///Top-5 Guess Papers v¥/Easy Answers v Simple Steps v wow yor? All v % Deleted Tension Reliever! TOP 5 Model Papers ~ 3% Mabus — Confidence Booster!! A ree OA Rate Rl tahatelBabypBullet'sp2}Rage (ChemistrygPracticall Sheet} + PE Che ’ "Practical Exam! IPE Chemistry ‘Practical Exam’ consists of 3 experiments. (1) Volumetric Analy sist® Marks) (11) Salt Analy sis(10 Marks) (II})Finding functional group. (6M) Record (2 Marks), Project Work (2 M: Viva (2 Marks). Total: 30 Marks V) Volumetric Analysis: IL is the process of estin Volume of solution, using a standard sol ing the weight of a substance mixed in a given rst find its Molarity and hence weight. Ev 1: Estimate the amount of ‘Sodium ¢ standard solution of 0.1 M HC/ Solution, voniate’ present in 500 m/ of the given solution, using a Chemical Equation: NayCOy+2HC/ > 2NaC/+H,0+C0,7 Step-L: Standard So Step-2: Sodium Carbonate solution is Add 1 or 2 drops o: aken into a conical flask using a 20 m/ Pipette. ndicator (Methyl orange) trated against Burette solution untill its colour is changed. 2 Step: End point USSR © [RUSIRME) readings in the Burette are noted in the observation table. Step-5: Calculations: Standard Solution (HC/): Molarity My=0.1M, Vj; Sodium Carbonate Solution: Mj=?, V= 20 mi; ny M2, Molarity My =MIML 22 = m4 = V2 Step-7: GM.W of given solution NayCO3=106 g; Given volume = 500 mi Molarity(M3) GMW x Given Vol. of solution(in mi, 1000 mt Step-3: Given solution Step-8: Weight of the substance= Step-9: Report: Weight of the substance =... & --Steps to be written in the exam: 1 aie >) Apparatus 3) Chernicals 4) Chemical Equation 5) Indicators 6) Formula ation Table 8) Calculations: M,,V), n; and V>,n; 9) Finding Molarity (M3) 1 Writing GM.W of the given substance 11) Finding weight of the substance 12) Report: Weight of the substnace Ex 2: Estimate the amount of Oxalie acid present in the given volume of solution, using standard 0.2M sodium hydroxide solution. = Chemical Equation: HyC;0,+2NaOH > Na;C,0,+2H;0 GMW of Oxalic acid (HC204) = 126 g Fx 3: Estimate the amount of Potassium Permanganate present in the given volume of solution using standard 0.05 M H,C,04.2H,0 solution (Oxalic Acid). + Chemical Equation: 2KMnO4+3H;SO4+5H,C,04.2H,0 > KS0,+2MnSO,+10CO,+18HO + nj=5 and ny=2; GMW of Potassium Permanganete(KMnO,) = 158 g + ny=2 and ny Ex 4: Estimate the amount of Mohr's salt present in the given volume of the solution, using standard 0,02 M KMn0O, solution. Chemical Equation; 2KMnO,+10FeSO,*BH,SOy > KySO,+2MnSO,+5Fe4SO,);+8H30 + ny=2 and ny=10; GMW of Mohr's salt = 392 * Please follow the latest revised practical syllabus.SENIOR INTER a (ar) MADE EASY BABY To Develop ‘Chemistry’ between U & IPE Do», en? aT Varn, PECIALLY {WADE FORYOU SRI PUBLISHERS MACHILIPATNAM Email: bulletbabystar@ gmail.com Facebook: Bullet Baby Star Youtube Channel: Bullet @Intermediate - SECOND YEAR CHEMISTRY : Minimum Learning Revision Material Total Pages: 72 + iv Edition: 2021 Copies: 6,000 Price: 70 /- Publishing & Marketing : SRY PUBLISHERS, \iACHILIPATNAM - 521 001 Printed at: SRI SIRI PUBLISHERS, 5-30, Jakkampudi, K.T.Road, Vijayawada-521012 Title Design: MSR Graphics, Machilipatnam For Postal Copies, please contact : 08672-223030, 9247878964 (Office) For Online copies, please visit : www.srisiripublishers.com For Bulk Orders, Please Contact our Area Managers: * E.G, W.G, Vizag, Vizianagaram, Srikakulam : 9246778431 * Warangal, Khammam, Komarambheem, Peddapalli,Mancherial ©: 9246778432 * Medak, Siddipet, Karimnagar, Adilabad, Vikarabad, Sangareddy, : 9246778433 Rajanna Siricilla, Nizamabad, Nirmal, Kamareddy * Prakasam, Nellore, Chittoor, Kadapa, Kurnool, Anantapur 9246778434 * Krishna, Guntur, Hyderabad, Nalgonda, Mahabubnaga! © Copy rights reserved by the Publishers. 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TF Fair Disclaimer: The Publishers disclaims the use of any content taken from any source in any pattern ‘as such content is used for ‘Education Purpose only' without involving any sort of Advertisement Purpose. “All disputes subject to Machilipamam Jurisdiction only. E&OE 1. This ‘Bullet Baby Book’ is prepared keeping inview of the needs of Pass Aspirants. 2. This is a ‘Minimum Leaming Reivision Material ' useful for Pass Aspirants. 3. This Booklet contains mostty the ‘previous IPE questions’. - 4. Most of the Answers are ‘reduced or simplified’ to make them ' read easy ' and‘ wirte easy’ 5. The Answers are written as per the ‘guidelines of Scheme of Valuation’. 6. But one ‘should not expect full marks’ for each and every Bullet Answer. : 7. Various features such as Hit List , Selection of Q's & orderly arrangement of sections, Bullet Baby Chit Chats, Bullet Model Paper, Model Guess Papers etc are prepared just keeping in view ‘of Pass Aspirants. 8. Sedan Ge a vad us captions or comments are written for motivation purpose only. Taking them as granted is disclaimed. 9. General Expectation of Marks from this Baby Bullet Book is around 50%, 10. However, any Expectation in Marks or Number of Questions is disclaimed.2021 new IPE BLUE PRINT «« SR CHEMISTRY CHAPTER(Total Marks) VSAQ(2m) SAQ(4m) LAQ(8m) Total SOLID STATE (6) P-BLOCK ELEMENTS (16) GROUP-16 ELEMENTS _| GROUP. ELEMENTS _ BIOMOLECULES (6) HALO ALKANES & HALO ARENES (6) | ORGANIC COMPOUNDS(C, H, ©) (10) TS MAR-20 | AP MAR-19 | TS MAR-19 2-516 Marks 7+ 24 Marks 8+ 16 Marks |9-+18Marks |B» 16 Marks 4 S6Marks | 54Marks | 56 MarksCHAPTER-WISE 30% DELETED PORTION CHAPTER DELETED PORTION 1 SOLID STATE SOLUTIONS "ELECTRO CHEMISTRY \ ” SURFACE CHEMISTRY — ~ GENERAL ‘PRINCIPLES P-BLOCK ELEMENTS { Group-15, Group 16] 7. d&tBLOCK ELEMENTS $ POLYMERS 2 ‘BIOMOLECULES 10. CHEMISTRY IN EVERY DAY LIFE 7 Batteries; Fuel Cells : Corrosi Electrical Properties; ‘Magnetic Properties Abnormal Molar Masses ; Collision theory | Catalysis; Emulsions ENTIRE CHAPTER G 18: Oxides of Nitrogen structures only; Phosphorus allotropic forms; Preparation & Properties of Phosphene; Preparation & Properties Phosphorus halides: (Oxo-acids of phosphorous; G 16: Sulphuric acid Industrial Process of manufacture. ‘Some important Compounds of Transition elements (Preparation & Properties of KmNO, and KzCrz0;) ; Chemical reactivity of Lanthanoids; Actinoids - Electronic configuration, Oxidation states and Comparision with Lanthanoids; isomerism in Co-ordination Compounds: Importance of Co-ordination Compounds. ENTIRE CHAPTER Sucrose, Lactose, Maitose importance, Polysacharides (starch, Carbohydrates) [ENTIRE CHAPTER ‘Poly Halogen Compounds Some commercially important alcohols. ‘Only Diazonium Salt topic is deleted1. LAQ CHAPTERS 1. ELECTRO CHEMISTRY & CHEMICAL KINETICS(8 Marks) 2 P-BLOCK ELEMENTS (8 Marks) 3. | ORGANIC COMPOUNDS (CHO) (8 Marks) a ll. SAQ CHAPTERS SOLID STATE __(4 Marks) (4 Marks) __(4Marks) _SURFACE CHEMISTRY : (4 Marks) »-BLOCK ELEMENTS. Marks) 12-13 14-18 19-23 (4 Marks) 35-96 | (4 Marks) 37-38 | -40 | | Il. VSAQ CHAPTERS | 12. _ SOLID STATE _ Marks) iz 42 | | 13. | SouuTions _(2Marks) a | 14. | EC&aCe (2 Marks) 44-45 URFACE CHEMISTRY (2. Marks) 46 | OCK ELEMENTS (@ 16,618) (2+2Marks) 47-4 | . | d&f BLOCK ELEMENTS (2 Marks) 49-50 | | 18. BIOMOLECULES ~— (@Marks) 81-52 | _HALO ALKANES & S& HALO ARENES (@Marks) 3 | 20. | ORGANICCOMPOUNDS(C:H.0) (2 Marks) 4 J j!V. STAR QUESTIONS PLUS | |v. BULLET MODEL PAPER - 66-70 ‘7 _The Chapters are Renumbered as per VSAQ, SAQ, LAQ division, J* SR.CHEMISTRY LAQt LAQ2 LAQs. LAQs. LAQS LAQe. LAQ LAQs LAQs. LAQ10. LAQIL ee ee ttt ELECTRO CHEMISTRY/CHEMICAL KINETICS[8 MARKS}* tt State and explain Kohirausch’s law of independent migration of ions. What are Galvanic cells? Explain the working of Galvanic cell with a neat, sketch taking Daniel cell as example. ‘What is inolecularity ofareaction? How isi different from ‘order ofa reaction? Name one bimolecular and one trimolecular gaseous reactions. & % & P-BLOCK ELEMENTS[8 MARKS]* * * How is ammonia manufactured by Haber's process? How does ammonia react with (i) Zn$O4,q, (ii) CuS04,. (il) ABChy) How is nitric acid manufactured by Ostwald's process? How does Nitric Acid react with (i) Copper (ii) Zn (iii) Sg (iv) Py How is ozone prepared? How does ozone react with ()CQHg Gi) Ag (ii) KI (iv) Hg (v) PDS ‘How is Chlorine prepared in the laboratory? How does chlorine react with (i) Iron (ii) acidified FeSOg (iii) Iodine (iv) H7$__(v) KI 1% % ORGANIC CHEMISTRY[8 MARKS]* * * Write the following named reactions with one example for each. (a) Williamson's synthesis _(b)Reimer- Tiemann reaction. (c)Carbylamine reaction _(d) Kolbe reaction Write the following named reactions with one example each: (a) Decarboxylation (©) Wurtz - Fitting Reaction (©) Cannizzaro reaction (4) Aldol condensation reaction. Explain the following named reactions. (@) Diazotization (b) Sandmeyer reaction. (c) Gattermann reaction. (6) HVZ reaction Explain the following named reactions. (@Esterification (b) Friedel Crafts Alkylation (©) Friedel Crafts Acylation (@) Warwz reaction re | BABY BULLET-Q(AP) * fo P 1DI ja P 122)1 [oP 13)1 lo P 14(5)] [oP 15(6)) JP 16(7)] [oP 18()] fo P 19(10)] [oP 20011) [oP 21(12)] [oP 22(13)}* BABY BULLET-Q(AP) SR.CHEMISTRY * SAQ HIT LisT TOP 24 SAG * * *SOLID STATE[4 MARKS] * * * SAQI. Derive Braga's equation, SAQ2. Explain Schottky & Frenkel Detects, Lar 2611694 * *SOLUTIONS[4 MARKS] * * SAQ3. Define Molarity Calculate molarity ofa solution containing Sgof NaOH in S00mlofsohution. | (> 77) SAQS. OS. pea Molly: Calculate molly) of 1Ogm of cose gH 20, in gm of Water? SAQS. lar P 271018) Define Mole fraction. Calculate the mote fraction of HyS04 in 98% HSOq, far P2719} SAQ 6 ‘Wiatis relative lowering of pour pressure? How ist usefil to determine the molar mis ofiasohite? lar P 28(20)) * *ELECTRO CHEMISTRY & CHEMICAL KINETICS[4 MARKS]* * SAQ7. State and explain Nemst equation with the help of ametallic electrode and a lar P 29024), ‘non-metallic electrode. SAQS. Give the construction and working of a ‘standard hydrogen electrode with | P 29(24)) neat diagram, ‘SAQ9. Derive the integrated rate equation for a fist order reaction. Ja P 10027) * * *SURFACE CHEMISTRY[4 MARKS] * * + SAQ 10, Define adsorption? Give any four differences between Physisorpion & Chemisorption, dar P28) SAQ IL. How are colloids classified on the basis of interaction between dispersed phase — | [vf 31(29)) and dispersion medium? SAQ 12. Explain Tyndall Effect and Brownian Movement, lo RENT * * *P BLOCK ELEMENTS[4 MARKS] * # SAQ 13. How are XeF2 and XeF4 prepared? Give their structures. ter an) SAQ 14. How are XeO3 and XeOF prepared? Give their structures, Jie 3431) SAQIS. What are interhalogen compounds? Give some examples to illustrate the lw P MO) definition. How are they classified? * * *d&t BLOCK ELEMENTS(4 MARKS]* * * SAQ 16. Write the characteristics properties of transition elements, SAQIT. Explain. ‘Wemer's theory of coordination compounds lor P 350353) SAQ 18. Using IUPAC norms write the systematic names ofthe alongs od oe OPC CHIC! GIN ENICIAP” (i) KIFCNG Go)KgIPUCIg) | ar P. 36038] S194 Meee muse daca cney besser en bz ie vay SAQ20. Write notes on vitamins, tarP 742)) SAQ21. Write the importance of carbohydrates. Lar P3843) * “HALO ALKANES & HALO ARENES* SAQ22. Explain SN1 reaction with examples, SAQ23. Explain SN2reaton with examples fear P 39147) SAQ24. Define() Recemic mixture (i) Enaniomers far P 39148)) lar P 40149))* SR.CHEMISTRY BABY BULLET-Q. (AP) * | | Vsagi vsaq2 VSags. ysao Vsags. VsaQe. ysag?, Vsags. VSags. VSAQ IL VSAQ 12, VSAQ EB VSAQ 14. Vsag Is. VSAQ 16. VSAQI7. VSAQ 18, vsaqis. VSAG 20. VSAQ2 VSAQ 22 Vsa 23, VSAQ 24. VsaQ25. VSAQ 26, VSAQ27, VSAQ 10, TOP 50 VSAQ ns-Page + & SOLID STATE [2MARKS] * ** What is Frenkel Defect? ‘What is Schottky Defect? What is interstitial defect? What are E-centres? How do you distinguish between crystal lattice and unit cell? & % ®SOLUTIONS[2MARKS] * * + ELECTRO CHEMISTRY/ CHEMICAL KINETICS[2MARKS] * ** State Faradavs first law of electrolysis? ‘State Faraday's second law of electrolysis, What is a galvanic cell or voltaic cell? Give one example. Define order of a reaction. Give one example. Give two examples for gaseous Zero order reactions, ‘What are pseudo first order reactions? Give one example. ‘& & SURFACE CHEMISTRY[2MARKS]* * & What are micelles? Give one example. What is colledion solution? What is Tyndall effect? ‘What is electrophoresis? What is coagulation? What is Brownian movement? 4 & #P-BLOCK ELEMENTS[2 +2 MARKS] * * * y0a anid vhile HoSie sas? What is ¢ tailing of mercury? How is itremoved? What happens when Clp reacts with dry slaked lime? ‘S09 can be used as an anti-chlor. Explain. [oP 4251) [a P 4252) [oP 42(55)] lar P 43(60)] [oP 43(61)} ar P 43(62)] Ja P 43(63)] far P 43(64)) Io P 44(69)) [oP 44(70)] [oP 447) [oP 44(73)] [oP 45(74)] IP 45(76)} [oP 46(85)) Io P 46(86)) la P 46(87)] [oP 46(88)] Ia P 46(89)) IaP 46(90)] [oP 47091) lo P 47(94)] [oP 47(93)] for P 47095) ta P 47(96)] How is ozone detected?* BABY BULLET-Q(AP) re SR.CHEMISTRY * YSAQ28. List out the uses of neon, | ier sory YSAQ29. Write any two uses of argon, | Lar P ano VSAQ 30. In modern diving apparatus, a mixture of He and O> is used - Why” | be P 4xioay YSAQS1. Explain the structure of Xe03 Lor P 4841009) VSAQ32. How is XeOF4 prepared? Describe its molecular shape. | ba P secon ‘% * #d&f BLOCK ELEMENTS [2 MARKS] & & YSAQ33. Why Zn?* is diamagnetic whereas Mn2* is paramagnetic? fa-P 49104) VSAQ34. Whatis amalloy’ Give example. Le P 491106), VSAQ3S. Whatis Lanthanide contraction? LP Socios) VSAQ36. What is Mischmetal? Give its composition and uses. | bP sociioy YSAQ37. What isa Ligand? Le P saan * * BIOMOLECULES [2 MARKS] & VSAQ 38, ‘What is Zwitter ion? Give an example. tar P StS) VSAQ39. What are amino acids?Give two ‘examples. JarP S116) VSAQ40. Differentiate between globular and fibrous proteins. jarP Sti VSAQ41. What are reducing sugars? | ta P s20120) VSAQ42. What are monosaccharides? tor P 5201225) ‘% *HALO ALKANES & HALO ARENES [2 MARKS] & YSAQ43, — Whatare ambident nucleophiles? far P 84127) VSAQ 44. Whatare Enantiomers? lor P S828) VSAQ4S. Write the structure of the following compounds ( 2-chloro-3-methy| pentane (i)1-Bromo-4sec-butyl-2-methyl benzene bo P S429) VSAQ46. Give the IUPAC names of the following compounds. far P 55130)) @CH-CH(CD-CHLCH3 (ii) CICH2,CH+CH-CHyBr %* * ORGANIC COMPOUNDS C.H.0 [2MARKS} VSAQ47. Give the reagents used for the preparation of phenol from chlorobenzene. for P S433)) YSAQ48. Write the structrues for !)Ethoxy Ethane 2) Ethoxybutane la P S41 VSAQ49. Whats Tollens reagent? Explain its reaction with Aldehydes. lor P 54135) VSAQ 50. Writ the reaction showing a-halogsnation of carboxslic acd and give its name [ar P $4 136)} | |* SR.CHEMISTRY ILLET-Q(AP) * ho] BABY BU! - ‘Ans-Page ** SOLUTIONS * * Pi. Define Molarity. Calculate the molarity ofa solution containing 5 g of NaOH in 450 ml solution. [a P27(17)] P2. Calculate the molarity of a solution containing 5g of NaOH in 500ml of solution. [a P 55(137)] P3. Calculate the molarity ofa solution containing 10 g of NaOH in $00 ml solution. [a P 58(138)) P4. Define Molality. {a P27(18)| Calculate molality(m) of 10gm of Glucose (C gH} 0g) in 90gm of Water. PS. Calculate molality of 25 grams of Ethanoic Acid (CH3 COOH) in 75 grams of Benzene. | {a P 55(139)] Po. Define Mole fraction, JP 2709) Calculate the mole fraction of 11704 in a solution containing 98% HySO4 by mass. P7. Calculate the mole fraction of sodium hydroxide in 10% (w/w) NaOH solution. [a PS8(140)] P8. Calculate the mole fraction of ethylene glycol (C>H0>) ina solution containing [a PS5(141)] 20% of CoHg02 by mass. P9, Calculate the mass of a nonvolatile solute (molar mass 40g mof-!) which should be [ar P28@21)) dissolved in 114g Octane to reduce its vapour pressure to 80%. P10. The vapour pressure of pure benzene at a certain temperature is 0.850 bar. far P 28(22)] Anon-volatile, non-electrolyte solid weighing 0.5 g when added to 39.0 g of benzene (molar mass 78 g mol~!), Vapour pressure of the solution, then, is 0.845 bar. What is the molar mass of the solid substance? ‘* ELECTRO CHEMISTRY * PIL. A first order reaction is found to have a rate constant, k=5.5x10~!45-1 [oP 45(77)] Find the half life of the reaction. P12. A reaction has a life of 10 minutes. Calculate the rate constant for the lo P 45(78)] first order reaction. P13. A solution of CuSO, is electrolysed for 10 minutes with a current of 1.5 amperes. le P 45(79)] ‘What is the mass of copper deposited at the cathode? ‘*d&f BLOCK ELEMENTS * P14, Calculate the magnetic moment of a divalent ion in aqueous solution ifits [eo P50(113)] i 25, atomic number is. (rsa*_BABY BULLET-Q(AP) rr} SR.CHEMISTRY-LAQ * | | YOUR MOST FAVOURITE SECTION AQ SECTION-C ELECTRO CHEMISTRY & CHE.KINETICS (8 Marks) @ — Easy Chapters: P-Block Elements Imp Chapters: Electro Chemistry & Chemical Kinetics*SR.CHEMISTRY-LAQ © Basy cuar State and explain Kohirausch’s law of independent migration of ions. eo 1) Kobirausch law :The limiting molar conductivity (49, ) of an electrolyte is equal to the sum of the limiting molar conductivities of cations (,° ) and anions (,2) of the electrolyte, at infinite dilution. 2) Formula: A° = 22° 3) Fa: For the electrolyte NaCl, we have ASvsc1) = 0 440 Nat Cr IS A KING 'Q" 4) Applications: Kohlrausch’s law is used to calculate the following (i) Limiting molar conductivities ( A°) of weak electrolytes. (i Degree of dissociation (a) of weak electrolytes a = A. An Tick Boxes Co? (Gil) Dissociation constant (K) of weak electrolytes K => What are Galvanic cells? Explain the working of Galvanic cell with a neat sketch taking Daniel cell as example. <<< 1) Galvanic Cell: It is an electro chemical cell which converts chemical energy into electrical energy by redox reactions (Spontaneous). 2) Construction: (i) Daniel Cell consists of two half cells (a)anode half cell (b)cathode half cell. - | (Gi) The two half cells are connected by asalt I} copper bridge containing a saturated solution of KNO3 in agar-agar gel, (iii) The anode half cell consists of zinc rod dipped in ZnSO, solution. (iv) The cathode half cell consists of copper i plate dipped in CuSO, solution. z sar ore 3) Represenation Zr) / Zn”? 4q) // Cu"aq/CX%s) DANIEL CELL 4) Working: When the two half cells are connected externally through a voltmeter, current flows out from the cell due to potential difference. 5) Reactions: Oxidation reaction at anode : Zn = Zn"? + 2e- Reduction reaction at cathode: Cu"? + 2e~ = Cu ) C5) @ RECHARGE © YouR'e'CeELL QwitH'G' CELL Tick Boxes 6) Net cell reaction: Zn, +Cu”%aq) > Z0"%(aq* BABY BULLET-Q(AP) = SR.CHEMISTRY-LAG ® 3 {13 | What is molecularity of a reaction ? How is it different from the order of action ar gaseous reaction. Zn(OH), + (NHq)2SOq (Ammonium sulphate) ii) Ammonia solution on reaction with Copper sulphate gives deep blue complex compound CuSO4(aq) + 4NH3 = [Cu(NH3 )4 SO4(aq) (Tetraaminecopper(I1)Sulphate) ii) Ammonia solution on reaction with Silverchloride gives a complex compound. AgCl +2NH3——>[Ag(NH3)2] Cl white ppt (aq) colourless (#4)SR.CHEMISTRY-LAQ * % BABY BULLET-Q(AP) Fis} 6(a) Howis nitric acid manufactured by Ostwald’s process? Manufacture of Nitric acid by Ostwald’s process © OH! OsTwato! ©sstersa 1) Step-1: Ammonia on oxidation gives Nitric oxide Drips gauze coat ANH g) +5024) EE SO VINO) +6420, | Ea stacES 2) Step-2: NO on oxidation gives NO} Tick 2NO ig) +078) = 2N0 79) — 3) Step-3: NO, on hydrolysis gives dil. HNO 3NO pq) + Hy) — 2HNO 4,4) + NO,y) 4) Concentration of Nitric acid in three stages: EE Boxes (i) Stage 1: The diluted HNO, is concentrated by distillation to give 68% HNO, (ii) Stage 2: 68% HNOy is dehydrated with pure conc. HySO, to give 98% HNO3, (lil) Stage 3: 98% HNO, on cooling in a freezing mixture gives 100% HNO, in crystal form. How does nitric acid react with the following? (i) Copper (ii) Zn (lil) Sy (iv) Py A: — Reactions of Nitric acid: ‘)(a) Copper on oxidation with dil. Nitric acid gives Nitric oxide. 3Cu +8HNO, —>3Cu(NO3)> +2NO+4H,0 id gives Nitrogen dioxide. (b) Copper on oxidation with cone. Nitri Cu+4HNO3—>Cu(NO3)) +2NO) +210 ii) (a) Zine on oxidation with dil. Nitric acid gives NjO 42n+10HNO3 —>42n(NO3)y +5H)0+N30 (b) Zinc on oxidation with conc, Nitric acid gives Nitrogen dioxide Zn+4HNO3; —+Zn(NO3), +2H30+2NO> iii) Sulphur on oxidation with Nitric acid gives Sulphuric acid. Sg + 48HNO; —+8H,S0, + 48NO) +16H;0 iv) Phosphorus on oxidation with Nitric acid gives Phosphoric acid. Py + 20HNO; —s4H3PO, + 20NO, + 4H,0A: BABY BULLET-Q(AP) * (b) How does it react with (1 CH, Gi) KE (iii) Hg. (iv) PbS (9) NO (9D AB (CRE Ozone is prepared when a slow dry stream of pure, cold oxygen is subjected to a silent (a) Preparation of Ozone: electrical discharge in ozonizer. 302 + 203; AH=+142 kJ mol-!, © KEEP OZONE (b) Reactions of Ozone: @©IN SAFE ZONE 1) Ozone reacts with Ethylene to give Ethylene ozonide. ox 0; + CH)=CH, —5 _ 2 Ozone Ethylene oo Ethylene ozonide Tick ii) Ozone oxidises moist Potassium lodide to lodine. CO 03 +2KI+H {0 —32KOH +15 +05 iii) Ozone oxidises Mercury to Mercurous oxide. LJ (This reaction is called as ‘Tailing of Mercury’, ) 0; + 2Hg——+Hg,0+0 Bexes iv) Ozone oxidises black leadsulphide to white leadsulphate. 40, + PbS —+PbSO, +40, JAP 18] Reaction with NO :Ozone oxidises nitric oxide to nitrogen dioxide. NO(g)+03(g)—> NO2(g) + O2(8) vi) Reaction with Ag : Ozone oxidises silver to silver oxide. 2Ag +O; —+Ag,0+0>* BABY BULLET-Q(AP) Pr SR.CHEMISTRY-LAQ * 8. How is chlorine prepared in the laboratory? | omacieccinienes SER | | (i) Cold dil. NaOH (ii) Hot cone. NaOH (iii) Excess NH, | (iv) Slaked lime (v) Hypo( Na,S,0,) @canu © PREPARE ME A: 9 1) Preparation of Chlorine in the laboratory: INVA LAB? Chlorine is prepared in the laboratory by heating a mixture of sodium chloride, manganese dioxide and conc. H,S0,, 4NaCI + 4H2S0, + MnO, + 4NaHSO,+MnCl, + 2H,0 + Cl, M1) Deacon's process: Chlorine is prepared by the Oxidation of hydrogen chloride gas by atmospheric oxygen in the presence of CuCl, catalyst at 723K produces chlorine CuCl, 4HC1+0)—SEe 4 2c, +2130 OrM mp n ©vsaa aso IL) Reactions of Chlorine: i) Chlorine reacts with cold and dilute NaOH to form NaCl and NaOCl. SNaCl + NaClO; +3H,0 fi) Chlorine reacts with excess of ammonia to form Ny <5 3Cly +8NH3 > Ny +6NHCL iv) Chlorine reacts with dry slaked lime to form Bleaching powder. Cl; + Ca(OH), —>Ca0Cl,.H,0 oe slaked lime Bleaching powder. Cl Vv) Cly reacts with Hypo to form Na,SO, Cl; + Nap803 + Hy + NaySO,4+2HCI+S Hypo Boxes ———BABY BULLET-Q(AP) * *SR.CHEMISTRY-LAQ 9. Hows chlorine prepared by electrolytic method? Explain its reaction with (Iron (ii) acidified FeSO, (iii) Iodine (iv) HyS_(v) KI A: 1. Preparation of Chlorine by Electrolytic Method: 2Na° + 2CI 2. Asbestos lining. 3. Brine solution 8) Electrode Reactions: S pHOH sehen collected 5 At anode : 2CH — Cl,+2e Fine inlet 9. Graphite anode At cathode: 2H,0+2e > 20H” +H | * Noneed todraw this in IPE 2Na* + 20H” > 2NaOH II) Reactions of Chlorine: i) Cly reacts with iron to form Ferric chloride. 3C1, + 2Fe > 2FeCls Cly oxidises ferrous sulphate to ferric sulphate in the presence of H2SO,. Cl; + 2FeSO, +H3S0, — Fe2(SO4)3 + 2HCI ili) C/y reacts with iodine in the presence of water to form lodic acid Tick SCI; +1, +6H,0 > 2HIO; +10HCI 1v) Cly reacts with HS to form Sulphur precipitate. LJ} Cl; + HS > 2HCI+S LI ¥) Cl displaces lodine from KI solution. Boxes Cly + 2KI > 2KCI+ Iz*_BABY BULLET-Q(AP) ragt SR.CHEMISTRY-LAQ * 3. ORGANIC CHEMISTRY © BABYCHAT: Maintain Friendly relation with kee, wee 1ed Reactioy They wil} heip'U in IPE. | | | 10. Write the following named reactions with ‘one example for each. (a) Williamson's synthesis (b)Reimer - Tiemann reaction, (c) Carbylamine reaction (4) Kolbe reaction A: | (Williamson's synthesis: Atkyt halides react with sodium alkoxide to give ether AP 15,16,18,19,20 Ex: Methyl iodide reacts with sodium Ethovide to give methovyethane CHgl + C)HsONa—>CH, - O-C3Hg + Nal (b) Reimer- Tiemann reaction; Phenol is treated with CHCI; in the presence of sodium hydroxide to give salicylaldehyde, j a +3KCI+ 3H,0 Aniline Phenyl Isocyanide (@Kolbe Reaction: Sodium salt of phenol is heated with carbon dioxide at 125°C and under 4-6 alm pressure to form Salicyclic acid, < = = BD=dsin6....(iii) «+. from (ii) & (iii), CB+BD = dsin@ + dsin® = 2dsin@ Tick Boxes + from (i), 0’ = 2dsind L This is known as Bragg’s equation. 16. Explain Schottky & Frenkel Defects with structures. P's 15,18] Fo4 f= A: 1) Schottky defect: It is a point defect in which an atom or ion is missing from its normal site in the crystal lattice. 2) Ex: NaCl, CsCl, AgBr etc. 3) Frenkel Defect: It is a point defect in which an atom or ion is displaced, from its normal site to interstitial site 4) Ex: AgCl, AgBr, Zns etc. Frenkel defect ine* BABY BULLET-Q(AP) SR.CHEMISTRY-SAQ * j | © Basy cHat ingle Definition 'n’ one Si roblem gives 'U' 4 Marks | 17. Define Molarity. <4 a Calculate the molarity of a solution containing 5g of NaOH in 450ml of solution. A: Molarity (M): Itis the number of moles of the solute dissolved in one litre of the solution, Tick 1) Given weight of NaOH solute w = 5g f Gur egotseyern ©] [—] 2)GMW of NaOH = 23 + 16 +1 =40 | s00 mt ot wink Taster} L_I 3)Given Volume of the solution V = 450 mL | uJ | } 4) Molarity M =" + , | ) Molar = Vint) AS 486° hee Boxes 18. Define Molality. Calculate molality(m) of 10gm of Glucose (C,H,30,) in 90gm of Water. A: — Molality(m): Itis the number of moles of the solute present in one kilogram (Kg) of the solvent. 1) Given Weight of Glucose w = 10g 2) GMW of CeH;20¢= 180 3) Weight of solvent =90 g 1000 10, 1000 4) Molality m= ——— ___. =x =0617 ) Molality m= Gray Weofsolventingm ~ 180” 90 = 19. Define Mole fraction Calculate the mole fraction of H;SO, in a solution containing 98% H,SO, by mass. A: 1) Mole Fraetion(X): The ratio of the number of moles of one component to the total number of moles of all the components present in the solution is called Mole fraction. No.of moles of one component 2) Mole Fraction X= —-o-* MOS OF one component Totalno.of molesof all the components 3) 98% H)SO, by mass means 98 gm of H2SO, is present in 100gm of solution Mass of solute (H)SO,) = 98 gm No. of moles of H,S0,, a = gg =! 2.1 Mass of H,0 = 2gm No. of moles of H;0, 8 =73="5 1k 4) Mole fraction of H,S0, is Xa = o LABOR Ratna 1+(1/9) Tick Boxes* SR.CHEMISTRY-SAQ BABY BULLET-Q(AP) * 28 20. What is rctative lowering of vapour pressure? How is it useful to determine the molar mass of a sol 1) Lowering of Vapour Pressure(LVP): It is the difference between the vapour pressure of pure solvent (p®) and the vapour pressure of the solution (pS) Thus, Ap = p-ps 2) Relative Lowering of Vapour Pressure(RLVP): Its the ratio between lowering of vapour pressure (p°-ps) and vapour pressure of pure solvent (p°) Thus, RLV 3) According to Raoult’s law, RLVP = mole fraction of the solute 7. ‘Tick Boxes J W.xMy xp? (p?- 4) From the above relation, molar mass of the given solute is Ms = r We |. Calculate the mass of a nonvolatile solute (molar mass 40g mol-!) which should be dissolved in 114g Octane to reduce its vapour pressure to 80%. ea ‘Vapour pressure is reduced to 80% means p°=100, p=80 Weight of Octane solvent is wy 114g, we know GMW of Octane (M,)=114 Given GMW of solute (M,)=40; Weight of solute (w,)=? 100-80 _ws 114 | 100 40 “114 "* 22. The Vapour pressure of pure benzene at a certain temperature is 0.850 bar. A non- volatile, non-electrolyte solid weighing 0.5 g when added to 39.0 g of benzene (molar mass 78 g mol). Vapour pressure of the solution, then, is 0.845 bar, What is the molar mass of the solid substance? ven that p°=0.850bar, pS = 0.845 bar ; Mg = 78 g mol- ; w.=0.5g, Wo = 39g ; M.=" 0.845 _ 0.5x78* BABY BULLET-Q(AP) SR.CHEMISTRY-SAQ * 23. 24, State and explain Nernst equation with the help of a metallic electrode and a non- metallic electrode. 1) Nernst Equation: [tis the equation which gives the relationship between the electrode a half cell reaction, potential (E) and concentration of ions (C) ART jg (Products) 2) Nernst Equation: Electrode potential E = E° lo nF [Reactants} Where E°- tandard reduction potential of the cell at 25°C. n= Number of electrons involved in cell reaction, R= Gas constant 3) For Metal Electrode: B=E° +22 ogc n 4) For Non -metal Electrode: E=E° Give the construction and working ofa standard hydrogen electrode with a neat diagram. 1) Standard hydrogen electrode (SHE): It is a reference electrode used to measure potentials of single half cell electrodes, 2) Potential of this electrode is taken as zero. 3) Construction: SHE consists of a platinum coated foil dipped in IM H* acidic solution. Pure hydrogen gas is bubbled through it at 1 bar pressure. 4) Working: Redox reactions occur at the platinum electrode. SHE acts as anode and Platinum other half cell acts as cathode. 5) Representation: costed Pt,Hacgy Hatm / Hfaq)(C =D : oak 6) Reaction: Hyg) +1e atkBABY BULLET-Q(AP) * COREA amperes. *SR.CHEMISTRY-SAQ 25. (i) State Faraday's first law of electrolysis. (ii)A solution of CuSO, ts electrolysed for 10 minutes with a current of 1.5 What is the mass of copper deposited at the cathode? Ga A: (i) Faraday’s first law of electrolysis: "The mass of element deposited or liberated at the electrode during electrolysis is directly proportional to the quantity of electricity passed through the electrolyte solution”, Thus, m= q (i) Given that t= 10 min= 10 x 60s =600s , current C= 1.5 amperes We know that Atomic weight of Cu = 63.5 Also we have Cu*? + 2e~ — Cu(s). Hence number of electrons n=2 AtwtxCxt _ 63.5x1.5x600 Deposited mass of = = 0.2934 Jeposited mass of copper m=—— a aOEs00 2 26. Derive the integrated rate equation for a zero order reaction. A: 1) Consider a zero order reaction: R> products. 2) Rate = “1B ) = QR] =k = d[R]= — kat & 3) Integrating both sides we get (R] = -Kt +1 .......(1) where I is the constant of integration. 4) Att =0, the concentration of the reactant, R = [RJp, where [Rp is initial concentration of the reactant. $) From (1), [RJp =-k x 0+1 = [RJ =1 6) From (1), we have [R] = -kt + [Rlp =[Rlo-1RI t 7) Hence kt = [RJp- (R] = k 8) This is the integrated equation for 'zero order reaction’. 27. Derive the integrated rate equation for a first order reaction. A: 1) Consider a first order reaction: R-> Products a(R} aR} : 2) Rate = KR)=> TR] ~kdt | 3) Integrating this equation, we get In[R] = -kt + I.....(1), where I is the constant of integration 4) Att =0, [RJ= [R]p where [RJp is the initial concentration of the reactant. 5) From (1) we have In{RJg =-kx 0 +1 = In[RJg =! 6) From (1), we have In{RJ = -kt +In{RJp => In{R] - In{R]Jq = —Kt 7 IR} = 1 plRhr y= 2303 op (Rlo 7) Hence Injgyy = Kt k= - epee 18 Ry 8) This is the integrated rate equation for ‘first order reaction’.* BABY BULLET-Q(AP) = SR.CHEMISTRY-SAQ » 31} ***7. SURFACE CHEMISTRY*** @©pasy CHAT: ADHESIVE O'S FOR SUPER SURFACE PAGES 28, Define adsorption < “4S Discuss the differences between Physical adsorption and Chemical adsorption A: 1) Adsorption: Itis the accumulation of gas or liquid molecules on solid or liquid surface E aints on various surfaces, Corrosion of metals, Adsorption of H2 on charcoal, cal Adsorption Vs Chemical Adsorption: Orn mice Physical adsorption ‘Chemical adsorption “| I) Phy: 1) Itis due to weak vander Waals forces. | 1) It is due to strong chemical bonds. 2) Itisreversible 2) Itisirreversible Vick 3) Itoccurs at low temperature 3) Ttoccurs at high temperature ay 4) It decreases with rise in temperature. | 4) It increases with rise in temperature. | [| 5) Enthalpy of adsorption is low. 5) Enthalpy of adsorption is high. Lt Ex 1: Paints on various surfaces. Ex 1: Corrosion of Metals. Ex 2: Adsorption of H, on charcoal. Ex 2: Adsorption of Hy on Nickel |#°*** 29. How are colloids classified on the basis of interaction between dispersed phase and dispersion medium? (OR) What are lyophilic and lyophobie sols? Compare the two terms in terms of stability and reversib ‘A: On the basis of interaction between dispersed phase and dispersion medium, colloidal sols are divided into two types, namely, lyophilic and lyophobic. 1) Lyophilic colloids: (i) Lyophilic means ‘solvent loving’ (ii) Ex: Water soluble organic substances like starch, gum,rubber with suitable dispersion medium. (iii) Lyophilic sols are highly stable and they do not coagulate easily on addition of electrolytes (iv) Lyophilic sols are reversible sols they can be reconstituted by simply remixing the dispersed phase with the dispersion medium. 2) Lyophobic colloids: (i) Lyophobic means ‘solvent hating’ (ii) Ex: Insoluble metal substances like Gold sol, Metal sulphides and oxides. (ii) Lyophobic sols are not stable and they can easily be coagulated by addition of electrolytes. (iv) Lyophobic sols are irreversable sols. They cannot be reconstituted back after once precipitated by heating or shaking.30. * SR.CHEMISTRY-SAQ P32 BABY BULLET-Q(AP) * oy How are colloids classified on the basis of physical states of components? 4: Classification of colloids based on the physical states of dispersed phase and dispersion medium. | Dispersed | Dispersion | Type of Examples | Phase Medium | Colloid | Solid Solid Solid sol ‘Some coloured glasses and gem stones) | Solid Liquid Sol Paints, cell fluids |_ Solid Gas Aerosol Smoke, dust Liquid Solid Gel Cheese, butter, jellies | Liquid Liquid Emulsion | Milk, hair cream | Liquid Gas Aerosol Fog, mist, cloud, insecticide sprays Gas ‘Solid Solid sol Pumice stone, foam rubber | Gas Liquid Foam Froth, whipped cream, soap lather uM Explain Tyndall Effect and Brownian Movement. (1) Tyndall effect: The scattering of light by colloidal particles is called Tyndall effect’ It is observed during the projection of picture in the cinema halls. It is due to ‘scattering of light’ by dust and smoke particles. ‘Tyndall effect is observed only when the following two conditions are satisfied. i) The diameter of the dispersed particles should be’a little smaller’ than the wavelength of the light. ii) The refractive index of the dispersed phase and the dispersion medium should differ \ greatly in magnitude. 2) Brownian movement; The zig-zag movement of colloidal particles is called Brownian movement. i) It is due to the ‘unbalanced bombardment of the particles by the molecules of the dispersion medium.. irring effect’ which is responsible for the stability ii) Ithas a of sols.* BABY BULLET-Q(AP) SR.CHEMISTRY-SAQ « 32. (I) How are XeF; . XeF,, XeF, prepared? (UD Give the structures of XeF;, XeFy, NeFy. (IID Explain the reaction of the above with water 1) Preparation : 1) Preparation of XeF: A mixture of Xenon and Fluorine is heated in the molar ratio of 2:1 to form XeF > 673K. I bar Keegy + Fag) Xe 2) Preparation of XeF : A mixture of Xenon and Fluorine is heated in the molar ratio of 1:5 to form XeFy 873K,7 bar Xe (gy + 2Fa¢g) —— > Xe) 3) Preparation of XeF, : Xenon and fluorine (1:20 ratio) reacts at 73K, 60-70 bar gives XeF¢. Xe ig) + 3Fayg) SOTO xe, M1) Structures: (1) Structure of XeF: ’) In XeFp, the central atom Xe undergoes sp}d hybridisation and forms five spd hybrid orbitals. ji) It forms two o bonds with two fluorine atoms = ii) It has two bond pairs and three lone pair. QD iv) As per VSEPR theory, the shape of XeF- is linear. © (2) Structure of XeFy: i) In XeF,, the central atom Xe undergoes spd? hybridisation and forms six sp3d2 hybrid orbitals. ii) It forms four 6 bonds with four fluorine atoms. i) It has four bond pair and two lone pairs. iv) As per VSEPR theory, the shape of XeF, is square planar. (3) Structure of XeF,: i) In XeFg, the central atom Xe undergoes sp3d° hybridisation and forms seven sp? hybrid orbitals. ii) It forms six 6 bonds with six fluorine atoms ii) It has six bond pairs and one lone pair, iv) As per VSEPR theory, the shape of XeF is distorted octahedral 111) Reactions with water: 1) 2XeFy¢g) + 2H30,1) —92Xe() + 4HF, ag) + On¢g) 2) 6XeF, +12H{0—+4Xe + 2XeO, + 24HF +30, 3) Xe +3H,0—>Xe0; + 6HF* SR.CHEMISTRY-SAQ fae] BABY BULLET-Q(AP) * 33. (a) How are XeO, and XeOF, prepared? ) in our bodye }43 ‘ rm a A Write the importance of carbohydrates. 1) Carbohydrates are essential for the life of both plants and animals. 2) Fx: Honey, Starch, Cellulose. 3) Honey is an instant source of energy. 4) Starch in seen in plants and glycogen is in animals 5) Cell walls of bacteria and plant are made up of ‘cellulose’. 6) Wood and cotton fibre contain cellulose. 7) “Streptomycin” is a carbohydrate antibiotic. 8) Anticarcinogenic carbohydrates are synthesised to fight against cancer. Explain the denaturation of proteins. 1) Denaturation: The loss of Biological activity of proteins is known as Denaturation of proteins. 2) It is due to breaking of Hydrogen bonds in 2° and 3° structure. 3) It is carried out by the change in pH (ot) by addition of chemicals. 4) Ex: Curdling of milk, coagulation of egg by boiling. What are enzymes? Give examples. 1) Emzymes: These are ‘simple or conjugated proteins’ that catalyse biochemical reactions. 2) The action of enzymes is highly specific. 3) They exhibit maximum efficienty at an optimum pH (5-7) and temperature (298-310K) . 4) The non-protein part associated with enzymes is known as Co-enzyme (or) Co-factor. 5) Ex: Maltase = Maltose Glucose; Pepsin = Proteins Peptides. Write notes on amino acids. 1) Amine acids: Amino acids are biomolecules which contain Amino (1 NH) eas carboxylic acid group (COOH) at a-carbon 2) Ex: @ Glycine HN-CH,-COOH CH3 1 @ Alanine H,N~-CH-COOH 45) Essential Amino acids: Amino acids which cannot be synthesised in the body and must be taken in diet are called essential amino acids. Ex: Valine, leucine, phenylalanine etc., 4) Non Essential Amino acids: Amino acids which can be synthesised in the body are known as non-essential amino acids.* BABY BULLET-Q(AP) Cri SR.CHEMISTRY-SAQ + P x 11, HALO ALKANES & HALO ARENES** 47. SN! reaction. A: SN1 reaction: < 2°> 1° 4) Rate of reaction of SN! depends on concentration of reactants only. 5) SN! mechanism takes place in two steps. 5 ‘Transition state 6) Ex: 2-Bromo octane undergoes hydrolysis to form octane-2-ol Mechanism: Step 1: Formation of Carbocation. { swtasn2 | cH, - 1 ecth are Bonn i Slow ' 3 Da Cae a Sepi Bre | CH, H3€ ‘cH; Step 2: Formation of product by the attack of Nucleophile | ic CH; CH; 1 1 m St + on BS. Ho-c-cH, +CH3-C- OH ‘ i H3C CH; CH; CH; | 48. Explain SN? reaction. a Retention P product product | A: SN? reaction: Tick | 1) Order of SN? reaction is two. — 2) SN? is a bimolecular substitution reaction’. eat 3) Order of reactivity of alkyl halides towards SN? : 1°>2° > 3° fo] 4) Rate of reaction of SN? depends on concentration of reactants and nucleophile. —! : a 5) SN? mechanism takes place in one step. { 6) Bx: 2-Bromo butane undergoes hydrolysis in aqueous KOH to form 2-butanol, L_! Mechanism: paca CoHs Slow C- Br + OH . — fe, Ho | DO Step WAN Step ; H CH; H CH, |* SR.CHEMISTRY-SAQ ae BABY BULLET-Q(AP) * | 49. . Explain the Grignard reagents preparation and application with suitable example? Define the following (i) Racemic mixture (ii) Retention of configuration (ili) Enantiomers i) Racemic mixture: The mixture of equimolar quantities of d-form & /-form is known as Racemic mixture. It is optically inactive due to external compensation. A racemic mixture is represented by prefixing d! (or) (+) before the name. Ex: () butan-2-ol. ii) Retention of configuration: The preservation of the spacial arrangement of bonds around an assymetric centre during a chemical reaction (or) transformation is called retention of configuration. Ex: When (-)-2-methyl butan-1-ol heated with concentrated hydrochloric acid, (+}1-chloro-2-methy! butane is formed. iii) Enantiomers: Stereoisomers which are non superimposable mirror image to each other are known as enantiomers (or) enantiomorphs. The enantiomers are also called optical isomers. They are described as d-(or) (+and /-(or) (-) ‘Alkyl magnesium halide is called is Grignard Reagent. Its general formulae is RMgX. It is an important class of organometallic compound. It was discovered by Victor Grignard in 1900. Preparation: 1) Grignard reagents are obtiained by the reaction of haloalkanes with magnesium metal in dry ether. CH, ~CH, ~ Br+Mg—S24CH, - CH»MgBr Grignard reagent 2) Bromo and iodoarenes react with magnesium powder in the presence of dry ether to form aryl magnesium halides (Grignard's reagent) Bromobenzene Phenyl magnesium bromide Applications: 1) Grignard reagents are highly reactive and they react with any source of proton (like water, alcohols, amines...) to give hydrocarbons. RMgX + H;0 —>RH + Mg(OH)X 2) CO, on reaction with RMgX followed by hydrolysis gives carboxylic acids. O=C=O0+RMgX > R -COOMgX R-coomMgx—12° , COOH + Me(OH)X 3) Aldehydes on reaction with RMgX followed by hydrolysis gives 2" alcohols. H -OH+Mg(OH)X* BABY BULLET-Q(Ap) pT ULETOIAR) - | SOLID STATE. . | SOLUTIONS . | P BLOCK ELEMENTS .| BIOMOLECULES _VSAQ _ SECTION-A VERY EASY & CUTE SECTION WITH TINY MANY ANSWERS } [ELECTRO & CHEM. KINETICS . SURFACE CHEMISTRY -| dat BLOCK ELEMENTS HALO ALKANES & HALO ARENES . | ORGANIC COMPOUNDS C,H,0 (2 Marks) 6s _ (Marks) (Marks) “@ Marks) 46 (2+2Marks) | 47-48 ‘(2Marks) 2 "(2 Marks) (2Marks) (2 Marks) @ Easy Chapters: Solid State, Solutions, Surface Chemistry, d & t block Elements Imp Chapters: Electro & Chemical Kinetics, P-Block Elements an SR.CHEMISTRY.VSAQ *=e * SR.CHEMISTRY-VSAQ fay BABY BULLET-Q(AP) * 56. 57. 53. |. What are F-centres? . How do you distinguish between crystal lattice and unit cell? What ***12. SOLID STATE” ** (__2Marks _) What is Frenkel Defect? 1) Frenkel Defect: Itis a point defect in which an atom or ion is displaced, from its normal site to interstitial site 2) Ex; AgCl, AgBr, Zns etc. What is Schottky Defect? 1) Schottky defect: It is a point defect in which an atom or ion is missing from its normal site in the crystal lattice. 2) Ex: NaCl, CsCl, AgBr ete. What is interstitial defect? Interstitial defect: It is the defect when some constituent particles (atoms or molecules) ‘occupy an interstitial site within the crystal . F-centres are the anionic vacancies occupied by unpaired electrons in crystals. 1) Crystal Lattice: It is the regular and repeated arrangement of constitutional particles and patterns of the crystals. Altogether there are14 types of Bravias lattices. 2) Unit Lattice: It is the smallest unit portion of a crystal lattice which represents & repeats the entire crystal. Altogether they are 7 primitive unit cells and 3 centered unit cells. Why X-rays are needed to probe the crystal structure. The wavelength of X-rays is 10-!°m which is comparable to the spacing between the lines or points in the crystal . That is why it is used to probe the crystal structure . What is meant by the term coordination number? 1) Coordination number of an atom is the number of nearest neighbours [atoms (or) ions] that a central atom holds in the unit cell of the crystal. 2) Ex: Coordination number of Na‘ in NaCl is 6. What is the coordination number of atoms in a cubic close pack structure? Coordination number of an atom in ‘cubic close pack’ structure(ccp) is 12. is the coordination number of atoms in a body centered cubic structure? Coordination number of an atom in ‘body centered cubic’ structure (bec) is 5.* BABY BULLET-Q(AP) = 60. . State Henry's law. ea 62. 64. . What are colligative properties? Give any one. qe - Define Elevation of boiling point. |. What is Ebullioscopic constant? . What is Cryoscopic constant? State Raoult's law. <— Raouit's la The Relative Lowering of Vapour Pressure of a dilute solution containing 'non- volatile solute’ is equal to ‘mole fraction(X)of the solute’. 1) Henry's law: The partial pressure of the gas in vapour phase is directly proportional to the mole fraction(X) of the gas in the solution 2) Thus, po X = p=KyX Define Osmotic Pressure Osmotic pressure: The extra pressure applied on a solution just to prevent osmosis is called ‘osmotic pressure, What are isotonic solutions ? BTS 16,19 BAP 17,19 | 1) Isotonie solutions: These are the solutions having the same osmotic pressure at a given temperature . 2) Ex: Blood is isotonic with saline . What is relative lowering of vapour pressure ? qo Relative Lowering of Vapour Pressure(RLVP): It is the ratio between lowering of vapour Po_p Pressure (P°-PS) and vapour pressure of pure solvent (P°), Thus, R-L.V.P = P ative properties: These are properties of dilute solutions which depend on number of non-volatile solute particles present in the solution. 2) Ex: i) RLVP of a solution ii) Osmotic pressure(r) Elevation of Bolling point(AT,): Itis the difference in boiling point of solution T,(s) and the boiling point of pure solvent T,(0) . Thus, AT,= Ty(s)-Ty(0) Ebullioscopic constant (K,): It is the elevation in boilin; #8 point observed when one mole of non-volatile solute is dissolved in 1kg of'solvent. Ceyoscople constant (Kq) : It is the depression in the freezing point observed when one mole of non-volatile solute is dissolved in 1kg of solvent,* SR.CHEMISTRY-VSAQ far }— 70. BABY BULLET-Q(AP) * roblems Page is Page is SP and ofcourse next page is What is electrolysis? Give "s first law of electrolysis. COREE 2NO2ig) Here, the rate expression is; rate=k{NOP{Q2]'. So the order of the reaction is 2+1 = 3.74, mm 78. n. * BABY BULLET-Q(AP) Sol: Sol: SR.CHEMISTRY-VSAQ * Give two examples for zero Order reactions. Ex 1:Hy +Cl—™ 42HC1; rate = K{H]° [Ch]? EB Ex 2:2HI—8 i, +1, 3 Tate = k{HI]® Give two examples for gaseous first order reactions. Ex 1:2N20s(g) > 2N,04(g) + O7(g); Ex 2:CpH4(g)+H 9(g) > CoH (g) What are pseudo first order reactions? Give one example. 1) Pseudo first order reactions: It is a reaction which is not truly of first order but under certain conditions becomes a first order reaction 2) Ex: Inversion of cane sugar is a bimolecular reaction but it is a first order reaction when concentration of HO is large. 0), +0 + a Cal 041+ HOF C40 CoHi26 rate = K{C3H330)1) A first order reaction is found to have a rate constant, life of the reaction. 1) Given rate constant k=5.5x10-!4s-!, a Sx10-Ms-1, Find the half 3 69: 2) Half-life for a first order reaction is ty2 =——— = KE S5xig yt eons A reaction has a halflife of 10 minutes. Calculate the rate constant for the first order reaction. 1) Given half life ty =10 min, Zn2*(aq) + Cus) F=96500, E24 =1.1V CaOCl, + HzO 94, What is tailing of mercury? How is it removed? ‘When ozone gas is passed through liquid mercury, the mercury loses its ‘meniscus nature and sticks to the glass surface. This is called tailing of mercury. 2) Itis removed by ‘shaking with water. A: 1) Tailing of merc 3)Reaction: 0; + 2Hg > Hg,0 + 0 95. SO, can be used as an an -chlor. Explain. A: 1) SO removes excess of chlorine. So, SO, is used as an anti-chlor, 2). It reduces Cl, to HCI. Cl+80z#2H;0-32HCI+HS04 96. How is ozone detected? A: Detection of Ozone: 1)Ozone turns starch iodide paper into blue colour. 2)In the presence of Os,mercury loses meniscus and stats sticking to glass. 3)ltturns alcoholic solution of benzidine to brown colour 2a gree* SR.CHEMISTRY-VSAQ 97, 98. 99, & 100. BABY BULLET-Q(AP) + fot our the vsee of uean, [Cu(NH3)4) SOx (blue) (deep blue) lectrons. So it is a lewis base and acts* BABY BULLET-Q(AP) fer} SR.CHEMISTRY STAR Q PLus * 148. What happens when white phosphorus is heated with conc. NaOH solution in an inert atmosphere of CO,? 1) White phosphorus when heated with cone.NaOH solution in an inert atmosphere of CO, Phosphine gas is liberated. 2) Py + 3NaOH +3H{0—+3NaHyPO, +PH;T 149. Give the hybridization of sulphur in the following: (a) SO, (b) SO, (c) SFy (d) SF, At (a) SO2~ sp? (b) $05 ~ sp? (c) SFy—sp3d (d) SF¢ ~ sp3d2 150. . What happens when Cl, reacts with dry slaked lime? 1) When Chlorine reacts with dry slaked lime ‘bleaching powder’ is obtained. 2) Ca(OH); + Cl, > Ca0Cl, + H,0 151. Write the reactions of F, and Cl, with water. AL 1)F2 oxidises HO to 0, and 3, 2Fa¢g) + 220) —> 4 Fag) + O76) 5 3F2¢g) + 3H20) —> 6H Fag) + Ox) 2) Cl reacts with HO to form hydrochloric acid and hypochlorous acid. Claeg) + Hp) —> HCl aq) + HOCKag) 152. Howis chlorine manufactured by Deacon's method? 1) Deacon's process: Hydrogen chloride gas reacts with atmospheric oxygen in the presence of CuCl, catalyst at 723K to form Chlorine. 2) 4HCL+0, SSE 5 21) +2H,0 153. What are interhalogen compounds? Give two examples. A I) Interhalogen compounds:These are the compounds formed when halogens combine themselves. They are four types: AX, AX, AX and AX;, where A is heavier halogen, 2) Ex: IF, CIF3. 154. Write the structure of the following compounds (a) 2-chloro-3-methyl pentane (b) p-bromo chloro benzene CH 1 (a) CHy-CH- CH-CH,~CH; —_(b) &—-a a*SR.CHEMISTRY STAR Q PLUS BABY BULLET-Q(AP) * Treatment of alkyihalides with ag. KOH leads to the formation of alcohols. While in | 185. presence of alc. KOH what products are formed? a : — when treated with aq.KOH form alcohols. e Alky puagel when treated with ale.KOH form Ethane, Water and KCI. 3) CyHsCl+ KOH (ale) + CyHy +H 0+KCI 156. Define Recemic mixture | A: 1) Recemic mixture: Tisis the miu formed by mixing equimolar {quantities of d- & /- isomers 2) Ex (2) butan 2 - ol. 157, Arrange the following in decreasing order of their basic ‘strength: CHeNHy, C;HeNH. (CH); NH, CgHsNHCH3 A: 1) Decreasing order: CgHsNH) > CsHsNHCH3 > C)HsNH2 > (C2Hs)2NH 2) P&® values: 9.38 9.30 3.29 3.00 NTS 158. Which oxides of sulphur can act as both oxidizing and reducing agent? Give one example each. A: SQ, acts as both oxidising and reducing agent. 1) $0, acts as a good reducing in presence of moisture Cl; +802 +2H,0 —>2HCI + HS0, 2Fe*? + SO +2H;0—>2Fe™? +8077 +4H* 2) $0» also acts asa mild oxidising agent particularly when it reacts with strong reducing agents. 2HyS+SO)—+2H20+ 3S 2SnCl; +SO> + 4HCI—> 2SnCl, +2H20+S BIOMOLECULES 159. Define the following ss related to proteins. (i) Peptide tinkage (ii) Primary structure (ii) Denaturation, A: 1) Peptide linkage: It is an amide linkage formed between COOH group and -NHp group. When carboxylic group of one amino acid reacts with the amino group of the other, a water molecule is eliminated and peptide linkage is formed. H,N-CH, ~COOH + H,N- CH-COOH #20, HyN ~CH, ~[CO=NH]- CH-COOH t cuts fnlage CH Giyeylalanine (Gly-Ala) li) Primary structure: The sequence of amino acids in @ polypeptide chain of a protein is known as Primary structure. Any change in the primary structure creates different protein. iii benaturation: The loss in biological activity of proteins by breaking of H- bonds in 2° and 3° Structures is known as denaturation of proteins. It is duc (0 physical change (temperature,pH Changes) (or) Chemical change (by addition of chemicals) . Ex: Coagulation of egg by boiling and curdling of milk* BABY BULLET-Q(AP) CHEMISTRY STAR Q PLUS * —[}—_8 e d & f BLOCK ELEMENTS 160. Explain the structures of the following using Werner's Theory.: (0) CoCh.6NHy (ii) CoCly.SNHy (ii) CoC. ANH, fiv) CoCh.INHy At i) CoCh.6NHy = Co(NH. ICo(NHy),C/, et 2 Inthe above complex ,Co has co-ordination number 6. Six neutral ‘ Fa = ‘NH, molecules satisfy secondary valencies. The Ci ions satisfy ZAN Primary valencies and they ionise in water giving 3CI ions. = cm be. fi) CoCls.SNH3 : [Co(NH)=3175, m=? anti-chlor. 2) Itreduces Cl to HCL Eat__ 31.751 511060. 92934 Cly+80312H20-V2HCI+H$0 2) We know m= oythe wees of Neon A: Uses of Neon: V)Neon is used in discharge tubes, fluorescent Bills, voltage regulators and indicators 2) Neon bulbs are used i Pla in botanical gardens and in green Write any wo uses of argon, Uses of Argon: 1)Argon is used mainly to provi nly to provide a jtmosphee fring eesti bubs tis used in the laboratory for handlin substances, cae 3) Argon is used in radio valves and rec Write the structure of Xe03 «1 Structure of XeOx: Im XeO3 Xenon undergoes sp} sp hybridisation Y 2) So, it has Tetrahedral or O Pyramidal structure with one Position occupied by lone pair of electrons. inert Q7: d&t BLOCK ELEMENTS: + _ Scandium is a transition element,but zinc is not. Why? A: 1) Electronic configuration of Se is [Ar]3d!4s2. It contains incompletely filled’ (n-1}d subshells. So, itis a transition element. 2) Electronic configuration of Zn is [Ar]3d!04s2 It contains ‘completely filled (n-1}d subshels So, itis nota transition element. + Why Zn2* is diamagnetic whereas Mn?* is paramagnetic? 1) Electronic configuration of Zn*2is{Ar] 4503410 Ithas paired d electrons. So its diamagnetic 2) Electronic configuration of Mn is [Ar|4s0345 thas five unpaired electrons. So it is paramagnetic. + What is lanthanide contraction? : Lanthanide Contraction: It isthe steady decrease in the atomic and ionic radi with inerease in atom numbers from Lanthanum to Lutetium, ive its composition and uses. 1) Mischmetal: It isan alloy of Lanthanide metal. 2) Itcontains 95% Lanthanide metal and 5% iron and traces of S,C,Caand Al 3) It is used in bullets & shells + What isa ligand ? 1) Ligand: [tis a molecule or ion which donates a pair of electrons to central metal atom to form a coordinate covalent bond 2) Bx: Hy, NH3, C- Q8: BIOMOLECULES: + What is Zwitter ‘As 1) Zwitter ion: Its. ‘dipolar neutral ion’ containing negative and positive charges. 2) ExeFree amino acids in cells 3) In Amino acids, proton transfer takes place from {COOH group to NH2 group. This results in the formation of Zwiter ion. STRY-BULLET MODEL PAPER * + What are anting acids?Give two exampl As 1) Amino acids are biomolecules which contain Amino (CNH) group and a carboxylic acid group (COOH) at a-carbon 2) Example: i)Glycine HyN-CH-COOH cHy i ii)Alanine . H)N-CH-COOH What are Proteins? Give an example. 1) Proteins: These are the biopolymers of high molecular ‘weight (10,000u) composed of amino acids linked by peptide bonds, They are made of Camino acids 2) Fx:Keratin in hair. ‘+ What are monosaccharides? 1) A carbohydrate that cannot be further hydrolysed is called monosaccharide. 2) Some common example: Glucose, fructose, ribose Q9: HALO ALKANES & HALO ARENE! ‘+ What are ambident nucleophiles? |A: 1) Ambident nucleophiles‘These are the nucleophiles with to donor atoms. 2) Ex Cyanide ion, Nitrite ion + What are Enantiomers? 1) Enantiomers:These are a pir of stereoisomers which {are mirror images to each other. These are ‘non-super imposable’ compounds 2)Ex: dLactic acid & LLactc acid the IUPAC names of the following compounds, CHy-CH(C)-C1 ORGANIC COMPOUNDS OF C,H,O: + Give the reagents used for the preparation of pheno! from chlorobenzene. Phenol can be obtained by heating chlorobenzene in the presence of a catalyst, with 10% NaOH solution and HCI at 350°C under 200-300 atm pressure Ns + Write the structra |)Ethoyy Ethane 2) Ethoxybutane 3) Phenoxyethane 1)pHs ~ O-CoHs 2) CpHs ~ O~CHy ~ CHy ~ CH) ~ CH 3)CGHs - 0 ~ Cots [+ Whats Tllen’s reagent? Explain its reaction with Aldehyde A: 1) Tollen’s reagent?Ammonical silver nitrate solution’ is called Tollen’s reagent, Ws formula is |Ag(NH)2 1" OH 2)When Toller’s reagent is boiled with aldehyde, it gets reduced to metallic silver. | This metallic silver gets deposited on the inner wall of the test tube to form a silver mirror.al SOLID STATE: Derive Brage’s equation. Ac 1) Suppose two X-rays of wavelength A are incideat on rw parallel planes of a crystal 3)First x-ray is diffracted from point ‘A’ in the first plane. Second ray is diffracted from ‘B' in the second plane. ‘Here, the second X-ray travels some extra distance than the first X-ray. ‘The extra distance (path difference) travelled by the second X-ray= CB+BD 5) When two waves undergo constructive interference then according to Bragg, the path difference must be an integral multiple of the wave lengtb(2). Helt oe 123... is known as order of diffraction. ©) IG we the angle of incidence and be the distance between the parallel planes then from ABC, Sin! In ABD, sin| => BD=dsind (iil) from (i) & (iii), CB+BD = dsin® + dsin® = 2dsin® ‘This ts known as Bragg’s equation. Explain Schottky & Frenkel Defects with structures, A: 1) Schottcy deflect: It is a point defect in which an atom ‘or ion is missing from its normal site i the crystal lattice. 2) Ex: NaCl, CsCl, AgBr etc 3) Frenkel Defect: iti a point defect in which an atom ‘or ton is displaced. from its normal site to interstitial site 4) Ex: AgCl, AgB, Zns etc. Q12: SOLUTIONS: + Define Molarity. Calculate the molarity of « solution coutniniag $2 of NsOH in 450m of solution. A: Molarity (M): It is the mumber of moles of the solute dissolved in one litre of the solution. 1) Given weight of NaOH solute w = 5g 2)GMW of NaOH = 23 + 16+ 1 = 40 3)Given Volume of the solution V = 450 mL. Joss 4) Mott te ne, = Sent + Define Mota Calculate molality of 10gm of Glucose (CgHj206) in 9gm of Water. 1s the number of moles of the solute present 078M BABY BULLET-Q(AP) * 1) Given Weight of Glucose w = 10g 2) GMW of CgH;20¢= 180 3) Weight of solvent =90 x 1000 __ 10,10 gm Ganw” Watering "100" 9 4) Mota Q13; ELECTRO CHEM&CHEM.KINETICS: + State and explain Nernst equation with the help of 4 metalic electrode and a non- metallic electrode. A: 1) Nernst Equation: It is the equation which gives the relationship between the electrode potential (E) and concentration of ions (c) in a half cell reaction. 2) Nerast Equation: Exe pol ena? 23080 Peo ‘Where E% Standard reduction potential ofthe se a 33 t= Number of electons involved in cel reaction, I Ges constant, 3) For Metal Electrode: E=E° +logC 0.059 0.059 exg-26 State Faraday’s first law of electrolysis A solution of CuSO4 is electrolysed for 10 minutes with a current of 1S amperes, What is the of copper deposited at the cathode? 's first law of electrolysis: "The mass of clement deposited or liberated atthe electrode during electrolysis is directly proportional to the quantity of electricity passed through the electrolyte solution”. Thus, me i) Given that 10 min=10%605~600s, current C=1.5 amperes We know that Atomic weight of Cu~ 63.5 Also we have Cu"? + 2e~ > Cu(s). Hence numberof electrons n=2 Deposited mass of copper 4) For Non -metal Electrode: log Q14: SURFACE CHEMISTRY: + Define advorption.Discuss the differences between Physieal adsorption and Chemica A: 1)Adsorptioa: Itis the accumulation of gas or liquid molecules on solid or liquid surface. 2) Physical adsorption: (itis due to weak vander Waals forces. Q)it is reversible (3) occurs at low temperature (G4) It decreases with rise in temperature (S)Enthalpy of adsorption is low. Paints on various surfaces. smical adsorption: (I)Itis due to strong chemical bonds (2)t is ireversible (3) It occurs at high ‘temperature(4) It increases with rise in temperature. (5) Enthalpy of adsorption is high. Ex: Corrosion of Metals »Q * BABY BULLET-Q(AP) Explain Tyndall Effect and Brownian Movement. ‘A: (1) Tyndall effect: The scattering of light by colloidal « particles is called "Tyndall effect. Itis observed during the projection of picture in the cinema halls Itis due to'scatterin of light by dust and smoke particles. Tyndall effect is observed only when the following two ‘conditions are satisfied. i) The diameter ofthe dispersed particles should be'a litle smaller than the wavelength of the light ii) The refractive index ofthe dispersed phase and the dispersion medium should differ greatly in magnitude 2)Brownfan movement: The zig-zag movement of colloidal particles i called Brownian movement. 1) It is due to the ‘unbalanced bombardment of the particles’ by the molecules ofthe dispersion medium. ii) It has a ‘stirring effect’ which is responsible for the stability of sols. 15: p-BLOCK ELEMENTS(G17, 18): (a) How are XeF2 and XeF prepared? (b) Give the structures of XeF and XeF y (c) Explain the reaction of following with water (i) NeFz (il) XeFg (ili) NeFe a) Preparation : 1) Preparation of XeF 2: Amixture of Xenon and Fluorine is heated in the molar ratio of 2:1 to form XeF. 673K, 1 bar Xe(g) + Fig) —— Xe) 2) Preparation of XeF 4: Amixture of Xenon and Fluorine is heated in the molar ratio of 1:5 to form XeF y 73K. 7 bar Xe) + 2g) Kes) by Structures: 1) Structure of XeFy: (in XeF>, the central atom Xe undergoes sp'd hybridisation to form five sp°d hybrid orbitals. 3) It forms two 6 bonds with two fluorine atoms ii) t contains two bond pairs andthree lone pairs {ivy According VSEPR theo, sap of Neier (9). So.the bond angle is 199" 2) Seructure of NeF Gin XeFg, the central atom Xe undergoes sp hybridisation to formsix sp*d2 hybrid orbitals 3) tt forms four & bonds with four Noorine atoms. tt contains four bond pairs and two lone pais, WpAccording 19 VSEPR theory. the shape of XeF is square planar (6) So, the Bond angle is 90°. 6) Reactions with water: 1), 2XeFys) +2H20y — Xe) + 4HFiay) + Org) Ii) 6XeFy +12H;0—?4Xe + 2XeOy + 24HF +30, 3q2 Ail) Xe +3H;O0—>XeO, + 6HF SR.CHEMISTRY-BULLET MODEL PAPER * Q16: d&t-BLOCK ELEMENTS: Explain Werner's theory of coordination compounds ‘ith suitable examples. 1) Werner’s theory "This theory explains the structures, ‘of ‘coordination compounds’ Inco-ordination compounds the central metal atom shows, two types of valencies, 2) Primary valency.) Secondary valency 2)Primary Valency 1) Itis equal to the oxidation numberof the central atom, i) Itis satisfied only by the negative ions. ) 1 is fonisable iv) 1s non-rctional and iis represented by dete fines 3)Secondary Valency: {tis equa tothe co-ordination numberof the central tom ji) Itis satisfied by negative ions, neutral molecues and rarely by positive ions. ii) Te is non-ionisable ix) Itis directional andi is represented by solid lines. I exhibits isomerism 4) Ex; Hexaarmine cobalt I} chionde-{CofNH)g)CI3 A: D Here, primey wacy CO gy iemitedty scree | ONIZ ipSecondary valeny of Cols 6 ae It is satisfied by 6 NH3 molecules. | “La i) Shape ofcomplexs Ocahedal.”(Co(NHy IC Q17: BIOMOLECULE:! + Name the sources and diseases caused by the deficiency of the vitamins(a) A (b) D (c) E (4) K A: D)Vitamin A: (OFish liveroil, carrots,butter and milk, (Gi) Xerophthalmia, Night blindness 2)Vitamin D: (Exposure o Sunlight fish and egg yolk (G)Rickets,osteo-malacia 3)Vitamin E: (i) Wheat germ oil, Sunflower oil, et. (Gi) Muscular weakness. (Green leafy vegetabies i) Increased blood clotting time. : HALOALKANES & HALO ARENES: + Explain SN! and SN? reactions. As SNF reactions: 1) Order of SN! reaction is one. 2) SN! is a unimolecular substitution reaction 3) Order of reactivity of alkyl halide :3°>2"> 1° 4) Rate of reaction of SN‘ depends on concentration of, reactants only 5) SN! mechanism takes place in two steps Ex: 2-Bromo octane undergoes hydrolysis to give octane2-01 SN? reactions: 1) Order of SN? reaction is two. 2) SN? isa bimolecular substitution reaction. 3) Order of reactivity of alky! halide :1°>2*>3° 4) Rate of reaction of SN? depends on concentration of reactants and nucleophile 5) SN? mecahnism takes place in one stp. Ex: 2-Bromo butane undergoes hydrolysis in aqueous KOH to form 2-butanol4 SR.CHEMISTRY-BULLET MODEL PAPER Q19: CHEMICAL KINETICS & ELECTRO CHEMISTRY: + State and explain Koblrausch’s law of independent migration of ions. A: 1) Koblrausch law: The limiting molar conductivity ( 4°.) ofan electrolyte is equal to sum of the individual molar conductivities of the cations( 23 ) and anions( Ag) of the electrolyte. 2) Thus, AQ, =29(cations) + 4° anions) 3) Applications: This law helps in the calculation of () molar conductivity( 42.) of weak electrolytes Gi) degree of dissociation a = 2 dissociation constant ¥8r weak electrolytes ca K, + What is molecatarity of a reaction ? How is it different from the order of reaction? Name one bimolecular and one trimolecular gaseous reaction A: 1)Molecularity:The ‘number of atoms, ions or molecules’ ‘participating in the ‘rate determiningstep’ of a chemical reaction is called molecularity of that reaction. 2) Order of @ reaction: The ‘sum of powers of ‘concentration terms’ of the reactant inthe ‘rate equation’ iscalled order of reaction. 3) Differences between Molecularity and Order Molecolarity: ') tis determined theoretically. ijl can have integral values only. ii) Itcan be unimolecular.bimolecular. iv) It is applicable only to elementary reactions. Order: i) Its determined experimentally. iit can have fractional values also. i) Ian be zero order, first order.. iv) It is applicable to elementary and complex reactions. 4) Bimolecular reaction: Dissociation of hydrogen iodide into H and 17 2HI Hy + Ip 5) Trimolecular reaction: Formation of NO2 from NO and 0» 2NO+07 92NO7 ee 020: p-BLOCK ELEMENTS: + How is ammonia manufactured by Haber's process? ‘A; Manufactare of Ammonia by Haber's process 1) Formation of Ammonia: Np and Ha are synthesized directly in the ratio 1:3 to produce NH3, No(g)+ 3H (g) = 2NH3(g); SH = 92.310 2) The above reaction is reversible, exothermic and it leads toa decrease in volume 3)So, Le-Chatelier principle is applicable. 4) Effect of Temperature: As the reaction is exothermic, low temperature is favoured. BABY BULLET-Q(AP) * 's)Effect of Pressure: As the reaction leads to decrease in volume, high pressure is favoured. {6)Optimum Conditions (a) Low Temperature : 725-775 (6) High Pressure: 200-300 atm (6) High concentrations: Pure Nz and Hi. *7)Catalyst : Finely divided iron; Promoter : Mo 8)Process: {) Mixture of Np and H is passed through the compres- sor at 300atm pressure i) It is then sent to catalyst chamber at SO0°C in the presence of iron catalyst. ili) Liqufied ammonia is collected at the receiver and ‘unreacted No and H is sent to pump. How isnitric acid manufactured by Ostwald's process? Manufacture of Nitric acid. by Ostwald’s process : 1) Step-1: Ammonia on oxidation gives Nitric oxide $50) UME HBE I AN L + ANHyg) +502) 500K tar NO) + H2%y 2) Step-2: NO on oxidation gives NO 2NO ig) + Ong) = 2NO21g) 3) Step-3: NO} on hydrolysis gives dil. HNO3 3NO zig) + H20y) —42HNO3iuq) + NO(g) 4) Concentration of Nitric acid. in three stages: (i) Stage 1: The diluted HNO} is concentrated by distil- lation to give 68% HNO3 (ii) Stage 2: 68% HNO3 is dehydrated with pure cone, HS04 to give 98% HNO3 (iil) Se2ge 3:98% HNO3 on cooling ina freezing mixture gives 100% HNO in crystal form How does nitric acid react with the following? () Copper Gi) Zn (ii) Sg tiv) Py Reactions of Nitric acid: §) (a) Copper on oxidation with dll. Nitric oxide ic acid gives 3Cu +8HNO; —43Cu(NO3)p +2NO+4H30 (b) Copper on oxidation with conc. Nitric acid gives Nitrogen dioxide. (Cu + 4HNO; —+Cu(NO3)2 +2NO> + 2H20 4i)(a) Zinc on oxidation with dil. Nitric acid gives N2O 4Zn +10HNO; —+4Zn(NO3)y +5H,0+N2O (b) Zinc on oxidation with cone. Nittic acid gives Nitrogen dioxi Zn + 4HNO; —+Zn(NOs)y +2H30+2NO> iii) Sulphur on oxidation with Nitric acid. gives Sulphuric acid, Sq + 48HNO, —+8H,S0, + 48NO> +1610 iv) Phosphor» on oxidation with Nitric acid gives Phosphoric uci, Py + 20HNO, —+ 4H;PO, + 20NO) + 4H20.* BABY BULLET-Q(AP} (a) How is Ovo with (Ag ( He (ii) PhS (i 1) Preparation of Ozom 302 = 203; AH= +142 mot! M1) Reaction KI Gil) Hy of Ozone: () 2Ag+039Ag,0+0) (ii2Hg+05-9Hg,0+09 GidPHS+4034PbS04+40y (iv) 2KI+H20+05-> 2KOH+1y+0 (9) CoHy+O3-9CpH 402 _zm0_,2HCHO+#H09+200 How is chlorine prepared ia the laboratory? How Chlorine is prepared in Des s process How does it react with the following? NaOH (i) Cold (ili) Excess NH, (9) Hypo( NayS705) {iv) Slaked time 1) Preparation of Chk Chlorine i prepared inthe laboratory by heating a mixture of sodium chloride, manganese dioxide and cone. HSO4 ne in the laboratory: 4NaCl+4H2S04+Mn02—> 4NaHSO4+MnCly+2H,0-Cly 11) Deacon's process: Chlorine is prepared by the Oxidation of hydrogen chloride gas by atmospheric oxygen in the presence of CuCly catalyst at 723K. produces chlorine aucl+0, S220, +2130 ) Reactions of Chlorine: ’) Chlorine reacts with cold and dilate NaOH to form NaCI and NaOCl (Cl; + 2NaOH > NaCl+ NaOCI+ 30 ii) Chlorine reacts with hot and conc. NaOH to form’ NaCl and NaCl, 3C 1, + 6NaOH — SNaCl + NaClO3 +3H30 iiiyCMlorine reacts with excess of ammonia to form Ny 3Clz +8NHy > Np +6NH,CI iv) Chlorine reacts with dry slaked lime to form) Bleaching powder, Cl; + Ca(OH); —>Ca0Cl; HO staked lime Bleaching powder V)Cly reacts with Hypo to form NaySOy ly + NayS;0, +0 NayS0, +2HC1+S Hype prepared? (b) How does it react | 1) Williamson's syne 2 » 4) 5) n 8) % 10) Sandmey r reaction: Benzene diazonium chloride reacts (021: ORGANIC CHEMISTRY SR.CHEMISTRY-BULLET MODEL PAPER + TOP 10 NAMED REACTIONS Alky! halides react with sodium alkoxide to give ether Fe CHyl + Cy HsONa—>CH -O-CpHs + Nal Ricmer- Tiemann reactioN: Phenol is treated with CHC/3, inthe presence of sodium hydroxide to givesalicylalehyde. Ht Heo + cHCye 3Na0H + 3NaCI+ 3H,0 Carby lamine reaction; Aniline is heated with ethanolic KOH and chloroform to give Phenyl isocyanide This reaction is Carbylamine test. NH, Nc f oO + CHCI+3KOH— + + 3KCI+3H,0 Aniline Phenyl Lsoeyanide Kolbe Reaction: Sodium salt of phenol when heated with carbon dioxide at 125°C and under 4-6 atm pressure 10 form Salicyclic acid, ee "Oo 8 2 Sods fee sie Decarborslation: Sodium Ethanoate Is heted wth sodalime to form methane CH,COONs + NaOH 4H, + Na:COs Ado! condensation Reacion: Aldehydes and Ketones having atleast on hydrogen undergo condensation n the presence f dilute NaOH to form Aldol. 2cH,cHo= ci, -CH- CH, -CHOLAL) ae : on Cannizzaro reaction: Aldehydes without having ‘a! hhydrogen in the presence of Conc. NaOH undergo self ‘oxidation and reduction to form a mixture of alcohol and salt of acid. 4 H H-C=0+H-C=0 SH scH,0H1+ HCOONs Wurtz-Fittig Reaction: A mixture of an alky| halide and ary! halide are treated with Na in dry ether to form alkyl ave 1 CoH, Fe @ - 2ne-ci-c,n, +2NaCl en thy! Benzene 1.V.Z Reaction: Carboxylic acids ar halogenated atthe = Position on treatment with chlorine (or) bromine in the _resenee of ed phosphorus to give dchalo carboxylic aids. Fer cit, coon tegen 4g cH cooH om 7 with (CugCls / HCY (or) (CupBrg / HBr) (01) (CuCN! KCN) to form chloro benzene (or) bromo benzene (ot) «syano benzene,Sn EIESTITOE 5 BABY BULLET-Q(AP) * MODEL PAPER-1 q SR-CHEMISTRY } Ans-Page I. Answer ALL of the following VSAQ: 10 x 2=20 Index 1 What is Frenkel Defect? [oP 42(51)) 2. Whatare isotonic solutions ? [oP 43(63)] 3. State Faradays first law of electrolysis? [xP 44(69)] | 4. What are micelles? Give one example. leP 46(85)] |S. Why is H0 a liquid while HS is a gas’ [xP 47091) |6. Write any two uses of argon [=P 48(98)| | 7. Whatis a Ligand? [#P s0(i11)) | 8 Whar is Zwitter ion? Give an example ixP s1(115)] 9. What are ambident nucleophiles? [oP $3(127)] 10. Write the reaction showing o-halogenation of carboxylic acid &give its name.| [#-P $4(136)] SECTION-B Il. Answer any SIX of the follawing SAQ: 6x 424 | IL Derive Bragg's equation. [eP 26(15} | 12. Define Molanity. [eP 27017) | Calculate molarity of 2 solution containing 5g of NaOH in 500ml of solution. 13. Give the construction and working of @ standard hydrogen electrode with | | P_ 29(24)] 2 neat diagram. 14. How are colloids classified on the basis of interaction between dispersed phase and dispersion medium? [xP 31(29)) 15. How are XeF2 and XeF 4 prepared? Give their structures. Ie P 33(32)| 16. Explain Werner's theory of coordination compounds with suitable examples | [@-P_35(36)] lo P 37(42)] 17. Write notes on vitamins. 18. Explain SN? reaction with examples. Io P 39(48)) SECTION-C II]. Answer any TWO of the following LAQ: 2 x 8-16 19. State and explain Kohlrausch’s law of independent migration of ions [oP 1201) | 20. How is ammonia manufactured by Haber's process? lar P 14(5a) | [oP 19(10) | 21. Write the following named reactions with one example for each (2) Williamson's synthesis (b)Reimer - Tiemann reaction. (c) Carbylamine reaction (4) Kolbe reaction Cd)* BABY BULLET-Q(AP) fer} SR.CHEMISTRY-TOP 5 WiP * MODEL PAPER-2 SR-CHEMISTRY SECTION-A I. Answer ALL of the following VSAQ 10 x 2=20 mee 1. What are F-centres? | [oP 42(54)] 2. State Raoult’s law. leP_ 43(60)| 3. State Faraday’s second law of electrolysis. | =P 44(70)] 4. Whatiscollodion solution? [oP 46(86)) $. What is a tailing of mercury? How is it removed? [oP 47(98)] 6. List out the uses of neon. [oP 48(97)] 7. Why Zn2* is diamagnetic whereas Mn2* is paramagnetic? [oP 49(104)} 8. What are amino acids?Give two examples. | [xP 51(116)] 9. What are Enantiomers? | le P 53(128)) 10. Give the reagents used for the preparation of phenol from chlorobenzene. | [2P 54(133)] SECTION-B | Il. Answer any SIX of the following SAQ: 6x 4924 11. Explain Schottky & Frenkel Defects. ieP 26(16)] 12. Define Molality. Calculate molality(m) of 10gm of Glucose (CgH1206) in 90gm of Water.? | |e P 27(18)} 13. State and explain Nemst equation with the help of a metallic electrode and | [oP 29(23)] anon-metallic electrode. 14. Define adsorption? loP 31028) Give any four differences between Physisorption & Chemisorption. 15. How are Xe03 and XeOF4 prepared” Give their structures. | IP 3433) | 16. Write the characteristics properties of transition elements. leP 3535)] 17. Name the sources and diseases caused by the deficiency of vitamins A,D, E,K | [oP 37(41)| 18. Explain SN! reaction with examples. [xP 3947) SECTION-C III. Answer any TWO of the following LAQ: 2x16 19. What are Galvanic cells? Explain the working of Galvanic cell with aneat | [a-P 12(2) sketch taking Daniel cell as example. 20. How is nitric acid manufactured by Ostwald’s process? lar P 15(6) | How does Nitric Acid react with (i) Copper (ii) Zn (iii) Sg (iv) Py 21, Write the following named reactions with one example each: le P 2011) | (a) Decarboxylation (b) Wurtz - Fitting Reaction (c) Cannizzaro reaction (d) Aldol condensation reaction. CNee S19. 21. * SR.CHEMISTRY-TOP 5 MP {se} BABY BULLET-Q(AP) * ; {QuESS PAPERS] MODEL PAPER-3 SR-CHEMISTRY SECTION-A Answer ALL of the following VSAQ: 10 x 2=20 \: Ans-Page Index What is interstitial defect? State Henry's law What is a galvanic cell or voltaic cell? Give one éxample. What is Tyndall effect? What happens when Clp reacts with dry slaked lime? In modem diving apparatus, a mixture of He and O2 is used - Why? What is an alloy? Give example. Differentiate between globular and fibrous proteins. Write the structure of the following compounds (i) 2-chloro-3-methy] pentane (ii)l-Bromo-4sec-butyl-2-methyl benzene Write the structrues for 1)Ethoxy Ethane 2) Ethoxybutane SECTION-B Answer any SIX of the following SAQ: 6x 4-24 . Derive Bragg's equation. . Define Mole fraction. Calculate the mole fraction of H2SOq in 98% H2SOq. . Derive the integrated rate equation for a first order reaction. |. Explain Tyndall Effect and Brownian Movement. ‘What are interhalogen compounds? Give some examples to illustrate the definition. How are they classified? Using IUPAC norms write the systematic names of the following: ()[PUNH3)CI(NH2 CH3))C1 (ii) [NiClg}- (iii) K3[Fe(CN)g] (iv) Ka[PdCl4] . Write the importance of carbohydrates. . Define (i) Recemic mixture(ii) Enantiomers SECTION-C Answer any TWO of the following LAQ: 2x B=16 ‘What is ‘molecularity’ of a reaction? How is it different from ‘order of a reaction? Name one bimolecular and one trimolecular gaseous reactions, |. How is ozone prepared? How does ozone react with (i) CoHg (ii) Ag (ili) KI. Gv Hg (v) PbS Explain the following named reactions (a) Diazotization (b) Sandmeyer reaction. (c) Gattermann reaction. (4) HVZ reaction nd [oP 42(53)] leP 43(61)] loP 44(71)) [oP 46(87)} IoP 47(93)) lo P 48(99)) [aP 49(106)} [xP $1(119)] [oP $3(129)| [oP 54(134)) [oP 26(15] [oP 27(19)] oP 30(27)] [oP 32(31)] loP- 34(34)| le P 36(38)) lar P., 38(43)) la P 40(49)) lo-P 1303) | la P 16(7) | la P2102) | | idSer ayawne ML ML. 12. 13. 14, 15. 16. 17. 18. 19. 20. 2. gs [QUESS PAPERS) : MODEL PAPER-4 ad SR-CHEMISTRY Answer ALL of the following VSAQ: 10 x 2=20 * BABY BULLET-Q(AP) feo} SR.CHEMISTRY-TOP 5 MP * Me Bem Ans-Page Index How do you distinguish between crystal lattice and unit cell? What is Osmotic pressure? Define order of a reaction. Give one example. Whaat is electrophoresis? S02 can be used as an anti-chlor. Explain. Explain the structure of XeO3 What is Lanthanide contraction? | What are reducing sugars? Give the IUPAC names of the following compounds. (i) CH3~CH(C1)-CHI.CH3, (ii) CICH2-CH=CH-CH2Br What is Tollen's reagent? Explain its reaction with Aldehydes. SECTION-B | Answer any SIX of the following SAQ: 6x 4-24 Explain Schottky & Frenkel Defects. ‘What is relative lowering of vapour pressure? How is it useful to determine the molar-mass of a solute? Derive the integrated rate equation for a zero order reaction. | How are colloids classified on the basis of physical states of components? How are XeF2 and XeF 4 prepared? Give their structures. ‘Using IUPAC norms write the systematic names of the following: ([Co(NH3)6)C13 (ii) [Ti(H20)¢}3+ | (iii) Ka[Fe(CN)g) (iv)[Cu(NH3)4]S0q Explain the denaturation of proteins. | Explain the Grignard reagents preparation and application with suitable example? SECTION-C Answer any TWO of the following LAQ: 2x 8=16 State and explain Kohlrausch's law of independent migration of ions. How is Chlorine prepared in the laboratory? How does chlorine react with (i) Iron (ii) acidified FeSOq (iii) lodine (iv) H2S_— (v) KI Explain the following named reactions. (a)Esterification (b) Friedel Crafts Alkylation (c) Friedel Crafts Acylation (d) Wurtz reaction eee [eP 4255) [oP 43(62)] leP 44(73)] [xP 46(88)} [xP 47(95)] [xP 48(100)| [aP 50(109)| [xP 52(120)] [xP 53(130)| [oP 54(135)] IeP 26(16)} leP 28(20)) [oP 30(26)} [xP 3200)] la P 33(32)) [xP 36(37)) le P 38(44)] oP 40(50)] [oP 120) | la P 18(9)] [oP 22(13)]* SR.CHEMISTRY-TOP 5 MP. iy ana ER-5 2 aaebone eo ML I 12. 13. 14. Is. 16. 7. 19. 20. 21. SR-CHEMISTRY Answer ALL of the following VSAQ: What is Schottky Defect? What is relative lowering of vapour pressure ? Give two examples for gaseous Zero order reactions. What is coagulation? How is ozone detected? How is XeOF4 prepared? Describe its molecular shape. What is Mischmetal? Give its composition and uses. What are monosaccharides? What are Enantiomers? Give the reagents used for the preparation of phenol from chlorobenzene. SECTION-B Answer any SIX of the following SAQ: 6x 4-24 Derive Bragg's equation. Calculate the mass of a nonvolatile solute (molar mass 40g mol~!) which should be dissolved in 114g Octane to reduce its vapour pressure to 80%. (i) State Faraday's first law of electrolysis. (ii)A solution of CuSOg is electrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of copper deposited at the cathode? Define adsorption? Give any four differences between Physisorption & Chemisorption. How are Xe03 and XeOF 4 prepared? Give their structures. What is Stereoisomerism? Explain geometrical isomerism in coordination compounds giving suitable examples ‘What are enzymes? Give examples. Explain SN? reaction with examples. SECTION-C Answer any TWO of the following LA‘ What are Galvanic cells? Explain the working of Galvanic cell with a neat sketch taking Daniel cell as example. How is ammonia manufactured by Haber’s process? Write the following named reactions with one example for each. (a) Williamson's synthesis (b)Reimer - Tiemann reaction. (c) Carbylamine reaction (4) Kolbe reaction BABY BULLET-Q(AP) * lo P 42(52)] [oP 43(64)] lo P 45(74)] laP 46(89)] loP 47(96)| oP 48(102)] [oP 50(110)} [oP 52(122)) lo P 53(128)] lo P 54(133)] [aP 26(15)] oP 28(21)] oP 30(25)] loP 31(28)] Ie P 34(33) | le P 36(40) | la P 38(45)] lor P 39(48)] [oP 1202) lo P 14(5) | IP 1910)* BABY BULLET-Q(AP} fr SR.CHEMISTRY-TOP 5 MP * Hi SENIORS! How are you? By the way, | am your favourite BULLET BABY BOOK. Ilike you very much and | was born only for you! Now, | am 5 years old. | always wish you get Good marks in IPE! “Every Page in me is set beautifully so as to make you Read and write easily" “Every answer is written in Simple steps for your Pleasure reading *. "9 STEP revision PROGRAM STEP 1: LAQ Section (P 12 to P 23]: Infact, LAQ might be your Most Favourite Section. © _ Practice each and every Q &A of LAQ Section. Finish one after another, by taking as much time as you require. Later finish the LAQ Hit List (P 6) without seeing answers. STEP 2: SAQ Section [P 26 to P 40]: Some SAQs are really very easy!. They save you © _ whenthe paper is Tough. You should have grip on some Easy & Important SAGs. Do ‘as many as you can from SAQ Hit list (7). If you do this, you are in ‘Sate Zone’, STEP 3: VSAQ section[P 42 to P 54 }: Cute Cute simple VSAQs are very easy to learn and © remember. They are ‘True marks Gainers’. Do all the VSAQs In Hit list & Problems (P 8 to P 10). If you do this, you are in ‘Super Safe Zone’ STEP 4: Bullet Model Paper [P 60 to P 65]: Now, its tum to do your most favourite ‘Bullet @ __ Model Paper’. You can take 2 to 3 days to finish each section. Within 10 days you should complete this Task. This keeps you in ‘Safe Pass Zone’. STEPS: Guess Papers [P 66 to P 70): Finally, practice all the 5 Model Guess Papers. © Answer each paper separately on white sheets as it it's like in Public Exam. That's itl. You did a wonderful job! No one can stop you from scoring "Super Marks in IPE’ [OPA] ‘THETICN BOXES’ TECHNIQUE [7][77] Very ‘powerful and successful method’ for Effective Revision’ - Tick Box Technique How to use the Tick Boxes? 1, Putone Tick (¥’) in the first box, when you can write the answer ‘without seeing it’. 28 SEMAN, om HAS Td, OH door aLnoAWgyeo ToS wk S “us OF DyOS. 2, Put two Ticks ( 7”) when you are able to write the answer ‘without any mistake’ 4s, Mistake Smer Shoo mew HadHDAGA 8054 mS Toe OB, Dod. 3, Put Three Ticks (¥ ¥ V’) when you write ‘ast is - Ditto Answers’ with 100% Contidence, PE PHAotim, 100% Seryn, S&F od Comsigre’ women PAMOASYL Sams ASF samc OH dyod + Just try this Technique and you see how MIRACLES happen in your Revision programme. 7 Be Honest in putting the Tick Marks. 2) Q © 8 ALL THE BEST IN IPE &&3)

Action of Heat: (i) Blue colour to White fo Cu"? (Copper ion) ‘Small quantity of saltis ) Green to dirty White (ii) Fe’? (Ferrous ion) taken into a Test tube and | (iii) Whiteto Yellow (iii) Zn"? (Zine ion) heated (iv) Pink to Blue (iv) Co'? (Cobalt ion) (v) White Subtimate (or) colourless gas | (v)NH,' (Ammonium) (vi) Water drops (vi) Hydrated salt ©) Flame Test: + Put salt on a watch glass. | (i) Green flame (cu? + Pore 2-3 drops of conc.HC/ and make a paste of salt. | (ii) Crimson red (ise? + Dip the loop of the platinum wire in this paste. (iii) Apple Green ii) Ba + Introduce the paste in the nous flame (iv) Brick Red (ivy Ca B) Secondary Confirmation Tests: Refer Practical Manua! Books. III) (a) Finding Funetional Group in a given Organic Compound Inference of Functional group 1. Physical Test (i) Solid (i) May be Aromatic acid Gi) Liquid with Pungent smelt (Gi) May be Amine or Phenol (iii) Liquid (iit) May be Alcoho!, Aldehyde, Ketone, Aliphatic 2, Ignition Test (i) Luminous and Sooty flame (ii) May be Aromatic (ii) Non-Luminous and Non-Sooty flame | (i) May be Aliphatic 3. Selubility Tests: (Cold water Soluble May be Alcohol (i) Baber Soluble May be Aldehyde(or) Ket May be Carboxylic acid (iv) NaOH Solution Carboxylic (oF) Phenolic (vy) diLHCL May be amino group.WHICH IS BEST? STAR-0/ BIG BULLET-0/ BABY BULLET-0 DON'T GET CONFUSED 1! CHOOSE YOUR BEST CHOICE I! YOU CAN HAVE ANY ONE or AKYTWO or ALLTHETHREE AS PER YOUR CHOICE! CEPT BIG BULLET-Q BABY BULLET-Q HYPOTHETICAL \STER BULLET BABY cuiowe waster |ST* MA BULLET MASTER ut I SERIES oe VIAMEDIA SERIES PASS TRACK SERIES STAR Ocounason [Complete STAR ——_| inj STAR-O Micro STAR-O unuty Study Material Study cum Revision IPE Revision SYNOPSIS Elaborate Synopsis | Single Page Synopsis | No Synopsis EXPECTED MARKS RANGE — | Mo, Marks High to Medium Medium to Poss Zone h SPECIFIC | Super Synopsis! Math Beats Bullet Baby Ci chats eT Hint best Phys Beos, Chem Beas, | Bullet Model Poper ~~ Full content |! |. Quotes HIT UST of LAQ, SAQ, ¥SAQ ©08X...! aren. PART A: Bac PE np OBA | Only Previous PART Bs Un-lgu Qs on_| IPE Questions All Solved Q 8A SHES Calero Anwes | wai Answers Simple Answers 800K St Bulk Compod Mi WHEN TO BUY Ar the boginning Ay time Belore IPE PRICE 200 Rs. 120 R570 a et : | WHAT DOU GET? [Subject Knowledge | Chapter wise Clarity Reading Pleasure COMPARISON Ghosicke ge [Cassie Mas ie Moss ike [_WITH CRICKET Test Marches | One day Me Tics Meals Tilia From [Protein] 1-20 Matches