¢ JEE MAIN Joint Entrance Examination INSTRUCTIONS a a > 2, The following observations were taken for ~ determining surface tension T of water by capillary method. Diameter of capillary, \ This test consists oF 90 questions. Each question is allotted 4 marks for correct response, [OFFLINE] Candidaves will be awarded marks as stated above in instruction no. 2 for correct response of each question. ‘1 mark will be deducted for indicating incorrect response of each question, No deduction from the total score will be made if no response is indicated for an item in the answer sheet. There is only one correct response for each question Filing up more than one response in any question wil be treated as wrong response and marks for wrong response will be deducted according as per instructions ‘Physics 1. An observer is moving with half the speed of light towards a stationary microwave source emitting waves at frequency 10 GHz. What is the frequency of the microwave measured by the observer? (speed of light = 3 x 10° ms") (a) 12.1 GHz (0) 17.3 GHz (c) 15.3 GHz (¢) 10.1 GHz d =125x 10 m rise of water, h= 145 x 107m. Using g = 980 m/s* and the simplified relation 7 =228 x 10°N/m, the possible error in surface 2 tension is closest to (a) 1.5%, (0) 24% (0) 0.15% energy levels ofa -e- molecule are shown in the figure. The ratio of | -#8E~ the wavelengths T=A,/2, isgiven by -26: . =3 @rnZ r= fe body of mass m = 10~*kg is moving in a medium and experiences a frictional force =~ ky*. Its initial speed isv) =10ms~. If, after 10 s, its energy is} my2, the value of k will be “ (@) 10°%kgs"* (0)10"kgrrr's (©) 10“*kgmr* (8) 10°kgm* ‘5, Gp and Gy are specific heats at constant pressure and constant —_volume, respectively. It is observed that C,~Cy =a for hydrogen gas C, Cy =b for nitrogen gas. The correct relation between a and b is (@a=b ()a=28b (b)a=t4b 1 eae The moment of inertia of a uniform cylinder of length / and radius R about its perpendicular bisector is I. What is the ratio//R such that the moment of inertia is minimum? oe wo 3 3 oF of2 JEE MAIN Solved Paper 2017 7. A radioactive nucleus A with a half-life T, Y decays into a nucleus B. Att =0, there is no nucleus B, After sometime t, the ratio of the number of B to that of Ais 0.3. Then, tis given by @t=7 a's ()t =Tlog 13 fog,2 Ca (at =o? iogts 2log 13 Which of the following statements is false? Tn’ the below circuit, the current in each resistance is of w < 1a S10 S Hy 1h nM a (20.254 ()05A @1A {a) In a balanced Wheatstone bridge, if the cell #9 pa phe lenemerar npa e ‘amplitude modulation, sinusoidal carrier stu is denoted and the signal (b) A rheostat can be used as a potential divide Hoauoues, use sendenplee, Watt ee (©) Kirchhoff's second law represents energy conservation (6) Wheatstone bridge is the most sensitive when all the four resistances are of the same order of magnitude xy ‘A capacitance of 2 uF is required in an electrical circuit across a potential difference of 1kV. A large number of 1 nF capacitors are available which can withstand a potential difference of not more than 300 V. The minimum number of capacitors requirgd to achieve this is @%6 (0) 24 22 @2 of In the given circuit diagram, when the current reaches steady state in the circuit, the charge on the capacitor of capacitance Cwill be fy i Y t—|}-ww— {wy 8 a (oy CE we wer 4+) fh (ace ()CE G0 frequency is denoted by ,,. The bandwidth (Ao,,) of the signal is such that Ao, << @,. Which of the following frequencies is not contained in the modulated wave? @a, 0) op + a, Oph - Go, in a common emitter amplifier circuit using an n-p-n transistor, the phase difference between the input and the output voltages will be on (b) 195° (0) 180° (45° copper ball of mass 100 gis at a temperature Itis dropped in a copper calori of mass 100g, filled with 170g of water st soon temperature, Subsequently, the temperature of iD system is found to be 75°C. T is (Given, room ae = 30°C, specific heat of copper =01 {@) 885° (c) 825°C (oy 12500 (@) 800°C J15. Ina Young's double slit experiment, slits ate 0.5 mm and the screen is placed a bey of light consisting of two chuatfhiee nm and 520 nm, is used (0 least distance 2 ae on the screen. The maximum (7.8mm (©) 186mm oe due to both te ott m the common cent where the bright fring®* © wavelengths coincide, is (0) 9.75 mm (8) 1.56 mm.f é 16; An electric dipole has a fixed dipole momer p, which ma When subjected to an ele. s angle @ with respect to X- field E, experiences a torque T, = tk. When subjected to another electric field E,=3E,j, it experiences a torque T, =~ T,.The angled is (a 45° (b) 60° (©) 90° (d) 30° AT, A slender uniform rod of mass M and length / is pivoted at one end so that it can rotate ina vertical plane (see the figure). There is negligible friction at the pivot. The free end is held vertically above the pivot and then released. The angular acceleration of the rod when it makes an angled with the vertical, is x ¢ 2. e h x 29 39 28 sing (0) 2 cos @ @ an (b) ae 29 e086 (6) 2Fsing © Boos © Pain 18) An external pressure P is applied on a cube at O°C so that it is equally compressed from all sides. K is the bulk modulus of the material of the cube and o is its coefficient of linear expansion. Suppose we want to bring the cube toiits original size by heating. The temperature should be raised by = ss Ka (dy OR Ope ©) 9PKa 0) Ee 19. A diverging lens with magnitude of focal Jength 25 cm is placed at a distance of 15 cm from a converging lens of magnitude of focal ~ Tength 20 cm. A beam of parallel light falls on the diverging lens. The final image formed is {@) virtual and at 2 distance of 40 em from convergent lens (b) real and at a distance of 40 cm from the divergent lens (©) real and at a distance of 6 om trom the convergent lens ‘(€) feal and ata istance of 40 om from convergent i AEE MAIN Solved Paper 2017. 3 in electron beam is accelerated by a potential difference V to hit a metallic target to produce X-rays. It produces continuous as well as characteristic X-rays. If Aji, is the smallest possible wavelength of X-rays in the spectrum, the variation of log Ay with log V is correctly repres t ae od 8] 2 fog Vv log ¥ © Jog ¥ Jog V The temperature of an open room of volume 30m? increases from 17°C to 27°C due to the sunshine. The atmospheric pressure in the room remains 1x 10° Pa. If n;and ny are the number of molecules in the room before and after heating, then n, ~ n, will be (@) 138 x 10 ()25x 10% (0)-25 x10 (@)-161 x 10% a coil of resistance 100 Q, a current is 2 ee by changing the magnetic flux through it as shown in the figure. The magnitude of change in flux through the coil is Tine 05 6) (@) 225 Wb (0) 250 Wb (©) 275 Wo (d) 200 Wo 28. When a current of 5 mA is passed through a galvanometer having a coil of resistance 15 Q, it shows full scale deflection. The value of ‘the resistance to be put in series with the4. JEE MAIN Solved Paper 2017 26 Ah galvanometer to convert it into a voltmeter: of range 0-10 V is (a) 2.045 x 10° @ (6) 4005 x 10° @ (0)2595x 10° 2 (@) 1985 x 10° @ 7 24. A time dependent force F = 6t acts on a particle of mass 1 kg. If the particle starts from rest, the work done by the force during the first 1 s will be (a) 22 (b) 90 (18) @) 48d 25. A_ magnetic needle of magnetic moment 67x10? Am? and moment of _ inertia 75x10 kg m® is performing simple harmonic oscillations in a magnetic field of 0.01 T. Time taken for 10 complete oscillations is (a) 8805 (0698s (876s (665s variation of acceleration due to gravity g with distance d from centre of the Earth is best represented by (A = Earth’s radius) a P @ IX (0) / _ oO F 5 Oo RF 4 4 co} @) eee ame ‘27. A body is thrown vertically upwards. Which one © of the following graphs correctly represent the velocity vs time? t t “Pe “he Se cll @ = 98 A particle A of mass m and initial velocity i m y collides with a particle B of mass ~~ i is head on, which is at rest. The collision is n, thd elastic. The ratio of the de-Broglie Wavelengths 24 0, after the collision is apne ae? Wins 18 ded om-t ote, fad 29. A particle is executing simple harmonic motion with a time period T. At timet = 0, it is at its position of equilibrium. The Kinetic energy-time graph of the particle will look, like Ke ee | 2 pla ea Tat i> key els dated ees ie en re . TT ¥ yal. 30. A man Tinga gfows into a. giant such that bis " a limensions increase by a factor of mee Baus that his density remains nd stress in the leg will change by @ 1 = a1 1 a soChemistry 31. Which of the following compounds will give significant amount of meta-product during mononitration reaction? 9H cock, ~ Sy @ ) @ CO [| NH NHCOCH, AU is equal to (@) isochoric work (©) adiabatic work The increasing order of reactivity of the following halides for the Sy1 reaction is I. CH,CH(CI)CH,CH, Pe Il, CH,CH,CH,Cl Ill. p-H,CO— CgH,— CH,Cl @im Na,Zn0, (ii) Zn0 + CO, —> znco, (@) base and acid (b) base and base (©) acid and acid (A) acid and base 40. Both lithium and magnesium display several similar properties due to the diagonal relationship; however, the one which is incorrect is (@) Both form basic carbonates (0) Both form soluble bicarbonates (©) Both form nitrides (@) nitrates of both Li and Mg yield NO; and O, on heating SA natsi-pent- ne on reaction with HBr in presence of peroxide forms an. addition product. The number of possible stereoisomers for the product is (a) six (b) zero (c) two (@) four _ BAe crystallises in a face centred cubic ture, If the edge length of its unit cell is * ‘a’, the closest approach between two atoms in metallic crystal will be (aj2a 22a (Wa a @) z 43. Two reactions R, and R, have identical pre- exponential factors. Activation energy of 2, exceeds that of R, by 10 kJ mol” '. Ifk, andk,, are rate constants for reactions R, and Ry,6 JEEMAIN Solved Paper 2017 of (k, ee” CT graphitey * 0,(g) — CO2(8)} respectively at 300 K, then un(*) is equal jo A He = ~ 3935 KJ mol” " YG (R=8314J mol "K"*) : G 2 —> H,0()); 8 wz 6 (4 H,(g)+ 50218) 0 44. The correct sequence of reagents for the A, H? = - 2858 Kjmol following conversion will be 0,(g)+ 2 H,00 CH,(g) + 20,(g) HQ. CHy A, H® = + 8903 kj mol” * Based on the above thermochemical equations, the value of A,H® at 208 K for CHO HC: OH the reaction, Cy Ciguphtey* 2 Ha(e)—> CH,(g) will be {@) [AGINH,)pI* OH", HT /;CH,OH, CH.MaBr jemokimor' + 4s0klmol’ {b)CH,MoBr, H” / CH.OH, [Ag(NHs),1" OH” (@-748kimol' (6) 1440ks mot"? (@) CH.MgBr, [Ag(NH,)oI” OH”, HT /CH,OH (@) [AG(NH.)e]" OH", CHyMaBr, H” / HOH 48. Which of the following reactions is an example of a redox reaction? 45. The ‘Tyndall effect is observed only when _ (@) XeF, + Of —» XeFs +02 following conditions are satisfied (0) XeF, + PF — > XeF] “PFs 1. The diameter of the dispersed particles is * "(c) XeFy + HJO—> XeOF, + 2HF much smaller than the wavelength of the (@) XeF, + 2H,O—> XeO,F, + 4HF light used. 2, The diameter of the dispersed particle is not 49. The products obtained when chlorine gas i Fe Ee gen th the Chea or a avid: ntl” Gilute “aqueous 4 light used. NaOH are 3, The refractive indices of the dispersed phase (a) CIO" and ClO, (0) 0103 and CIOs | and dispersion medium are almost similarin __(@)CI"andiCiQ™ (@) Gr and Clog | magnitude. i 4, The refractive indices of the dispersed phase ST a major product obtained in the \ and dispersion medium differ greatly in wi ant i magnitude. Be Hi (e)tand 4 (b)2and4 (6) 1and3 (0) 2end3 can oan a 46. Which of the following compounds will behave vec ducing sugarin an aqueous KOH solution? (@)(4) CoH.CH(CFBUICH,CyH, | 0. 0. ()CHSCH = GHO,H, ity og uot HOKE coon i i} @ a o 7 Ol) CaH.cHO'BYCH,CH, ococHs (6) C,H «CH(O'BU)CH.C,H, ? a 51, Sodium salt of an organi ma ganic acid Produces effervescence with conc. H,S°s reacts with the acidified aqueous Ca: HOHG HOH — oan to give a white precipitate whit © es OK on soo lourises acidic solution ofKMn0.* I, (@)CcH,COONa (©) HCOONa ()CH,COONa (NaC.52. Which of the following species is not 53. 55. paramagnetic? {a) NO. (co (0, @B, The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20g of benzene, If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be (K; for benzene = 5.12 K kg mol” +) (@) 64.6% (804% (746% (94.6% . Which of the following molecules is least Tesonance stabilised? @)| O On treatment of 100 mL of 0.1 M solution of CoCl,.6H,O with excess of AgNO, ;1.2x 107” ions are precipitated. The complex is (@) [(Co(H,0),Cl,] C!.2H,O (©) [Co(H,0),C1,}. 3H,0 ()ICOH.O)pICl, (@) [Co(H,0),Ci] Cl,.H,O ® UJ @ ar o . The major product obtained in the following, Teaction is oO & sacks ‘COOH oFn 57. 58. 59. JEE MAIN Solved Paper 2017 7 OH OH @ Cree ) Qcve ‘CHO. ‘CHO CHO ‘COOH © Qe COOH (0) A water sample has ppm level concentration of following anions F-=10; S03 = 100; NO; =50 the anion/anions that make/makes the water sample unsuitable for drinking is/are (@) OnlyNO; (b) Both SO{~ and NO; (©) OnlyF- (@) Only so- 11g of a carbonate (M,CO,) on treatment with excess HCl produces 0.01186 mole of CO,. The molar mass of M,CO, in g mol”? is (a) 1186. (0) 84.3 (0) 1186 (@ 11.86 Given, BG, jq- = 136 V, Eos, =-074V Boot 1c2+ = 138 V, Bio, yyge = 151V Among the following, the strongest reducing agent is (cr (cr* (b) Mn? * @er 80_-Phe Group having isoelectronic species is RYO", F°, Na*, Mg? (0)0", F>, Na, Mg? (0)0*>, F>, Na, Mg?* (d) 0", F, Na*, Mg? *&. Mathematics 7 vailable for fencing off 61. If is the set of distinct values ofb for which 67. If 20 m of wire is. available for fencing off a the following system of linear equations x+ay+z=1 and ax+by+z=0 has no solution, then S is, {@) an infinite set (0) finite set containing two or more elements 4) singleton set (aeripty set >—“@BusThe statement (pq) + {(~p 4) als (@) a tautology (©) equivalent to ~ pq (6) equivalent to p> ~q (@)a fallacy 3, If 5(tan® x-cos? x) = 2cos2x+9, then the value of cos 4x is 3 1 @ E b) 3 @-2 2 OF jf oh. For three events A, B and G, if P(exactly one of A or B occurs) = P(exactly one of B or C occurs) = P (exactly one of C or A occurs) = + and P (all the. three occur simultaneously) = then the probability that atleast one ofthe events occurs is es OG Os (@) a6 events 65. Let wbe a complex number such that 20+1= 2, where z= -3. If [2 t tr] 1 -#-1 | @ @| @-z @-1 = 3k, then k is equal to ®z @1 vertices (k,~ 3k), (5, k) and (—k,2) has area 28 sq units. Then, the orthocentre of this triangle is at the point 3) ot-) oe3) 68. 3B 9. 20. Vv a Let k be an integer such that the triangle with 72, |. If the image of the point P(1,— 2,3) f a circular sector flower-bed in the form o , had the maximum area (in sq m) of the flower-bed is (@)125 (025 (0) 10 (d) 30 ‘The area (in sq units) of the region {(x,y)ix20,x+y $3,x S4y and y sit vx} is 59 (ee 7 re (0) le @s ) in the plane 2x+3y-4z+22=0 measured parallel to the line * == 5 is Q, then PQis equal to sve (e242 (9) Jaz (@) 65 |. For xe(o.2) if the derivative of aa ( 8xVix tan (2 a -a02,ten ata 9 sabes 3 Ee oe 3x (Gene 3 (2) ” Oo If @ +siny Y V+ Neos x=0 and ¥(0) =1, then ¥& is equal to @t 3 )- S os Let a vertical tower AB have i have its end A on the {evel PFpund: Let C be the mid-point of Af Point on the ground such th#! ae 2AB. If 2BPC = 8, then tan B is equal '0 eo ot 1 @-4 2 4 5 @5/ Tyta=|* 7 44 [7-24] 51 63 )| c alae ~ (seal 51 84 [72 -63] ole fal | sa si | 1 5 For any three positive real numbers a,b andc, if 9 (25a? +b*) +25 (c? — 3ac) = 15b (3a+c), then (@)b,c and aarein GP (b) b,c and a are in AP (Q)abandearein AP (d)a, bande are in GP ‘75. The distance of the point (1,3,-7) from the plane passing through the point (1, - 1, - 1) having normal perpendicular to both the lines Bh WEBS 4 oy a2 le 1 +6 3 2 o's 247 vis -1 20 10 (@) unis (©) Jag unis 5 10 (Oo zegents () nits Let J, = tan” xdx(n>1). If I,+Ig=a tan’ x+bx°+C, where C constant of integration, then the ordered pair (a,b) is equal to =,0 eG) a ef} atts PC The eccentricity of an ellipse whose centre is at the origin is 1/2. If one of its directrices is 4, then the equation of the normal to it at 76. is a (@)2y-x=2 (b) 4x-2y=1 © 4x+2y=7 (x+2y=4 778. 1f a hyperbola passes through the point P(V2,/3) and has foci at (2,0), then the tangent to this hyperbola at P also passes point the (@) (V2, 23) (b) (2v2, 33) (©) W3,.2) @- 2, -¥3) then adj(3.4* +124) is equal to 4, The function f :R > at 2 80. JEE MAIN Solved Paper 2017 9 0 1M) dathied Ss 2] f(x) is ate (a) invertible (b) injective but not surjective (©) surjective but not injective (@) neither injective nor surjective cot x-cos x jim, moar otals 1 1 1 1 A an il @t 3 Pia ben 81 et a=2i+j-2k, b=i+j and e be a a2. the 84, G3) 83; If two different numbers are taken from the vector such that |e~a|=3. |(ax-b) x e|=3 and the angle between ¢ and ax bis 30°. Then, a- eis equal to 25 1 fa) in (2 (5 @) a normal to the curve y(x - 2)(x- 3) =x +6 at the point, where the curve intersects the Y-axis passes through the point steal (es) @(-4-2 a 2 4) ali.) 2 3, set {0, 1, 2, 3, ..., 10}, then the probability that their sum as well as absolute difference are both multiple of 4, is 6 12 Os (b) S 14 7 OF Og Aman X has 7 friends, 4 of them are ladies and 3 are men. His wife Y also has 7 friends, 3 of them are ladies and 4 are men. Assume X and Y have no common friends. Then, the total number of ways in which X and ¥ together can throw a party inviting 3 ladies and 3 men, so that 3 friends of each of X and Y are in this party, is (e485 (0) 468, (469 (¢) 48410 JEEMAIN Solved Paper 9017 85. The value of (1C,-"C,)+('C, - "C,) +OC, = 9G) + FIC, - "C) +t Cio ~ *Cq)is (a) 27 — 245 (p) 27 — 2° (2 - 2° (ay2™ -2° ¥ A box contains 15 green and 10 yellow balls. If 10 balls are randomly drawn one-by-one with replacement, then the variance of the number of green balls drawn is 12 6 ae 6 4 Ox 88. The radius of a ci Je having minimum area, which touches the curve y = 4— x and the lines y =|x\, is 22+? (402-0 (22 - 1) (0) 4(W2 +1) 89. For a positive integer n, if the quadratic equation, x(x-+ 1) +(x +1) (x+ 2+ +(x+n—)(x+n)=10n has two consecutive integral solutions, then n is equal to 9 87. Let a,b,c € R. If f(x) = ax+ bx +c be such Oe thata+b +c=3and oe os Fx+V)=f0)+ fi) + a mye Rethen gy i eto, ¥ fla) is equal to Moree n21 (a)-2 (b) 2 (330 ()) 165 = (190 (255, (4 @-1 . : Answer with Explanation Physics ‘ 4. (b) As the observer is moving towards the source, 50 frequency of waves emitted by the source will be given by the formula Her, frequency © =! c2 1 3/2) = few (22 m, fila ana (342) fotmerved = 10% V3 = 173 GHz 2. (a) By ascent formula, we have surface tension, rhg y ag9 7a x 10° [oiven, gis constant] (2 +82) log 13 = At B UeT al, thon 2 82 = gia BE. T Tog (9) Toa. 8. (a) Ina balanced Wheatstone bridge, there is no effect on position of null point, if we exchange the battery and™galvanometer. So, option (a) is incorrect. 9. (c) As each capacitors cannot withstand more than 300 V, so there should be four capacitors in ‘each tow became in this condition 1 kV ie. 1000 V will be divided by 4 (e250 not more than 300 V). ‘Now, equivalent capacitance of one row i x IMF = 0251F {sin series combination, Cy, Now, we need equivalent of 2uF, so let we need n such rows B nXx0.25 =2uF + in parallel combination C,, = nc] a peal 0.25 =8 .."Total number of capacitors = number of rows number of capacitors in each row =8x4=92 10. (b) In steady state, no current flows through the capacitor. So, resistance r,, becomes ineffective So, the current in citcut, = = “ T+ 2 (Total Resistance) “Potential drop across capacitor = Potential drop Eb, r+) across % = 4b +h +. Stored charge of capacitor, = CV = CE. 41, (¢) Bach resistance is converted with two cells combined in opposite direction, so potential drop across each resistor is zero. Hence the current ‘through each of resistor is zet0.12 JEEMAIN Solved Paper 2017 12. (d) Frequency spectrum of modulated wave is 188} use a aay Bandwth Cteatly, ©, isnot included in the spectrum, 13. (0), y 1 too (Opa Ina CE npn transistor amplifier output is 180° out of phase with input, 414. (@) Heat gained (water + calorimeter) = Heat lost, by copper ball = m,5yAT+ m,s,AT = mpsghT => 170% 1%(75=30)+ 100 x01 x (75~30) 100 x01 x(T -75) 85°C T 15, (a) Let nth fringe formed dus to first wavelength ‘and nyth fringe formed due to second wavelength. coincide ie. their distance from common central maxima will be same e Yn =m ( = PAD sm mh 8004 a ae ee Bencoadieance otha feat cipeldenne’aom the central maximd is BPAD _ Mabe _ 4 x650 107 x15 _ 5, BRD mh. Pain 4080 107 415 d da 05 x 10° a ‘Torque applied on a dipole t = pE sin @ where @=angle between axis of dipole and electric field. i For electric field £, = Bi it means field is directed along positive x direction, so angle between dipole and field will remain @ therefore torque in this direction r= phsin® 3 Bi, jeans field is meter ela B= V5 tenn Jae alive Y-aii, 9 ange between, aeeataad wile dine ws dction 7; = PBatn 60 ~ 8) ABE, cos 8 er According to question T; unadill 2 . ‘pb, sin 0= pvi3 B,c0s0 ano = of = tan O= tan 60° a 0=60° 417, (d) As the 10d rotates in vertical plane so a torque is acting on it, which is due to the vertical ‘component of weight of rod, Initial condition Atany timet Now, Torque t = force x perpendicular distance of line of action of force from axis of rotation mg sin 6x! 2 ‘Again, Torque t = Ie. Where, I = moment of inertia [Force and 3 ‘Torque frequency along axis of rotation Passing through in end] = angular acceleration * mgsingx! mF ae ox 3asin @ zi 18: (e)ae PI av Pp Caviv) Vv Ak > ence nA = AV K Change in volume AV = yar 1 = costficient of ace ost Fae ‘volume expé (8 coefficient of tear expansion AV = V3 oy Vea) AT 7 Y Go) ar ars? 30Ka 49. (d) Focal length of diverging lens is 25 cm. ‘As the rays are coming parallel, so the image (/,) will be formed at the focus of diverging lens ie. at 25 om towards left of diverging lens. ison 23. Now, the image (I,) will work as object for converging lens. For convergying lens, distance of object u (le, distance of J,) = ~ (25 + 15) 40cm f=20cm 24, -+ From en's formula 2 vis positive o image willbe real and will form at right sie of converging lens at 40 cm. 20. (4) rn = 7 25, 109 Pan) = va (%2)- leg¥ y2c-me So, the required graph is given in option (d) 21, (C) From pV = nRT =—— RT 26. 22. (b) Induced constant, I Here, ¢= induced emf do 27. at 2 (a4) 4 R la) F ig =IRat = [mat Here, Ris constant JEE MAIN Solved Paper 2017 13 = RI tat ff-at = Area under I= ¢ graph =1x10x05=25 2 = x25= 100 x 25= 250 Wh: (d) Suppose a resistance R, is connected in series with galvanometer to convert it into voltmeter ai Ry v 1,(G+R)=V > a-t-o are, 1995 x 10° 2 = R=1985=1985kQ or R |. (6) From Newton's second law, SP = F = Ap= Fit pafdp=[' Fa: p= [erat =o From wotk-energy theorem, work done = change in Kinetic energy. So, work done (A) Time period of oscillation is Ak =45J Hence, time for 10 oscillations ist = 6655. (c) Inside the earth surface g S r ie, ger ut the earth surface g = 2 1 te. get Z So, till earth surface 'g’ increases linearly with distance r, shown only in graph (c). . (b) Initially velocity keeps on decreasing at a constant rate, then it increases in negative direction with same rate. 28. (a) For elastic collision, @14 JEEMAIN Solved Paper 2017 Ye =Va Now, cosfficient of restitution,’ ¢ = “2 =YA ua - Ve (Particle at rest) and for elastic 1 wt, From Eg. (i) and Eq, (i) Here, u collisione Oo) Chemistry 34. (¢) Aniline in presence of nitrating mixture (conc. HNO, + conc. H,SO,) gives significance amount (47%) of meta-product because in Presence of H.SO, its protonation takes place and anilinium ion is formed. ee NH, NEHSO, Hys04 Ailing Aniliniom ton Here, anilinium ion is strongly deactiva Group and meta-directing in nature. So, it gives meta-nitration product, @ 6 NH Ni,H50, Cone 4,804 “¥en HNO; No, 32. (¢) According to first law of thermodynamics, AU=q+W=q- pay In isochoric process (AV = 0), aU=q 1n isobarie’prbcess (Ap aU =q In adiabatic process(q = 0) AU=Ww | In isothermal process (AT = 0) and AU =0 ~. AU is equal to adiabatic work. 33. (6) () The rate of 8,4 reaction depends only upon the concentration of the alkyl halide. (i) Syf reaction proceeds through the formation of carbocation. ‘The reactivity is decided by ease of dissociation of alkyl halide, . (d) Stress = mean position and 20. (ch psetiess ae r t= minimum at extreme position | at Weight ‘Area *) times. Volume will become (9° ) tim So weight = volume x density x g will also become (@9P times. ‘Area of cross section will become (9F times. 8 XM ~o() "Fx Ay (Ay Hence, the stress increases by a factor of 9. R—X = R® + x® Higher the stability of R* (carbocation), higher ‘would be the reactivity towards Sy1 reaction. P-H,CO— C,H, —CH,® is the most stable carbocation due to resonance and then CH, CHQH,CH, (2° carbocation) while CH,CH, CH, (1°) is least stable. Thus, the correct increasing order of the reactivity of the given halides towards the Sy1 reaction is. CH,CH,CH,Cl < CH, CHCH,CH, aq Ve a oO HN cH}—c—0 — Se ses Nylon-6 37. (c) Given, abundance of elements by mass oxygen =614%, carbon =229%, hydrogen = 10% and nitrogen = 26% arenas 100 ‘Mass due to "H= =75kg ‘Hatoms are replaced by *Hetoms, Mass due to 7H =(7.5x 2)kg ‘2 Mass gain by person = 75kg 38, (a) To show decolourisation, compound must be unsaturated. 2} ter BUGN, oe em Fe ' (Saturated) (cannetdeclin Bs wat Cr s L OT tet BON B (sostuie Bi wait ta BON, (eet . sas Bo, 4 ) // (Wasaturated) (decolourise Br, water) ¢ ° am =e a a (Unsaturated) (deco Bi wate) JEE MAIN Solved Paper 2017 15. 39. (d) Zinc oxide (ZnO) when react with Na,O it act as acid while with CO, it act as base. Therefore, it, is an amphoteric oxide ZnO +Na,O —> Na,Zn0; ed Bae Ent ZnO +O; —>ZnCO; Base Aad sat (a) Mg can form basic carbonate while Li cannot. 5Mq’* + 6 CO} + 7H,0—» 4MgCO, -Mg(OH), “6H,0 + 2HICO; 41. (d) The number of stereoisomers in molecules ‘which are not divisible into two equal halves and have n number of asymmetric C-atoms = 2". 3-methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product i.e, 2-bromo-3-methyl pentane. It has two chiral centres. Therefore, 4 stereoisomers are possible = rae” Smethyipent 2-éne ‘Anti-Matkownikoffs addition our steeoisomers are possibla (ds molecule has two chal ‘centres and asymmetric) 42. (d) For foc arrangement, 4r = 2a where, r =radius and a = edge length fia a sag aya, 43, (d) According to Archenius equation ke Ag Eel FT ‘where, A = collision number ot pre-exponential factor. R =gas constant T = absolute temperature E, = energy of activation #, Closest distance = For reaction R,, ky = Ae * "7 0) For reaction Rp, ky = Ae “2 /*7 i) On dividing Bq. (i) by Ea. (i), we get a eat (a) {t: Bfe-exponential factor ‘A’ is same for both reactions] Taking In on both the sides of Eq. (ii), we get Ez &, Rr Given, B,,=E,, + 10k) mol =E,, + 10000 J mol” * rt Be Serato 5 8314) mol” 'K-*x 300K16 JEEMAIN Solved Paper 2017 44. (a) ° 9 (ag (NH 08, atenfcation, Tollesis veagent HORA? Ho cooH coock, cHMoBr (Beco) HO. CH, oH Before final product is formed, intarmediate is HO CH o 45. (b) Colloidal solutions show ‘Tyndall effect due to scattering of light by colloidal particles in all directions in space. It is observed only under the following conditions. (@) The diameter of the colloids should not be much smaller than the wavelength of light used. ii) The refractive indices of the dispersed phase and dispersion medium should differ greatly in magnitude, 46. (a) Sugars that have an aldehyde, a ketone, a hemiacetal or a hemiketal group is able to reduce an oxidising agent. These sugars are classified as reducing sugars. none °X_ GHOH HoH °\ cHon sa0H, BY) ood on ~cH,600K o ou on e Ht iG SOR Ho ou (cetytonetne) Hemiacetal can be easily reduced by oxidising agent such as Tollen's reagent oe hon HOH tbls BOUBDE 5 pocitve ster reagent“ niror test oy eetocna 98) 47. (c) Based on given. A,H° ‘AyH? = Heo, =~ 3935 kd mol : ® AyH? = Hye =~ 285840 mol * a A)? = H3, = 0.00 (elements) a Roquited thermal reaction is for AH of CH, ‘Thus, from I 890.3 =[A,H°(CH,) + 24/H® (O,)] = [BpH (CO,) + 28,4" (H,0)] = A,H°(CH,) +0) - [- 393.5 - 2 x 2855) oA HP (CH, 74.8 kJ/mol 48. (a) The reaction in which oxidation and eduction ocour simultaneously are termed es redox reaction, ents ae (X)eR + 0, (R)— X e& +0, Since, Xe. undergoes'oxidation while O undergoes reduction. So, it is an example of redox reaction, 49. (Cc) Cl,, By, and J, form a mixture of halide ant hhypohalites when react with cold dilute alkalies while a mixture of halides and haloate when ree ‘with concentrated cold alkalies. Gl, + 2NaOH—> NaCl+ Naclo+ HO Cold ana ate ar att GLO” ae cbtained as products when Gas reacts us Noor ‘with cold and dilute aqueo 50. (b) An alkyl halide in ‘presence of a bulkier be® me a ee @ carbon adjacent ots catbon bonded n E2( ‘the halogen. This reactio! (B-elimination reaction). ema, Fy oats Cat, nea aR + tar: Bu08+#51. 52, (@) The reaction takes place as follows 'NajC,0, + H,S0,—> Na,S0, +#,0 A sane +001 +00, 7 Na,C,0, + CaCl, —»CaC,0, + 2Nacl te vine 5CaC,O, +2KMn0, + 8H,SO, —> K,S0, + 5CaSO, Pale +2MnSO, + 1000, + 8H,0 Capua Hence, X is Na,C,0, (b) To identify the magnetic nature we need to check the molecular otbital configuration. If all orbitals are fully occupied, species is diamagnetic while when one or more molecular orbitals is/are singly occupied, species is paramagnetic. (@) NOW +8 =15)- ots", ots? o2s?, o'25", raph = nap raph, w'2p) = wap (One unpaired electron is present. Henoe, it is paramagnetic. (b) COG + 8=14)—o1s*, ois", ods", o' 25", 2p; = Wp}, Ope No unpaired electron is present. Hence, itis diamagnetic. © 0, : ‘ (@+8=16)- ots", of 1s", 02s", 025", a2p?, raph = 1p, W 2p =n 2p}, ‘Two unpaired electrons are present. ‘Hence, it is paramagnetic. (d) BYG + 8)- ots", 0 15%, 02s", o2s*, nap, = op} ‘Two unpaired electrons are present. Hence, itis paramagnetic. 53. (d) Let the degree of association of acetic acid (CH,COOH) in benzene is o, then 2CHCOOH*—* (CH,COOH), 1 ° © a teal moles Motos st equlixium t= Be Total moles =1-a+ & ey or ‘Now, depression in freezing point (AZ;)is given as AT, =1Km et) Where, K, = molal depression constant ot cxyoscopic constant at m= molality “Molatty = umber of moles of solute ‘weight of solvent (in kg) 702, 1000 0° 2 JEE MAIN Solved Paper 2017 17 Putting the values in Ba. () 4 gyp)[02 046 =[1- 2] (612)|92 x [ 2] Le 046 X60 20_ 612 x02 x 1000 ey 20 21-0527 2 A 020948 ‘Thus; percentage of association = 946% 54, (d) Aromatic. compounds are stable due to resonance while non-aromatics are not, According to Huckel’s tule (or 4n+2 tule), “For a planar, Cyclic compound to be aromatic, its m cloud must contain (4n + 2)n electrons, where, nis any whole number,” ‘Thus, OG O (Ge sysec) ie + 2a yam) are aromatic and stabilised by resonance, "They follow Huckel's ule (exe sya) 's non-aromatic, hence, least stabilised by resonance. 0 Number of moles of solute Volume of solution (in L) Number of moles of complex X volume (in mL) 1000 =" =001 mole 4000 Number of moles of ions precipitate 12107 602 x10" ¢, Number of I present in ionisation sphere = Number of moles of ions precipitated ‘Number of moles of complex 55. (d) Molanity (JM) = 01100 002 moles . 2 Cl” are present outside the square brackets, i.e. .. in ionisation sphere. Thus, the formula of complex {s[Co(H,0),Ci/Cl, H,0 56. (a) DIBAL-H (Di-isobutyl aluminium hydride) is a reducing agent with formula. This is generally ‘used for the preparation of aldehydes. Using DIBAL —H, Lactones are reduced directly to aldehydes.a. Se 18 JEEMAIN Solved Paper 2017 Number of moles of M,CO; reacted = Number of ° oH ‘moles of CO; evolved P 1 opis [M=molar mass of M,CO,] DyRALH oS af 1 2¢43gmol"! coo tg Mo or186 . a 5) i .es which have lower reduction 57. (¢) NO The maximum limit of nitrate (NO})in gg, (a) Te re ee eyagene eee drinking water is 60 ppm and its source is oventials ere PR) i the strongest reducing fertilisers. If the maximum limit is increased in (Fea (Ghg all the other given options ‘water it will cause methemoglobinemia“(blue get baby syndrome ) 60. (a) lsoelectronic species are those which contains SO{” The maximum limit of sulphate (S07) samenumberofelectrons, according to WHO is 500 pm and its sources are Number of acid rain, industries. Excess SO;~ has laxative Species Atomic number lectrons effect = 3 10 F- The maximum limit of fluoride (F°) is about _ i ms 15ppm. Its higher concentration converts F enamel to more harder _—_fluorapatite. Nat u 10 ‘Concentration (>2ppm) causes brown mottling of Mg" a * teeth and: high concentration (>10 ppm) are harmful for bones and teeth o 8 9 «802° (100 ppm) and NO; (60 ppm in water is x + fe suitable for drinking but the concentration of Mgt 2 4 F” (10 ppm) makes water unsuitable for drinking, = ete eel nel 58. (b) M,CO, + 2HC1—> 2MC1+ H,0+ CO, Option (a) is correct which contains isoelectronic on von species OF”, Na Mg? Mathematics 2 ay Ash =46uy 61. (d) 7 A=|1 a 1/=1(e-b)-1(1-a)+ (0-22) ee ase x+ytz=1 a and x4 y+ 220 . ee eee (¢RHS is not equal) | eo eaue sh Gira ay Hence, for no solution b = 1 only =|t aa a ee 2. (a) The truth table ofthe ven expression is ge | @-1) EISIS8R6|= 5] pele pada | diet Tir) or lr sali 's © rm T 1ilesm-t0-a+10-g-0 TIF] OF |r| i ; OM a Mh S 7 0 -elel_p irl : e cn Hence, itis a tautology, * |, BAC aeen - S. ON Gm cain +8 | Bol 3 (12022 14 conan ' =-al@=1) 1 eosaie ~~ |= 2oosx + i Putcos2x = y, we have a ! B)—Y¥ ity A= ity eeeae = 5@-2y-1-y¥ -2y)=21 + yay +9) => &1-4y— 7) =22y+9+2¥ +9y) a 8-20y -5y =22y + 18+ 4y = 9 + 42y4+13=0 = of +3y4a0yer => 3yBy + 1)+ 1987+ 1)=0 = Gy+Ney43)=0 = Bn siaiig) cos2x = = cost =- . (b) We have, P (exactly one of A or B occurs) = P(AUB)- PAB) = P(A) + P(B)-2P(A 0 B) According to the question, P(A) + PUB) 2P(A 0B) = P(B) + P(C)-2P(B NC)= and PC) + Pla)-2ntC 04)=7 On adding Bas. (), i) and (i), we get 2IPtA)+ P(B)+ P(C)- PAN B)- PBA) =7IC may =2 4 =P(A)+ PB) + PIC)- PA NB)- PBMC) -pona=2 +. P (atleast one event occurs)‘ = P(A UBUC) = P(A)+ P(B)+ P(C)- P(A NB)- PB NC) =PONA)+ ADB OC) 7 4 aid | “ [pptanzno ral 85. (a) Given, 2@+1=2 66. (SEE MAIN Solved Paper 2017 19, [ ne 9 Now, |1. - a? | =3% h wel fit = 1 @ o/=3k h wo o| [140+ oF =Oanda’ =(0'f-w= 0) On applying R; Ry + Ry + Rj, we get i 1+ 0+ oF 1+o+ar| Mets of |=3K ho @ @ po 0 ot o o|-3% h @ o = de? - 0") =3k = t-a=k 3 (-uetilefa+ 8) z =-VBi=-2 (0) Given, vertices of triangle aré (ke, 3k), 6, k) and (~ k, 2). ke. ~8k. 1 45k tJ=t28 te 2 | kK ~8k 4 = 5k 1-456 be 2 4 Hk ~2)43k6 + k)+ 1110 + K)= 2 56 = ‘= 2k + 15k + 3k? +10 + 1 = 4 56 = 61 + 18k + 10 = +56 = 5iP + 13k - 66 = 0 or 5K? + 13k ~ 46 =0 = (ken ‘Thus, the coordinates of vertices of triangle are A, ~6), BO, 2)and Cl 2,2)20 JEEMAIN Solved Paper'9017 x Now, equation of altitude from vertex Ais 69, (b) Any line parallel to + a1 Y~O)=7 he aed 4) a PUt, -2, 3)i8 (2-2) through Pl, P(1,-2,3) (2-8) <1, 4, 5> Equation of altitude from vertox Cis = RE R 2x +3y~47429=9 = a+8y-10=0 (i On solving Eqs. ()) and (i), we got x= 2anay =! + Orica =f) (say) 2) 87. (0) Total ength <2 + 70.299 Any point on above line can be written as e o=20-2r (A142 2,54 4 3) ar ty * Coordinates of R are (A. + 1,42 ~2,5 + 3) Now, aren of eign L\ Since, point R lies on the above plane ast 2 #4 1)+ 94K —2)— 4644 3)+.22=0 = / i => het = So, point Ris (2,2, 8) Te Now PR= Oa + 2427 4-37 + POs2pR = ormaxina or inna, ps4» Gaane a a Bx 2-8) ] = 70. (a) Let y = tan- =tanc| 2:6") = 1-98 1-@x7} | TR ata te. ign Oe 1-% | 4 Sess 8x 8¢qy2 68. (d) Required area TF BF a4 2 9 =f (+ Vide +f @ 2a ~ a = ie. = 693 @+ainxy Solution is given by WO minx) =f. =2+sinx Re grit +0Also, 0)=1 1+ sin0)=—sin0 +. = C=2 2-sinx 7" 2ysinx ee JEE MAIN Solved Paper 2017 21 74. (c) We have, 2254 + 9b* +250” -75ac - 45ab - 15be =0 = (lah + (bP + (of - (15a)(5c)- (15a)(3b) ~ (@by(60)=0 = fits anf + (> - 50 + Bo—180F =0 =» 16a = 3b, 3b = 5c and 5c = 15a 16a = 3b =6e = = a=2,b=5A,0=3) Hence, abandcarein AP be 75. (b) Given, equations of lines are « a1 yt? 2-4 40g Be bigenSe we aes Lorn, = 1-2) + dfeand n, =2i-j-ke +. Any vectorm perpendicular to both n,, m, is given a Fae 3 | =8i+7j+3k R= 0 by Bx ~te My +1) +e+ 1120 * ets! =022 JEE MAIN Solved Paper 2017 a 77. (b) We have, e= ; and : tT 7; a Now, BF = #(1- e)=@af|1-(3 na{s-2)=3 era => b=8 7 zy, oy: : Equation of the ellipse is + ef War 4 Now, the equation of normal at (. 3) is éx_By ge mm n = Maan 1 @/2) % dx-2y=1 78. (b) Let the equation oftypeibola be Seal . ce =2add =4 a 2+ i esar =4-2 < 2 ‘Now, equation of hyperbola is“ -£ 1 “i Bquation of tangent at(v2, f(x)= f(x) + 0) +0 => f(0)=0 =c=0 Again, puty=-x & £0) = flxe) + f(- x) - x? = ax? + bx + ax? — bx — 2? = = Also, atb+c=3 = 1sbs0=35n-5 2 2 x +x o A(x) (x) 5 Now, tin)= "+82 ; 2 2 2 183,58 * +2 Sn 22 am e110 x11 x21 5 10x11 a 6 a Ue 9 = 885 , 275 _ 680 _ 399 Se gn 424 JEE MAIN Solved Paper 2017 88. (Cc) Let the radius of circle with least area ber ‘Then, then coordinates of centre = (0,4 - r) But wis 20 a [ = | 4 rae a4 (2-1) N24+1 , 89. (d) Given quadratic equation is xx 1) (x4 Dox + 2)+..4 00 DD) (x+n)=10n wo? 4x28 +t A) 4 (44 SH + One DY . + ((0-2+2-3+...+(2- 1a) = 100 = me + atx + 2) 1000 nx + 2 Pe haar] fe ax? + 9nx +1? -31= Let o.and B be the roots. Since, and are consecutive ja-B) = (a-By =1 Again, . (ax BP =(0+BF — 408 i 4 in meee) ae ® 3 (=) Le 3 mp 4p ~~ 1=n* qa -31) = 3=3n" - 4n’ + 124 > 121 = #1 11 fen>0] on a4 (b) Let I Be leg fA AK OORH ay Is T+cosx /v4 1 cos x 4 1 aft 22082 ae paroisn m4 : =f, (Coed? x —cosec x cot x}dx axa 4 = (+ V2)-(-14 V2 =2 = [-cotx + cosec x1