CLS MED 20 21 XIII Che Package 1 Level 1 Chapter 2

Chapter 2
Structure of Atom
Solutions
SECTION - A
1. Answer (1)
1 1
v   2.5  104 cm1 .
 400  107
2. Answer (1)
3. Answer (4)
4. Answer (3)
No. of protons = No. of electrons = Z = 93, No, of neutrons = A – Z = 237 – 93 = 144.
5. Answer (2)
6. Answer (3)
7. Answer (2)
8. Answer (1)
9. Answer (3)
KE of electron = h – h0.
10. Answer (3)
rn = n2r0  r3 = (3)2x = 9x.
11. Answer (3)
1 1
For 4s1 : n = 4, l = 0, m = 0 and s   or 
2 2
12. Answer (2)
For s subshell, l = 0.
13. Answer (2)
n(n  1) 5(5  1)
No. of spectral lines =   10 .
2 2
14. Answer (3)
h
 .
mv
Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456
26 Structure of Atom Solutions of Assignment
15. Answer (3)
13.6Z2 13.6  12
KE    3.4 eV
n2 22
PE = –2KE = –2 × 3.4 = –6.8 eV.
SECTION - B
1. Answer (2)
2. Answer (2)
3. Answer (2)
 hc 
Energy of ‘n’ photons = n  
  
 hc 
n   1
  
 6.6  1034  3  108 

n  1
 7000  1010 
7000  1010
n  3.52  1018
6.6  3  1026
4. Answer (4)
 hc 
Energy required for dissociation of 1 mole of I2 molecules =   NA
  
 6.6  1034  3  108  23

   6.022  10  57.3 kcal/mol
 4995  1010 
5. Answer (1)
(I.E.)M = 13.6 Z2 = 73.6 x(1)2 = 13.6 eV = x(kJ)
 1 1  1 1 5 x  5 5x
E  13.6  2  2   13.6     13.6    kJ
2 3 2 3  4 9 36 36 36
6. Answer (4)
7. Answer (1)
8. Answer (2)
9. Answer (4)
10. Answer (2)
11. Answer (3)
12. Answer (1)
13. Answer (2)
Energy of atomic orbitals can be decide on the basis of ‘n + l’ rule.
14. Answer (1)
Solutions of Assignment Structure of Atom 27
15. Answer (4)
16. Answer (3)
17. Answer (2)
18. Answer (4)
19. Answer (3)
n( n  1) 4  5
Maximum number of spectral lines    10
2 2
{where, n = n2 – n1}
20. Answer (3)
21. Answer (2)
22. Answer (3)
23. Answer (4)
24. Answer (2)
25. Answer (2)
26. Answer (2)
27. Answer (3)
28. Answer (2)
Circumference of (2r) = n
= 2 = 2 × 5 × 10–9 m = 10–8 m
29. Answer (4)
30. Answer (2)
31. Answer (1)
32. Answer (4)
33. Answer (4)
34. Answer (1)
35. Answer (2)
36. Answer (4)
hc 6.6  10 34  3  108

Work function (W0)    6  1019 J
0 330  109
37. Answer (2)

(KE)max = h – h0
2E = h(3.2 × 1016) – h0 ...(i)
E = h(2 × 1016) – h0 ...(ii)
2{h(2 × 1016) – h0} = h(3.2 × 1016) – h0
4 × 1016 – 20 = 3.2 × 1016 – 0
0.8 × 1016 = 0
0 = 8 × 1015 Hz
SECTION - C
1. Answer (4)
Total number of nodes = (n – 1)
3=n–1
n=4
Number of angular nodes = = 3  f-subshell
 Correct answer is 4f.
2. Answer (3)
rn = a0n2
r2 = 52.9 × (2)2 pm
Again,
n = 2r
2
= r
n
2
=  52.9  4
2
 = 211.6  pm
3. Answer (1)
(n + l) values for, 4d = 4 + 2 = 6
5p = 5 + 1 = 6
5f = 5 + 3 = 8
6p = 6 + 1 = 7
 Correct order of energy would be
5f > 6p > 5p > 4d
4. Answer (2)
In H-spectrum, Balmer series transitions fall in visible region.
5. Answer (4)
According to Hund's Rule of maximum multiplicity, the correct electronic configuration of N-atom is
1s2 2s2 2p3
OR
2 2 3
1s 2s 2p
 Option (4) violates Hund's Rule.

6. Answer (4)
Energy of 2s-orbital and 2p-orbital in case of hydrogen like atoms is equal.
7. Answer (1)
An orbital can accommodate maximum of 2 electrons with anti-parallel spins.
8. Answer (3)
z y
dz 2 dx 2 – y 2
9. Answer (1)
Fact.
10. Answer (2)

Angular momentum = l  l  1 = l  l  1
2
11. Answer (1)
It represents 3p orbital
12. Answer (4)
hc 6.63  10 34  3  108 6.63

E  9
  10 17 = 4.42 × 10–18 J
 45  10 15
13. Answer (2)

14. Answer (3)
Value of m = –1 represents one orbital. Therefore maximum number of electrons will be two.
15. Answer (2)
c 3.0  1017 nms1 1

    102 nm
v 6  1015 s1 2
 0.5  102 nm = 50 nm
16. Answer (3)
In (n = 1) 1st shell e– is tightly held compared to n = 6 (6th shell)
17. Answer (1)
Rb = 37 = [Ar] 4s2, 3d10, 4p6 last 5s1 e–
1
 n = 5, l = 0, m = 0, s = 
2
18. Answer (3)
n = 4, l = 3 represents 4f subshell having 7 orbitals
 Total number of electrons = 14

19. Answer (1)

Angular momentum = l  l 1
2
20. Answer (3)

2
Number of orbitals = n (n = orbit number)
= 42 = 16
21. Answer (3)
hc hc
1  2  E1 = 25 eV E2 = 50 eV
E1 E2
hc
1  ...... (1)
25
hc
2  ...... (2)
50
hc
1 25 1
 2  2 1  2 2
 2 hc 2
50
22. Answer (2)
Putting the value of n and calculating the (n + l) value
6s < 4f < 5d < 6p

6  0  4  3 5  2  6  1
6 7 7 7
(lower energy)   high energy 
23. Answer (1)
Because (E2 – E1) > (E3 – E2) > (E4 – E3) > (E5 – E4) > (E6 – E5)
As the difference is of one energy levels
 (E6 – E5) have less energy
{Alternatively value of E [difference between two successive energy level decreases] as the distance from the
nucleus increases.}
24. Answer (3)
h 6.6  1034 kgm2 s2 - s

   1.0  1035 m
mv 0.66 kg  100 m/s
25. Answer (4)
KE = Energy observed by molecule – Energy required to break one bond
4.4  1019 J  4.0  1019 J

KE =
2
 0.4  1019  19 20
KE per atom     0.2  10 J   2  10 J
 2 
26. Answer (4)
27. Answer (2)
1
n=3 l=2 m = –3 s= 
2
Value of m (orbital) depends upon l i.e., it cannot be more than 'l '. Therefore is wrong.
28. Answer (3)
29. Answer (2)
h
x × p =
2
30. Answer (2)
31. Answer (4)
32. Answer (1)
h h
x  mv = v 
4 x  m  4  
6.6  1034 J-s

v  6
0.1  10 10 m  9.1  10 31 kg  4  3.14  5.799  10 m/s
33. Answer (3)
34. Answer (4)
1312
En   kJ mol–1 for hydrogen
n2
35. Answer (3)
h 6.6  1027
x    1.93 cm
4mv 0.001
4  3.14  9.1 1028   3  104
100
36. Answer (3)
r0  n2 0.53  (1)2
rn    0.176 Å
Z 3
37. Answer (4)
1312
Energy of electron when n = 1, E1   kJ/mol
12
1312 1312
Energy of electron when n = 3, E3    kJ/mol
3 2 9
E  E3  E1
1312  1312 
    1166 kJ/mol = 1166 × 103 J/mol = 1166 × 10+10 erg/mol
9  1 
= 0.1936 × 10–10 erg/atom
Alternatively
hc 1 1
E   hc  R  2  2 
  n1 n2 
1 1
 3.0  108  6.6  1034  8.314  2  2  J
1 3 
8 
 3.0  108  6.6  1034  8.314   J
9 
38. Answer (4)

Gd have exceptional configuration e– will enter in 5d because 4f have 7 electrons and have half filled stability
Gd = [Xe]54 4f 7 5d 1 6s 2
39. Answer (1)

Isoelectronic means same number of electrons
CO = Number of electrons = 14
CN– = 6 + 7 + 1 = 14
40. Answer (4)
r0  n2
rn  n = Number of orbit, Z = charge on nucleus
Z
n2
Ist excited state for H =
Z 1
0.53   2 
2

1
 0.53  4  2.12 Å
41. Answer (4)
h
Δx electron  Pelectron 
4
h
xelectron 
4 Pelectron
x electron  xHe  1.0 nm
h
xHe  PHe 
4
h
xHe 
4PHe
h h
 
4Pelectron 4PHe
PHe  5.0  10 26 kg ms 1
42. Answer (4)

Fe = 26 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 4s 2, 3d 6
43. Answer (2)
N3+ = 4 = 1s 2, 2s 2 Zero unpaired
Fe2+ = 24 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 3d 6 Four unpaired
Zn = 29 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 4s 1, 3d 10 One unpaired

Cu = 28 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 4s 0, 3d 10 Zero unpaired
44. Answer (4)
1 2
n length of major axis 3

k length of minor axis
Number of elliptical orbit in shell = (n – 1)

45. Answer (3)
h
 , m = 1 g = 0.001 kg, v = 100 m/s
mv
6.6  1034 kg m2 s2

0.001 kg  100 m/s
  6.63  1033 m
46. Answer (1)
As the value of m = + 2
i.e. one value
Therefore one orbital is represented.
47. Answer (3)
c 1 1
  c  R  2  2  Z2
  n1 n2 
1 1
  3.0  1010  109678  2  2   1
2
1 4 
10 15 
  3  109678 cm1    3.09  1015 s1
1010 16 
Alternatively
I  E = E – E1
2.18  1018  E  E1
E1  2.18  10 18 J
2.18  1018 2.18  1018

E4     0.136  10 18 J
 4 2 16
E = E 4  E1  0.136   2.18    10 18  2.04  10 18
hc
 .... (1)
E
c
v .... (2)

Put equation (1) in equation (2)
c E
v  E 
hc h
2.04  10 18
v 34
 0.309  10 16  3.09  1015 s 1
6.6  10
48. Answer (1)

Electronic configuration [Ar] 3d6 represents 24 electrons
i.e. Co3  24 e
Ni3+ = 28 – 3 = 25 e–
Mn3+ = 25 – 3 = 22 e–
Fe3+ = 26 – 3 = 23 e–
49. Answer (4)
Bohr's model explain the energy level i.e. Energy of electron in each orbital is quantized.
1312
En  2
Z2 kJ/mol
x
50. Answer (2)
51. Answer (3)
 kZ2
En 
n2
1 1 1
 E1 : E2 : E2 = : : = 36 : 9 : 4
1 4 9
SECTION - D
1. Answer (4)
Isotones are the atoms having same number of neutrons.
2. Answer (2)
0.529n2
rn  Å
Z
0.529  22
r2 (H)   0.529  4Å
1
0.529  42
r4 (Be3 )   0.529  4Å
4
3. Answer (1)
Number of peaks in graph of 4r22 and r is n – l
4. Answer (2)
5. Answer (3)
KZe2
PE  
r
6. Answer (4)
5th excited state n2 = 6
1st excited state n1 = 2
No. of lines in Paschen = 6 – 3 = 3
No. of lines in Brackett = 6 – 4 = 2
No. of lines in Pfund = 6 – 5 = 1
 Total number of lines in infra red region = 6
7. Answer (4)
8. Answer (3)
13.6 13.6
En   eV   1.51 eV   eV
n2 n2
n3
2  rn 2(3)2 .x
  =  6x
n 3
9. Answer (2)
For 2p orbital : n = 2 ; l = 1
2h
Orbit angular momentum =
2
h h
Orbital angular momentum = l(l  1)  2
2 2
10. Answer (4)
11. Answer (3)
Number of orbital = (2l + 1) in subshell
12. Answer (4)
More the nuclear charge lesser will be energy
 E 2sO  E 2sC
13. Answer (2)
Last electron enters in 3d orbital  n  3 l  2

14. Answer (3)
15. Answer (1)
Angular nodes = l
3d have zero angular node

z2
16. Answer (3)

17. Answer (4)
For photoelectric effect
KE = h( – 0)
KE = h – h0
No. of photons 
KE 
0  Intensity of light 
(II)
(IV)
0 = Threshold frequency
 [KE of e– increases after crossing. Threshold frequency]
18. Answer (2)

All the wavelength are in visible region i.e. between 400 nm to 760 nm. Therefore maximum wavelength line
will be 656 nm.
19. Answer (1)
KE
 1
ETotal
Total energy = –3.4 eV (Given)
 KE = –(–3.4 eV) = +3.4 eV
20. Answer (4)
As 1st excited state means n1 = 2
For 5th excited state means n2 = 6
 e– will transit between 6th level to 2nd level
No transition will be upto 1st level. Because no line will appear in Lyman series i.e. UV region.
21. Answer (1)
st
1 line in the Balmer series means n1 = 2, n2 = 3
1 1 1
v  R  2  2  Z2 for H Z=1
  n1 n2 
1 1 1  1 1 5R
v   R  2  2   12  R     cm1
  2 3   4 9  36
22. Answer (2)
Eground   x eV given
Eground state 
En   Z2 n  3 because 2nd excited state
2
n 
 Z  2 because He 
x 4
  2    x eV
2

3 2 9
23. Answer (1)

n1 = 1 For He Z = 2
n2 =  given
1 1 1
 R  2  2    2
2
He 1  
1
 109678  4 cm1
He
1 1
He    2.2  106 cm
109678  4 438712
 2.2  108 m
24. Answer (2)
Third line means third excited state
i.e. n1 = 2 Balmer series (visible region)
n2 = 5 Third line
 Third line will appear when electron comes from 5th energy level to 2nd level.
25. Answer (1)
In H atom
1312 1312 1312 1312 1312
E1 = E2 = E3 = E4 = E5 =
12 4 9 25 36
 (E2 – E1) > (E3 – E2) > (E4 – E3) .......
[Alternatively as the distance from the nucleus increases the value of E (energy difference between two shell)
decreases]
26. Answer (3)
Largest amount of energy is required for the transition between 1 
1 1 1
E  hc   hcR  2  2  [Large the difference between n and n large will be the value of DE]
  n1 n2  1 2
27. Answer (2)
circumference 2r n3
Time period =   2  1.5  1016 seconds
velocity vn Z
Time period  n3
28. Answer (1)
First time of paschen series n1 = 3, n2 = 4
1 1 1 
 R  
1  9 16 
1 7R 144
 1 
1 144 7R
Second line of paschen series n1 = 3, n2 = 5

1 1 1 
 R  
2  9 25 
1 16R 225
 2 
 2 225 16R
1 144 16R 2304 256

   
2 7R 225 1575 175
29. Answer (4)
1 1 1
 R  2  2  Z2
  n1 n2 
1
  , more the nuclear charge smaller will be the 
Z2
HZ=1
DZ=1  Li2+ have shortest wavelength
He  Z = 2
Li2+  Z = 3
30. Answer (1)
P = 10–5 kgms–1
h
x  P 
4
6.6  1034 J
x  5
 5.2  1030 m
10  4  3.14
31. Answer (2)
h h 1
A  B  PB  PA (Given)
PA PB 2
h
 A PA PB 1
 
B h PA Putting PB = 2 PA
PB
 A 1 PA

B 2 PA
B = 2A [A = 5 × 10–8m]
B = 2 × 5 × 10–8
= 10 × 10–8m ∵ 1 m = 100 cm
= 10–7 m= 10–5 cm
32. Answer (3)
n  4, l  3 means 4f
for l = 3, m = –3, –2, –1, 0, 1, 2, 3 = 7 orbital

Therefore, maximum 14 electrons are present.
33. Answer (1)
34. Answer (2)
Energy of an electron depends upon (n + l) value
More the (n + l) value more will be the energy
n l m s (n + l)
(1) 3 2 1 +1/2 5
(2) 4 2 –1 +1/2 6 Max. (n + l), max. energy
(3) 4 1 0 –1/2 5
(4) 5 0 0 –1/2 5
35. Answer (3)
Total number of e– in X+3 = [Ar] 3d4
= 18 + 4 = 22
 Number of electrons in X = 22 + 3 = 25
Atomic number = 25
36. Answer (3)
Ions having all the electron paired will be non-paramagnetic or diamagnetic
Ne+2 = 8 = 1s2, 2s2, 2p4 2 unpaired e–
Be = 3 = 1s2, 2s1 1 unpaired e–

2s
Cl– = 18 = 1s2, 2s2, 2p6, 3s2, 3p6 0 unpaired e–

3p
As = 33 = 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p3 3 unpaired e–
37. Answer (1)

Isoelectronic species have same number of electrons
CO = 14 e  NO  14 e  
  
 [All have same number of electrons]
CN = 14 e C22   14 e  
38. Answer (2)

(ii), (iv), and (v) are not possible
(ii) n = 2 l=2 m=1 s = +1/2 l not equal to n not possible
(iii) n = 1 l=0 m = –1 s = –1/2 Not possible because m = –1 where l = 0
(iv) n = 3 l=2 m=3 s = +1/2 Not possible because m = 3 is not for l = 2
39. Answer (3)
Any orbital have maximum of two electrons with opposite spin.
40. Answer (1)
For l = 3, m = –3, –2, –1, 0, +1, +2, +3
i.e., 7 orbitals are present
41. Answer (3)
K = 19 = 1s2, 2s2, 2p6, 3s2, 3p6, 4s1 last e–
Last electron 4s1
1
n=4 l=0 m=0 s= 
2
42. Answer (1)

M shell means 3rd orbit
2 2 6 2 6 2 5
Mn = 25 = 1s , 2s , 2p , 3s , 3p , 4s , 3d total 13 e– in 3 orbit
8 5
Co = 27 = 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d7 total 15 e– in 3 orbit
Ni = 28 = 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d8 total 16 e– in 3 orbit
Fe = 26 = 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d6 total 14 e– in 3 orbit
43. Answer (2)
n = 3, l = 3 [Not possible because value of l can never be equals to n]
44. Answer (2)
h
Orbital angular momentum = l  l  1
4
For 4s electron, the value of l = 0  [orbital angular momentum = zero]
45. Answer (2)
Radial nodes = (n – l – 1)
for 3s (3 – 0 – 1) = 2 ; For 3p (3 – 1 – 1) = 1
46. Answer (3)
Energy = (n + l)
A=n=4 l=1 =4+1=5
B=n=4 l=0 =4+0=4
C=n=3 l=2 =3+2=5
D=n=3 l=1 =3+1=4
According to Pauli exclusion principle
(1) Larger the (n + l); larer will be energy
(2) Same value of (n + l) ; smaller n ; more will be energy
 DBC A
47. Answer (4)

48. Answer (2)
Value of m = 0 for 3s, 2Pz and 3d z2
49. Answer (3)

Total number of electron in subshell = 2(2l + 1) l = angular quantum number
2  2l  1
Number of electrons having same spin =   2l  1
2
[Because half e– have clockwise and half e– have anti clockwise spin]
50. Answer (4)
For 2nd period electronic configuration = 2s2, 2p6
If each orbital have 3e– then electronic configuration = 2s3, 2px3, 2py3, 2pz3
Total 12 e– will present
51. Answer (1)
According to Heisenberg,
h
x  mv 
4
For particle A,
x = xA
m=m
v = 0.05
h
So, x A  m  0.05  ...(i)
4
For particle B,
x = xB
m=5m
v = 0.02
h
So, xB  5 m  0.02  ...(ii)
4
Equation (i) / (ii), we get
x A 5  0.02
  2.
xB 0.05
52. Answer (4)

The kinetic energy of an electron is directly proportional to accelerating potential.
1
∵ mv 2  eV
2
 KE  V (where, V = potential difference)
53. Answer (3)
According to Heisenberg's uncertainty principle
h
x  p 
4
But p (momentum) = mv
h
or x  mv 
4
h
x 
4mv
54. Answer (3)
According to de-Broglie equation,
h 6.62  1034
   105 m
mv 6.62  1029  103  103
55. Answer (2)
h h 1
  v  3  108  3  106 ms1.
P mv 100
6.626  1034
   2.424  1010.
9.11 1031  3  106
56. Answer (1)
c 3  108 ms1
 
v 8  1015 s1
= 0.375 × 10–7 m
= 3.75  101 nm  4  101 nm

57. Answer (3)
Number of atomic orbitals in an orbit = n2 = 42 = 16
58. Answer (2)
6s, 4f, 5d, 6p. It is the correct sequence of filling of electron.
59. Answer (3)
For N shell, types of orbitals : 4s, 4p, 4d, 4f
Number of orbitals = 1 + 3 + 5 + 7 = 16
Number of electrons = 32
60. Answer (2)
The electronic configuration of K (Z = 19) is 1s2, 2s2, 2p6, 3s2, 3p6, 4s1
Thus the outermost configuration is 4s1, the four quantum number for this e– are
1
n = 4, l = 0, m = 0 and s =  .
2


CLS MED 20 21 XIII Che Package 1 Level 1 Chapter 2

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

CLS MED 20 21 XIII Che Package 1 Level 1 Chapter 2

Uploaded by

Copyright:

Available Formats

Chapter 2

15. Answer (3)

PE = –2KE = –2 × 3.4 = –6.8 eV.

 6.6  1034  3  108 

 6.6  1034  3  108  23

hc 6.6  10 34  3  108

37. Answer (2)

1s2 2s2 2p3

 Option (4) violates Hund's Rule.

hc 6.63  10 34  3  108 6.63

13. Answer (2)

c 3.0  1017 nms1 1

 Total number of electrons = 14

20. Answer (3)

6s < 4f < 5d < 6p

h 6.6  1034 kgm2 s2 - s

4.4  1019 J  4.0  1019 J

6.6  1034 J-s

38. Answer (4)

39. Answer (1)

x electron  xHe  1.0 nm

PHe  5.0  10 26 kg ms 1

42. Answer (4)

Fe2+ = 24 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 3d 6 Four unpaired

Zn = 29 = 1s 2, 2s 2, 2p6, 3s 2, 3p6, 4s 1, 3d 10 One unpaired

Number of elliptical orbit in shell = (n – 1)

2.18  1018 2.18  1018

E = E 4  E1  0.136   2.18    10 18  2.04  10 18

48. Answer (1)

13. Answer (2)

Last electron enters in 3d orbital  n  3 l  2

3d have zero angular node

16. Answer (3)

18. Answer (2)

22. Answer (2)

23. Answer (1)

27. Answer (2)

Second line of paschen series n1 = 3, n2 = 5

1 144 16R 2304 256

31. Answer (2)

B = 2A [A = 5 × 10–8m]

for l = 3, m = –3, –2, –1, 0, 1, 2, 3 = 7 orbital

Ne+2 = 8 = 1s2, 2s2, 2p4 2 unpaired e–

Be = 3 = 1s2, 2s1 1 unpaired e–

Cl– = 18 = 1s2, 2s2, 2p6, 3s2, 3p6 0 unpaired e–

37. Answer (1)

38. Answer (2)

42. Answer (1)

47. Answer (4)

Value of m = 0 for 3s, 2Pz and 3d z2

49. Answer (3)

52. Answer (4)

55. Answer (2)

= 3.75  101 nm  4  101 nm

You might also like