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    13 views4 pages

    Clases Eq S-L

    Uploaded by

    Sebastian Bonanni

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 4

     3.4 104 3.

    4 104
    T = 475 K  3.4 104 3.4 104
    T = 485 K
    Equilibrio Sólido-Líquido (I)
    3.8 10 3.8 10
    4 4

    4.2 10 4.2 10


    GL ( x) 4 GL ( x) 4

    𝑇𝑓1 = 580 𝐾 𝑇𝑓2 = 485 𝐾 GS ( x) GS ( x)


    4.6 10 4.6 10
    4 4

    𝐿 5 10 5 10
    = 𝑥1 𝐺1𝐿 + 𝑥2 𝐺2𝐿 + 𝑅𝑇 𝑥1 𝑙𝑛 𝑥1 + 𝑥2 𝑙𝑛 𝑥2
    4 4

    𝐺𝑀
     5.4 104  5.4 104
    5.4 10 5.4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

    𝑆
    𝐺𝑀 = 𝑧1 𝐺1𝑆 + 𝑧2 𝐺2𝑆 + 𝑅𝑇(𝑧1 𝑙𝑛 𝑧1 + 𝑧2 𝑙𝑛 𝑧2 )  3.4 104 3.4 104
    T = 505 K  3.4 104 3.4 104
    T = 525 K

    3.8 10 3.8 10


    4 4

    4.2 10 4.2 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4.6 10 4.6 10
    4 4

    5 10 5 10
    4 4

     5.4 104  5.4 104


    5.4 10 5.4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

     3.4 104 3.4 104


    T = 555 K  3.4 104 3.4 104
    T = 595 K

    3.8 10 3.8 10


    4 4

    4.2 10 4.2 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4.6 10 4.6 10
    4 4

    5 10 5 10
    4 4

     5.4 104  5.4 104


    5.4 10 5.4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999
     3.2 104
    T = 455 K  3.2 104
    T = 478 K
    3.2 10 3.2 10
    4 4

    Equilibrio Sólido-Líquido (II)


    3.56 10 3.56 10
    4 4

    3.92 10 3.92 10


    GL ( x) 4 GL ( x) 4

    𝑇𝑓1 = 580 𝐾 𝑇𝑓2 = 485 𝐾 GS ( x) GS ( x)


    4.28 10 4.28 10
    4 4

    4.64 10 4.64 10


    4 4

    𝐿
    𝐺𝑀 = 𝑥1 𝐺1𝐿 + 𝑥2 𝐺2𝐿 + 𝑅𝑇(𝑥1 𝑙𝑛 𝑥1 + 𝑥2 𝑙𝑛 𝑥2 )  5 104  5 104
    5 10 5 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

     3.2 104
    T = 485 K  3.2 104
    T = 495 K
    𝑆 3.2 10 3.2 10
    = 𝑧1 𝐺1𝑆 + 𝑧2 𝐺2𝑆 + 𝑅𝑇 𝑧1 𝑙𝑛 𝑧1 + 𝑧2 𝑙𝑛 𝑧2 + 𝐺𝐸,𝑆
    4 4

    𝐺𝑀
    3.56 10 3.56 10
    4 4

    𝐸,𝑆
    𝐺 = 6000 𝑧1 𝑧2 [J/mol]
    3.92 10 3.92 10
    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4.28 10 4.28 10
    4 4

    4.64 10 4.64 10


    4 4

     5 104  5 104
    5 10 5 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

     3.2 104
    T = 525 K  3.2 104
    T = 555 K
    3.2 10 3.2 10
    4 4

    3.56 10 3.56 10


    4 4

    3.92 10 3.92 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4.28 10 4.28 10
    4 4

    4.64 10 4.64 10


    4 4

     5 104  5 104
    5 10 5 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999
     2.2 104 2.2 104
    T = 350 K  2.6 104 2.6 104
    T = 400 K
    Equilibrio Sólido-Líquido (III)
    2.4 10 2.8 10
    4 4

    2.6 10 3 10


    GL ( x) 4 GL ( x) 4

    𝑇𝑓1 = 580 𝐾 𝑇𝑓2 = 485 𝐾 GS ( x) GS ( x)


    2.8 10 3.2 10
    4 4

    3 10 3.4 10


    4 4
    𝐿
    𝐺𝑀 = 𝑥1 𝐺1𝐿 + 𝑥2 𝐺2𝐿 + 𝑅𝑇(𝑥1 𝑙𝑛 𝑥1 + 𝑥2 𝑙𝑛 𝑥2 )
     3.2 104  3.6 104
    3.2 10 3.6 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

    𝑆
    𝐺𝑀 = 𝑧1 𝐺1𝑆 + 𝑧2 𝐺2𝑆 + 𝑅𝑇 𝑧1 𝑙𝑛 𝑧1 + 𝑧2 𝑙𝑛 𝑧2 + 𝐺𝐸,𝑆  3.0 104 3 10
    4
    T = 440 K  3.4 104 3.4 104
    T = 470 K

    3.2 10 3.6 10


    4 4

    𝐺𝐸,𝑆 = 12000 𝑧1 𝑧2 [J/mol]


    3.4 10 3.8 10
    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    3.6 10 4 10
    4 4

    3.8 10 4.2 10


    4 4

     4.0 104  4.4 104


    4 10 4.4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999

     3.6 104 3.6 104


    T = 500 K  4.2 104 4.2 104
    T = 550 K

    3.8 10 4.4 10


    4 4

    4 10 4.6 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4.2 10 4.8 10
    4 4

    4.4 10 5 10


    4 4

     4.6 104  5.2 104


    4.6 10 5.2 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    110 3 x 0.999 110 3 x 0.999
     4.4 104 4.4 104
    T = 600 K  4.0 104
    T = 550 K
    4 10
    4

    Equilibrio Sólido-Líquido (IV)


    4.6 10 4.2 10
    4 4

    4.8 10 4.4 10


    GL ( x) 4 GL ( x) 4

    𝑇𝑓1 = 580 𝐾 𝑇𝑓2 = 485 𝐾 GS ( x) GS ( x)


    5 10 4.6 10
    4 4

    5.2 10 4.8 10


    4 4

    𝐿
    𝐺𝑀 = 𝑥1 𝐺1𝐿 + 𝑥2 𝐺2𝐿 + 𝑅𝑇(𝑥1 𝑙𝑛 𝑥1 + 𝑥2 𝑙𝑛 𝑥2 )  5.4 104  5.0 104
    5.4 10 5 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    0 x 1 0 x 1

     3.4 104 3.4 104


    T = 500 K  3.0 104
    T = 450 K
    𝑆 3 10
    = 𝑧1 𝐺1𝑆 + 𝑧2 𝐺2𝑆
    4

    𝐺𝑀
    3.6 10 3.2 10
    4 4

    3.8 10 3.4 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    4 10 3.6 10
    4 4

    4.2 10 3.8 10


    4 4

     4.4 104  4.0 104


    4.4 10 4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    0 x 1 0 x 1

     2.8 104 2.8 104


    T = 430 K  2.4 104 2.4 104
    T = 400 K

    3 10 2.6 10


    4 4

    3.2 10 2.8 10


    GL ( x) 4 GL ( x) 4

    GS ( x) GS ( x)
    3.4 10 3 10
    4 4

    3.6 10 3.2 10


    4 4

     3.8 104  3.4 104


    3.8 10 3.4 10
    4 4
    0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
    0 x 1 0 x 1

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