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AL NOOR INTERNATIONAL SCHOOL

BRITISH SENIOR SECTION


MODEL EXAMINATION 2020 - 2021(E- Assessment)
CHEMISTRY 0620/41
March 2021
Paper 4 Theory(Extended) 1 hour 15 minutes
Date: 17/3/2021
READ THESE INSTRUCTIONS FIRST
 Answer all questions on a separate A4 paper with margin on both the sides, page
numbers and your name class and division on all the pages you hand in.
 Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
 Do not use correction fluid.
 You can use a calculator wherever appropriate.
 You may lose marks if you do not show your working or if you do not use appropriate units.
 You must write clearly the question number and show all necessary working clearly;no marks
will be given for unsupported answers from a calculator.
 You will have to remain live in the Zoom meeting with your camera switched on whiletaking
the test. The camera should be kept at an angle to get the view of both the student and the
answer script.
 Scan all the pages with your smart phone using Scan App (Cam Scanner/ Adobe Scan) in
portrait only.
 If there is any technical issue in uploading, take the photograph of the entire script and e-mail
it to your subject teacher and try uploading later.
 The number of marks for each question or part question is shown in brackets [ ].
 A copy of the periodic table is on page 10

SECTION Total

Max. Marks 80
Marks
Obtained

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1. The symbols of the elements in Period 2 of the Periodic Table are shown.

Li Be B C N O F Ne

For each of the following, give the symbol of an element from Period 2 which matches the description.
Each element may be used once, more than once or not at all.

Which element:

(i) makes up approximately 21% of clean, dry air

................................................................................................................................................................... [1]

(ii) combines with hydrogen to produce ammonia

................................................................................................................................................................... [1]

(iii) is a soft metal stored in oil?

................................................................................................................................................................... [1]

(iv) has atoms with only two electrons in the outer shell

................................................................................................................................................................... [1]

(v) is a monoatomic gas

................................................................................................................................................................... [1]

(vi) has atoms with only seven protons

................................................................................................................................................................... [1]

[Total: 6]

2. This question is about copper and copper compounds.

(a) Copper is a metal.


Explain why copper conducts electricity.

................................................................................................................................................................... [1]

(b) Describe a test for copper(II) ions.

test .................................................................................................................................................................

observations ............................................................................................................................................. [2]

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(c) Aqueous copper(II) sulfate is electrolysed using graphite electrodes.

(i) Describe what is observed during this electrolysis:

• at the positive electrode...........................................................................................................................

• at the negative electrode .........................................................................................................................

• in the electrolyte. .................................................................................................................................. [3]

(ii) Graphite conducts electricity.

Give one other reason why graphite electrodes are used in electrolysis.

................................................................................................................................................................... [1]

(d) Aqueous copper(II) sulfate reacts with magnesium.

CuSO4 + Mg  Cu + MgSO4

Construct the ionic equation, including state symbols, for this reaction.

................................................................................................................................................................... [2]

(e) A 2.25g sample of an oxide of copper contains 0.250g of oxygen.

Deduce the empirical formula of this oxide of copper.

[3]

(f) There are several commonly used alloys of copper. What is the meaning of the term alloy?

..................... ............................................................................................................................................. [1]

[Total: 13]

3. (a) Sulfuric acid is made from sulfur in a four-stage process.

stage 1 Sulfur is converted into sulfur dioxide.

stage 2 Sulfur dioxide is converted into sulfur trioxide.

stage 3 Sulfur trioxide is converted into oleum.

stage 4 Oleum is converted into sulfuric acid.

(i) How is sulfur converted into sulfur dioxide in stage 1?

................................................................................................................................................................... [1]

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(ii) Describe how sulfur dioxide is converted into sulfur trioxide in stage 2.

Your answer should include:

● an equation for the reaction


● the temperature used
● the name of the catalyst used.

........................................................................................................................................................................
........................................................................................................................................................................
................................................................................................................................................................... [3]

(iii) The reaction in stage 2 can reach equilibrium.


What is meant by the term equilibrium?

........................................................................................................................................................................

................................................................................................................................................................... [2]

(b) Sulfur trioxide is converted into oleum, H2S2O7, in stage 3.


What is sulfur trioxide reacted with to convert it into oleum?

................................................................................................................................................................... [1]

(c) Oleum is converted into sulfuric acid in stage 4.


Write a chemical equation for the conversion of oleum, H2S2O7, into sulfuric acid.

……............................................................................................................................................................. [2]
(d) When sulfuric acid reacts with ammonia the salt produced is ammonium sulfate.
Write the chemical equation for this reaction.

.................................................................................................................................................................. [2]

[Total: 11]

4. The structures of two carboxylic acids are shown.

(a) An isomer of carboxylic acid B has the name methylpropanoic acid.

(i) What is the name of carboxylic acid B?


................................................................................................................................................................... [1]

(ii) What is the meaning of the term isomer ?


........................................................................................................................................................................
................................................................................................................................................................... [2]

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(b) Vinegar contains ethanoic acid.
Describe the formation of vinegar from ethanol.

................................................................................................................................................................... [1]

(c) Ethanoic acid reacts with calcium carbonate.

(i) Give the formula of the calcium salt formed in this reaction.

................................................................................................................................................................... [1]

(ii) Name the other two products formed in this reaction.

………………....................................................... and ................................................................................... [1]

[Total: 6]

5. Alkenes are made in an oil refinery by cracking hydrocarbons.

(a) (i) Give one other reason why petroleum companies carry out cracking.

................................................................................................................................................................... [1]

(ii) Complete the equation for the cracking of tridecane, C13H28, to form propene, C3H6, and one other
hydrocarbon.

C13H28  C3H6 + ............... [1]

(b) Propene is an alkene.


(i) Write the general formula for an alkene.

……………………………..................................................................................................................................... [1]

(ii) Propene reacts with steam by an addition reaction.


Predict the molecular formula of the product of this reaction.

................................................................................................................................................................... [1]

(iii) When propene undergoes incomplete combustion, a small amount of carbon dioxide is formed.
Name two other substances formed when propene undergoes incomplete combustion.

………………................................................................ and .......................................................................... [2]


(c) Methanoic acid reacts with propanol, C3H7OH, to form an ester.
Name and draw the structure of this ester, showing all of the atoms and all of the bonds.

name .........................................................................................................................................

structure

[2]

[Total: 8]

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6. This question is about polymers.

(a) Polyesters and polyamides are both polymers formed by condensation reactions.
What is meant by the term condensation reaction?

........................................................................................................................................................................

................................................................................................................................................................... [1]

(b) The partial structure of a polyester is shown.

(i) From the diagram, identify and write the ester linkage. [1]

(ii) Draw the structures of the two monomers used to produce this polymer.

[2]

(iii) Terylene is a polyester.


State one common use of Terylene.

................................................................................................................................................................... [1]

(c) Poly(ethene) is made from ethene monomers.

(i) Draw the structure of ethene, showing all of the atoms and all of the bonds.

[1]

(ii) Poly(ethene) is a non-biodegradable plastic. What is meant by the term non-biodegradable?

................................................................................................................................................................... [1]

(iii) Describe one pollution problem caused by the disposal of non-biodegradable plastics.

................................................................................................................................................................... [1]

[Total: 8]

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7.a) Aluminium oxide reacts with acids and with alkalis.

(i) What term is used to describe an oxide that reacts with acids and with alkalis?

................................................................................................................................................................... [1]

(ii) Aluminium oxide reacts with dilute sulfuric acid to form a salt.
State the name and write the formula of the salt formed.

name ..............................................................................................................................................................

formula ..................................................................................................................................................... [2]

(iii) Aluminium oxide reacts with dilute sodium hydroxide to form a salt and one other product.
Name the other product.

................................................................................................................................................................... [1]

(iv) Aluminium hydroxide, Al(OH)3, decomposes when heated to form aluminium oxide and water.
Write the chemical equation for this reaction.

................................................................................................................................................................... [2]

(v) Suggest the names of two other aluminium compounds that decompose when heated to form
aluminium oxide.

................................................................................................................................................................... [2]

(b) Aqueous sodium hydroxide, NaOH(aq), is a strong alkali that reacts with dilute sulfuric acid
exothermically.

(i) What type of reaction is this?

................................................................................................................................................................... [1]

(ii) Complete the equation for the reaction between aqueous sodium hydroxide and dilute sulfuric acid.

2NaOH + H2SO4 → ......................... + ......................... [2]

(c) A student wanted to find the concentration of some dilute sulfuric acid by titration.
The student found that 25.0cm3 of 0.0400mol/dm3 NaOH(aq) reacted exactly with 20.0cm3 of H2SO4(aq).

(i) Name a suitable indicator to use in this titration.

…………………………....................................................................................................................................... [1]

(ii) Calculate the concentration of the H2SO4(aq) in mol/dm3 using the following steps.

● Calculate the number of moles of NaOH in 25.0cm3.

moles =…………………………….

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● Deduce the number of moles of H2SO4 that reacted with the 25.0cm3 of NaOH(aq).

moles = ..............................

● Calculate the concentration of H2SO4(aq) in mol/dm3.

concentration = .............................. mol/dm 3 [3]

(iii) Calculate the concentration of the 0.0400mol/dm3 NaOH(aq) in g/dm3.

concentration = .............................. g/dm 3 [2]

[Total: 17]

8. Magnesium exists as three isotopes,

(a) State, in terms of the total numbers of electrons, neutrons and protons, one difference and two
similarities between these magnesium isotopes.

difference .......................................................................................................................................................

similarity 1 .....................................................................................................................................................

similarity 2 ................................................................................................................................................ [3]

(b) Magnesium is a metal.

Describe the structure and bonding of metals. Include a labelled diagram in your answer.

........................................................................................................................................................................
........................................................................................................................................................................
................................................................................................................................................................... [3]

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(c) Magnesium reacts with oxygen to form the ionic compound magnesium oxide.

(i) Complete the dot-and-cross diagrams to show the electronic structures of the ions in magnesium
oxide. Show the charges on the ions.

[3]

(ii) Magnesium oxide melts at 2853°C. Why does magnesium oxide have a high melting point?

…………………………………………………....................................................................................................................

................................................................................................................................................................... [1]

(iii) Explain why molten magnesium oxide can conduct electricity.

………………........................................................................................................................................................

................................................................................................................................................................... [1]

[Total: 11]

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