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UNIT 2 - PAPER 02
2 hours 30 minutes
2. Section A consists of THREE structured questions, ONE from each Module. Section B
consists of THREE extended response questions, ONE from each Module.
3. For Section A, write your answers in the spaces provided in this booklet. For Section B,
write your answers in the separate answer booklet provided.
SECTION A
M ODULE 1
NO, NH,
CH,
(iii)
(ii)
spA- Benzene
0)
C H ,CI (iv)
Cl OH OH
Br Br
1. N aO H
high tem p. + press. (v)
2. d ilu te HCI
Br
Suggest reagents to be used in EACH of the transformations, (i), (ii), (iii), (iv) and (v).
(i) _________________________________________________________________
(ii) __________________________________________________________________
(iii) __________________________________________________________________
(iv)
(v)
[ 5 marks]
(b) Draw structures for the monosubstituted products formed from the reaction of chlorine
with EACH of the following:
(i)
Benzene
CH,
(ii)
Methylbenzene
no 2
(iii)
Nitrobenzene
[ 4 m arks]
(c) Suggest a reason for the position of the chlorine on the benzene ring in EACH of the
products drawn in (b) above.
(i)
(ii)
(iii)
[ 3 m ark s]
(d) List the compounds, benzene, methylbenzene and nitrobenzene, in order of increasing
ease of reactivity with chlorine (least reactive first), and explain your answer.
Order:
Explanation:
[ 3 marks]
Total 15 marks
MODULE 2
2* (a) Sodium hydrogen carbonate (NaHC03) is sometimes used as a primary standard, yet its
molecular mass is only 84 g mol-1.
State THREE reasons why N aH C03 can be used as a primary standard and ONE reason
why sodium hydroxide (NaOH) may NOT be used.
' N aH C 03:
NaOH:
[ 4 marks]
(b) A student standardized a solution of sulphuric acid, using sodium hydrogen carbonate
as the primary standard, and found the concentration of the acid to be 6.00 mol dm-3.
(i) Write the balanced equation for the reaction between sodium hydrogen carbonate
and sulphuric acid.
[ 2 marks]
(ii) Calculate the mass in grams of sodium hydrogen carbonate that the student used
Lo neutralise the acid if 23.00 cm3 of the acid were used from the burette.
[ 4 m arks]
(c) In order to determine the ethanoic acid content of vinegar, a sample of vinegar was
titrated using sodium hydroxide solution.
Outline FIVE experimental steps to be carried out in the determination of the ethanoic
acid content of the vinegar.
[ 5 marks]
Total 15 marks
MODULE3
3. (a) Human activity is greatly responsible for the introduction of harmful substances into
the water cycle.
(i) List THREE human activities, OTHER THAN agricultural, which lead to water
pollution.
[ 3 marks]
[ 2 marks]
(b) (i) Suggest TWO reasons why farmers need to use chemical fertilisers in crop
production.
[ 2 marks]
[ 2 marks]
(c) Describe a simple laboratory test that would confirm the presence of EACH of Pb2+ and
N 0 3" ions in a sample of water.
Pb2+: _________________________________________________________________
N 0 3- :
[ 6 marks]
Total 15 marks
SECTION B
MODULE !
4. (a) Phenols, alcohols and carboxylic acids all contain hydrogen in their structure but they
exhibit different acidities. To illustTate these differences their reactivity with sodium
and its compounds, sodium hydroxide (NaOH) and sodium carbonate (N<1:zC03) may
be compared.
Copy Table 1 in your answer booklet. Predict the outcome of the following reactions by
completing Table l in your answer booklet.
Na NaOH
Ethanol sodium
ethoxide
and hydrogen
sodium
phenoxide
Phenol and water
[ 6marks]
(b) The loss of a proton by phenol results in the formation of the phenoxide ion.
OH to ?
ir
o© o o o
R - OH -> R -----------Of
• •
+ H+
(R = alkyl group)
With reference to the Lewis structure and resonance forms of the phenoxide ion and the
Lewis structure of the alkoxide ion, compare and explain the difference in acidity between
alcohols and phenols. [ 4 marks]
(ii) Using the molecular formula, C3HgO, draw the displayed formulae of TWO
structural isomers. [ 2 marks]
Total 15 marks
M ODULE 2
(2 )
CD (3)
© to vacuum pump
(i) and(T
Identify the parts of the mass spectrometer numbered (^2), ( T ) ,( 4 ) and ( 1)) inin
Figure 2. [[44 m
marks]
arks]
re provided
Data from the mass spectrum of the halogen, bromine, atomic number 35 are
below.
GO ON TO THE N EX T PAGE
22212020/C APE/2008
- 11 -
(c) (i) Copy Figure 3 in your answer booklet. Sketch, in your answer booklet, the
spectrum of bromine vapour in the m/e region indicated in Figure 3.
[ 4 m arks]
«o
t- SSa«“
>
-2 "1sD
3 -32
C5
(ii) W hat is the origin of EACH of the THREE peaks in your spectrum?
[ 3 marks]
Total 15 m arks
M ODULE 3
(b) Outline,
Outline,using
usingrerelevant equations, the process by which
which sucrose
sucrose isis converted
converted to
to ethanol.
ethanol.
[ 4 marks]
(c) The
The
harmful
harmful
effects
effe of alcohol are due to its oxidation
ition
to ethanal.
to ethanal.
Write
Write
an equation
an equation
for for
the oxidation ooff alcohol
; (ethanol) to ethanal. [[22marks]
marks]
(d) Identify
Identify TW
TWOO pphysiological changes in the body
3dy which result from the abuse of
consump
alcohol consumption. [[22 marks]
marks]
Total 15 marks
END OF TEST
22212020/C APE/2008