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‫قسم الكيمياء‬ ‫اسم الطالبة‬

Title

:Student Name

:Supervisor

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‫قسم الكيمياء‬ ‫اسم الطالبة‬

Abstract

Introduction

In one or two laboratory sessions, students will complete three primary kinds of

kinetics experiments: the graphical approach, the method of beginning rates, and the

production of an Arrhenius equation. Students who use all three kinds of approaches to

explore a single reaction are more likely to notice how these methods connect to one

another in terms of determining the rate of a reaction, which is valuable knowledge for

them to have. An integrated pharmacokinetics experiment has also been constructed for

the dissociation of ferroin,7 however it relies more heavily on a spectrophotometer than

the previous experiment. In the past, inexpensive colorimeter circuits and Smartphone

configurations have been characterized as cost-effective alternatives to commercial

spectrophotometers for measuring solution concentrations. For the experiment described

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‫قسم الكيمياء‬ ‫اسم الطالبة‬

in this paper, extremely cheap light meters with 50 mL solution quantities are used to

measure the degradation of the dye. This has the benefit of increased simplicity, as it

eliminates the need for water baths, circulators, and jacketed cells, which are required

for air temp measurements.

In order to confirm the sequence of reaction and get an accurate estimation of

the rate constant, the graphical approach of charting concentration was measured as a

function of time using the integrated rate equations may be utilized. 20 As part of our

efforts to understand the reaction between Blue 1 dye and hydrogen peroxide, we

employ the graphical method to determine the reaction order with respect to the Blue 1

dye (expressed as an integer in eq 1), and the method of initial rates to decide the

reaction pattern with respect to the hydrogen peroxide released from the sodium

percarbonate solution (expressed as y in eq 1) as determined by graphing the

relationship between Blue 1 concentration and reaction order, sodium per carbonate

concentrations are such that the hydrogen peroxide produced from the sodium service

delivery is over 1000 times greater than the Blue 1 concentration, and the hydrogen

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‫قسم الكيمياء‬ ‫اسم الطالبة‬

peroxide concentration can be considered to be approximately constant throughout the

course of the reaction.

Then, if a colored substance is available, the concentration of that substance

can be determined, and this protocol can be used to track the progress of a reaction in

which the consumption of reagents or the appearance of products results in a significant

transformation in the color intensity of something like the sample solution. In particular,

the bleach reaction, which generally incorporates redox processes, serves as a great

illustration of how redox processes work. In bleaching, one of the oxidizing agents

utilized is the hypochlorite ion, which attacks primarily by adding double bonding and

aromatic rings to the bleaching solution and may also induce hydrogen abstraction.

Materials and Methods

A standard size (10 oz) colorless drinking glass, which will only be used for chemical
experiments, and a bleach solution (which must have a concentration of sodium
hypochlorite indicated)

 Blue food coloring (optional)


 Smartphone;
 Measuring cup (12 cup); and (125 mL)
 A plate made of glass or ceramic;
 A teaspoon (5 mL)

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‫قسم الكيمياء‬ ‫اسم الطالبة‬

 A thermometer; a metal spoon;


 a timer;
 a stand for a Smartphone (which may be a taller drinking glass, ideally
colorless);
 And a thermometer

Results and Discussion

References

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‫قسم الكيمياء‬ ‫اسم الطالبة‬

REFERENCES

(1)  NALLIAH, R. E. REACTION OF FD&C BLUE 1 WITH SODIUM PERCARBONATE: MULTIPLE KINETICS
METHODS USING AN INEXPENSIVE LIGHT METER. J. CHEM. EDUC. 2019, 96 (7), 1453–1457.
HTTPS://DOI.ORG/10.1021/ACS.JCHEMED.8B00589.

(2)  KUNTZLEMAN, T. S.; JACOBSON, E. C. TEACHING BEER’S LAW AND ABSORPTION SPECTROPHOTOMETRY
WITH A SMART PHONE: A SUBSTANTIALLY SIMPLIFIED PROTOCOL. J. CHEM. EDUC. 2016, 93 (7), 1249–

1252. HTTPS://DOI.ORG/10.1021/ACS.JCHEMED.5B00844.

(3)  VANDERVEEN, J. R.; MARTIN, B.; OOMS, K. J. DEVELOPING TOOLS FOR UNDERGRADUATE SPECTROSCOPY:
AN INEXPENSIVE VISIBLE LIGHT SPECTROMETER. J. CHEM. EDUC. 2013, 90 (7), 894–899.
HTTPS://DOI.ORG/10.1021/ED300396X.

(4)  BROUILLETTE, L. S. Y. THE RATE LAW IN CHEMICAL KINETICS USING BLUE FOOD DYE; 2020.

(5)  HENARY, M. M.; RUSSELL, A. A. AN INEXPENSIVE KINETIC STUDY: THE REACTION OF FD&C RED #3
(ERYTHROSIN B) WITH HYPOCHLORITE. J. CHEM. EDUC. 2007, 84 (3), 480.
HTTPS://DOI.ORG/10.1021/ED084P480.

(6)  ARCE, J.; BETANCOURT, R.; RIVERA, Y.; PIJEM, J. THE REACTION OF A FOOD COLORANT WITH SODIUM
HYPOCHLORITE: A STUDENT-DESIGNED KINETICS EXPERIMENT. J. CHEM. EDUC. 1998, 75 (9), 1142.
HTTPS://DOI.ORG/10.1021/ED075P1142.

(7)  SPECTROSCOPY IN A SUITCASE: UV-VIS TEACHER RESOURCES HTTPS://EDU.RSC.ORG/DOWNLOAD?


AC=12907 (ACCESSED 2022 -04 -03).

(8)  MADRIZ, L.; CABRERIZO, F. M.; VARGAS, R. EXPLORING CHEMICAL KINETICS AT HOME IN TIMES OF
PANDEMIC: FOLLOWING THE BLEACHING OF FOOD DYE ALLURA RED USING A SMARTPHONE. J. CHEM.
EDUC. 2021, 98 (6), 2117–2121. HTTPS://DOI.ORG/10.1021/ACS.JCHEMED.0C01427.

(9)  SELCO, J. I. USING HANDS-ON CHEMISTRY EXPERIMENTS WHILE TEACHING ONLINE. J. CHEM.

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EDUC. 2020, 97 (9), 2617–2623. HTTPS://DOI.ORG/10.1021/ACS.JCHEMED.0C00424.

(10)  OAKES, J.; GRATTON, P. KINETIC INVESTIGATIONS OF THE OXIDATION OF ARYLAZONAPHTHOL DYES IN
HYPOCHLORITE SOLUTIONS AS A FUNCTION OF PH. J. CHEM. SOC., PERKIN TRANS. 2 1998, NO. 10,
2201–2206. HTTPS://DOI.ORG/10.1039/A805949G.

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