals which have wave function  A and  B are combined
in two ways ( A   B ) . They have two types of electron density, one is bonding [( A   B ) 2 ] where e
density increases between nucleus and another is antibonding [( A   B ) 2 ] where e density decreases between
nucleus. These molecular orbitals are filled according to Hund, Pauli, Aufbau principle.
7. Correct trend about bond energy is:
(A) N 2  N 2 (B) N 2  N 2 (C) N 2  N 2 (D) Not comparable
8. Which of the following paramagnetic species have highest bond order with maximum number of
antibonding electrons?
(A) N 2 (B) O 2 (C) F2 (D) C 2
Paragraph for Question 9 – 10

The ionization energy (IE1 ) of an atom is defined as the energy needed to remove an electron from gaseous atom in
its ground sate. The 2nd ionization energy (IE 2 ) is the additional energy needed to remove the 2nd electron and so
forth. The successive ionization energy of any species is increasing always.
9. Suppose a gas mixture of He, Ne, Ar and Kr is irradiated with photons of the frequency appropriate to
ionize Ne. What ions will be present in the mixture.
(A) He only (B) Ne  only
(C) He  , Ne only (D) Ne  , Kr  , Ar  only
10.  Na  is less than that of which of
The numerical value of energy involved in the given process; Na 
the following processes.
(A) Na  
 Na (B)  Na 
Na 
(C) Both (A) and (B) (D) None of these

As a result of the isobaric heating by T  72K, one mole of a certain ideal gas obtains an amount of heat Q = 1.60
kJ.
11. The magnitude of work performed by the gas is:
(A) 8.60 kJ (B) 0.60 kJ (C) 16.60 kJ (D) 4.60 kJ
12. The increment of its internal energy (in kJ) is:
(A) 1.0 (B) 1.6 (C) 2.2 (D) 2.0

SECTION-2
81, 1.50, 3.25, 0.08)
1. How many of the following compounds have zero dipole moment?
PCl3F2 , PF3Cl2 , OCl2 , H 2O , CCl4 ,SF4 , SF6 , C 2 H 4 , NCl3
2. Find the group number of element ‘X’ which belongs to s-block or p-block, having successive ionisation
energies as per the graph given below:
3.  Y , if the value of H 10.5

The standard entropy change (in cal/K-mol) for the reaction : X 
kcal/mol and K P  e10 at 300 K is_______.
4. For 1s orbital of Hydrogen atom radial wave function is given as
3/2
  1 
R(r)    e  r/a0 (where a 0  0.529Å)
  a0 
The ratio of radial probability density of finding electron at r  2a 0 to the radial probability density of
finding electron at the nucleus is given as (x.e y ) . Calculate the value of (x + y).
5. A mixture containing 1.3 millimoles of HNF2 gas and equal moles of chlorine gas, was led into a flask
containing 5.0g of KF solid and allowed to stand for 18 hours at room temperature. The gas ClNF2
 100 
 % yield  and the solid KF – HCl were formed. If the volume percent of ClNF2 in the gaseous
 3 
X
mixture present after the reaction is X, then the value of is:
8
6. 100 ml of a mixture of NH3 and H 2 was completely decomposed by sparking into nitrogen and hydrogen
gas. 80 ml of oxygen gas was then added and the mixture was sparked again. After cooling to the room
temperature the mixture was shaken with alkaline pyrogallol and a contraction of 6 ml was observed.
Calculate the fraction of ammonia, in the original mixture.

SUBJECT III : MATHEMATICS 60 MARKS
SECTION-1 | Type A
1. If (3  5  72 ) P  ( 5  7  32 ) P  (7  3  52 ) P  0, P  I , then P can be:
(A) 4 (B) 5 (C) 6 (D) 7
   1 z2 
2. If arg z   ,  and z  1 , then arg  can be:
6 3  1  z 2 
 
 5  5
(A) (B) (C) (D)
3 12 2 6
3. If a, b, c  R (a, b  0) and equations ax 2  bx  c  1  0 and bx 2  ( c  1) x  a  0 have exactly one
common root, then a + b + c =
(A) –1 (B) cos 2   sin 2 
(C) ei (D) sec 2   tan 2 
50
4. 
If 1  2 x  3x 2   a0  a1 x  a2 x 2  a3 x3  ....  a100 x100 , then:
(A) a0  1 (B) a1  100

100
(C) a2  a12  a1 (D)  ar  650
r 0
5. Which of the following statements is/are incorrect?
(A) f  x   sin 4 x  cos2 x has fundamental period 
(B) g ( x)  sin(tan x )  cos (sin x) has fundamental period 2
(C) h( x) | sin x |  | cos x | has fundamental period 
(D) k  x   [ x ]  sin 2x has fundamental period 1 ([] denotes GIF and {}
 denotes fractional part)
6. A man has 3 friends. The number of ways in which he can invite one or more of them to a party, equals to:
(A) The number of roots of 7-degree polynomial equation.
(B) Numerical value of distance of z1  1  2i from z2  7  (2  13)i in Argand plane.
x 2  3x  10
(C) Value of f ( x )  at x = 2
x2
(D) Number of zeroes at the end of value of 31

SECTION-1 | Type B

n n n n 2 n 3 n n
Given, (1  x )  C0  C1x  C2 x  C3 x  Cn x .
101
7. C1  4 101C4  7  101C7  100  101C100 
101 100 101 100 101 100 101 100
(A) (2  1) (B) (2  1) (C) (2  1) (D) (3  1)
2 3 3 3
101
8. C1  3  101C3  5  101C5  7  101C7  99  101C99  101101 C101 
(A) 250 101 (B) 250 101 (C) 251  100 (D) 251 101
1 x 
Given: f ( x )  2 f (1  x )  x 2  2  x  R and 2 g ( x  1)  g    x.
 x 
9. 2 f (1)  3 g (0)  4 g (1) 
(A) 2 f (5) (B) 3 f (5) (C) 4 f (5) (D) 5 f (5)
10. The function f ( x ) is minimum at x 

(A) 1 (B) 2 (C) 3 (D) 4

1
Let f ( x )  ax 2  bx  1, a  0, a, b, x  R . The graph of y  f ( x ) is minimum at x   .
2
11. If exactly one root of f (0) x 2  f (1) x  f ( 1)  0 lies between 0 and 1, then a 
 3 
(A) (0, ) (B)   ,0 
 2 
 3 
(C)  ,  (D) No such value of a exists
 2 
12. f ( x )  0 has real and distinct roots, if and only if a 

(A) (, 0]  [4, ) (B) (4, )
(C) (0, 4) (D) (, 0)  (4, )

SECTION-2
81, 1.50, 3.25, 0.08)
1. Let complete values of x satisfying

 x  1 x  1  1  0 be [a, b]  [c, d ) , then
(e x  1)  x  2  3
a + b + c + d = ________.
2. The number of real roots of x 4  x3  2 x  4  0 , is ________.

1 12 13 14 15 16
3. The digit at tenth place in the number 111  111  111  111  111  111 , is _______.
4. Evaluate: 55  4 221 i where | z | represents modulus of complex number z
5. The area (in square units) by |x – 1| + |y + 1| = 1 in xy plane, is _______.
6. The rank of the word ‘VACCINE’ in the dictionary of words formed by permuting the letters of the word
‘VACCINE’ in all possible manner, is_______.
   End of JEE Advanced – 2 | Paper - 2 |JEE -2023 (GEN 1 & 2)  

Jee Advanced 2 Paper 2

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Jee Advanced 2 Paper 2

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General Instructions

2. Section 1 contains 2 types of questions [Type A and Type B].

VMC | JEE-2023 | Paper-2 2 JEE Advanced-2 | Gen 1 & 2

SUBJECT I : PHYSICS 60 MARKS

VMC | JEE-2023 | Paper-2 3 JEE Advanced-2 | Gen 1 & 2

(A) v A  0.5 m/s , downward

VMC | JEE-2023 | Paper-2 4 JEE Advanced-2 | Gen 1 & 2

Paragraph for Question 7 - 8

7. The angular velocity of the combined system just afterwards is:

9. The correct relation between v and the other quantities is:

VMC | JEE-2023 | Paper-2 5 JEE Advanced-2 | Gen 1 & 2

Paragraph for Question 11-12

11. The coordinates of the man B at the instant t  t1 are:

4. A sphere of radius 5 cm and mass 4 kg rests on two point supports

from the support A is _______.  g  10 m/s2 

VMC | JEE-2023 | Paper-2 6 JEE Advanced-2 | Gen 1 & 2

VMC | JEE-2023 | Paper-2 7 JEE Advanced-2 | Gen 1 & 2

SUBJECT II : CHEMISTRY 60 MARKS

VMC | JEE-2023 | Paper-2 8 JEE Advanced-2 | Gen 1 & 2

Paragraph for Question 7 - 8

Paragraph for Question 9 – 10

Paragraph for Question 11-12

VMC | JEE-2023 | Paper-2 9 JEE Advanced-2 | Gen 1 & 2

3.  Y , if the value of H 10.5

VMC | JEE-2023 | Paper-2 10 JEE Advanced-2 | Gen 1 & 2

SUBJECT III : MATHEMATICS 60 MARKS

(A) a0  1 (B) a1  100

VMC | JEE-2023 | Paper-2 11 JEE Advanced-2 | Gen 1 & 2

Paragraph for Question 7 - 8

Paragraph for Question 9 - 10

10. The function f ( x ) is minimum at x 

Paragraph for Question 11-12

12. f ( x )  0 has real and distinct roots, if and only if a 

VMC | JEE-2023 | Paper-2 12 JEE Advanced-2 | Gen 1 & 2

1. Let complete values of x satisfying

2. The number of real roots of x 4  x3  2 x  4  0 , is ________.

4. Evaluate: 55  4 221 i where | z | represents modulus of complex number z

5. The area (in square units) by |x – 1| + |y + 1| = 1 in xy plane, is _______.

   End of JEE Advanced – 2 | Paper - 2 |JEE -2023 (GEN 1 & 2)  

VMC | JEE-2023 | Paper-2 13 JEE Advanced-2 | Gen 1 & 2

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