A ee ye DAT HOC Quéc aia rp WO CHI MIN TRUGNG DAL HOC BACH KHOA Nguyén Thj Thu Van BAI TAP VA SO TAY PHAN TiCH DINH LUONG (Tai ban lan thit sdu) NHA XUAT BAN DAI HQC QUOC GIA TP HO CHi MINH - 2019 Scanned with CamScannerMUC LUC oHAN 1 CAU HOI VA BAL TAP Chuong 1: Bai evong vé héa phn tich : Chung 2: Nhie lai mot so kién thie edin cho hoa phan tich 6 Chuong 3: Hang sé dac trung cia cdc cain bling hoa hoe don gidn trong nude i : . Chyong 4: Hing so dic trung dieu kién ciia cae cin bing héa hoc trong nude Chuong 5: Xir ly 17 ligu thyc nghiém theo phuong phap théng ke 20 a Chuong 7: Phuong phap phan tich thé tich . (phuong phap chudn 46) 24 Chuong 8: Bai tap on tap 33 Chuong 9: Phé nguyén tir 37 Chuong 10: Phé tit ngoai - cha kién (phé kich thich electron) 39 Chuong 11: Phé héng ngoai va phé raman (phé dao ding quay) 43 Chuong 12: Phé huynh quang va lan quang 46 Chuong 13: Phé cong huéng tit 48 Chuong 14: Phuong phép khdi phé (phé khoi lugng) 53 Chuong 15: Bai tap téng hgp cae PPPT phé nghiém 37 Chuong 16: Phuong phap dign kh6i lugng va do dién lugng 39 Chuong 17: Phuong phap phan tich dua vao viée do thé 62 Chuong 18: Phuong phap phan tich volt - ampere 65 Chuong 19: Bai tap phuong phép phan tich sde ky 67 PHAN II LOI GIAI VA DAP 86 1 Chuong 1: Dai cuang vé héa phan tich 3 Chuong 2: Nhic lai mét sé kign thie edn cho héa phan tich 14 Chuong 3: Hing sé dae tring ciia cae can bang héa hoe don gian : trong nudge 80 Chuong 4: Hang sé d lic trung diéu kién eta cée can bing hoa hoe trong nuée 7 Chuong 5: Xit sé ligu thye nghiém theo phuong php thong ké 110 ‘hung phép phan tich khoi lugng 113 : Phuong phap phan tich thé tich (phuong phap shudn 46) Chuong 8: Bai tap én tap 120 : 139 Chuong 9: Phé nguyén tit M1 Chuong 10: Phd ti ngoai-Keha kin (phé kich thich electron) 3. amet wth CamScannerPHAN I cAU HOI VA BAI TAP Scanned with CamScannerchuong 1 DAI CUONG VE HOA PHAN TICH pé xc dinh ham lugng AlpO3, Fe2O3, CaO, MgO va TiO, ng mot mau dat sét, ngudi ta cn 0,3000g mau chuyén vao chén j va thém vao 3g KOH. Nung chay hén hgp néi trén 6 nhiét 46 ‘ch hop, lam ngudi va hda tan khdi rin thu duge bing acid HCl. nem nude cat dén thé tich xac dinh. Sau khi thu duge dung dich, ang EDTA dé chudn 46 ‘Al’, Ca’", Mg’ 6 diéu_kién thich hgp; Hang 1,10- phenanthroline tao phife 4 cam véi ion Fe (dang Fe”), ‘ang HaOotqo phife mau vang vai Ti rdi dem do. va so sinh gi cde dung dich chifa Fe?*/chita Ti"* da biét trude néng 46. Ngudi ta xc dinh duge ham lugng cdc chat khao sat nhu sau: ' FeO; | cao | MgO | Tide Ham lugng (%) 0,08 Hay cho biét: a) Phuong phdp (PP) da duge st! dung dé hda tan mau? PP khs b) Tén goi cia PP da duge sit dung dé dinh lugng Al,Os, 7@)03, Cad, MgO va TiO.: \- Theo ban chat cua PP )- Theo ky thuat phan tich (PT) Botnw {eng - Theo ham lugng chat khao sat. Scanned with CamScannerCh “ony nuAc Lal MOT SO KIEN THUG CAN CHO HOA PHAN TIcH , foreectang falance the ratums ant Letermuay the teatong wel wah 4 Can bang cdc phan ting va xae dink n trong biéy ea tte, duong Inong D =“ etta cde chat ¢6 gach dudis —- NaS + 2H,0 — Naso, + *H,0 — NH, + NaCl + Ho — Fe(OH), + 2NaCl — NaznO, + YNaCl +2H.0 —- CaHPO, + -2H,0 — FeCl, + —H,0 — HS + FeCl, + —~ [Ag(NH;),JCl +2 HO — [Cu(cN),” flute ¢ i he < 10, chad |} { — [Fe(CN).l — 32ZnSO, + § +/'H,0 —-i7nso, + HS + H,0 —= 2Zn(NO,), + NH,NO, +H,0 — Prcl, 0 0R 4 xt Scanned with CamScannerCol -rhatrs Kray bandg CO Ghat C ueies edad 96! ets bout # nde lot mot nd Ils hate edn oli Iida phi tol fool ant vatel na * “8 — ps ‘ ue tegen Col oor ibn + H,80, — Cr (80), *KSO, + H,0 13. KMnd, “ko, ¥3H,SO, —= YMNSO, 140, + K,8O, +2H,0. ad 19. PbO, + HO, sseh,c00H —= PvICH,COO), + 0, +yH,0 ipa aed,” OH = AOS" * 380%" gH, Weg ne 7 a1. Fe(SO)s v2 — "FeSO, + IL, + K,SO, 7 ( 2-5 CHE aig 43H,80, —> SCH {COOH 2MnSO,+ K,S0, H,O 23. ic HOH WK, Ker, HJH,SO, — 3CH,CHO +Cr,(SO,),+ K,SO, 4H,0 Cée Base ué néng dé dung dich . Cin bao nhiéu gam NaOH dé pha 3 lit dung dich NaOH 10%, bidt dd NaOH 10% ¢6 d= 1,110g/mil. mg.s 22209 Wa = 9829 Xée dinh néng do Cy va néng 49 Cy ca dung dich NaOH 16%, bth NoOH ed = 2arsend Cus a 48M 2 Gye - Xée dinh wong NaOH 40% clin ham vao 600y nude a8 duge dd © NaOH 10%? Xie dinh lugng Na,0 edn hda tan vao 676g dd chia 160g NaOH dé duge dd NaOH 40%? C6 dd HCl 36,5% (d = 1,180g/ml): - Tinh sé gam HCl nguyén chat trong méi ml dung dich? = 2 = s - Tinh néng dé mol cla dung dich? - Tinh sd mi dung dich trén cn ding dé pha 200ml dd HCl 3M? Cfin thém bao nhiéu ml nu6e vao 100ml dd HCl 20% (d = 1,10g/ml) dé 6 dd HCI 5%? Xe dinh lugng nude can hoa tan 44,8 lit HCl (6 diéu kién tiéu chuain) dé duge dd acid chlohydric 14,6%? . Phai hda tan bao nhiéu ml dd HNO; 98% vao 100ml nude dé duge dd HNOs c6 khéi lugng riéng d = 1,200g/ml? Phai ding bao nhiéu ml dd CHj;COOH 98% dé pha 250ml dd acid acetic 1M? - = @ S 10. Xie dinh lugng anhydric acetic (CH,CO),0 va nude can dé pha 500g dd acid acetic 54%? Scanned with CamScannerChuang y 10 rn % (d = 1,84g/ml) dé pha 1 lit q 1. Cin bao nhidu md dd HsS0, 96% (d = 1,849 A H,SO, 0,5? - ‘ A {i dung bao nhiéu m/ d 12, Mudn pha 5 lit dd HySO, 0,14 thi phai ding a M280, 96% (d = 1,835¢/n1)? _ PO, 6 trong 1 lit dung dich 98,48% (d = Wai) 9 mol - néng do duong lugng a ns au nhat, itu va theo ea ba chitc cia dd HyPOs 17,9%? PO, 17,87%; bist Cur = 2,054 3 ; 18, Tinh so gam Hal YM Nite dinh néng theo hai chtie d, 15. Tinh khéi lugng riéng cia dd H. . . 16. Tinh khoi luong NHy nguyén chat 6 trong 1 lit dd aMoning 24.03% (d= 0,910¢/mi)? Cain lay bao nhiéu gam hay bao nhiéy ml dd trén dé pha 1 lit dq amoniac 0,0500M? 17, Cin 2,8614g Na:C0,.10 H,0 haa tan trong nude thinh 250m) ad, Tinh néng dé duong lugng cita dd dé? 18. Tinh khdi lwong tinh thé Na,SO,.10 H,0 thu duge khi ¢6 cay 500m/ dung dich NaySO, 2N; bist ring Na,SO, 1a san pham cia qué trinh trung hoa hoan toan NaOH bing H,SO,. 19. Tinh néng do duong lugng eila dd Al(8Oq)3 15% KLU/KL (d ~ 1,12g/ml); biét ring Ale(SO,)5 14 san pham cda qué trinh trung hoa hoan toan Al(OH); bing dd H.SO,. ‘Yo, Xac dinh lugng CuSO, 5H,0 va dd CuSO, 8% can dé pha 560g © dd CuSO, 16%9 21. Tinh sé gam KCr.0, edn dang dé pha 250ml dung dich 0,050N; biét ring K3Cr,0; sau khi tham gia phan ting bi chuyén thanh Cr'¥? . 2: Tinh néng d6 phan mol clia cde thanh phan trong dd CaCl, 10%? 23. Tinh nong d6 phan mol cua cdc thanh phan trong dd chita 40% chloroform (CHCls) va 60% aceton [(CH,),CO]? ti i CamScannert Chitang 3 HANG 80 DAG TRUNG GUA CAG CAN BANG HOA HOG DON GIAN TRONG HUGE Trang thal edn bang cia he (rong dung dich nude 1, MO ta trang thal efin bing trong nude ean | ay HE b) CHCOOH, cHL8O.4 a) HLC,04 6) NaOH | ON Q NTC hy KEN: i) CuO, jy Na,SO, 2 MO tl trang thii cin bhng trong nude cua BaCl, va Na,SO, (te dung vita dit vdi nhau). 3. MO tit trang thii cin bling trong nude cia AgNO, va NH, (NH, thita so vdi AgNO,). 4. Viet ede biéu thie dinh luAt bao toan néng do va bao toan dién tich cho cde hé sau: a) dd nud via NH, (ndng d@ mol ban dau C,), b) dd muide etia NHy (néng do Cy) va NH,NO; (ndng do C,) c) dd nude etia NH, (ndng d@ Cy) va HCl (ndng dé Cy). Nhdn dign ede doi acid! baz trong nhiing phan itng sau day: 1, Z2n(OH), + 20H" = 70; + 2H,0 On + HO ws 20H 3. NHe + NH, 9 === NHy + NoHo 4. HNO; + HpSO, 2% NOs + H,SO,* 5. HCIO, + NoHy ==® ClOg + NoHs* 6. CsHsNH® + (CHa)gN S=® CsHsN + (CHs)3NH* 7. HxCOs + HO =e HCOy + HAO 8. CoHsOH + NH2 ==® CHsO7 + NH PH ctia ede dd 1. Gidi phuong trinh day di ohan duge gid tri pH (lam tron dén hai s6 1é),eda ede dd don acid hose don baz nhu sau: ‘Scanned with CamScanner‘dd dan acid hose dan baz phy HIOy phios = 0.70 Cl,CHCOOH pkerencoon = 43 HF kur = 3, 17 ‘CH;COOH pkcxsccoon = 441 H202 Pkyeoe = 11,70 NH,OH Pkrinnas = 924 NH,CI Pkunee = 9,24 eee Coe Phexaccoon = 4,76 76 0,001 eo 0,100 11,10 KON Pkew = 9,21 0,010 70.60 0,001 10,08 is ay ay zs cia cdc dd trén bing cdch gidi cde phiong ti" at va so sénh voi cde két qua tf i Phuong trinh day dd cho 6 trén. saa doe a Scanned with CamScannern_biing héa hoe don gidn tro, ni g dac trung cua cite cal nude 4 ts phuong trinh day du nhan duge gid tri pH dd diacid hoac dibaz nhu Pete (lam tron dén ai 20 Ie) cua cdc ga giacid Rode aIbaz eee on H 1:02:01 pkar = 1.25 0,100 ” pkyo = 4.27 0,010 re 2,06 0,001 2,90 | 0.0001 3,89 1 acid o -Phthalic pkst = 2,95 0,100 xt (COOH pha = 5.41 0.010 te 0,001 a 0,0001 4,02 ‘Acid m -Phthalic pkar = 3,70 0,100 2,38 CeHle(COOH)2 Pkaz = 4,60 0,010 207 0,001 aa | 0,0001 4,05 HiCOs | kas = 6,35 0,100 i pkae = 10,32 0,010 0,001 0,001 ., NazCOs kor = 3.68 0,100 - “| phe = 7.35 0,010 * 0,001 0,0001 iacid (hoae dibaz) bang cdéch xem diacid nm acid (hod don baz) [gidi PT day di ¢ dung cdc PT don Hay tiah pH cita cde di (ho&e dibaz) tusng duong do! cia don acid (hoa don baz) tuoné duong va s gian hon nia]. tron dén hgp cla baz yéu), ge gid tri pH (am hn day dé nban 4 d-y6u + baz lien d dém acid (gdm aci baz yéu + acid lién hop cua d - baz nhu sau: 3. Giai phuong tril hai s6 1é) cua cée d acid yéu), dd dém baz (gam. dd dém chifa hai chat luone tinh acl Scanned with CamScanneraa ee pee __—— wma a aang actd (CA) v8 N69 00 ‘dgng baz (Cah Hg dd dem i ce 0,100 ‘Acid yéu CHyCOOH 0,010 (kina = 10°) 0,001 va baz (lin hop) 0,100 yéu NaCHsCOO 0,100 0,010 0,010 0,001 Be aa 0,100 676 0,100 0,100 9,24 Baz yéu NHOH 0,010 ent Set (en = 107) 0,001 0,001 9,23 va ee ee 0,100 0,010 8.24 0,100 0,001 7.24 0,010 0,001 8,24 0,010 0,100 10,23 0,001 0,010 40,17 0,001 0,100 10,96 es 0,100 0,100 7.21 ia oe 0010 + 0,010 7.24 sc ni 0,001 0,001 7.21 y6u NaHPO, 0,100 0,010 621 0,100 0,001 5.21 9.010 0,001 6,21 0.010 0,100 8.21 0,001 L_ — 0,010 a2t || 0,100 9,20 sing Hy th PH ciia cde : 0 sénh véi trinh day da cho g a di i é “ am fies dgm trén bing céng thiic gf a inh duge bling cach giai phuond) Scanned with CamScanner¢ trung cia cae cfin bang héa hoe don cop pH (lam tron dén hai s6 1é) bang eb os . tinh pl g cong the gin di an dung cia d duéi day: id CH.COOH 5.10°°M HH 2.10°M e) Hon hgp fh Hon hop c@u e) sau khi thém 10 HCI vao 1 tit da g) Hon hop ¢ cau ) sau khi oe 10 “M NaOH vao 1 lit dd h) Hon hop 2,0.10°M NH, va 10 2M NHLCl. 5. Phai thém bao nhiéu mol HC! vao 1 lit dd chtta 0,010M C! v7 0)010M CH,COONa dé duge da e6 pH 3,02 uf CUSCOOH ¢, Tinh 56 ml dd HCI 6,0M phai thém vio 100m! dd 0,1M CHC G6 due dd c6 pH 4,25? 1M CHCOONa 7, Tinh néng 46 mol cia dd acid acetic cé pH = 3,6? 8, Tinh kh6i lugng NH,CI ean dé pha | lit dd 6 pH = 5,5? Cae bai todn lién quan dén cdc can bang xdy ra trong nuée 1, Cho hai d6i oxy héa khir MnO, (H") / Mn® va ClO," (H*)/ Clr a) Can bing phan cing xdy ra gidia hai doi va xc dinh biéu thite tinh duong lugng cua hai tae chat? by Tinh hiing s6 edn bing eda phan ting 6 pH 0? 2, Tinh K va Ey ca phan ting xy ra khi tron 100ml dd Cx0;* 0,1N vao 100ml dd Fe 0,1N 6 pH 0? 3. Hay xée dinh gid tri hé sO diéu kign cy tir pH 1 dén pH 14, biét Y* Ja anion cia EDTA H.Y voi fa = 1071; fey = 10%; hy = 10°" va ky = 107%, 4, Tron 100ml dd 0,0030M Pb(NOs)e v6 ¢é thé c6 két tia tao thanh khéng? 5. Cho mot miéng Cu vao dd AgNO: 0,05M. Viet phan \ trong dd? Tinh hing sé 47 bing cia phan ng va néng dé cia cae chat trong dd sau Kthi cain bing dat duge. 6.2,2g NaOH rain duge thém vao 250m! dd FeCl, 0,10M. Tinh lugng tia Fe(OH), tgo thanh va ndng 46 Fe" trong dung dich? 1. Them di NH, vio dd CuSOs 01M a6 tao mot phic bén nhat. Xe dinh néng d9 Cu” trong ‘dd sau khi can bing da dat duge? i 400ml dd 0,040M Na,SOs, Viet phan ting xdy ra xe dinh Scanned with CamScannera nong do Ag’ con lai khi thé 0,001M. Cho biét [NHs] = 9, an bling sau day: 8, 'I'inh ndng d6 cde phite tao thanh NIH vio dd chita Ag’ vdi [Ag* va trong dd xem nhu chi xy ra I [Agi Be 312 ‘~ [AQ(NHA))" # NH, S== (Ag Ha): Te 7 10 ; ) “ _ ( 9) Tinh pH] can dd HPO, 0,147, biét acid nay ©° 7 a as a : va pH nay, tinh néng do can bang on Ag’ + Nia oe phy = 12,2 trong dung dich? ee — 10, pif cnn dal H,CO,0,15M duge gidi tir PT day dit Ia 3,64. Hay 2c dh _ ev he thanh phan & trang théi can bing khi hda néng 6 cia cae thanh phan a 1558. py = 10°10 0,15 mol 11,CO, vao mot lit nude. Cho har = 100"; Raa = a 1, Xae dinh néng do cia cée thanh phan é trang thai can bai cua dd H,C,0, 0,1M; biét pH cia dd HaC20« o1M duge giai PT day di la 1,28. Cho ha: =10"9; haz = 10°". a ; : ie voi Fe. Phi 12. Ding ligand L 1a 1,10 - phenanthroline tao phic véi Fe**. tao thanh cée dang FeL, Fel, va Fels vdi Bi: = 10°; Bis 10! va By = 107, Hay x4c dinh néng d6 cia cdc phitc tat thanh va néng d@ Fe”* con lai trong dd, néu néng do Fe** ban da 1a 0,001M va néng do L 6 can bang 1a 0,1M. 13. Fe** tao vi SCN” thanh phite [Fe(SCN-),]°"* v6i x c6 gid t tir 1+6. Gid tri hang sé bén cia cde phic [Fe(SCN-),]®"* 14 lugt nhu sau: Bia = 10°; Baa a FTF hUree Bis = 10" va Bio = 10°°*, Xde dinh néng d6 cia cdc phitc ta thanh va nong 49 Fe* con lai trong dd khi them SCN- vao d chita [Fe**]p = 0,001M véi: a) [SCN"] = 1M b) [SCN Gia st trong diéu kién dan Ung gitta Fe* va SCN”, M4. Thém KSCN 5.10°M vao dd chi $m i 10M cha [Fe], = 0,0 én'k ane mau dé ciia phite (Fe(SCN-)} kha ot ae ane i id KSCN (5.10°M edn sit dung had otal r 2+ ea . ae D SCN oF xudt hign khi néng 49 cia ion phite nay 1én ‘ht 16. ion-g/l (bé qua anh auéng cla OH- Jén io: ne ve : mn Fe**). ¥ Scanned with CamScanner ig x6t trong dd chi xdy ra cde phaChuong 4 HANG SO BAC TRUNG BIEU KIEN cUA CAC CAN BANG HOA HOC TRONG Nude Hing 86 dée trung (HSBT) dieu hign cia cén bing trao déie ns, é 62 eth + 24 1. Tinh ed bonis cua coe 1Co’ va alia Fe? “/Fe® trong dd KCN du. he su phite cH tao thanh véi sé ligand lén nhat va bd qua anh huéng cia OH ~ lén ede ion kim loai, ching minh Fe* (duéi dang phue vai CN") sé oxy hoa Co” (duéi dang phite vi CN") mot céch hoan toan. Vote Lubing duz Ligand, the tui tao BY * a - y 4 yo 2, Cho hai déi oxy héa kh: th orn, put ce Ligand WhE Au'+1e° soe Au E°= +1,68V Cu'+ te == Cu Ee = +0,52V Xé6t chiéu phan ung va tinh hing sé cin bang cia phan ung xay ra khi tron hai doi oxy héa khti néi trén trong hai trubng hgp: a) Khong c6 sy hién dién cia CN” trong dung dich phan ting. b) C6 sy hién dign ca lugng(thita) CN” trong dung djch phan tng. Cho biét ede can bing phy eda ON” Ién ede déi oxy hoa khit déu la can bing phy tao phic va bé qua anh hudng cua tat cd cde can bing phu khdc. ~ >kMOt ion kim logi héa trj 2 ¢6 cm (MM) = 0,900V. Sau khi trén 25,0 0,100M vei 25,00ml dd Y* (EDTA) 0,20 tao béi chp M"*/M néi trén 1a 0,570V- a) Tinh thé oxy héa chudin diéu kign cia cp M*/M ndi trén neu bé qua anh huéng cia H* lén y* va anh hudng cla OH lén M”, b) Tinh hing sé bén eda phic t20 béi kién dé c6 thé sit dung Y* chudn do dd M* é pH 10. phng M+ 2e == M véi Er Om dd M** ndi trén c6 néng 46 OM; ngudi ta do duge thé M? va Y'va cho biét diéu Scanned with CamScanner«rt dé gidi phong ra Hy me 4. Gidi thich tai sao Ag chi tac dung voi HI dé giai phone ema Khong tae dung véi HCI? Cho tich 6 tan etia AgCh Ae Toe va Tyr = 10°; I (Ag’/Ag) = 0,80V. View phan ding xAy ra. HDT digu kign cia can being trao di tidu phan 1. Tinh pH ciia cdc dd sau day: : 10M; 10°M; 10°M a) dd NH: ‘i b) dd NH,CN: 10M; 107M; 10°M ¢) dd (NH, )sHPO,: 10° . @ac hon hop: — 5.10°M NaH,PO, + 10°M NaHSO; +10 7 Ni (pk; = 4); HBe (phe = 7) co néng di 2, Cho hén hop hai acid HB; méi acid 12107. ; a) Tinh pH cua dung dich? : b) Thém vao 100m/ hén hgp trén 100ml NaOH 10°M. inh p cia dd mdi? 3. Acid boric duoc xem tuong duong mot don acid cé ka = 10°"* va biét rang H,BO; dé tao phttc vai mannitol (ky hiéu M, 1a m6t da rugu co cong thc nguyén CsH,40¢) theo:phan ting sau day: HB + M == BM + H* B, =10748 BM + M = BM Bo =1079 Trong dd mannito}. :‘nh acid cia H3BO; thay déi thé nao? Cho biét (M],, = 1M. 4. Trong dd Cu* 10"*M, tinh acid cia glycine NH,CH,COOH cé thay ong? Cho biét On khong anh huéng dén céc ion trong dd va hCHsCOOH) = 10°°"*. 8 (NHLCH; COOCuy* = 10% ] ee Tinh dé tan cha CuS tron; anh huéng cia Ht va OH’. 6. Tinh 6 tan eda AgCl (’ 6nd Trecr = 107275 stn ; ©6 néng do [NH,] = agcl = 10°") trong moi truéng ammoniac 0,1M trong hai ti - . rudng hgp: y a) Khong xét anh huéng cia OH- 7 ; b) Co xét anh hug ; yéu béi lugng Ni, eae “a OH (pH cia dd duge quyét dinh chi . Scanned with CamScannerac trung digu kin cia ede fin bing héa hoe trong nuée 19 Cho biét NHs 6 thé tao phtie vdi Ag* theo hai can bang sau day: Ag’ +NHy s== [Ag(NHs)]" (By = 10°) : [Ag(NHa)]" + NHa === {AQ(NHs)2]" (Be = 10°) Ol gay nhiéu lén Ag* voi Bia =10°°; Biz = 10° va B,, = 192 7. Ching minh ring HgS khong tan trong HNO, ma tan trong nuée axing thiy (10 HNOs 44 va 3v HCI Aa), Cho biét Hg tao phite voi Cl’ duéi dang HgCl, mah S” bi oxy hea bhi NOS 5 |g. Cho dd [Cu?*lp= 10M vao dd EDTA cé [Y*}, = 10 *M 6 tao phiie. Néu phic CuY? khong bi anh hung béi H' va OH-pifan ting tao phuic CuY®* cé tinh dinh lugng khong? g. Tinh hang 80 bén diéu kién cla phic CuY~ & pH 18? Biét rang cuY*_bi_anh_huéng béi OH” do tao phue [CulOHIY? 6 B [Cu(OH] Y* = 10°”. 10. Xét tinh dinh lugng khi dung EDTA chudn 6 Hg”: a) GO pH = 10? b) Cang 6 pH = 10, nhung trong méi trugng cé CN’ voi [CN"] = 10°M 11. Tinh hing sé bén diéu kién cia phuc [Fe(SCN)I** 6 pH tit 1 = 4, biét HSB cia phic trén 1a 10°; Fe® bi nhiéu boi OH” voi Bia 10", By = 107; Big = 10 va acid HACK €6 ht. = 10 88, 12, Tinh hing sé bén diéu kign 6 pH ti 4 +7 cua phiie Fela voi L Ta anion cia 1,10 - phenanthroline, bist phic tren 6 Bis =10 ; ae og) cet ne och 556. = 107 fp, = 10°" va Fe* bi nhiéu boi OH” voi fii = 10°; Bia = 3 Bas Bia= 10°, Acid HL c6 hy = 10 Scanned with CamScannerChuong ¢ NGHIEM i LY $0 LIEU THYC NG a XU LY énG KE THEO PHUONG PHAP TH og TiO, trong mau Ihodng cie dinh ham lugng G TiOz ng m c i ne Néu ham lugng thu ctia TiO, 1a 0,125 _ 6 mae phai sai so hé thong hay khong & 90 va 99%? ' 99; 7,35; 7,31; 7,33. Tinh: khoang ti v6i hai mtie xtc suat 2. Do 4 lin pH co két qui 7, cay khi P = 90%, 99%. ; ah aye 3. Ham lung (%) Pb trong mau hop kim duge xc dinh 3 tan vi ke qua nhu sau: 0,184; 0,189; 0,179. Tinh cn tin cy va Ihoang tin 4 cia gid tri trung binh ham lugng % Pb véi xdc suat 95%. 4. Khi x4c dinh % SiO. cia mot mau dat sét, két qua cla 5 lan t nghiém thu dugc 1a 55,95; 56,00; 56,04; 56,08; 56,23. Bang cach s sdnh v6i d hodc s hoac ding chudn Q véi P = 95%, cho biét nén gil lai két qua 56,23 hay bé di? 1 5. Fluor 1a tap chat 6 hai trong nuée néu vuot qua ngudng chi ae Qua 4 lan phan tich ham lugng ppm F~ trong mau, két qu thu duge nhu sau: 1,82; 1,28; 1,36; 1,50ppm. Hay xée dinh gidi ha trén cia F véi xdc sudt 95%. i 4 nghiém Jan luot la 0,27; 0,28; 0,32 va 0,37ppm ; 2 Sit dung chudin Q dé cho biét nén gif lai ha: "37 tng v6i cde mie xée suat 90, 95 va 99% b : ' a eee dinh khoang tin cy cla gid tri trun, 8 Voi cdc mite xde suat 90; 95 va 99%, y nén.bé di gid tri g binh ham lugng Fe Scanned with CamScannerChuong 6 pHUONG PHAP PHAN TICH KHOI LUGNG (PPPTKT) nai mau quang chi: Maul: % d = 1,56; % Pb = 24,02 Mau 2: % d9 dm = 0,58% —% Pb = 24,26 Tinh 2, Két qua phan tich do am mét mau phan b6n photphat bang phap phan tich khéi lugng cho cée s6 liéu nhu sau: 1, Phan tich I ham lugng Pb cla méi mau d dang khé va nhan xét. phuong - Chén sti: . mM, = 9,4358g _ Chén stf c6 mau (chua sy): my = 11,4585¢ -Chén sit c6 mau (da say): m2 = 11,3762g a) Tinh dé 4m cla mau phan bon ndi trén? b) Tinh thanh phan % cua P.O5 va Ca(H2PO,)2. H20 trong mau phan bon chua lam khé, biét két qua phan tich ham lugng P205 trong mau da say kh 1a 16,5%. xit sét nang 0,5000g duge lam két tha dudi 3. Mot mau quang 0: a can nang 0,4980g. Tinh dang Fe(OH); va nung thanh oxit sat b: ham luong sét dudi dang % Fe va % FeO? 4, Dinh lugng photpho trong méu phan bén, 1,000g mau duge tao tia dudi dang MgNH,PO., Nung tia 600°C dugc dang can Mg:P,0; c6 khdi lugng 0,2350g. Tinh % P va % P20; trong mau phan bén? 5. Mot mau 44 voi edn nang 1,2300g duge hda tan trong acid. Loe ba tila, dung dich qua loc cho tée dung vai NH,OH. Khoi ligng cde oxit kim loa hoa tri 3 thu duge 1a 0,0584g. Nhom duge cd lip riéng va dang can thu duge 1a AlsOs nfing 0,0282¢. Tinh % Fe va % Al trong mau? 6. 0,8325g mét hgp kim Cu + Sn + Zn. Phan tich bing PPPTKL * thu duge 0,6728g CuSCN va 0,0423¢ SnO». Xdc dinh ham lugng cae thanh phan trong hgp kim. Scanned with CamScanner. {dé 1am ket old = o,g90gin 1 ee ir 0,2008 quing 6 30% Fe’ aa tan v f rong, BaCls xH,O, ngudi gm nh sau: yo nhieu 4, Pha dang bY ya phan tich ¢ * yong ¢ ham hon jot tinh ¢ 8 Oe TL ya duige te kot qual ne nghi - Dia caine m = 167208 _ pia cn 66 mau? » = 287628 Chen sth my = 9, 27388 chen st + BaSOy #4 = 9,9464g Tinh & Ba, % BaCh ya xde dinh tri s sx trong cong thife phi 9, Phin hoy 0,1500¢ mot hgp chat hitu co c6 cong thite CoHs.C uve jon CY. Két tua ion CP bing Ag’ thu duge 0,4040g AgCl da: cin, Nac dinh x trong cdng thie Pp xem Ja nguyén chat). to. Dé xée dinh him lugng cia mot méu KAI(SO,)2xH20, nguoi ’ can 0,5260¢ miu; hoa tan va tgo tia bing dung dich Ba”. Kha re dang can thu duge 14 0,4591g va ti’ dé ngudi ta tinh duge KANSO,)2sH.O trong mau la 88,7%. Hay xde dinh: ; “ Gis tri euia x trong cong thie phan ti néi trén ) % KAUSO,)p trong mau. , M1. Dé don gidn héa ti iin h6a tinh ton, phi can mo phai cin m6t lugng phan bén kal 1a bao nhiéu dé ho % : can KCIO,2 10 % KO thu duge bing 100 lan khéi luon, i Ong dan; het Fe jp nui ain tr, (NHo,Ptc] lc. N la et a 01085 Pas ne EPIC 6 ae tia NH," duéi dan 9 et dQ thich hg; | Gp, thu dug of Scanned with CamScanneré tich khdi ligng so 23 ppudh enn —<—<—<——— oe ot ine chi e6 CaS val Zn8. Cn 0,498%q mau hoa tan - qe va Zn", Lam két tia het hai kim 09; bang thus p dudi dang MeNH,PO,. Nung dén Kkhi duge khoj lang 0,6987g MesP20>. Tinh Ikhéi lvong ZnS c6 bong hin dem phan tich? (Me 14 Zn hay Cd). 16. Mot mau hop kim zirconium (Zr) cé lan mot ith 6, sng tinh chat HOA hoc véi nhau. Can 0,2000g mau, hoa tan va an xe sia bang acid mandelic (C(lg¢CHOHCOOHD. Nung tia ¢ nhiet Ichi Ing khong adi duge 0,1380¢ ZrO2 + HiOe ag thich hop dén piet ti lé ikhdi Luong HfO2 / ZrO, = 0,023. ie 0 ae 17, Chi thong qua két qua xdc dinh COp, ngudi ta tam két Juan mot mau hoa chat ¢6 thé 18 SrCO,nguyén chat. Tuy nhién sau khi tién hanh phan tich dinh tinh mét cach ky luGng, ngudi ta thay rang jon St" khong c6 mat ma thay vao dé 1a ion Ca2* va Ba®’*. Tinh % gua CaCOs Va BaCO, trong mau hoa chat ndi trén? 18, Phan tich mét dung dich chiét ra tif mot mau dat bang cdc PPPTKL, thu duge két qua nut sau: 7,59% CaO; 5,61% SOs; 2,20% MgO va 5,29% COp. Tir cdc s6 ligu tren, tinh % CaCOs, % MgCOs va % CaSO, trong mau dat khao sat? t khd tinh khiét chi cé thé 14 ZngP20- 0 (M = 458,1) nang 0,2000g duge Lay 25,00mi dd A dem tao tua (NH,)s (PO;.12Mo0Og) (M_ = 1876,3) va dem nung tia trén 6 nhiét dg ego dé chuyén thanh (P20s.24MoOs) (M = 3596,6). Khéi lugng dang can thu duge 1A 0,2950g. Cho biét mau hoa chat dem xde dinh 1a ZnzP207 hay Zng(PO«)2.4H20? b) Hay dé nghi mot PPPT khéi luong khée gidip xée dinh héa chat hon nhiéu so véi PP trén. can tim don gidn va nhanh chong 20, Hoa tan mot miu ‘dé voi chita Ikhoang 0,500g CaCO, réi 1am két tia Ca? bing dd HyC,0, 6 diéu kién thich hgp. Thé tich chung ctia dd lic tg0 tia xong 1a 100m, pH cia dd la 4,0 va [C.0,2"] = 0,010M. a) Tinh 36 mg Ca bi mat do tiia bj tan? b) Tia tao thanh duge loc va rua bing dd (NHy)C20; 0,050M. Tia duge ria § lin, méi lan dig 10,0m/ dd (NH,).C:0,. Tinh sé mg Ca bj mat do qua trinh rua tua? ¢) Tinh sai sé tuong ddi cia phép phan tie tia va rita tia gay nén? 15. dd co h hop a afnium (Hf) ¢6 19. a) Mot mau hoa cha (M = 304,7) hode Zn3(PO4)2-4 He hoa tan thanh 200ml (dd A). h do qua trinh tao Scanned with CamScannerhe phuang pHa? © oxy an “dua tre” ia nid of rie 1 den duge tint! , a thi ‘rong 4 hoan an va U bd qui at hoa tan thar id 0: tinh khiét (H2C20+ sh oom! dd nay ding ¢ an d g2,40ml dd KMn0x. ve ang ci 68 OETA rand /FeSO4? ang sit can nang 1,79508 duge hoa tan rol kh va pha chi nh xdc thanh 250,0ml dd phan tich. Bié KMnO, ¢ dd nay 44 duge chudn dé b T= ,001842g/ml. ‘Tinh % Fe trons quang? ] tinh khiét thanh 500m dd chuai 5, Hoa tan 0,24863 K,Cr07 Ydrs0, Hat 25,00ml 4d nays them mot lugng HCl va KI thich hyp roi chudn 4 bing 95,50ml dd NasS,03. Tinh néng a6 duon, Iugng cia dd NasS,0s va 6 chudn cia dd dé. 4 Mi le 6 FeCl; can nang 4,8900g duge hoa tan thanh 250ml id phan tich, 25,00ml dd nay duge chuén do bing 32,10ml de NayS.03 0,0923N tr a ‘ b ‘ong méi trud f a Sar Tinh % FeCl, trong m: a i truéng acid trung binh va co du KI. 5. Hoa tan 0,2136g mot mai NasC,0. tinh k 136g mot miu quing chia M . adv ahaa i Pi; moi truing H,SO. ne ae 0,40208 ay ra hoin toin, chun d6 lai lugne C.0.2- ‘au khi phan « 10,0000 Tey ee luong C,02- bE i phan uni €. Hinton 1864, ne ba ing 24,20m dd | et mi wang. ; dang Cr thank cone miu the ang KMn0,. Big IM réi chug a8 thue hi ig win a9 we hién haa ung #08) Mota TaN cay a aa ns MM shit beats ting gia = 35,28m, nO, na * sh) J 4 nay tn. Th Gr ne soe 100m dl i mAu thép? 2 ‘pe Scanned with CamScannerbc PI bai tgp uit 7+ 12 duoc tinh todn trén gid thiét cée phan Ca an toan va co tinh dén sai 86 chi thi trong qué trink ag xy 7 HO bud Fa : vin do 20,0ml ad Fe" 0,050N bing dd KMnO, 0,100N pit y tinh thé tich dd KMn0O, 0, 100N céin dung dé dat didn Wong Jong. os 7 p) Tinh sai § so chi thi va thé cua dd khi thém vao dd chudn do; gon; 10,00md va 10, 10ml KMnO, 0,100N. Cho BE? (MnO, /Mn*) = 1,51V; E° (Fe**/Fe**) = 0,77V va é diéu ian chuan dd, ngoai H* khong con cdu tit nado gay nhiéu cho hé phan ung. . Can 1,6057g mau KMn0O, va hoa tan thanh 500,0ml dd A. Dé hud d6 100,0ml dd Fe®* 0,100M pH 0, phai ding 100ml dd A via ha 6 trén. a) Tinh néng a@ duong lugng cla dd A va % KMn0Q, trong mau an dau (bd_qua-sai-sé-chudin 46). ‘nh sai s6 chudn d6 va thé cia dd tai diém cudi, biét ring trong ‘1 dd KMnO, da sit dung, ngudi ta da ding thira 040ml. ¢) Tinh % KMnO, thuc chia trong mau ban dau. . Chudin dé 50,0m/ dd Fe** 0,100M bing dd K,Cr,0; 0,050 6 pH =0. a) Tinh thé tich dd KyCr,O; 0,050M can ding dé dat diém tuong duong. b) Tinh sai sé chi thi khi dimg chat chi thi diphenylamine sulfonate ‘a (E° = 0,85V; n; = 2e) dé x4c dinh diém_cudi. Cho E? (Cr,0,"/Cr**)-=-1,88V; By (Fe®/Fe”*) = 0,77V va 6 diéu ién chudn dé, nee Ht 4 EO ‘6 su hién dién cua mot cdu tr iéu nao khac. Ywoy Crm E 0. Uhudn dé dd le vale dd Fem trong méi truéng Had = = 1M. neon ‘a) Tinh thé oxy héa chudn diéu kién cia cip Fe®*/ Fe’ va cap n''/Sn%*, cho bist: E(Fe™/Fe™) = 0,77V; E°(Sn**/Sn*) = 0,16V: - Fe bi nhigu béi Cl véi Bia = 10°? va B gue i ae bi nhigu béi CI’ véi Bia = 10°° n”* bi nhiéu bai CI” vdi Bra = 10°°! va Bie = 10°" 5 Tinh sai sé chi thi néu ding chudn dé khi dd chuyén mau 6 gid tri E, = 0,33V. Scanned with CamScannerML. CA 500,0mi dd (ddA), Dé chun dj 20,00ml : i dita trinh chudn a6, 04 vd b6 qua sai s6 chi thi trong ou mau KyCr,0) bi nhiem ban, hoa Gan thay dung dich A, can diy 8825e mot n 26,A0mi dd sulfat sit mbi 0,0100N. 6 chu’in d6, hay ie K.CrO- trong mau ban dau? tinh néng dé duong lugng, né; a) Bo que 4} mol cua dd A va © ’ 5 sd chuin do néu phiin ting trén duge thye hi trong moi trivng HSO, (pH_1) voi chat chi thi diphenylamj sulfonate Ba ( ),85V; 0, = 2c"). Cho EB? (Cr,0;° /Cr™) = 1,33 E(Fe"Fe"*) = 0,77V va 6 diéu kién chudn d, ngoai H” khong b) Tinh sa suf hién dién cua mot cau ti nhiéu nao Ihae. c) Tinh &% K,Cr,0; thue suf trong mau ban dau? 12, De xcic dinh ham lugng mot mau mudi Mohr [(NH,)2Fe(SO,)2.6 Hy eas) ‘¢ mau; hoa tan va dinh mde thanh 200m! dd. Chuan do Fe! 20.00n1/ dd néi tren véi chat chi thi ferroin (B®, = 1,06V; n; = 1 phai ding 13.501 dd Co(SO,), 0,0100M. a) Bo qua Sai sd chuan dé, hay tinh néng d6 duong lugng, nén, Sormol cog dda eee ae dd chuan dé va % ((NH,)2Fe(SO,)..6H2O] trong ma b) Tinh sai sé cua Brome) 98 bang chinh. phép chuan 6 néi trén, cho E*(Ce/Ce*) = 1 ae 7V va bé qua cdc can bing nhiéu bén : a canh ci Phuong phép chudn d6 dcid-baz © Cae bai tap tir é1 h todn dua t T ap tw I dén 8 duac ti i no ge tin) ré i \ hin ing sdy 0 ho N dua trén gic thiét ca T) 15,00ml dung dich 14 ojordom, 8 “ith HINO; 0,02008 duge chusin a6 bi don vi la se , f : eo don vi 14 s6 md da Naony .100N aan 0 chua cia , ‘ung dé chu Scanned with CamScannerphugnsP 1g dg cia mot dd NaOH, lay 10,00m1 dd dd pha loang . ; gooml dd A; tiép theo lay 10,00ml dd A pha thanh’50,00m/ tanh chuiin dp 10,00m/ dd B bing 12,5m! dd HCI 0,0500N. Tinh a 7 ‘6 duong lugng va néng a6 khéi lugng cia dd NaOH dam dac n6ne i theo két qua ghi nhan duge, gia sit mau NaOH hoan toan carbonat héa. an bao nhiéu gam dd KOH ¢6 d = 1,41ghnl (40% KL/KL) 4, Phai ¢ F ~ a 5 dem chudn dg bang dd HCl 0,2N, néu muén khéng ché lugng acid HC] ean dang xép xi 20ml? Aetluws 5, pé chun do Iai 1 dd HINO, 06 T = 140g/mt (ly thuyét) vita pha, madi ta Ky 50,00m1 dd néi trén pha loang thanh 1000nt dd lodng. ay 20,00m! dd KOH ¢6 46 chuiin chinh xte T (KOH/H,S0,) = 0.01904g/n! vato erlen, ngudi ta phiii sti dung 26,88m dd HNO, loang vita pha dé trung hoa hotn toin KOH. Tinh % HINOs e6 trong dd acid 5, Biah noni ban da renong Dt ban dau? 6. Chufin do 25,00m/ mot dd X chita HsPO, va NaH,PO, bang dd NaOH 0,0500M. Luong NaOH da ding dé chudin do dd X bang chi esol luc 1a 20,00ml va sau khi thém chi thi phenol phtalein, p g 28,00m! NaOH nits. Hay xéc dinh néng 46 mol cia cae chit trong dung dich X. 7, Mat miu NaOH can nang 0,9184 duge pha loang thanh 250ml dung: dich, dem chuiin dg bang dd HCI 0,1042N. Biét rang: - Néu ding chi thi phenol phtalein: — V(HC1) = 20,70! - Néu ding chi thi metyl da cam: WHI) = 21,48ml ¢ thanh phan trong mau NaOH, biét thé thi bromos Xée dinh ham lugng c4 tich mau dem chudin dé 1a 25,00m!. 8.6 dung djch sau day chtfa 1 hay 2 trong sf ede chat NaOH, NaHCO,,.Na,COg, Biét ring 100m/ dd mau da duge chudn dé bing dd HC) 0,100N vai 2 chat chi thi 1a phenol phtalein va metyl da cam. Thé tich dd acid cén dé chudin do dén khi chi thj ldn lugt doi miu (phenol phtalein d6i mau trudc) 1a: a) 27,30ml va 30,70ml; b) 0,0mi va 18,10m! ©} 460ml va 12,20ml; 4) 27,10ml va 27,10m! ©) 15,10ml va 30,20ml; f) 15,60ml va 48,10ml “ Xae dinh cde chat hién dign trong ting dd va néng d6 khdi lung cua cde chit dé. Scanned with CamScannerpron gid thd 28 14 duge tink tongs - 66,chi_thi t an va bnon-b? ” Lor Cae bai tap te 9 dén an ung xdy TO hoan to! qua trinh chudn do. . bude hay-pH ( 07 9. Tinh khoang bang dd Na g nang. By Ms a)1M_ »b) 01M oot! a cp.cOOH 10, Tinh sai 56 chi thi Bo aa xt chi thi /@ © NaOH 0,1M néu pT cia chat chi Sooke il. can 0.5008 da HF vA P i aOH 0,100. ng 10,00ml dd trén. phai : aiém ieee a a) Tinh pH cba ad chudl 9 ai “\ p) Tinh % % HF trong mau ban dau theo két qua chuan do. ¢) Tinh sai <6 chun 46 néu ngudi ta da ding chat chi thi pT = 8,2 dé xde dinh diém cudi. ; 42, Dé xée dinh lai néng 46 cua mot mau NH,OH, ngudi ta 0,8235¢ mau va pha thanh 900,0ml dd. Chuan 46 10,00ml dd phai ding 16, A5ml dd HCl 0, 050N. - - % a) Tinh pH cia dd chudn d9 tai diém tuong duong va % NI trong mau ban dau? ) Tinh sai s6 chi thi va % NH,OH (thye) chifa trong mau lsdu, néu két qua chudin d9 trén-duge x4c dinh bing chi thi m a6 (pT = 4,2). 13. Can 0,4070g CH,COONa va héa tan thanh 200,0ml dd. Chi 49 20,00ml dd am vita pha, phai ding 4,77ml dd HCl 0,100M. : ‘nh % CH;COONa trong mau ban dau? ) Tinh sai sé chi thi kl hi chua, E ne i wan dé 20. _ voi chet chi thi metyl da cam Halwa Aetes a i ung dich chuyén tit vang sang cam (pT = 3 ae hes 75) chuan 46 mot dd ang hdp sau: pha - Dung dich chu én tit vang san, g héng ( pT = 3,10). 14. Muén ta ae ang eu dinh lugng khi chudn d6 gp chat mnnitol dé c6 nine ae dd H3BOs, ig d6 1M trong dd. | a) Néu dix 46, tinh pH dd NaOH 0, tinh pHy ciia dd? ,1M dé chudn a6 9 dd HBO; cin g 8 b) Tink gai i “nt sai sé chi thi inh digm eugin St RE Khi ding chat chi th ‘ i thi co pT = 9.4! Scanned with CamScannertich (phugng ap chudn d6 60 tia 1 dén & duge tink fn toan va va 66 qua sai 36 cht thi trong qué todn dia trén gid thiét cde sacl va NaNO, edn nang 0,8180g duge hda tan thanh a, 20,00ml dd nay duge chudn d@ theo phuong phdp smi dd AgNO; ¢6 T (AgNO/KCI) = 0,003442g/ml. aC] trong mau? zg mot hgp kim chia 84% Ag da can, biét rang nay da duge hoa tan thanh 200,0ml dd phan tich va ga nay duge chudn 6 truc tiép bang dung 25,00ml dd ju KBr nang 0,3038g duge hda tan bling nude cat réi chudn g0ml dd AgNOs c6 T (AgNOs/CI) = 0,003546g/ml. Tinh 6 khiét cla mau KBr? "cin 3,0360¢ méu KCI pha thanh 500,0ml dd mau, 25,00m! dd 23y dupe thém vao 50,00ml dd AgNO, 0,847. Luong AgNO; thita Jiuce chun 46 bing 20,68 ml dd NHSCN ¢6 T(NH,SCN/Ag) = 01165g/m/. Tinh ham lwgng % KCl trong mau? 5. Hoa tan m(g) NH,Cl tinh Kkhiét thanh 200,0ml dd mau. 20,00m/ nay duge cho tée dung v6i 40,00ml dd AgNOs 0,050N. Luong AgNO; thita duse chudn dé bang 12,50m! dd NH,SCN_0,100N. ‘inh lugng m(g) mau da can? , Céc bai tap tit 6 dén 10 duge tinh todn dua trén gid thiét cde hin wing xy ra hoan todn, b3_qua_ede can bing nhiéu nhung chudn dé. ic dinh ham lugng NaCl thong b6 qua sai s6-ehi-thi trong qué trinh . Phusng phap Mohr duge sit dung dé xa Tong mot mau mudi an. Hoa tan 0,5318g mau thanh 100,0m/ déA}; 20,00ml dd A duge pha loang thanh 250,0ml (dB). Lay ae Eng 3,50ml dd AgNOs 0,0200N véi Scanned with CamScannera) tinh % NaCl trong mau mudi ban atu? cel ant didn al b) ‘Ninh sai sé chudin do, nda ndng do [CrOe TH ) sni s oe 1Cl 01M. La hom 25,00ml da AgNO, 0,1 vito a chi ini tl fc in do bang dd NEH\SCN 0, ‘ . al thita AgNO, duise chuiin dg bing dd eet ait wdi nbng dot ‘ Ai ding thita 0,09, ding, mudin nhin duige sy chuyén mau elia dd phai dt dd NHSON 0,1M. , ( 3 i 1 AgNO; 0,07, 8. Chuan d6 100,0md dd NH,SCN 0,0375N bing dd Ag ae \ at chi thi. Diés Oi duge xac dinh tu va ding K,CrO, lam chat chi thi. Diém cu ee i ung véi th dd c6 [CrO,*}; = 2.10°M. Tinh sai sé chi tl iy phép chuiin d6 noi trén va thé tich dd AgNO; 0,075N da ding diém cudi. ~ inh sai sd chudn dd, phon s 9. Can 0,6870g KI, hda tan thanh 200,0ml dd (ddA). Chudn 40,00ml dd A bing phuong phap Mohr, phai ding 19,35m AgNO; 0,040. a) B6 qua sai sé chudn 46, hay tinh néng 49 mol, né luong cia dd A va % KI trong mau ban dau? b) Viét can bang chudn 6 va can by 46 néu ding chi thj Sai sd chu: ae K,Cr0, 06 [CrO?), = 10-44¢ va diing chudn ‘a xuat hién tig Ag.CrO, (lugng +2 os Ong tua Ag,Cro, dang ké), Tinh % KI thue 06 trong mau ee Me 10. Can 1 0000g mau LiBr va : 7 T va hoa tan th, ; i dé 25,00mi dd tran can dang 14 75m m om nad K.Cro,. _ dd AgNO, 9,060 vei chi ¢ Scanned with CamScannerthé Lich (phuong phay ch Jin tich nis phar phan tich phvione Po phap chudn dé tao phite pai tap tt 1 +4 duoc tinh todn dua trén gid thiét ede hoan toan va bd qua sai 86 chi thi trong qua trinh prions Cac an ung xay 1O yh Pain 16 chudtt 1. can 1, 32508 30, that tinh khiét, hda tan thanh 250ml dd - té dinh lai néng do dd EDTA. Biét ring 26,47ml dd cau iy da duge ding a6 chudin db 25,00ml dd Ca” & diéu kién 1 hop. Tinh T (EDTA/Ca)? 9, Hoa tan 0,3000g mot mau khodng cé chtfa FeO; va Al,O; thanh 950,0ml dd. Chuan 46 25,00mi dd c6 chia Fe** va Al* 6 pH 2 véi chi thi la acid salicylic, ding 2,50ml dd EDTA 0,0100M. Thém 20,00ml dd EDTA. Bun sdi dd, chudn dé lugng EDTA thita 6 pH 5 bang 4,90ml dd chudn Zn** 0,0100M vai chi thi xylenol da cam. E thich a) Tinh néng d9 mol cia dd Fe* va Al* trong dd chudn 49. b) Tinh % FesO3 va Al,O3 trong mau ban dau. 3, Mot mau khodng chia chr yéu CaCOs va MgCO, can nding 0,2258¢ due hda tan thanh 100,0ml dd. Lay 10,00m/ dd trén dem pha Joang thanh 50,00m/ réi.méi Jay 10,00ml dd loang dem chudn d6 6 pH 12,5, phai dang 3,20md EDTA 0,0100M. Thyc hién mét thi nghiém khée cing trén 10,00ml dd loang nhung chudén 46 6 pH 10, phai ding 4,35ml dd EDTA 0,0100M. Tinh % CaCOs va % MgCO; trong mau ban déu. 4. Can 2,0250g mau dolomite (chtta chi yéu CaO, MgO va CO,) pha thanh 500,0md dd phan tich. Biét ring 25,00mi dd nay da duge chuan dé bing 20,20ml dd EDTA 0,1025M 6 méi trugng pH 10. Dang 100,0mi dd mau loai bé Ca 6 dang tia, dd qua loc duge chudin d9 bing 38,50md EDTA 0,1025M & méi trudng pH 10. Tinh % CaO va % MgO trong mau? Cac bai tap tix 5 dén 8 duge tinh todn dua trén gid thiét cdc Phin ting xdy ra hoan toan va khong b6 qua sai sO chi thi trong Qua trinh chudn dé. = 5. Dang dd EDTA 0,0100M chuin 46 50,00m! dd Cu” 0,0120M 6 PH 6 va dinh diém cuéi bang chi thi thich hgp. Scanned with CamScannerChun, n, néu tai dig y 32 j tré in d6 noi Sai sé chi thi cia phép cha” . ae diém on pee taney 20,09, ng 20,00ml ED, a) Tinh Cui PCur = 19,9, 4 ») Tinh thé tieh EDTA 0.010001 da 0,0 thanh 250, A 6 Can 0.38799 MnS0, va hoa tan 7 10, phai a trén dem chudn 6 tao phite ¢ pH 4” 0,0100a2. id chu 2 trong 4 4) Tinh néng do mol cia Mn trong ‘use. du ban dau theo s6 ligu ghi nha m dung chudn dd dq j OH vdi Bi, = Lys, dn do va % Mngy 1 trong m. ae b) Tinh sai so chi thj néu tai ee bdi pMn®, = 6,0. Cho Bay? = 10°; Mn” bi nhie Bia = 1083. «yy 10-24 bling dd chudin EDny 7 Chuan dé mot dung dich kin, logi a , ‘hi (ain = 1. Tinh ig cing néng do 6 pH 5 va ee “ ' un IY") = 10% 4 | 86 chi thi trong phép chudn do nay?’Cho biet B ® Tva B (ting i thi ¢6 céng thie tong quat HoInd vdi ph ° e » bang chudn dy of 16.10". O pH 5, OH” khéng gay nhiéu Jén car Ov 0,4326g duoc hda tan thanh 200,04 ne 200,0m/ (ddB). Lay 20, 00m OM & pH 12,5. edn bang chi thi, 8. Mot mau dé voi can na (ddA). Lay 20,00m/ dd A pha } loang th dd B dem chudn d6 bang 4 ** cia dd B va % CaCO5 t a) Tinh néng 5 mol Ca? Scanned a CamScannerChuong 8 BAI TAP ON TAP Mat dung djch chua 0,4166g BaCl, trong 200ml (dd A). * ) Tinh ong do mol, nong do duong lugng va néng dd khdi ugng (gil) cia BaClz trong dung dich A? p) Tinh khéi lugng AgNO; ran/thé tich dd AgNOs 0,100M duge dung dé Jam két tua ion Cl trong dd A, biét ring lugng AgNO, duge dang thifa 20% so vdi lugng ly thuyét. Tinh khéi lugng két tia AgC] thu duge néu AgCl duge xem nhv tao thanh hoan toadn, ¢) Tinh khoi lugng Al,(SO,)3.18H2O cin ding dé phan tg via Idd voi ion Ba”* trong 200ml dd A? Tinh khéi lugng két tha BaSO, thu duge néu xem phan ting tao tua 1a hoan toan? 2. a) Can bing va tinh duong lugng gam cia NH, trong cic phan ting: Ag’ + NHg = [Ag(NH,)]" q@) Ag’ + NHs = [Ag(NHa)2]" (2) b) Thém NH vio dd chifa ion Ag’ vdi [Ag'lo = 107M cho dén khi pH cia dd c6 gia tri bing 11. Tinh néng do NHa trong dd 6 thdi diém can bang va néng d6 Ag’ con lai trong dd sau khi tao phttc vdi NHy va OH". Cho biét lugng NHz thém vao khong lam thay déi thé tich dd ding ké vA pH eda dung dich xem nhu duge quyét dinh chi yéu béi lugng NHg ty do. ©) Sue Ikhi NHg qua tia AgCl. Néu sau khi sue Ikhi (NF) = hay tinh tich sé tan diéu kién, do tan diéu kién cla AgCl trong hai truing hop bé qua va khong bé qua anh hudng cla OH? 3.a) Tinh hang sé phan ly acid cda Ag’, biét AgOH 06 he ») Tinh pH ca dd NaCN 10°M ©) Khi hoa tan ta AgCN vao nude 6 2! hon hay nhé hon 7? Trong qué trinh tinh ton néu lay pH = 7 e6 bj sai 80 ding ké hay khong? 0,1M = 1077? 5°C, dd sé cé pH Ién hon Scanned with CamScannerfe (lay pH © ) Tinh dé tan cia AgCNY trong nude cy P. ; Na e) Tinh a6 tan cia AgCNY trong a aiéu 6? 4 ding ON" a chun ad Ag’ nén lI AEN aa tg 4. BE xée dinh ham lugng cia mot aaa i 2,6460g méu va hda tan thanh 250,0” ray 02 can ding a " a) Tinh thé tfeh dung dich DMG (CaN eich A (tong a) Tinl : 32+ chia trong 20,00! a i o trong mil ta hoan toan Ni” chia t Me a % Nile 6H OF 80M ae ali thu duige 18 0,24398. duge ding thita 5% \ iia Ni(CsNoO2H} dau, biét khoi lugng tua Ni(C,N2O2Hr)2 an a bing 21,10ml en ban d4u va so sanh két ¢ chu b) Ni trong 10,00m/ dd A duge ‘i O trong mau énh 200M. Tinh % NiCl,.6Hs a . 3 cau ae véi két qua xdc dinh bing PP phan tich khéi lugng ). a éi her = 10 5. a) Tinh pH cia dd acid glutaminie (ky hiéu HeA vdi ker hag = 107°) 0,180. ns b) Tinh néng dé cia cdc cau tit trong dd 6 théi diém can bing ©) Chuan d6 20,00m! dd HpA néi trén bing dd NaOH 0,200 Tinh thé tich ca dd NaOH can dig tai c4c diém tuong duong sai si chuéin 46 tai diém cuéi thi nhat néu ding bromothymol xaj (pT = 7,6) lam chat chi thi. 8. Hoa tan 2,449de acid benzoic C5HsCOOH (ka = 107471) tha 500,0m dd phan ‘tich (ddPT) dn 46 manage cl ). Chudn 6 20,00mi daPpT bang se lin ; & Rong a 0 Vag 20,0 aP chat va iA me tie gy mnie NEG rg nae 4d a5 mae ee nuéc thai Or bng ty ¥80 20 i dd pha ct Mong NaOH 00, i 90m ag N ml dq Hq] 200" Luong NH; 26 — 50H 0,9 WN. 1200, Chug, = youl m. scanned ath Comeeannerbai jp on Lop 46 1 che chn ban trong, qu 4 tink phi " Phan tich ma in do tren IA cach chun ag a ae b) Tink % NHACI trong mau rin ban dju i yen va cho biét do Cl bing Ag’ bang phuang H a) Tinh tich 86 tan diéu kién va do tan didu kié Agl é f éu kién eda AgC a (NHz] = 0,1M. ‘fen nt phap Mohr “rong moi truang b) Xac dinh néng do NH, t6i da cho phép hién dién trong dd dé qué trinh chudn do Cl bing Ag’ cén 6 tinh dinh lugng? Cho biét kién dé, OH” khong gay nhiéu lén Ag* va NH, chi tao véi hanh phi c6 86 ligand ldn nhét. Xée dinh pH cia dd é diéu 6G die Ag’ t kién dé. ¢) Chudin do dd Cl 0,050M bing dd Ag’ 0,050M trong méi truong 6 (NH;} = 5,75.10°M. Tinh sai 86 chudn do néu sit dung KzCrO, lam chi thi, biét diém cudi duge x4c dinh véi néng do [CrO,*] trong dd Ia 10M? 4) Tinh % KCl trong mot mau héa chat, biét ngudi ta da can 0,3145g mau va hoa tan thanh 100,0ml (dd A). Dé chudn dé 10,00ml dd A, phai ding 7,65ml dd Ag’ 0,050M. O (M = 138,9) va hda tan thanh 100,0ml An dé truc tiép ion Br trong 9, Can 0,5860g NaBr.2He! (ddPT), Dang dd AgNOs 0,950N dé chu ddPT ¥6i chi thi KyCrO.- 4) Tinh néng 4) mol eda Br’ t ban d4u, biét thé tich dd AgNOs 10,00ml ddPT 1a 800ml. b) Tinh sai #6 chi thj néu ding 6) inh ndng a9 (CrO42-] thich hap aé sai 8 46 bling khong? rong ddPT va % NaBr trong miu 0,050N edn ding 46 chufin dp chin dp & thei diém 06 pAg'r= 422 6 oda qué trinh chudin 10, 4) Thém CHCOONa vao dd chtia ion Cu” cho dén a a dd 66 gid tri bing 9,6. Tinh nbn6 a ion CHyCOO™ va néng dg Cu! trong dd & thai diém ean bing néu xem CH,COONa phan y hoan loan va pH eda dd quyé ajnh chit yéu bdi lugng CH;COO™ ty do. Scanned with CamScanneroO ' -, va lugng Sho [Cup = 10M, og, = acu ichigcoo",on”) them vao lam thay déi thé tieh dd khong ding —_ an ca" tll b) Ching minh ring cé thé ding EDTA dé aE dung dich 6 [CH3COO"] = 0,17. dé chudna - Tinh sai s6 chuéin 49 Ichi dng dd EDTA 0,0100M dé ch ag dd Cu’* 0,0100M trong su hién dién cia CHsCOO™ 0,17M néu a chi thi c6 §'(Culnd) = 10% dé xde dinh diém cudi? ‘a “Tinh % CuSO,,5H,0 trong mau, biét ring ngudi ta da can 0,523 mau va hda tan th’nh 200,0ml dd. Dé chudn d6 10,00ml dd tra phai sir dung 9,30ml dd EDTA 0,0100M. } 11. Ding 20,00mi dd Co™ 0,050N dé xde dinh néng dé ctia dd Fe? a) Tinh hing sé can bang cia phan ting va thé cia dd tai dié, tugng duong? b) Tinh sai so chudn do, néu Co** dung chat chi thi c6 E°, duge chtta trong erlen va si = 1,60V; n; 2c" dé xéc dinh diém cusi? Scanned with CamScannerChuong 9 PHO NGUYEN TU 1, Giai thich vi sao phuong phap quang phé hap thu nguyén tut ¢6 do chinh xde va do nhay cao hon nhiéu so véi phuong phap quang phé phat xa nguyen ti? 2, Phan tich ham lugng Cr trong mau hgp kim bing cach do do den S ap vach dong dng (ic, = 292,216nm va fre = 279,388nm) trong cua phé cua 3 etalon va cia miu khdo sat, thu duge bang so ligu sau: ; tidy chuan Tham sé Mau khao sat C G Cs cr(%) 1,44 3.16 6.31 2 2 So 0.39 0.58 081 0.67 0.65 Sre 0.22 0.24 0.23 0.22 0.24 "Tinh % Cr trong mau hgp kim. 3. Dinh ham lugng indium trong mau bing phuong phap quang phé phat xa ngon lita. Bang gid tri cia dudng chuan nhu sau: Ci (ppm) 0 20 40 60 80 92,4 |__Pepnatxat 0 23.4 46.3 69,3 a) Do dé phat xa cia dd mau duge gid tri In = 30,5. Tinh ham lugng In trong mau theo den vi ppm? ») Thém vao mau (gitf thé tich dd khong thay déi dang ké) mot lugng In sao cho néng 46 In chudn trong dd mau 1a Cc = 40ppm, do duge do phét-xa 1’, = 72,5, ‘Tinh ham lugng In trong mau theo don vi ppm? 4. Dé xde dinh ham lugng chi trong mau méu, ngudi ta lam déng ty vitae trong 10,00m! mau bang acid trichloroacetic. Sau khi ly male da ben trén duge dua vé pH 3 va ding APDC (Amoni Sg ay eithaearbemate dé tao phic chi hitu cg. Sau dé, ding BK (Metyl IsoButyl Ketone) chiét phtic chi hitu co ndi — Scanned with CamScannerOng kém vei may trdn Orang maul ; gS chita mot | 4 7 Rider ME Mu ob inh pore “UE FEE len CaO, gy hi hay Khong? Néy ia, : Ung dén key Qua dinh su dung phuong ph "Dg phy Php gy, ; nk lugng } Nang phé i. BPG hap ¢ Tubng hap nao sg 1 hon ee peat xa thy anh hiding P “ et eg nay tro ch kha phue 38 Chuong 2. ba PP quang p trén va dem xdc dinh ham lugng Pb trong mau bang : : Au 1a 0,388 & hap thu nguyén ti ngon lita. Dé hap thu A cia dd ma = 283,3nm. Si dung 3 dd chudn cé ham lugng = 7" A 0,100 va 0,150ppm do duge do hap thu A tuong ung 18 a va 0,748. Tinh ham lugng Pb trong miu miu theo don vi pp! 5. Dé xdc dinh ham lvgng Na,O trong mau xi mang, nguii we h tan 0,1000g mau thanh 50,0m/ dd do. lon Na‘ trong dd duge dinh bing phuong phap quang pho hap thu nguyén ty ngon hia. ot 1A 0,05 a) Tinh thé tich dd chudn Na’ lg cdn dang dé ph 100,0ml dd chudn c6 néng dé Na’ lin lugt 1a 1, 2, 3 va 4p tha b) Tinh % Na,O trong mau ban ddu néu hap thu cda loat dd chudn va cde dd m gid tri phan tram dudi day: du duge tom tat trang ba: Dung dich chuin Scanned with CamScanner10 chuong PHO TU NGOAI - KHA KIEN (PHO KICH THICH ELECTRON) Phuong phap quang pho hdp thu tt ngogi 5) Cae hyp chat CH,-Cl, CHs-Br va CHy-I c6 cite mai hap thu 6 ie dp dai song 173; 204 va 259nm. Cho biét cae mai héip thu trén ling voi cde sig chuyén mite nao va xde dinh dg dai séng hap thu adi voi timg hgp chat. 2, gp chait X hap thu btfe xa Apo = 305nn trong dung méi hexane wi hiip thu bie xa Ama = 307m trong dung moi etanol. Mai hap thu cua hgp chat X ung vdi su chuyén mtfe nao? Gidi thich. 3)Trong dung mdi 1a nude, aniline hap thu bude séng 280nm vdi = 1430 mol .cem™ tt. Néu muén pha ché 100m! dd aniline c6 a6 truyén sudt 30% déi vdi bue xq trén thi phai phai can bao nhiéu 1g aniline nguyén chat (ding chau do e6 b = lem). £)20,00m! dd quinine duge pha long thanh 50,0m!. Bo do hap thu in dd loaing & max = 348nm duge gid tri A = 0,316 (str dung cuvet c6 b= 1m). Pike Chu = Lay 20,00m/ dd quinine khée them vao 10,00m/ dd quinine 25ppm, dua dén thé tich 500m! rdi cing dem do do hap thu cla dd vita pha (sit dung euvet e6 b = lem), duge gid tri A = 0,610. Tinh nong 9 ppm cia quinine trong mau ban dau. Phuong phap quang phé hdp thu thay duge 1. Dinh lugng Fe® trong nuée bang phyong phap £° ™% KSCN, mai trudng HNO», pH 1+2. Phite tgo thanh cé mau thu 6 2 = 480nm véi € = 6.300molt.cm™ I. : ‘ a) Tinh khoang néng d@ mol thich hgp cho loat dd chuan & nel ding may do cho sai s6 cha’p nhan duge kht ‘A nam trong khodng 0,2+0,8 vA may do c6 A < 3,0 (chau do 6 b = lem). au, thudée thir dé, hap Scanned with CamScannerne ypanb nie " do; tao vd do Cu = 9.10°M. Tinh } cua nv ppm? -. can 5,0008 mau va " , “nue ¥6i eS i ton ine sind 2% qugc tao Po CCl, vor! ih Hi gh. Cu A ai nd eo gc chudn bi tuong dic! an Ba 20, 00m. Do dé 0 , y zi ané veh dT = Jom, ket qua A pia 10% ag k= odonm V du? | (Qo mi Te chudn va mau : a lugng Cu (ppm) trong n ‘ § fe Ay = 0,225. Tink ham IM g bing phuong phap So mai 0,35: a k An, ‘TiO, trong mau kod Ara ‘ ena, SiO», AlzOs, Fes va i{* va trong méj Miu gém 70 “HCL, Tid, tan thanh dang Ti : duge hoa tan . ang H:S0, manh, Tit tgo phise voi Hz02 tanh dane phite " TOUEO,¥*, hp thu 6 410nm véi € = 720mol om . i 4 a) Cho biét anh hung cia Si0,, Al,Os, Fe,03 én dd do biét cdch loai cde anh hudng, néu c6? at 66 oxit kim loai khi 5, Dinh wong gt $0 oxit i b) Néu muén xéc dinh TiO, khi ham lugng cia né chia trong mau chia khoang 0,5%; phai can lugng mau 1a bao nhiéu dé héa tan thanh 100,0m/ dd méu. Lay 25,00md dd mdu tao phic thanh 50,0ml dd do; ding chgu do b = dem vA sit dung may do cho A hich hgp trong khoding 0,2 + 0,89 hh lugng Cr trong mau hop kim bang PP so sdnh: id mau: hoa tan 0,509, . /g mau ya 6, 4 C107") pha thanh 250,01 ad de doh fe Ge thanh Cr + dd chugn: : lige An = 0,250, 0,20 ; Raat 5,00ml dd A 8 KaCr055 hoa 0 tan thanh ha thanh 50,0 me tong mia yp at 900% 6 do do ane (Binh tuong ci tron 5) inh tu uh thu thay duge voi thus hi arn bn Po 9 thir ay fe 09 Pha ~ din agen rsenazo (hit 66 uP P quang ®* (dang ml ddA; lay c= 0,490. Tinh % Phé hap L 1000007 te ~ hie thank 50,0md dd do, co Aan emt ks dango + dd chudn: 1g 9 68 An = 0,49 % ding 5,00mz7 ¢, chun: lay 5,00 dd Pb* 39-3 i dd do; ¢6 Ac = 0,50, Ti "20 phute tha 1 PO ong mi op king 200,007 Scanned with CamScannerphd. tt ngoai- kha kién (phé kich thich electron) . Tt g. Dinh lugng crome trong mau rin chtta Cr dan, : ace (if = 400,15). Oxy héa Cr™ thanh Cr.07 bing | en a 91,0 vai do 69 hiip thu 6 % = 455nm voi = 1800mol"en a dd §, fs i a) Néu ham lugng Cr(NOs)s.9120 khoding 1%, tinh gidi han eta lugng médu 6 thé cin dé sau Kkhi hoa tan thanh 100,0ml m&u; le 50,00m dd dem oxy héa thanh 100,0mJ dd do? Biét may ch vd han vige véi A < 3,0; chu do 06 b = dem. te b) Néu ding 1,000g méu, pha nhu trén do duge Ay, = 0,35; 1,00m! aa chuiin KsCr20; 0,0100M pha thanh 100,0ml da do; 06 Ac = 0,72. Tinh % Cr(NOs)3.9H,0 trong mau? 7. Dinh lugng Ni?* bing cdch do d@ hap thu 6 dang phite NiX, voi X la NTA (acid nitrolo triacetic). Tinh khoang pH thich hgp tao phic khi dang X véi lugng thie [X’] = [X], = 0,01M. Biét phute 11,2; lgBe = 4,6; gid tri lg o X(H) theo pH duge cho & NiX ¢6 IgBi = bang sau: pH 1 2 3 35 4 5 6 Igax(H) | 114 10,7 7.0 63 58 48 3.8 8, Phite chat gitta Cu va EDTA cé thé tgo ra theo cdc dang CuY, CuYH, CuYOH. a) Cho biét cdc can bang téng quat b) Tinh Bt (CuY) 6 pH 5? c) Dinh wong oe He phuong phap so mau, dang phe cuv®, tinh Khoang pH thich hgp (trong khong pH ti 2 dén 6) dé tao phite CuY”, bigt (YP = [¥"], = 0,001M; JeBon: = 35 IeBowon = 26. ; 9. Dinh lugng Fe trong mau khodng bang phuong phap so mau. Mi duge hoa tan bing PP thich hop, edu tt xée dinh aye ees dang Fe va duge tgo phie bling anion a le ating (CiaHaNe) - ky higu L - voi (1 = (Lhe = 10M Ee erate Abi 6 i [A = tao trong méi trugng dem acetat voi [Ale snes F F eB. tao véi Fe tha hong mau FeA, Fels, FeAs ( 2 i ie. eae oe pai H’ vi HA Ia acid yeu = 3,2; IgBi2 = 6,1; lgBis = 9°" (lug = 108), Ngoai va, HL 06 Phe xay ra trong dd tao phttc? ‘Ar bj nhidu 249. Scanned with CamScanner} Chuting ly 42 SS a) Cho biét moi can bang xdy ra trong dd tao phitc? Tinh Bry, trong khodng pH 3+7. Chon pH thich hap tao phi (.b) Ngudi ta edn 8,000 mau réin va hoa tan thanh 100,0md 4 mau; ding 20,00m dd tao phic pha thanh 50,0ml dd do. Dung dich chuaén duge pha trong binh dinh mie 50,0ml tt dd Fox dn va mE G v1 pan fa da mau 0,001M. Sé liéu pha ché, tri sé do cia day chuan va Auge tém tat trong bang sau: Dung dich chugn cdma C c, @ |} oa fla Ce, = My N Thé tich dd Fe 0,001m 00 | 1,00 | 2,00 | 3,00 | 4,00 5,00 f Le D6 hap thu a 9,000 | 0,221 | 0,432 | 0,653 0,875 | 1,092 0,005 | 0,543 MY Co: trang chuan (thye hign ging nh chuan nhung khéng cha Fe**chudn)- Mo: trang mAu (thyc hién giéng nhu mau nhung khéng chita mau). Tinh luong Fe (ppm) trong mau? 10. Dang ligand L tao phic véi ion M™* theo can bang: M42 y=» MLy Ngudi ta pha va do 46 hap thu cia hai dd chita trong hai chau do c6 bé day gidng nhau & cling gid tri Annoy: . “dd thir nhat gém Mt 9.50.10-9 ya L 5,60.10°M; do duge Ai = 0,640, - dd thit hai gdm M"* 2,50.10°M va L 5,76.10°M; do duge As = 0,480, Hay xéc dinh hang s6 bén cia Phtic ML», biét rang ML, duge tao thanh hoan toan khi L thia it nhat 10 lan so voi M"* va trong diéu kién tao ‘phiic, khong c6 can bang nhiéu nao gay anh huéng Jén can bing chinh.PHAN II LOI GIAI VA DAP SO Scanned with CamScannerChuong 1 DAI CUGNG VE HOA PHAN TicH a) PP da duge su dung dé hda tan mau 1a PP khé. p) Tén goi cua PP da duge sir dung dé dinh lugng: Al,05, Fe2O3, CaO, MgO va TiO, - Theo ban chat cua PP: dinh lugng Al,O3, CaO va MgO theo PP héa hoc; dinh lugng Fe203 va TiO, theo PP héa ly. - Theo ky thuat PT: PPPT ban vi lugng. - Theo ham lugng chat khdo sat: PT AlOs, Fe,03, CaO, MgO theo PPPT lugng ldn va PT TiO theo PPPT lugng nhé. Scanned with CamScanneri — oa «len THUG wHAc Lal MoT ne ‘icH CAN & 0 HOA vac dink trong biéu thite Can bang cae phan wing va" “ac Be i ait ac! auong tong D = u iia ote eat 60 8 + 2H, 1 HS 7 2NaQH Na,S 2 nee net 2 SO, * 2NaOH Na,SO3 + HO nad net 1 3. nul + NaQH | NHg NaCl + HO” net net q 4 + aNaoH —— Fe(OH, * 3NaCl 3. + 4Na0QkH — Na,zZnO, + NaCl + 2H,0 6. + Ca(OH), —~ CaHPO, + 2H,0 ne? i a . 2HCclL oo net FeCl, + H,0 8 . onc! 2HCl =o H ow 8 + FeCl, 9 Lo NH,OH — bp A 10, mei IAG(NH,),IC1 + H,0 * gon 11, n= 413 [Cu(CN),}°- B Cane 6CN- ne13 [Fe(Cn),]*~ f Scanned with CamScanner20. 21. 22. 23. Dae bai tap vé néng dé dung dich cho héa phan (ich = tb 3zn 4H,SO, —~ 3ZnSQ, + S$ + 4H,0 a n=6 . aan + SHSQ, 4ZnSO, + HS + 4HO 22 n=8 . azn * 10HNO, —~ 4Zn(NO,). + NH,NO, + 3H,0 nee ne ‘ PbO, 4HCl —~ PbCl, + Cl + 2H0 nz2 n= so, + 2HS — 38 + 2H,0 n=2 360, + K,Cr,O, + HSO, —> Cr(SO,), + KO, + H,0 n=2 n=6 2kMnO, + 5H,O, + 3H,S0, —~ 2MnSO, + 50,+ K,SO,+ 8H,O nsS n=2 . PbO, + HO, + 2CH,COOH —~ Pb(CH;COO), + O, * 2H,0 n=2 n=2 As,S, + 14H,O, +120H” —~ 2AsO;7 + —3S0{" + 20H,0 n=28 n=2 4 Fe(SO,); + 2K —- 2FeSO, + L + K,SO, n=2 n= 5CH,CHO + 2KMnO, + 3H,SO,— 5CH,COOH + 2MnSO.+ K,SO,+3H,0 nee n=8 3C,H.OH + K,Cr20, + 4H,SO,— 8CH.CHO * Cr,(SO,)s* K,SO.47H20 n=2 n=6 . m _ 100. _ 99,09 mi L. Thé tich eda 100g dd NaOH: V = a7 iio 100g dd tite (emt = 90,09ml) dd chita 10g NaOH 3 lit = 3000ml dd > — Xe — ” _ 10 x 3000. 333 9 90,09 Scanned with CamScannerDS: Cars Cy = 4,70 SBS: Wg dd NaOH 40% / 4, ST dung quy tie duiing chee ae dain tat 08 ede da vd cng dane 1 chat) juyer chat) 40) = 100 t ey yuyon doi tit dd Naoy odd a ies) = % (NasO) duge chuyé ne ea: X = Aad H% (NayO) vee : a NO + 0-2 g trinh hoe 3 80, gag 188 g oh tC 1 pha HOM say ae di diy e NaxO# yng Dua vio phuon: 40x62 - 31% Voi : dd c% (Na) = Go 160 x 100 x 62 _ 18.34% dd b& (Naz0) = —erex 80 x 80 Ta cd so dé quy tie dutng chéo nhu sau: 100 31 - 18,94 = 12,66 (PKL) dd Na,O 100% aa \ NZ 183 100 - 31 = 69 (PKL) dd Na,O 18,34% Theo so dé trén, edn phai ldy 12,66 phan khéi lugng (PI cia Na;0 tron véi 69 PKL cia dd Na,O 18,34%: 3 m¢Na,O) _ 12,66 m(dd b%) ~~ 69 : Khoi luong Na,O cn hoa tan vao 676g dd chia 160g NaOH m(Na,0) = er = 124g 9 585g HCl nguyen chat trong 1d dd m(HC) = 885 x 1,180 HCI 36.5%: ~ Nong 4 mot cia dd eas 5%: ae Cy(HCl < 285 1.180 1099 ~ ThE tich da HL 36 59, bee = 180M aé VUHCH) = 200 x 3 Pha 200mt da HCL aM: Tap = 50,801 : Scanned with CamScannerdung quy tie duéng chéo dé xe dinh ti 1¢ pha tron (trong 5 hap nay, nude duige xem 1a dl FIC 0%: ru 20 5 -0=5 (PKL) dd 20% NZ 5 ZN 0 15 (PKL) dd 0% (nude) theo so dé trén, edin phai ly 5 PKL eda dd HCI 20% tron vai 45 PKL cua nude: m(dd20%) _ 5. m(Hy ar 15 Khéi hing 100md da HCl 20% 1a m = V.d = 100 1,10 = 110g Khéi lugng nuéc can cho vao 110g dd HCl 20% la m(H,0) = Hoxie x15 _ 330g ‘Thé tich nue sit dung: V = = 380 = 330m! 7. Khéi lugng HC] nguyén chat trong 44,8 lit khi = 2 mol la: 36,5 x2 = 73g Khéi lugng dd HCl 14,6% trong 6 chia 73g HCl nguyén chat duge tinh tit quy tc tam sudt ahu sau: 100g dd chia 14,6g FC] nguyén chat X?g ———- — _ 73g ———_ 100 x 73 = = 500, X= 86 a { HCl: Lugng nude cdn hoa tan 44,8 lit khi m(H,0) = 500 - 73 = 4278 8. DS : 33,6ml 9.DS : 14,5ml 10. DS: 230g (CHsCO),0 va 270g H:0 1. DS: 13,87ml , 12, DS: 13,92ml 13. DS: 1821,9g 14. Néng a} mol tia dd HsPOs 17,9%: 17,9 «1000x1100 _ 991 Cy = M 100 x 98 Scanned with CamScannerlug! é ng 46 avon 9,01) anit gau cua dd HsPO, 17,99, N gg quan IME” oon xing 8 Eo HN gia HPO, 17,9%, N theo c# dg dudne 1ugne Ty 2 6,03N) Nong welll 2 3.CN 1%: gg HPOs 178 s 1008 ya. thé teh 8 7,87 _ go,95m! « jeng ol Khéi lugng n "100. 4,099g/md d= v 90,95 it dd ‘. Hy nguyen chat c6 trong 1 lit dd amoniac 24,934, 16. Knsi lang Ne 721 1000 0.910 _ 218,7¢ m(NH3) = 100 i 0: sas mol eda dd amoniac 24,03 Ning oo mal te 2408 «1000 0.910 ~ 19 964 Cyy(NHs) = "99 x 17 ‘Thé tich dd amoniac 24,03% can ding dé pha 1 lit dd 0,0500x, 1000 x 0,0500 - eee = 3,89ml VINHs) = “Tp 9g Khéi lugng dung dich amoniac 24,03% can ding dé pha 1 li 4d 0,0500M: m= V.d = 3,890,910 = 3,54 17. DS: 0,0800N 18. poe (NaSO,) = M (Na,SO,) : 2 nén Cy = Cy:2=1M Khdi lugng tinh thé Na,SO,.10 H,O thu duge khi dun can 5000! dd NaySO, 20 Ta: m(NayS0, .10H,0) = 32%2% 500 x1 _ 644 19. DS: 2,95NV 00 es 20. Cho CuSO, Ithan yao nude: aa + 5H,0 = CuSO,.51,0 § 90g 250; % CuSO, trong Cuso, 5H, 0: -5H.0: % CuSO, = 160x100 359 = 84% Mrs Scanned with CamScanner‘Ta co $0 dé quy tdée dudng chéo nhu 64 16 - 8= 8 (PKL) Cuso, - 5 NZ 2 16 ZN 8 64 - 16 = 48 (PKL) dd CuSo, a% now vay, ldy 8 PKL CuS0,.5H,0 tron véi 48 PKL ge cing ta 68 thu duge 56 PKL dd CuSO, 16%, dd Cuso, mn(CuSO,.5H,0) = 55928 - g0g m(dd CuSO, 8%) = 560x 48 _ , 8%: 56 480g Vay phai tron 80g CuSO,.5H,O vao 480g dd CuSO, 8% sé nhan duse 560g dd CuSO, 16%. ° a1. Khéi lugng ctia KeCr20; can ding dé pha 250ml dd c6é néng dé 0,050N la: 0,050 x 294,2 x 250 ‘K,Cr,0,) = ———_—— emcee 1000 x 6 (Trong cdc phan tng oxy héa Khir sit dung K,Cr20; lam chat chun, KyCrz0; nan 6e" dé chuyén thanh 2 Cr, do 46: D(K,Cr,07) = M(KsCr201V/6 = 294,2/6 ) 22, Trong 100g dd CaCl, 10% c6 10g Cae va 90g HzO = 0,613g $6 mol CaCl, trong 10g CaCl = 77 it = 0,09mol $6 mol Ca” trong 10g CaCl, = 0,09mol Sé mol Cl trong 10g CaCl = 9, a $6 mol H,O trong 90g H20 = 22 = 5,0mol 0,09 = 0,017 4. - ye ee Phan mol ciia Ca’: n(Ca”") = 59,09 + 0,18 Pha _ 0,18 ___ = 0,084 din mol eda Cl: (Cl) = 570,09 + 018 Ph, 60 = = 0,95 an mol cia H,O: n(H29) = 55 0,09 + 018 Sn CHOI, = 0,245; n (CHs00 = 075° Scanned with CamScannerChuong 3 6 Ne CUA CAC CAN BANG HANG sd DAG TRUNG C | HOA HOC DON GIAN TRONG nuéc Trang thai edn bang eta he cin bing trong nude cua 1, M8 ta trang thé a) HCl: HCI 1a acid manh: HCl + H,0 + H,O* + Cl hay viét dudi dang rit gon: HCl + H* + Cr Nuc la dung méi ludng tinh (vita cho, vita nh4n H*): H,0+H,O === H30° + OH™ hay: H,0 === Hts OH" Nou néng d) HCI 16n sé sinh ra lugng 1én HO" lam cho ein bing H.0 === H’ + OH" chuyén dich v8 phia bén trai. N6i céch khie, trong dd acid manh véi néng do khé lén, sy phan ly cia nue trd nén khong déng ké (thuding duge bé qua). b) CH,COOH: CH,COOH 1a acid yeu; CH. =a wes sCOOH+H.O == H;0" + CH,COO- ay: CH;COOH = + = Ht+cH,coo CHsCOO™ bj thay phan: CHCOO"+ H,0 Nude cing phan ly: HO = ©) H,S0, MSO, 1a dincid 06 p = == CHsCOOH + OH™ Hts OHS Scanned with CamScannerph c trung ctia etic efin bling héa hoe don gin trong nud a ic d) HxC201 (tar = 1075; kas = 10~*7) duge xem 1A da aa huong trinh (rut gon) trong nuée nhu sau: H2C,0; === HC20. +H* HC,0, === Cz 0.7 +Ht HO 9 === H*+OH™ e) NaOH Ja baz manh: NaOH +H,0 —» NaH,0* + OH™ Hay: NaOH ects! Nat dort va H,0 HO 5 tl f) NH, 1a don baz yéu: NHs +H2O === NH," + OH" HO === Ht + OH" 81 yéu; cde g) NH,Cl (mudi ctia acid manh HCl va baz yéu NH,OH) phan ly hoan toan: NH,«Cl —* NH,*+CIr NH," bi thay phan: NH,* +H,0 === H,0* +NH3 H,0 === H*t+OH™ h) KCN (muéi cia baz manh KOH va acid yéu HCN) phan ly hoan toan: KCN —* K*+CN™ CN” bi thiy phan: CN" +H,O === HCN +OH™ H,O === H*+OH” i) Cu(NOg)) phan ly hoan toan: Cu(NOs)2 —® Cu’ + 2NOs” Cu?* bi thay phan: cue*+H,O === CUulOH)' +H" culo)’ + H,0 ===. CulOH) 2 +H" HO == H+ OH j) NagSOy phan ly hon toan: . Na;SO; —" 2.Na* + SOs Scanned with CamScannerSO,* bi thtiy phan: S02 +H,0 Fe NSOY + OH at He HSO; +H:0 HeSO, + OH H,0 Hy OW C&e ean bing cia qué tinh tidy phan that PA chia ' can bing acid-baz theo quan nidm acid-bas eva Bronatog Cy nue, ion NH,’ 14 don acid you, ion CN IN don bax yoy, ion cyntt mot da acid yéu va ion S07 1A mdt da bax yeu), a ~ 2. Mo ta trang thai cin bing trong ntise cia BaCly y, NV Na80, (4 dung vita dit véi hau): It BaCl; vd Na2SO, phan ly hodn todn: BaCh, — Bay 2cr NazS0, — 2Na's so, Ba* +S BaSo, | 4.0 = H+ OH : Ba®* +H,0 == Ba(OH)' +H" Ba(OH)"+H.0 == Ba(OH)p + Ht ty SOM +H =e Hg0- ; HSOr+Ht = Hs, ” _ Theo chidu tir trai sang phai, cin bang (") gén nhy hota toan, can bing (**) ya (™*) Ba an nm nhy khong xy con lai xdy ra khong ding ké. Kh tinh toiin ga xét cain bang (*) ya bd qua tat ¢ aa ‘i ce cin bin, 8. MO ta trang thai can bing t 80 V6i AgNO,), ray ete cfin bing gan dung thudng dl iB cdn lai. TONG nude cia AgNO, va NH; (thi ne — Agt + NOs ) 9" + NH == tagtvHyy ‘ TAGINHS SNH, me (aati " NH + M20 Se NHR on H20 se =] Ho Ag* + OH 2! gion) ANON Oe agionys 5 Scanned with CamScannerAION muae jy in bing (") va (™) say pa pa DEN as xdy ra rit manh theo ehidy 5 phi $0 vi ede cin bing cbn lai, Khi tinh tote a tir sin ching ‘ trai ony dn bang (*) va C") (bd qua tat ca ete ean bhing edn Iai), 6 cn Ini, Shutsng chi xét 4, Vit cae biéu thtte dinh lua bao toan ny tich cho cde hé sau: 6 1) vA bio toan din a) dd nude cua NHg (ndng d6 mol ban dau Cy: 6 trang thai cfin bing dd chia NH, NH", 1, Biéu thuie dinh luat bao toan néng do: (NHg] + (NH,'] = C, Biéu thie dinh luat bdo toan dién tich: (H*] + [NH,‘] = [OH] b) dd nuée cia NHg (néng d9 C,) va NH,NOs (néng a6 C,) G trang thai can bing dd chita NH, NH,*, H’, OH va NO, Biéu thutc dinh luat bdo toan néng dé: (NHs] + [NH,'] = C; + C Biéu thic dinh luat bdo toan dién tich: (H‘] + (NH,‘] = [OH‘] + [NOs] c) dd nude cia NH, (néng d6 C,) va HCI (néng d6 Cs) G trang thai can bing dd chia NH, NH,*, H’, OH" va Cr Biéu thie dinh luat bdo toan néng dé: ([NHg] + [NHy‘] = Ci va {Cr] =Cs Biéu thi dinh luat bdo toan di¢n tich: (H"] + (NH,'] = [OH] + [CV Nhén dign ede doi acidlbaz trong ede ph Ou an wing: 1. Zn(OH),/ ZnO," va Hz0/OH™ 2. OHIO va HO/OH™ 3. NH NH” va NeHuNeHs” 4. HNOyNO” va Hau Urs 5. HCIOYCIO, va taHa"INoFle 8. OAHgNHIICSHaN va (CH)SNH'CHS)N 7. HyCOsHCOs va Ha0"20 2 CyHgOH/CHg0” va NHolNHe” Scanned with CamScanner-— Tinh pH e#a 8 1. Tinh pH cua cA phuong, trinh ddy du a P ) HIOs 0,100 (pk wos = 0,79) HIOs 0,010M HIOs 0, oom : oe pH= 9 (09,0001 = 4,00 H103 0.0001 | i — ‘CL,CHCOOH 0,100M 1,30 (pk. =) | ‘Cl,CHCOOH 0,010" 2,07 ‘ChGHCOOH 0,001M 3,01 HF 0. 9.100 M 2,40 pHe tpi Lig Cur (pkue = 3.17) 2 2 HF 0,010 M 2,64 1 pH= 19.47— 41g 0,010 = 2,59 r z 2 " a HF 0,001 M 3,26 b HF 0,0001 M 4, 05 " pH = -Ig 0,0001 = CH;COOH 0,1M Dee ot = 4,00 1 (Oheracoon = 4,78) DH = 5 phevaccoon i Cousecoon 1 . = 1476-1190 CHsCOOH 0,01M a gig 0.1 2,88 3.39 j ph= 4476-1 cH 76-4 COOH 0,001M 2478 - 519 0,01 = 3,38 391 7 pHs 1 1 HO. 1M 2178~ 31g 0,001 = 3,88 (hvece = 11,70) 5,85 7 - pH= H.0, 0,1 pho - 1 100M 2p Pkrzoe - S19 Crzce = 4 1 6.34 2 fiir pit pH= 1 OF 2 Phzce — $10 Crece= Tarlty ale 5 3 tr 50 Scanned with CamScannerc trung clia ciic cin bang hoa hoc don gian trong nud: c 8: a) (2) (3) 0; 0.001M 6,96 He tay 7d i pHs 117 319 0.001 = 7.35 (1 NH.OH 0,1M 112 | pH a7 JP + #9 Caption (phous = 9.24) : 1 =74+ -9,244 = 2 + 51901 11,12 NH.OH 0,01M 10,61 pH=74 p98 + 39 0.01 = 10.62 1 NH.OH 0,001M 0.09 pH=74 p924 + 349 0,001 = 10,12 5AM NHACI0,100M 12 pH= A Phn ~ F19 Cine (pkonis = 9.24) 1 1 = 59,24 - -Ig 0,100 = 5,1. 2 29 : NH,CI0,010M 5.62 pH = js 24 - t!9 0,0100 = 5.62 NH,CI 0,001M 6.12 pl = $9224 - #9 0,001 = 6.12 NaCHsCOO 0,1M 8,88 pH=7+ }Pkersecoon + #9 Canecocms (Pkexscoou = 4,76) Lz p476+ fi90.1 = 8.88 NaCHCOO 0.01M 8,38 pH=7+ 4476 + fla oot = 8,98 NaCH;COO 0,001M 7,88 pH=7+ 3476 + 319 0,001 = 7,88 1 KCN 0,100M 14,10 | pH = 7+ Phen paar (Pkicw = 9,21) 1 1 11,10 =7+ 19.21 + 1ig 0.100 = 11, =7+ 2°? + 2 Ig KCN 0,010M 10.60 | p=7+ $921 + ji90010- 10.60 KCN O,001M 10.08 | pH=74 3921+ lg 0.001 = 10,10 Scanned with CamScannernich git Phin or fav | 8° prt xg 0.0001 4,00 1 rot | 402 | 403 ; 1g.70- $19 01 = 2.35 2 13,70- 5190 yor | 23s | 236] PN 2 2 ‘cid phthalic . = 1g70- $19 0.01 = 2 an 8 | PH 0-5 ‘CHa (COOH) yo? | 287 | 2 2 3x kay = 3.70 to? | 342 | 3.45 ss Phar = 4.60 10° 4,05 | 4.14 1 1 . HCO to | aes | s68 | pH= $835- 3190.1= 968° | aro Phy = 6,95 to? | ate | 418 | PH= 38.38 - Ho oorsate | an pke= 1032 | 10° | 468 | 468 | pH= 38.28 ~ }9 0001 468 | an 1o* | 519 | 5.19 | pH= 35.35 - dis o.coots a NasCO3 Yo" 1/4165 | 1,65 | pH= + $102 a hig 0,102 11,65 1a 7 1 ke: = 3,68 a 10°} a4t9 | 14,13 PHe7s 310.92 edig o.oo. 11,16 | : ; ; pees 7.35 | 10° | 1086 | rose ae 10° | 987 | oy be (1°) Ding PT d&y ad; (2 Pd 1 Xem tying eu (81) Kem nang assng don acid Ot gos non 8d PT ey DY (4° Dang PT [Hf ¢, !on gin hon) Scanned with CamScanner3. Tinh pH cua cde dd dém acid (gém acid yéu + baz lién hop cd acid yous ad dem baz (gém baz yéu + acid lién hgp etia i ' ga dem chifa hai chat lugng tinh acid-baz bing PT day aa va a thie gan dung: oo He dd dem Ca Ce sah pH Tinh plt bang PT day di | bing CT gén ding (+) 0,100 | 0,100 4,76 476 acid yéu CHsCOOH | 0,010 | 0,010 4,76 aa (kun = 1079) 0,001 | 0,001 477 a hap) yéu i va baz (ier h9P) YE4 | O409 | o,010 377 376 NaCH;COO : 0,100 | 0,001 3,04 276 0,010 | 0,001 3,83 3,76 0,010 0,100 5,76 5,76 0,001 0,010 5,76 5,76 0,001 0,100 6,76 6.76 0,100 0,100 9,24 9,24 Baz yéu NH.OH 0,010 0,010 9,24 9,24 (hen = 10°") 0,001 | 0,004 9.23 9.24 va acid (lign hap) YSU | 499 | 0,010 024 8,24 NH.CI 0,100 | 0,001 7.24 ioe 0,010 | 0,001 8,24 8,24 0,010 0,100 10,23 10,24 0,001 | 0,010 10,17 10,24 0.001 | 0,100 10,96 11,24 4 0,100 | 6,100 721 72 ose 7.24 Acid yu NaH2PO. 0,010 0,010 7,24 724 (kaa = 107724) 0.001 | 0.001 724 va baz (lién hgp) yeu [> 499 | 0.010 6.21 6.24 7 5.21 NagHPO. 9,100 | 0.001 5.21 621 6.21 0,010 0,001 " B21 824 0.010 | 0.100 . - Bat 82 0,001 0,010 : ; 0,100 9.20 a ee 0,001 . *) Se () pH = phys + 19g Scanned with CamScannerCOONa | nau e), phan ting va cau e) sé lim 1 lit hon hgp ¢ do dang acid Bs nong ving 65 can bing oe HC them 1 oe oe 2 (NaCHs 00) gidm xuon, ning (COOH) tang én: a a \ Ca _ 476+ 1p 5210 = 6,03 pH = pha * Wg, =" 35 x10 2y7 NaOH vao 1 lit dd. g) Hén hgp @ cau e) sau khi them 10° p cua cu e), phan tng Khi thém 107M NaOH vao 1 lit hon hg xy ra nhu sau: CH,COOH +NaQH == NaCH;COO +Hz0 Ban dau 25.10? 107 Cin bing 15.10? re apace , 10? ay, ‘m lim ning dang bes te OF Nae 1 lit hn hop etia oA a4 (CH,COOHD giam urn BOO f H) giém subng: ) tang Ten, némg do dane * PH = ph tu WEE sag 5 1g85% 10%. 561 h ) Dung dich dém pH bag: 15107 = Phy + g© Bore 924 + ig2x IO" = 9.54 102 E Scanned with CamScanner