2019

AP Chemistry
®

Scoring Guidelines

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 1




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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 1 (continued)

1 mol

60.06 g
0.0897 mol
= 17.9 M
0.00500 L

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 1 (continued)

 ⋅

DSsoln 


S soln  S (H 2 NCONH 2 (aq))  S (H 2 NCONH 2 (s ))

70.1 J/(molK)  S (H 2 NCONH 2 (aq))  104.6 J/(molK)
S (H 2 NCONH 2 (aq))  174.7 J/(molK)

DSsoln

Ssoln

 


     ‒    
   

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 2

 
  

  

  

  

  
 


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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 2 (continued)

H

nRT (0.100 mol)(0.08206 L atm mol -1 K -1 )(298 K)

=
V 2.00 L

[Br2 ][Cl2 ] PBr2 PCl2

Keq = Keq 
[BrCl]2 ( PBrCl )2


(0.26)(0.26)
Keq = = 0.13
(0.71)2

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 2 (continued)

 

    
 
 

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 3

 

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 3 (continued)

1 mol CaCO3
0.93 g CaCO3 ´ = 0.0093 mol CaCO3
100.1 g
1 mol Na 2 CO3
0.0093 mol CaCO3 ´ = 0.0093 mol Na 2 CO3
1 mol CaCO3

 

   [HCO3- ][OH - ] 

[CO32 - ]

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 3 (continued)



   


 

 

  




( x )( x ) ( x )( x )
Kb =  ci = +x
ci - x Kb

 

 

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 4

P1 P 0.70 atm P2
T1
= 2
T2
 299 K
=
425 K


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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 5

0.980 ´ 10-18 J

hc hc
E = hn =  l=
l E
(6.626 ´ 10 -34 Js)(2.998 ´ 108 ms-1 )
l=
0.980 ´ 10 -18 J
l = 2.03 ´ 10-7 m

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 6

1
[NO 2 ]

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 6 (continued)




[N 2O4 ]
Keq 
[NO2 ]2

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 7
 →

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 AP® CHEMISTRY
2019 SCORING GUIDELINES

Question 7 (continued)


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