eee Coie wae iculate the percentage sompusition | empusition in orm of oe ; mi 4 swintion el ting 200 of 20% and 0 of w 40 siti ps Jar mass 180 § mol "is present in 600 em! of uf its aquest z a solution is also required to be calculated ? ~ <0 lucose (CyH,,0,) in water is lat a Malai ofthe solution? metal ioreping segue of 10% (ui) solution of NaC, wil be require wo neutralise 5) be z lution containing 3.65 g of He (Assam Sit 2012) vat me of 95 mass % sulphuric acid (density = 1.85 wem') and what mass water must be taken to prepare 100 cm! of 15 mass “solution aulphuri _/ 84 density = 1.10 gem")? ? $< aleulate the mole fraction of ethanol and water in a sample of rectified spirit hich contains 95% ethanol by mass. (HPS.B. 2009, Ph SR. 2011, Meghalaya 8.B, 2013) 7. Calculate the mole fraction of water in a mixture of 12 g water, 108 ¢ Answers io Practice Problems 1. 98.57%. 66.40% 2, 0.2 M, density of the solution is ¢ ‘nowded to enleutvte molality of ‘the solution, ing 26 0.88, water = 0.12 tor Probirm: cid and 02g ethanol | 8. One litre solution of N2 HCL ix heated in eater, He wan observed tha the volume af the sation is reduced to) m3 25 af HC lone Calc @ ang =o 5 the normality ofthe new solution. Mote fraction = 0.0036 8. Concentrated sulphuric acd asa density 19 gf andi 99% H,S0, byw ase caleulate molarity ofeulphuri acid inthe aed 6 SB 20 ia aM 10. Calculate the molality and mole fraction of the solute in aqueous » 18. 005 F tuning 3 ¢ of urea per 250 «of water 14, G) 0038 42) IM i) 2.002 m 11. The molaty ofa solauon of ethyl alahol (CJH,OH) in war ie 1.5m Wes 18 76M,1L4m any grams of ety) alebol are dissolved in 2 hg of water ? 16. 081, 95878 12 Commercially available concentrated hydrorblori acid contains 36° 6 17, 602» 10" matocules ceaerind ha density 1.19 y can Calculate the molarity of thi soln 18. 348% (PhS. 2006, 2007 Te Gheds M Giy0.24 Ui) 0.0043 18, Caleulate the formality of sodium thioslpho'e (Ne,S,0,, 5H,0) = j 20. 025M 124g of which are dissolved in 100 cn of the solution 21. 6.55 M 14, 40 af NaOH are contained in one deciitre of «soliton, Caleulat 22.229m tea NPNott Gi) molanty of NaOH (a) molality of soltin (ens 28. 23.6em° folution = 1038 mle. rose 2, | 24. 5135m 15. Calculate the molunity and molality of «solution prepared by musing cata Mo‘ by weight of H,S0, (dcoity = 1-218 et) and 70% by eSB 25, 0.427 M,0.470m of H,SO, of solution © == So dh 16. Th ceca rare 4 Te solution? eee alee 17. Galea the (02 N oxalic acid solution Se 19, 80575 x 1 TM) to m2 {) the molarity (i) Atomic muses {density = 1.610 g/mL). {solution of sulphuric acid is 18 M and has is the mole fraction and weight percentagwof H,SO, number of molecules of oxalic ueid (H1,C,0,. 2H,0) in 100 Ina solution of benzene in chloroforin (CHCI,), the (0.45. Caleulate its percentage by weight in the mixture (0k of Glaubor’s salt is dissolved in water to obi of density 1077.2 kg m~ Calculate the molality and (ii) mole fraction of N Na = 23.00. 8 nleulate the molarity of a solution mole fraction of bea: fain 1 dm of ia, in the <4 16.00, H= LOL 2.10, 0 of CaC}, ifon chemic 11.605 x 108 Cl ion: © m= (000%) Te g00 mls af CaCl, solution en : more 0 ml. of a solution vontaining 5 g of NaOH are mixed with 200 wt ZAM") Fe eet ei reuling vlote as Sohbet 122, ‘The density of 2,05 M acetic ncid in water is 102 g om ° Calculate the Sete coe Be terra a arena ara, Ov fe eon 0g Awh of wert of eoncontrated HINO, ix 1.41 g em cat o} Se 4. Baitary seid 4.27 M 1,80, (ay) and has density of 1.25 g al! Woe rie ina Pray of H80, in the shor i he J pleut eRe ag st Sera 0.9082 gc andFenn seth seh nswers to Practt ‘osent ih A glass of wales AL roo \ perature of 25°C. ¢ otal pres Latmoxpiere gq, 499 104M >) OAM mole fraction of nitrogen in wiv of 78 97. 7.15 » \o'atm (© Wapbor nitrogen = 8.42 « 10% Minn (ATS 20091 $8. 585 PE Ope litre of water unvder w nitrogen proseure 1 atm diasolve 002g of nitrogen 29, 1.58 bor @_ @B293 K. Calculate Henry " stant 90. 0.181 bar B}-CEleaate the amount of C0, caved at atm in 1 di? of water at 908 K ; A We tionry’s law constant for CO, at 208 K is 167k bar RSZAAN that partial preerure, oxygen will have W ball lity of 0.06 gl. ‘in water : $2. O}-293 K? Henry's law constant (K,.) of O, in water at 303 K ie 46.82 k har v Assume the density of the solution to he the same as that of water), * AAEE Ae mmie fraction of He uae in a anturated solution at 20°C in 28 x 10 f Calculate the pressure of He gos above the solution. (Ky of He at we MA.98 A bar 31. 0.601 82. 44.25 torr of He 38. 0.448 bar 34. 104.1 torr 85. 66.15 mm Hg, 0.657 36, p(CH,OH) = 60.3 mm He, P(C,H,OH) = 16.8 mm Hg, p (Total) = 77.1.mm Hg 81, The vapour peur of ei At OC 0.18 Ba, The vapeur of this liquid in solution with liquid B is 0.095 bar. Calculate the mole SC Ain the ation te intr sbeye Rape 88, AL 285 Xgl acta as repr prewure oC TE8 tro Hand propionate has vapour pressure of 27.7 torr of Hg. Assuming their mixtures hy tulle. determine the vapour prem oft ane ee a ot ethyl arate 88 0g fe prope 8, An aquerus solution cntning 207 by eght o «gi Ani tact = 140 basa wep peer of 0330 barat S.Ct pressure af pure lig ap presere f watsn SP°C e016 be) ‘34, Benzene and toluene form nearly ideal solution. At a certain ‘ see cea ae eer ae anaes alelte te vapour pressure of the altan contains ep weg subwances othe teen 85. The vapour prevere of etenel and methane ae 445 and 687 mm ; respectively. An ideal solution is formed at the same temperature by the 60 g of ethanol and 40 g of methanol, Calculate the total vapour preseurs@l Dis the solution and the mole fraction of methanol in the vapour phase. PbSBE. 2009, 2018 is 86. Methanol and ethanol forms nearly ideal solution at 900 KA solution made by mixing 32 g methanol and 23 g ethanol, Calculate the pressure of its constituents and the total pressure of the solution. (at 300 © p' (CH,OFD = 90 mm Hg, p'\C,H,0H) = 51 mm He). 37. At 20°C, the vapour pressure of pure liquid A is 22 mm Hg and that of "liquid B is 75 mm Hg. What is the composition of the solution of these’ ‘components that has vapour pressure of 48.5 mm Hg at this 87. x, = xp = 0.5 equal moles of assume ideal behaviour) ? e ? Aand B. 8. Two liquids A and B have vapour pressure of 0.658 bar and 0.264 bar respect eat Pe Tea Nical sous 6 te tee eal oat ae z two liquids have equal partial pressures, Ae ‘89. ‘The liquids X and Y form ideal solution having vapour pressures 200 and, 40. p(CH,OH) = 254 mm Hg 100 mm Hg respectively. Calculate the mole fraction of component X in vapou (pC, HOH) = 135 mm Hg to Practice Pro! 11.2355 am He kPa Goose wy 17491 S conena ‘ aogaet! ime eine 85m fo. 40 mm He oo. 1800 1m of Hy eee ee a 40, Atacertain temperature, the vapour pressure (in tam Ha) of CH solution iseepresented by P= 119.» 195 where xis the male faction of C.F ' ‘What are the vapour pressures of pure components at this temperature U9 sof urea (M = 60 g mol) is dissolved in 846g of water Calelate the vapour} ressure of water for this solution if vapour pressure of pure water at 298 K 523.8 mm Hy. (ALS.B 2017) YD. The vapour pressure of water is 12.3 KPa at 800 K. Calculate vapour pressure #1 molar solution ofa solute init G3» The vapour pressure of water a¢ 20°C is 17.5 max Hg. A solution of sucrose (wolar as = 342) is prepared by dissolving 68.4 y in 1000 g of water, Calocige relative lowering of vapour pressure apour pressure of solution The vapour prossure of pure benzene at a co the sams temperature the vapour pressure volatile, non-electrolytic sali in 10 of b cular mass ofthe solid ? PO.S.B, 2004 ain temperature is 2 of a solution containing 2 bar. to, 8 bar, What isthe ; HPS oor Ug, “+ vapour prstures of pure liquids A and Bare 450 mim ana Pestivaly a 360 K Catal he compontionl ands on sure i 60m of Hy Also tn he eg : CASE mm of Hig otal vapour mple Paper 2010, Avsam SRAiken ese i) oe volatile organic substance naa w molar mass of the solute, (Vapour pressure hin 373 K = 760 mm Hg). iSharkhand 8B. 2072, eosiiae ‘iG rh °C, the vapour pressure of pure water in 29.76 datas seous dilute solution of ' 1.76 mm of Hg and that of an cae urea is 22,08 mm of Hg, Calculate the molality of UG) Nhat mane of a non-volatile solute, CX ae 11 be the molality of the solution ? Coe eas ‘Crew forme an ideal rolution in water, Determi tote ution in water, ine tho ay re of a Sc alton contin 10% by mae f urn at 4° Vapar prs e Phsaclides aatins Jigs {AIS.B, 2008, Nagaland 8B. 2015) «vapour pressure of water st 209 K is 0.0281 bar and th ei stress and the vapour pressure of pound in 1000 g of same temperatiire o O.0ias tas. Opies tin ola nase SPAG8 WADE oe S|. \ bling point of water ( anuce pan. At what 1 and boiling point of FCB. RAB SB. 2008) 100°C) becomes 100.62°C if 3 g of a non-volatile solute Eechvedin 20mlofit Calculate the molar mass of the solute (K, for water =0.52 xn G+ _\ tution containing 0.513 of naphthalene (malar mass = 128) in 50 fof C1, Rives 2 Sling point elevation of 0.402°C, while a solution of 0.625 g of an vinknown solute Eves a boiling point elevation of 0.650°C. Find the molar mass ofthe unknown solute .on-volatile solute when dissolved in 100 gram of benzene raises its 56 amatan ~Srypaney 12 What ithe molecular aes ofthe solute fr benzene = 2.59 Bact (PSB 2016 Meghalaya SB. 2016: rea molar Svat elevation in boiling point of alcobol is to be expected when 5 g of {60) are dissolved in 75 g of it ? The molal elevation constant for og ss leohol is. : nee i wre pont siren of Seen eacteme 3) tear in war as fesag Pit 200.18 Th wat if ering pt "| ig of « non-electrolyte substance in 176 g of water gave ‘0.20 K. Caleulate the molar mags of the substance (HLP.S.B. 2070, 2013, Pb.S.B. 2012) 59. A 10% solution (by mas Calculate the freezing point of 10% glucose water is 278.15 K. (Molar snass of sucrose = 342 ¢ mol”) 180 g mol") 60. Calculate the mass of a compound (mmplar mass = 256 g mol!) ‘o be dissalved 75 g of benzene to lower ite freezing point by 0.48 K (Ky = 5.12 K ke mot (DSB. 2014 Given (ALSB. 2017, DSB. 2017 (Molar mass of glucos G1. 15.0 g of an unknown material was dissolved in 450 g of water. The rerultind anton was found to freeze st -0.24 °C. What in the aiolar ises/of thi material? (K, for water = 1.86 K kg mol!) (DS.B. 2012, ALS.B. 2012, Pb.S.B. 2013 62. 1.00 g of nun-electroiyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. Find the molar mass of the solute, (Mizoran.S.B. 2013, AIS.B, 201 UK, for benzene = 5.12 K kg mol 63, When 2.56 of sulphur was diss:Ived in 100 g of CS,, the freezing point loweres hy 0.383 K. Calculate the formula of sulphur (S,) tomie mass of sulphur = $2 g mol!) i, for CS, = 3.83 K kg mol, At DSB. 2016 64. What mass of ethylene glycol (molar maas = 62.0 g mot) must be added tc 5.50 ke of water to lower the freezing point of water from O*C to ~10.0°C (ALS.B. 2010 A, for water = 1.86 K kg mol) solutions containing respectively 7, 5 g ure (molar mass = 60 X in 100 g of water freeze at the same temperature 65. ‘Two aquevus and 42.75 g substance Calculate the molecular weight of X 66. When 30.0 of « nurvlutile aulute having the empiey formula CHO ars Ws 3 getter he lution rc t~1 10°C, What i ae a of the solute Kf 1.86 Km!) formu Answers 19 Practice Problems 51, 128.25 g mol ' 52, 146.6 g mol! 68. 373.202 K 54. 150 @ mot" | 95. 96.54 mot! 56. 253 g mol * 67. 128°C 158, 59.06 g mot ' 1 Practice Problems 59. 265.55 K 60. 156 61. 182.35 g mol" €2. 256 g mol @. 5, 64, 1.833 ke 65, 342 g mol 66. C.H.0.$= winter, the normal temperature in a Himalayan's valley was found to be © Is a 30% by mas 62) suitab “termine the molality and boiling point of tl wen K, for water = 1.86 K/m, Ky aur radiator 21K, for water » 1,86 tho solution, 0.612 K/m), (Hr. 8.B, 2006, Mizoram S.B. 2015) K/m) (Pb.S.8. ¥ aqueous solution of ethylene glycol (molar 2011) aqueous solution freezes at 272.07 K, while pure water freezes at 273 K. D}+ > olution of ures in water has a boiling point 101.128°C, Caleulate the freez ng “int of the same solution. Molal constant for water, K, and K, are 186°C au 5 (Ph S.B. 2006) C respectively ® cold climate, water gets frozen =0. wusing damage to the radiator of a car. ‘hylene glycol is used as an antifreezing agent. Calculate the amount of ethylene = soul to be added to 4 kg of water to prevent it from freezing at ~ 6°C. (Ky sater = 1.85 Km!) TTL. A solution of sucrose (molar mass = 42 g mol!) i, for (HPS.B 2010) prepared by diss clus An: O Answers to Practine Peoblerss 67. It is suitable because ware froenes at ~ 12.86°C 68. 0.5 m, 979.256 K 69. —4.1°C 70. 804.32 swers 0 Practice Py 68.4 of it per litre of solution. What ithe oem prenture at 300 71. 4.92 ate 72 pressure of a solution containing 3.5g of dnolved protain per Beceol 7a, 460.7 lution is 25:mm (Hg) at 37°C. Calculate the molar mass of protec ie lene AB 78. 0.0621 litre atm/moVdegree 78, The osmotic pressure of a solution containing 9.2 g of a substance (moar mad: 74 4.20 atm, 176) in 302 ml of solution was found to be 4.1 atomsphere at 16.5°C. Cabeutole 75. 37.35 ¢ mol? the value of solution constant, 76. 2.10 bar 74 Calculate the osmotic pressure of a solution obtained by mixing 100 mia} 11-77. 91.8 solution of urea (molar mass = 60) and 100 ml of 8.49% of cane sugarérolal 78, 5 ol! tase = 842) at 20°C. (R= 082 hive atm K wart 7p. segue el 7S, Thre grams ofnon-valatie sltawhen dialed inate of water sbminan 7B 92 smotic pressure of 2 bar at 300 K. Calculate the molar mass of theacluse (R= 0.083 L bar K™ mol”) 76. Calculate the osmotic pressure of a solution containing 10 gram each of (68,0) 9.083'L bar K mol) 77. & solution containing 10.2 g of glycerine per litre is found to be isotoki C with, 8 2% sation of gocose, Calulate the molar man of gyerine nolarwadop slucose = 180) 78. A 5% solution of cane sugar (molar mass = 34: of urea. Calculate the molar mase of urea. 78. What is the concentration of solution of sucrose (molar isotonic with a solution containing 6 g of urea per litre ‘80. Osmotic pressure ofa golution containing 7 is 3.3 x 10% ) and sucrose (C,,Hz,0,,) in 1000 cm® of the solution at 25: Gfizoram 8. cock, Ge 12) is isotonie with 0.877% solahi6ny mass = 0x6) hina of protein per 100 cm of golaibh ar at 37°C, Calculate the molar mass of protein 1. A solution of an organie compound is prepared by dissolving 684g in I Uter, Calculate the molecular mass of the compound and osmotie po OF re ths solution ot 209 K when elevation in boiling point is 0.104 and K, fet oO is 0.52 Km 582. A solution of an organic compound is prepared by dissolving 34. Hr SB water, Calculate the molecular mass of the compound and freezing pat tsluton Gen tht aa ier waier 18 ae ir SE ‘88. The average osmotic pressure of human blood is 7.7 atm at 40°C. ‘2) What would be the total concentration of various solutes in the bl ‘) Assuming the concentration to be essentially the calculate the freering point of blood (K, for water = 6°C m9), 2 g in goo" the: Shusy ‘84. The osmotic pressure of blood is 8.21 atm at 37°C. How much glucose ghould hie used per litre for an intravenous injection that is isotonic with Hod 85. 600 ml. of aqueous solution containing 2.5 ¢ ofa protein shows an eemote of 26 mm Hg at 27°C. Determine the relative molecular mos of protels, ode 86. Decinorinal solution of NaCl developed an osmotic pressure of 4.6 atm at 30. K Calculate the degroe of dissociation 87. Calculate the freezing point ofa one molar aqueous solution density 1.04 gL-" ot Ke iK,for water = 1.86 kg mol", atomic masses of 88. Calculate the boiling point ofa one molar aqueous solution of KBr (density 1.06 gr, dk, for water = 0.52 kg mol, atomic masses 39, Br = 80), i) 89. Calculate the amount of sodium chloride (electrolyte) which must be added tc #AE Jalogram of water so that the freezing point is depressed by 3K. Give K, for wes) , (Wagaland 8.8, 2 1.86 K ky mol 90. Phenol associates in benz of association of phendl in beneene,(K for benzene 512K m") 1: of phenol in 250 g of benzene is lowered by 0.70°C. Calculute the dl Pb S.B 2 to form a dimer C,H, OH),."The freezing point ofa soi MO?) legee 81. 342, 4.80 atm 82. 542, 374°C 88. 0.30 mol L, 0.5580 M4, 58.06 g ve 52 K mr bot of soltion = 100 10, Kp 97. 88, 29, 90, 85. 3119.8 g molt | ~ 8.852" 101.106" 47.161 72% aon in boiling point is equal solution in water Km, K,= 052K m ') at 0.062°C: What i the apparent 1.86 K kg mol!) (Pb, 8B. 2002) ‘Must be added to 1 kg of water so that the (Kyfor water = 1,86K kg mol!) (2.8.8. 2012) 9 ofa solue dissolved in 500 mL of the solution at 27°C, What is the nature of the d ern amu)? (Hr. SB. 2006) land BaCl, are prepared in water. The freezing point of KClis freezing point would you expect for BaCl, solution assuming ae {00, nt of an aqueous solution containing 10.50 g of MgB, in 200 ¢ eeMaBns = 184, Kyfor water=1.86K kg mol) D.S-B. 2011) Answers 10 Practice Pro} 81% 0.052% 94.6% - 259°C 1.34 m 11.1% 40.05 g Associated solute -3C ). -1.59°C SERS RRP SSE